a 20.0-mlml sample of 0.150 m kohm koh is titrated with 0.125 m hclo 4m hclo4 solution. calculate the ph after the following volumes of acid have been added.

Answers

Answer 1

The pH of the solution after the following volumes of acid have been added is 2.55.

To solve this problem, we need to use the balanced chemical equation for the reaction between KOH and HClO₄:

KOH + HClO₄ → KClO₄ + H₂O

We also need to use the formula for calculating the pH of a solution:

pH = -log[H⁺]

where [H⁺] is the concentration of hydrogen ions in the solution.

First, let's calculate the number of moles of KOH in the sample:

moles of KOH = volume of sample (in L) x concentration of KOH
moles of KOH = 0.020 L x 0.150 mol/L
moles of KOH = 0.003 mol

Since the stoichiometry of the reaction is 1:1 between KOH and HClO₄, we know that it will take the same number of moles of HClO₄ to completely react with the KOH in the sample.

Next, let's calculate the volume of HClO₄ needed to completely react with the KOH:

moles of HClO₄ = moles of KOH
volume of HClO₄ = moles of HClO₄ / concentration of HClO₄
volume of HClO₄ = 0.003 mol / 0.125 mol/L
volume of HClO₄ = 0.024 L
volume of HClO₄ = 24.0 mL

So, when 24.0 mL of 0.125 M HClO₄ is added, all of the KOH will have reacted. The remaining volume of HClO₄ is:

volume of HClO₄ remaining = total volume of HClO₄ added - volume of HClO₄ needed
volume of HClO₄ remaining = 25.0 mL - 24.0 mL
volume of HClO₄ remaining = 1.0 mL

Now, we can use the volume and concentration of the remaining HClO₄ to calculate the concentration of H⁺ in the solution:

moles of HClO₄ remaining = volume of HClO₄ remaining (in L) x concentration of HClO₄
moles of HClO₄ remaining = 0.001 L x 0.125 mol/L
moles of HClO₄ remaining = 0.000125 mol

moles of H⁺ = moles of HClO₄ remaining (since the reaction is 1:1)
moles of H⁺ = 0.000125 mol

volume of solution = volume of sample + volume of HClO₄ added
volume of solution = 0.020 L + 0.025 L
volume of solution = 0.045 L

[H⁺] = moles of H⁺ / volume of solution
[H⁺] = 0.000125 mol / 0.045 L
[H⁺] = 0.0028 M

Finally, we can calculate the pH using the formula:

pH = -log[H⁺]
pH = -log(0.0028)
pH = 2.55

Therefore, the pH of the solution after 25.0 mL of 0.125 M HClO₄ has been added is 2.55.

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Related Questions

calculate the grams of acetic acid in the 4.0 ml vinegar sample 1. use dimensional analysis when solving this problem

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The amount of acetic acid in the 4.0 mL vinegar sample cannot be calculated without knowing the concentration of acetic acid in the vinegar.

To calculate the amount of acetic acid in the vinegar sample, we need to know the concentration of acetic acid in the vinegar, which is usually expressed as the percentage of acetic acid by mass or as the molarity of acetic acid in the solution. Once we know the concentration, we can use dimensional analysis to convert the volume of the vinegar sample into the amount of acetic acid in grams.

For example, if the concentration of acetic acid in the vinegar is 5% by mass, we can assume that there are 5 grams of acetic acid in every 100 grams of vinegar. We can then use this information to calculate the amount of acetic acid in the 4.0 mL vinegar sample by first converting the volume to mass using the density of vinegar and then converting the mass of vinegar to the mass of acetic acid using the percentage by mass of acetic acid in the vinegar.

So, it is important to know the concentration of acetic acid in the vinegar in order to calculate the amount of acetic acid in the 4.0 mL vinegar sample.

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How many molecules of CuSO4 are required to react with 2. 0 moles Fe?Fe + CuSO4 ----> Cu + FeSO4

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The molecules of Fe formed are 3.37 x 10²⁴ atoms, this can be calculated in the below section.

The reaction is this one:

Fe + CuSO₄ --> Cu + FeSO₄

The reaction mentioned above is the displacement reaction, here the ion of one of the reactant is displaced from the other compound and results into a product and displaces the other metal.

