7.23 One equivalent of sodium methanethiolate is added to an electrophile that has two leaving groups. Which product will be major

Answer:

CaCO₃(s) => CaO(s) + CO₂(g) ... GpIIA Decomp

Explanation:

Metallic Carbonates decompose into a metallic oxide and carbon dioxide.

Examples:

Na₂CO₃(s) => Na₂O(s) + CO₂(g) ... GpIA Decomp

MgCO₃(s) => MgO(s) + CO₂(g) ... GpIIA Decomp

Answer:

BF3

Explanation:

The octet rule describes atoms' preference and affinity for having eight (8) electrons in their valence shell. Whenever an atom is encircled by eight(8) electrons, it forms a stable configuration. This octet can be composed of its' own electrons as well as some shared electrons. In the periodic table, only the s-block and p-block electrons are considered for the octet rule.

However, out of the given option, only BF3 does not comply with the octet rule: This is because the Bromine contains 2 lone pairs of electrons and 3 other shared bonded pairs of electrons with Flourine making a total of 10 electrons in the valence shell and which does not conform with the octet rule.

Answer:

a. minus 10

Explanation:

An element in group 13 = Boron ,valence electrons = 3 , therefore, valence electrons in group 13 = group no. -10

An element in group 18 = Neon, valence electrons = 8 , therefore, valence electrons in group 18 = group no. - 10

For groups 13 through 18, the number of valence electrons in an atom is equal to the group number minus 10. Therefore, option (A) is correct.

Valence electrons in an atom can be described as the electrons occupying the outer most electron shell of an atom while the electrons in the inner shell are core electrons. Lewis structures can be helpful to calculate the number of valence electrons.

Valence electrons can be filled in several electron shells as they are caused interaction between atoms and responsible for the formation of chemical bonds. Only valence electrons can contribute to the formation of a chemical bond and decide the reactivity of the element.

The general electronic configuration of group 13 is ns²np¹ has three valence electrons. It can be determined as group number - 10 = 13 - 10 = 3.

The general electronic configuration of group 18 is ns²np⁶ has eight valence electrons. It can be determined as group number - 10 = 18 - 10 = 8.

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Answer:

[Na⁺] = 1.99 M

Explanation:

Na₂S is a ionic salt that can be dissociated.

Dissociation equation is:

Na₂S  →  2Na⁺  +  S⁻²

1 mol of sodium sulfide can give 2 moles of sodium cation.

We convert moles of salt: 78 g . 1mol / 78.06 g = 0.999 moles

As ratio is 1:2, after dissociation we have (0.999 . 2) = 1.998 moles of Na⁺

Molarity is a type of concentration.

It indicates moles of solute in 1 L of solution and in this case, we have 1 L as final voulme.

Moles of Na⁺ are 1.998 moles. Then molarity (mol/L) is:

M =1.99 mol/L  

Answer:

The answer is in the explanation.

Explanation:

A solution is defined as the homogeneous mixture of a solute (In this case, NaCl) and the solvent (water).

To prepare 1L of the solution, the student can weigh the 3g of NaCl in the volumetric flask but need to add slowly water to dissolve the NaCl (That is very soluble in water). When all NaCl is dissolved the student must transfer the solution to the 1L volumetric flask. Then, you must add more water to the beaker until "Clean" all the solute of the beaker to transfer it completely to the volumetric flask.

Answer:

The major use of sulfuric acid is in the production of fertilizers, e.g., superphosphate of lime and ammonium sulfate. It is widely used in the manufacture of chemicals, e.g., in making hydrochloric acid, nitric acid, sulfate salts, synthetic detergents, dyes and pigments, explosives, and drugs.

The major use of sulfuric acid is in the production of fertilizers, e.g., superphosphate of lime and ammonium sulfate. It is widely used in the manufacture of chemicals, e.g., in making hydrochloric acid, nitric acid, sulfate salts, synthetic detergents, dyes and pigments, explosives, and drugs.

Answer:

0.465

Explanation:

To find the volume of a substance, divide the mass by the density.

M/D = V

10.0 / 21.5 = 0.4651163

Then round to 3 significant figures: and the density is 0.465

Answer:

1.60 g of Fe₂O₃

Explanation:

We'll begin by calculating the number of mole water that reacted. This can be obtained as follow:

Volume (V) = 6.50 L

Temperature (T) = 50.2 °C = 50.2 + 273 = 323.2 K

Pressure (P) = 0.121 atm

Gas constant (R) = 0.0821 atm.L/Kmol

Number of mole (n) =?

PV = nRT

0.121 × 6.5 = n × 0.0821 × 323.2

0.7865 = n × 26.53472

Divide both side by 26.53472

n = 0.7865 / 26.53472

n = 0.03 mole

Thus, 0.03 mole of water reacted.

Next, we shall determine the number of mole of Fe₂O₃ produced from the reaction. This can be obtained as follow:

2Fe + 3H₂O —> Fe₂O₃ + 3H₂

From the balanced equation above,

3 moles of H₂O reacted to produce 1 mole Fe₂O₃.

Therefore, 0.03 mole of H₂O will react to produce = (0.03 × 1)/3 = 0.01 mole of Fe₂O₃.

Thus, 0.01 mole of Fe₂O₃ was produced from the reaction.

Finally, we shall determine the mass of 0.01 mole of Fe₂O₃. This can be obtained as follow:

Mole of Fe₂O₃ = 0.01 mole

Molar mass of Fe₂O₃ = (56×2) + (16×3)

= 112 + 48

= 160 g/mol

Mass of Fe₂O₃ =?

Mass = mole × molar mass

Mass of Fe₂O₃ = 0.01 × 160

Mass of Fe₂O₃ = 1.60 g

Therefore, 1.60 g of Fe₂O₃ were produced.

Answer:

it's atomic number is 5 and total number is 10

The atom has an atomic number of 20 and has a total of 12 p electrons.

The azimuthal quantum number (l) of the 19th electron is 0 and the magnetic quantum number (m) of the 19th electron is 0.

It is an element of group 2

The number of electrons in the neutral atom is equal to the number of protons and is also the atomic number of an atom.

An atom is known to be electrically neutral. This is because the number of electrons in the atom is equal to the number of protons in the neutral atom.

The number of protons in the neutral atom is called the atomic number of the atom.

For an element that has 20 electrons, its electronic configuration is;

1s2 2s2 2p6 3s2 3p6 4s2.

The 19th electron is in the 4s orbital hence both the azimuthal and magnetic quantum numbers are zero.

The element has outermost electron configuration ns2 so it mus belong to group 2 of the periodic table.

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Answer:

To 318.18 mL would you need to dilute 20.0 mL of a 1.40 M solution of LiCN to make a 0.0880 M solution of LiCN

Explanation:

Dilution is the reduction of the concentration of a chemical in a solution and consists simply of adding more solvent.

In a dilution the amount of solute does not vary. But as more solvent is added, the concentration of the solute decreases, as the volume (and weight) of the solution increases.

In a solution it is fulfilled:

Ci* Vi = Cf* Vf

where:

In this case:

Replacing:

1.40 M* 20 mL= 0.088 M* Vf

Solving:

[tex]Vf=\frac{1.40 M* 20 mL}{0.088 M}[/tex]

Vf= 318.18 mL

To 318.18 mL would you need to dilute 20.0 mL of a 1.40 M solution of LiCN to make a 0.0880 M solution of LiCN

Answer:

Classify each of the following as either macroscopic, microscopic or particulate:

a. a red blood cell.

b. a sugar molecule.

c. baking powder.

Explanation:

a. A red blood cell is a microscopic particle.

It can be viewed under a microscope.

b. A sugar molecule is also a microscopic substance.

It can be viewed under a microscope.

c. Baking powder is macroscopic substance.

Answer:

1, 1, 2, 3

Explanation:

The numbers 1 and 8 both have 1 sig. fig.

The number 13 has 2 sig. figs.

The number 104 has 3 sig. figs.

Answer: There are 0.779 moles of gas were added to the bottle.

Explanation:

Given: [tex]n_{1}[/tex] = 0.650 mol,     [tex]P_{1}[/tex] = 730 mm Hg (1 mm Hg = 0.00131579 atm) = 0.96 atm

[tex]n_{2}[/tex] = ?,           [tex]P_{2}[/tex] = 1.15 atm

Formula used is as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}[/tex]

Substitute the values into above formula as follows.