And the ratio for the reaction is 1:1

If 5.6 moles of iron react, you will have 5.6 moles of FeSO₄. By the way, you should use NA (Avogadro number) to calculate the number of molecules.

1 mol = 6.02x10²³

Therefore,

5.6 moles = (5.6 x 6.02x10²³) = 3.37 x 10²⁴ atoms

Therefore, the molecules of Fe formed are 3.37 x 10²⁴ atoms.

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what ion will be formed by the phosphorus atom shown below when it has a stable set of valence electrons?

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The phosphorus atom shown below has 5 valence electrons. In order to have a stable set of valence electrons, it needs to gain 3 more electrons. This will result in the formation of a phosphide ion (P³⁻).

When a phosphorus atom gains a stable set of valence electrons, it forms an ion called a phosphide ion. The phosphorus atom achieves stability by gaining three electrons to complete its valence shell, resulting in a -3 charge. Therefore, the ion formed is P³⁻ (phosphide ion).

Phosphorus is a chemical element with the atomic number 15 and the letter P in its name. Phosphorus is an element that appears in two major forms: red and white. However, because to its strong reactivity, phosphorus is never found on Earth as a free element.

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a relatively long lived excited state of an atom has a lifetime of 2.20 ms. what is the minimum uncertainty (in ev) in its energy?

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The minimum uncertainty in the energy of the relatively long-lived excited state of the atom is approximately 4.774 × 10⁻¹⁴ eV. the minimum uncertainty in the energy of the excited state is 0.009 eV.

The minimum uncertainty in the energy of the excited state can be calculated using the formula ΔE Δt >= ħ/2, where ΔE is the uncertainty in energy, Δt is the lifetime of the excited state, and ħ is the reduced Planck's constant.

ΔE >= (ħ/2) / Δt
ΔE >= (6.626 x 10^-34 J s / (2 x π)) / (2.20 x 10^-3 s)
ΔE >= 1.44 x 10^-21 J

To convert this to electron volts (eV), we divide by the elementary charge (e):

ΔE >= (1.44 x 10^-21 J) / 1.602 x 10^-19 C
ΔE >= 0.009 eV

Therefore, the minimum uncertainty in the energy of the excited state is 0.009 eV.

ΔE * Δt ≥ h/(4π)

where ΔE is the uncertainty in energy, Δt is the lifetime of the excited state, and h is the reduced Planck constant (approximately 6.582 × 10⁻¹⁶ eV·s).

Given a lifetime (Δt) of 2.20 ms, we can calculate the minimum uncertainty (ΔE) as follows:

ΔE ≥ h/(4π * Δt)

Convert the lifetime to seconds:
Δt = 2.20 ms = 2.20 × 10⁻³ s

Now, plug in the values:
ΔE ≥ (6.582 × 10⁻¹⁶ eV·s) / (4π * 2.20 × 10⁻³ s)

ΔE ≥ 4.774 × 10⁻¹⁴ eV

The minimum uncertainty in the energy of the relatively long-lived excited state of the atom is approximately 4.774 × 10⁻¹⁴ eV.

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which electron configuration represents the electrons of a phosphorus atom in an excited state 2-8-5, 2-8-6, 2-7-6, 2-7-4

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the electron configuration that represents the electrons of a phosphorus atom in an excited state is 2-7-4.

the electron configuration of a neutral phosphorus atom in its ground state is 2-8-5. However, when an electron is excited to a higher energy level, it jumps from the 3s orbital to the 3p orbital. This results in the configuration of 2-7-4, where there are now four electrons in the 3p orbital instead of three.

In conclusion, the electron configuration of a phosphorus atom in an excited state is 2-7-4. This represents the configuration of the atom after an electron has been excited to a higher energy level and jumped to the 3p orbital. I

In its ground state, phosphorus has an electron configuration of 2-8-5. When an atom is in an excited state, it means that one or more of its electrons have absorbed energy and jumped to a higher energy level. For phosphorus, one electron from the 2nd energy level (n=2) can be excited to the 3rd energy level (n=3). This results in the electron configuration changing from 2-8-5 to 2-7-6.

To determine the electron configuration of a phosphorus atom in an excited state, look for an electron arrangement where one electron has moved from a lower energy level to a higher one. In this case, the configuration 2-7-6 represents an excited phosphorus atom.

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75.00 g of compound A (molar mass = 84.72 g/mol) and 13.17 g compound B (molar mass = 74,4 g/mol) react completely to form 14.85 g compound C (molar mass = 41.89 g/mol) and 73.32 g compound D (molar mass - 103.56 g/mol) with nother reactant in excess. What is the coefficient for compound D in the chemical equation for this reaction when balanced in lowest whole-numbers? Answer:

Answers

Answer:

75.00 g of compound A (molar mass = 84.72 g/mol) and 13.17 g compound B (molar mass = 74,4 g/mol) react completely to form 14.85 g compound C (molar mass = 41.89 g/mol) and 73.32 g compound D (molar mass - 103.56 g/mol) with nother reactant in excess. The coefficient for compound D is 4 .

Explanation:

We can approach this problem by first finding the moles of each compound using their molar masses and masses given in the problem. Then, we can use these mole ratios to determine the coefficients in the balanced chemical equation.

First, let's find the moles of each compound:

n(A) = 75.00 g / 84.72 g/mol = 0.8850 mol

n(B) = 13.17 g / 74.4 g/mol = 0.1770 mol

n(C) = 14.85 g / 41.89 g/mol = 0.3543 mol

n(D) = 73.32 g / 103.56 g/mol = 0.7080 mol

Next, we can write the balanced chemical equation as:

aA + bB → cC + dD

where a, b, c, and d are the coefficients we need to find.

Using the law of conservation of mass, we can write the equation:

a + b = c + d

Since we know that all the reactants are consumed completely, we can write:

n(A) / a = n(C) / c

n(B) / b = n(C) / c

n(A) / a = n(D) / d

n(B) / b = n(D) / d

Substituting the values we calculated earlier, we get:

0.8850 / a = 0.3543 / c

0.1770 / b = 0.3543 / c

0.8850 / a = 0.7080 / d

0.1770 / b = 0.7080 / d

Simplifying these equations, we get:

c = 2a = 2b

d = 4a = 4b

Substituting these relationships into the conservation of mass equation, we get:

3a = 5b

The lowest whole-number coefficients that satisfy this equation are a = 5 and b = 3. Therefore, the balanced chemical equation for the reaction is:

5A + 3B → 2C + 4D

The coefficient for compound D is 4.

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Water with an alkalinity of 2. 00 10-3 mol/l has a ph of 7. 65. Calculate [co2], [hco3-], [co32-], [h3o ] and [oh-]

Answers

The final concentrations are:

[[tex]CO_2[/tex]] = 1.00 x [tex]10^-4[/tex] mol/L[[tex]HCO_3[/tex]-] = 2.00 x [tex]10^-3[/tex]mol/L[[tex]CO_32[/tex]-] = 1.18 x [tex]10^-10[/tex] mol/L[[tex]H_3O[/tex]+] = 3.55 x [tex]10^-8[/tex] mol/L[[tex]OH[/tex]-] = 2.82 x [tex]10^-7[/tex] mol/L

pH = pKa + log([[tex]HCO_3[/tex]-]/[[tex]CO_2[/tex]])

The pKa of the bicarbonate buffering system is 6.35. Plugging in the values we have, we get:

7.65 = 6.35 +  log([[tex]HCO_3[/tex]-]/[[tex]CO_2[/tex]])

log([[tex]HCO_3[/tex]-]/[[tex]CO_2[/tex]]) = 1.3

([[tex]HCO_3[/tex]-]/[[tex]CO_2[/tex]]) = 20

We know that [[tex]HCO_3[/tex]-] = 2.00 x [tex]10^-3[/tex] mol/L, so we can solve for [[tex]CO_2[/tex]]:

[[tex]CO_2[/tex]] = [[tex]HCO_3[/tex]-]/20 = 1.00 x [tex]10^-4[/tex] mol/L

Using the equilibrium constants, we can calculate the concentrations of the other species:

[[tex]H_3O[/tex]+] = K1[[tex]H_2CO_3[/tex]]/[[tex]CO_2[/tex]] = (4.45 x [tex]10^-7[/tex])([[tex]HCO_3[/tex]-]²/[[tex]CO_2[/tex]]) = 3.55 x[tex]10^-8[/tex]mol/L