[tex]\frac{P_{1}}{n_{1}} = \frac{P_{2}}{n_{2}}\\\frac{0.96 atm}{0.650 mol} = \frac{1.15 atm}{n_{2}}\\n_{2} = 0.779 mol[/tex]

Thus, we can conclude that there are 0.779 moles of gas were added to the bottle.

Answer:

False

Explanation:

An object with a density greater than 1.00g/mL (greater than the density of water) will sink. An object with a density less than the density of water, will float.

If the water has a density of 1.00 g/mL. If you put an object that has a density of 0.79 g/mL into water, it will sink to the bottom, this statement is false.

The density of an actual content is its mass per unit volume. The most common symbol for density is d, but the Latin letter D can also be used.

Three of an object's most fundamental properties are mass, volume, and density. Mass describes how heavy something is, volume describes its size, and density is defined as mass divided by volume.

The density of something is a measure of how heavy it is in relation to its size. When an artifact is more dense than water, it plunges; when an object is less dense than water, it floats.

Density is a property of a substance that is independent of the amount of substance.

As in the given scenario, water is having density 1 g/mL and object in having density less then it so it will float on water.

Thus, the given statement is false as the material will not sink, rather it will float on water.

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Complete question:

What mass of steam initially at 120 ⁰C is needed to warm 200g of water in a 100 g glass container from 20.0 oC to 50.0 ⁰C

Answer:

the initial mass of the steam is 10.82 g

Explanation:

Given;

mass of water, m₁ = 200 g

mass of the glass, m₂ = 100 g

temperature of the steam = 120 ⁰C

initial temperature of the water, 20⁰ C

final temperature of the water, = 50⁰ C

let the mass of the steam = m

specific heat capacity of water c = 1 cal/g ⁰ C

specific heat capacity of glass c₂ = 0.2 cal/g ⁰ C

laten heat of vaporization of steam L = 540 cal/g

Apply principle of conservation energy;

Heat given off by the steam = Heat absorbed by water + heat absorbed by glass

[tex]mc\Delta T_1 + mL + mc\Delta T_2 = m_1c\Delta T_3 + m_2c_2\Delta T_3\\\\mc\Delta T_1 + mL + mc\Delta T_2 = [m_1c + m_2c_2]\Delta T_3[/tex]

m(1) (120 - 100)  +  m(540)  + m(1) (100 - 50) = [200(1)  +  100(0.2)] (50 - 20)

20m + 540m + 50m = 6600

610 m = 6600

m = 6600 / 610

m = 10.82 g

Therefore, the initial mass of the steam is 10.82 g

Answer: The molarity of an HCl solution is 0.218 M if 43.6 mL of a 0.125 M NaOH solution are needed to titrate a 25.0 mL sample of the acid.

Explanation:

Given: [tex]V_{1}[/tex] = 43.6 mL,      [tex]M_{1}[/tex] = 0.125 M

[tex]V_{2}[/tex] = 25.0 mL,        [tex]M_{2}[/tex] = ?

Formula used to calculate the concentration of acid is as follows.

[tex]M_{1}V_{1} = M_{2}V_{2}[/tex]

Substitute the values into above formula.

[tex]M_{1}V_{1} = M_{2}V_{2}\\0.125 M \times 43.6 mL = M_{2} \times 25.0 mL\\M_{2} = 0.218 M[/tex]

Thus, we can conclude that the molarity of an HCl solution is 0.218 M if 43.6 mL of a 0.125 M NaOH solution are needed to titrate a 25.0 mL sample of the acid.

The molarity of the HCl solution used in the neutralization reaction has been 0.218 M.

The reaction of NaOH with HCl has been a neutralization reaction. The resultant will be salt and water.