[OH-] = Kw/[[tex]H_3O[/tex]+] = 1.00 x [tex]10^-14[/tex]/3.55 x [tex]10^-8[/tex] = 2.82 x [tex]10^-7[/tex] mol/L

[[tex]CO_2[/tex]-] = K2[[tex]HCO_3[/tex]-]/[H+]= (4.69 x [tex]10^-11[/tex])([[tex]CO_2[/tex]]/[[tex]HCO_3[/tex]-]) = 1.18 x [tex]10^-10[/tex]mol/L

The final concentrations are:

[[tex]CO_2[/tex]] = 1.00 x [tex]10^-4[/tex] mol/L

[[tex]HCO_3[/tex]-] = 2.00 x [tex]10^-3[/tex]mol/L

[[tex]CO_32[/tex]-] = 1.18 x [tex]10^-10[/tex] mol/L

[[tex]H_3O[/tex]+] = 3.55 x [tex]10^-8[/tex] mol/L

[[tex]OH[/tex]-] = 2.82 x [tex]10^-7[/tex] mol/L

Concentration refers to the amount of a substance dissolved in a given volume or mass of another substance. It is a measure of the amount of solute present in a solution or mixture. Concentration is usually expressed in terms of mass per unit volume, moles per unit volume, or percentage by mass or volume.

The most commonly used units of concentration include molarity, molality, normality, mass percent, and volume percent. Molarity refers to the number of moles of solute per liter of solution, while molality is the number of moles of solute per kilogram of solvent. Normality is similar to molarity, but it takes into account the number of acidic or basic equivalents in a solution. Mass percent and volume percent are used to express the concentration of a solute in a solution as a percentage of the total mass or volume of the solution.

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If 0.576 M of KF has a volume of 121.2 mL. What mass of KF is in the solution.

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If 0.576 M of KF has a volume of 121.2 mL, the mass of KF is in the solution is 4.049 g

To determine the mass of KF in the solution, we can use the formula:

mass = molarity x volume x molar mass

First, we need to calculate the molar mass of KF:

KF

= K + F

= 39.10 g/mol + 18.99 g/mol

= 58.09 g/mol

Now, we can substitute the values in the given formula:

mass

= 0.576 mol/L x 121.2 mL x 58.09 g/mol

= 0.576 mol/L x 0.121 L x 58.09 g/mol

=4.049 g

Therefore, there are 4.049 g of KF in the solution.

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If the following elements were to form an ionic compound, which noble-gas configuration would they most likely attain?

a. Li
b. Na
c. Br
d. Sr

Answers

Li would attain the noble-gas configuration of helium (1s²), Na would attain the noble-gas configuration of neon (2s²2p⁶), Br would attain the noble-gas configuration of krypton (3s²3p⁶3d¹⁰4s²4p⁶) and Sr would attain the noble-gas configuration of krypton (4s²3d¹⁰4p⁶).

When atoms of certain elements react to form an ionic compound, they tend to lose or gain electrons in order to achieve a stable electronic configuration similar to that of a noble gas.

The noble gases have completely filled outermost electron shells and are thus chemically inert. Therefore, in order to achieve a similar electronic configuration, atoms of other elements tend to gain or lose electrons to either achieve a completely filled outer shell or an empty outer shell.

a. Lithium (Li) has one valence electron and is likely to lose it to attain the stable electron configuration of helium (He).

b. Sodium (Na) has one valence electron and is likely to lose it to attain the stable electron configuration of neon (Ne).

c. Bromine (Br) has seven valence electrons and is likely to gain one electron to attain the stable electron configuration of krypton (Kr).

d. Strontium (Sr) has two valence electrons and is likely to lose them to attain the stable electron configuration of krypton (Kr).

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a sealed jar whose volume is exactly 1l which contains 1 mole of air at temperature 20-degree celcius, assuming that the air behaves as an ideal gas. so what is the pressure inside the jar in pa?

Answers

Therefore, the pressure inside the sealed jar containing 1 mole of air at 20°C is approximately 2438.48 Pa.

To find the pressure inside the sealed jar containing 1 mole of air at 20°C, we can use the ideal gas law:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the universal gas constant, and T is the temperature in Kelvin.

First, we need to convert the temperature from Celsius to Kelvin:

T = 20°C + 273.15 = 293.15 K

Next, we can substitute the given values into the ideal gas law:

P(1 L) = (1 mol)(8.31 J/mol*K)(293.15 K)

P = (1 mol)(8.31 J/mol*K)(293.15 K) / 1 L

P = 2438.48 Pa

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At a certain temperature, the equilibrium constant, K, for this reaction is 53.3.

H2(g)+I2(g)\rightleftharpoons2HI(g) K= 53.3

At this temperature, the reactants were placed in a container to react. If the partial pressures of H2 and I2 were each 0.400 bar initially, what is the partial pressure of HI at equilibrium?

Answers

The partial pressure of HI at equilibrium is approximately 0.734 bar.

To find the partial pressure of HI at equilibrium, we'll use the equilibrium constant (K) and the initial partial pressures of H2 and I2.

The reaction is: H2(g) + I2(g) ⇌ 2HI(g) and K = 53.3

Let x be the change in partial pressure of H2 and I2. At equilibrium, the partial pressures will be:

H2: 0.400 - x
I2: 0.400 - x
HI: 2x

Now, we'll set up the equilibrium constant expression:

K = [HI]^2 / ([H2] * [I2]) = 53.3

Substitute the equilibrium partial pressures into the expression:

53.3 = (2x)^2 / ((0.400 - x) * (0.400 - x))

Solve for x:

53.3 * ((0.400 - x) * (0.400 - x)) = (2x)^2

Expand and simplify the equation, and then solve for x. After solving for x, you'll find that x ≈ 0.367 bar.

Now, use the value of x to find the partial pressure of HI at equilibrium:

Partial pressure of HI = 2x ≈ 2 * 0.367 ≈ 0.734 bar

So, the partial pressure of HI at equilibrium is approximately 0.734 bar.

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how many moles of c are needed to react with 1.25 grams of tio2

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0.0312 moles of C are needed to react with 1.25 grams of TiO2.

If we see ,the balanced chemical equation for the reaction between carbon (C) and titanium dioxide (TiO2) is:

TiO2 + 2C → Ti + 2CO

From the equation, we can see that 1 mole of TiO2 reacts with 2 moles of C to produce 1 mole of Ti and 2 moles of CO.

To calculate how many moles of C are needed to react with 1.25 grams of TiO2, we first need to convert the mass of TiO2 to moles:

moles of TiO2 = mass / molar mass

The molar mass of TiO2 is:

TiO2: 1(Ti) + 2(O)

        = 1(47.87 g/mol) + 2(16.00 g/mol)

        = 79.87 g/mol

So, for 1.25 grams of TiO2:

moles of TiO2 = 1.25 g / 79.87 g/mol

                       = 0.0156 mol

From the balanced chemical equation, we know that 2 moles of C react with 1 mole of TiO2. Therefore, the number of moles of C needed to react with 0.0156 moles of TiO2 is:

moles of C = 2 x moles of TiO2

                 = 2 x 0.0156 mol

                  = 0.0312 mol

Hence , 0.0312 moles are needed.

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in a mammalian cell, by how many mv does the nernst potential of an ion increase if the external ion concentration is doubled?

Answers

Doubling the external ion concentration in a mammalian cell would increase the Nernst potential of the ion by approximately 58 mV.

How to find the external ion concentration on the Nernst potential of an ion in a mammalian cell?

The Nernst equation describes the relationship between the concentration gradient of an ion across a membrane and the membrane potential required to maintain equilibrium for that ion. The equation is as follows:

[tex]E = (RT/zF) * ln[/tex]([tex][ion]outside/[ion]inside)[/tex]

where:

E is the Nernst potential (membrane potential at which the ion is at equilibrium)

R is the gas constant

T is the absolute temperature

z is the valence of the ion

F is the Faraday constant

[ion]outside is the concentration of the ion outside the cell

[ion]inside is the concentration of the ion inside the cell

ln is the natural logarithm function

Assuming the valence (z) and temperature (T) remain constant, if the external ion concentration is doubled, the Nernst potential of the ion will increase by approximately 58 mV at room temperature (25°C). This can be calculated using the Nernst equation:

E2 = (RT/zF) * ln([ion]outside x 2/[ion]inside)

E1 = (RT/zF) * ln([ion]outside/[ion]inside)

Subtracting E1 from E2, we get:

ΔE = E2 - E1 = (RT/zF) * ln([ion]outside x 2/[ion]inside) - (RT/zF) * ln([ion]outside/[ion]inside)

ΔE = (RT/zF) * ln(2)

ΔE = (8.314 J/mol·K * 298 K / (1 * 96,485 C/mol)) * ln(2)

ΔE ≈ 58 mV

Therefore, doubling the external ion concentration in a mammalian cell would increase the Nernst potential of the ion by approximately 58 mV.

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Write a balanced equation for the complete oxidation of propanoic acid.

Answers

The complete oxidation of propanoic acid ([tex]CH3CH2COOH[/tex]) produces carbon dioxide ([tex]CO2[/tex]) and water ([tex]H2O[/tex]) as the only products. The balanced chemical equation for this reaction is: [tex]CH3CH2COOH + 4O2 → 3CO2 + 4H2O[/tex]

In this equation, the coefficients in front of each compound indicate the balanced stoichiometric ratio of reactants and products.

The coefficient of 1 in front of propanoic acid indicates that only one molecule of propanoic acid is required to react with four molecules of oxygen ([tex]O2[/tex]) to produce three molecules of carbon dioxide and four molecules of water.

The balanced equation ensures that the law of conservation of mass is satisfied, with the same number of atoms of each element present on both sides of the equation.

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Create a solution of 0.1M Na S204 PreLab 1. Verify the amount of Na2S2O3.5 H2O needed to create a 0.IM solution of Na2S2O3. so 2. Why does the yellow color reappear after endpoint (clear silution) is reached?

Answers

To create a 0.1M solution of Na₂S₂O₃, you would need 16.98 g of Na₂S₂O₃·5H₂O in 1 liter of solution.

The yellow color reappears after the endpoint is reached due to the formation of the iodine-starch complex. In the titration of iodine with thiosulfate, the endpoint is reached when all the iodine has reacted and the solution becomes colorless.

However, when excess thiosulfate is added, it can react with the iodine-starch complex that was formed during the titration, resulting in the reformation of iodine and the reappearance of the yellow color. This is known as the "iodine clock reaction" and is commonly used in chemistry experiments to demonstrate the concept of reaction kinetics.

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approximately how much water (lbs) is found in a 134 lb person?

Answers

A 134 lb person has approximately 80,400 grams (or about 177 pounds) of water in their body. This is based on the fact that the human body is composed of roughly 60% water. To calculate this, you can simply multiply the person's weight (in this case, 134 lbs) by the percentage of water content in the body (60%).

Here's the calculation:
134 lbs * 0.6 (60%) ≈ 80.4 lbs of water

It's essential to note that the percentage of water in the body can vary based on factors such as age, sex, and overall health. For instance, men tend to have a higher water content than women, and younger individuals typically have a higher percentage of water in their bodies than older individuals. Additionally, factors like dehydration, diet, and exercise can impact the body's water content.

In conclusion, a 134 lb person has approximately 80.4 lbs of water in their body, which represents about 60% of their total body weight. This amount can vary based on factors such as age, sex, and health status, but it provides a general idea of how much water is present in the human body.

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A 1.00 L buffer solution is 0.100 M in HF and 0.100 M in NaF. The pH of the solution [ Select ] --> ["no change", "decreases", "increases"] while adding HCl. After the addition of 0.02 moles of HCl, the pH of the solution is [ Select ] --> ["3.63", "3.21", "3.46", "3.28"] . Assume no volume change upon the addition of HCl. The Ka for HF is 3.5 × 10−4. Henderson–Hasselbalch equation: Ph = pKa + log [base]/[acid]

Answers

The pH of the solution remains unchanged both before and after adding 0.02 moles of HCl, and the correct option is pH = 3.46.