In the reaction the molarity can be calculated as:

Molarity of HCl [tex]\rm[/tex][tex]\times[/tex] Volume of HCl = Molarity of NaOH

Given,

The volume of HCl solution = 25 ml

Molarity of NaOH = 0.125 M

Volume of NaOH solution = 43.6 ml

Substitute the values in the equation:

Molarity of HCl [tex]\times[/tex] 25 = 0.125 [tex]\times[/tex] 43.6

Molarity of HCl [tex]\times[/tex] 25 = 5.45

Molarity of HCl solution = [tex]\rm \dfrac{5.45}{25}[/tex]

Molarity of HCl solution = 0.218 M

The molarity of the HCl solution used in the neutralization reaction has been 0.218 M.

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Answer:

Electrons

Explanation:

Electrons are produced when light with enough energy is directed onto the cathode where electrons are ejected as beam towards the screen.

Answer:

3KOH(aq) + FeCl3(aq) --------> Fe(OH)3 + 3KCl

Explanation:

The rule for balancing chemical equations is that the number of atoms of each element must be the same on both sides of the reaction equation.

Hence, the two reactants are potassium hydroxide and aqueous iron(III) chloride.

The balanced molecular reaction equation is;

3KOH(aq) + FeCl3(aq) --------> Fe(OH)3 + 3KCl

The question is incomplete, the complete question is;

What functional group results when cyclopentanone reacts with ethylamine in the presence of trace acid? A) cyanohydrin B) semicarbazone C) imine D) enamine E) oxime

Answer:

imine

Explanation:

An imine is an unsaturated amine. An imine contains the carbon- nitrogen double bond.

Imines are obtained when a carbonyl compound is condensed with NH3 or an amine. The reaction involves several steps in its mechanism.

Since cyclopentanone is a ketone (carbonyl compound) and ethylamine is an amine,in the presence of trace acid, condensation of the two compounds occur to yield an imine

Answer:

B.9.710-11M

Explanation:

Answer:

Fill in the blanks with each titration term with its definition.

a. Solution of an unknown concentration that has another solution slowly added to it ________________

b. Process of slowly adding a solution to react with another solution and determine the concentration of one of the solutions based on the reaction between them ______________

c. A reagent added to the analyte solution that changes color when the reaction is complete ______________

d. Glassware that allows a solution to be precisely and slowly added to another solution _____________

e. Solution of known concentration that is slowly added to a solution of unknown concentration ________________

f. When the required amount of one solution has been added to the second solution to complete the reaction ____________

Explanation:

a. Solution of an unknown concentration that has another solution slowly added to it is called analyte.

b. Process of slowly adding a solution to react with another solution and determine the concentration of one of the solutions based on the reaction between them is called titration.

c. A reagent added to the analyte solution that changes color when the reaction is complete is called an indicator.

d. Glassware that allows a solution to be precisely and slowly added to another solution is called a pipette.

e. Solution of known concentration that is slowly added to a solution of unknown concentration is called titrant.

f. When the required amount of one solution has been added to the second solution to complete the reaction is called neutralization.

Answer:

To transfer leftover solids to the filtration funnel and wash out crystals after recrystallization, ice cold methanol should be used (the mother liquor used for recrystallization).

Explanation:

Hope this helped

Answer:

a. the proportion of elements to compounds is constant.

Answer:

0.5024 g

Explanation:

Step 1: Calculate the concentration of H⁺

We will use the definition of pH.

pH = -log [H⁺]

[H⁺] = antilog -pH = antilog -12.40 = 3.981 × 10⁻¹³ M

Step 2: Calculate the concentration of OH⁻

We will use the ionic product of water expression.

[H⁺] [OH⁻] = 10⁻¹⁴

[OH⁻] = 10⁻¹⁴/[H⁺] = 10⁻¹⁴/3.981 × 10⁻¹³ = 0.02512 M

Step 3: Calculate the initial concentration of NaOH

NaOH is a strong base and the molar ratio of NaOH to OH⁻is 1:1. Thus, the initial concentration of NaOH is 1/1 × 0.02512 M = 0.02512 M.

Step 4: Calculate the moles of NaOH

We will use the definition of molarity.

M = moles of NaOH/liters of solution

moles of NaOH = M × liters of solution

moles of NaOH = 0.02512 mol/L × 0.5000 L = 0.01256 mol

Step 5: Calculate the mass of 0.01256 moles of NaOH

The molar mass of NaOH is 40.00 g/mol.

0.01256 mol × 40.00 g/mol = 0.5024 g