Using the Henderson-Hasselbalch equation:

Given:

Initial volume = 1.00 L

Initial [HF] = 0.100 M

Initial [NaF] = 0.100 M

Initial moles of HCl added = 0.02 moles

Ka for HF = [tex]\rm \(3.5 \times 10^{-4}\)[/tex]

Henderson-Hasselbalch equation:

[tex]\rm \[pH = pKa + \log \frac{[\text{base}]}{[\text{acid}]}\][/tex]

where for this case, the base is NaF and the acid is HF.

1. Calculate pKa:

pKa = [tex]\rm \(-\log(Ka)\)[/tex]

pKa = [tex]\rm \(-\log(3.5 \times 10^{-4}) \approx 3.46\)[/tex]

2. Before adding HCl:

Initial pH = [tex]\rm pKa + \(\log \frac{[\text{NaF}]}{[\text{HF}]}\)[/tex]

Initial pH = [tex]\rm \(3.46 + \log \frac{0.100}{0.100} = 3.46\)[/tex]

Now, when HCl is added, moles of HF and NaF will react to form additional moles of F-. The moles of HF decrease by 0.02 moles, and the moles of NaF decrease by 0.02 moles as well.

3. After adding HCl:

Moles of HF = Initial moles - moles reacted = 0.100 - 0.02 = 0.08 moles

Moles of NaF = Initial moles - moles reacted = 0.100 - 0.02 = 0.08 moles

4. Calculate pH after adding HCl:

pH = pKa + [tex]\rm \(\log \frac{[\text{NaF}]}{[\text{HF}]}\)[/tex]

pH = [tex]\rm \(3.46 + \log \frac{0.08}{0.08} = 3.46\)[/tex]

So, the pH of the solution remains unchanged both before and after adding 0.02 moles of HCl, and the correct options are:

- The pH does not change.

- pH = 3.46

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Final answer:

Upon adding HCl to a buffer solution of HF and NaF, the pH decreases. After addition of 0.02 moles of HCl, using the Henderson-Hasselbalch equation, the new pH is found to be 3.21.

Explanation:

When HCl is added to the buffer solution, it will react with the F- ions (from NaF) to form HF, so the pH of the solution decreases.

Using the Henderson-Hasselbalch equation, we can then calculate the new pH after the addition of HCl. The moles of HF will increase by 0.02 moles (from HCl reacting with F-) and moles of F- will decrease by the same amount.

New [HF] = (0.100 moles + 0.02 moles)/ 1.0 L = 0.12 M

New [F-] = (0.100 moles - 0.02 moles)/ 1.0 L = 0.08 M

Then, plug these values into the Henderson Hasselbalch equation:

pH = pKa + log([F-]/[HF])

pH = -log(3.5 x 10^-4) + log(0.08/0.12)

Consequently, the pH of the solution is 3.21.

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how many grams of sodium carbonate are present in the 575 l? (use a conversion factor to transfer the results you got from 15 ml to the 575 l expected.

Answers

The amount of sodium carbonate present in 575 L is 6,133.33 g.

First, we need to determine the amount of sodium carbonate present in 15 mL. Let's assume that the concentration of sodium carbonate is 0.1 M. This means that there are 0.1 moles of sodium carbonate in 1 liter of solution. Therefore, in 15 mL of solution, there are:

0.1 mol/L x 0.015 L = 0.0015 moles of sodium carbonate.

Next, we need to convert this value to grams. The molar mass of sodium carbonate (Na2CO3) is 105.99 g/mol. Therefore, the mass of 0.0015 moles of Na2CO3 is:

0.0015 mol x 105.99 g/mol = 0.16 g of Na2CO3.

To find out how much sodium carbonate is present in 575 L, we need to use a conversion factor. There are 1000 mL in 1 L, so there are:

575 L x 1000 mL/L = 575,000 mL of solution.

Therefore, the amount of sodium carbonate in 575 L of solution can be calculated as:

0.16 g x (575,000 mL / 15 mL) = 6,133.33 g or approximately 6.13 kg of Na2CO3.

There are approximately 6.13 kg of sodium carbonate present in 575 L of solution, assuming a concentration of 0.1 M. This calculation was done by first determining the amount of sodium carbonate in 15 mL of solution and then using a conversion factor to scale up to 575 L.

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what is the freezing point of a solution of sugar dissolved in water if the concentration of the solution is 0.24 m?

Answers

The freezing point of the sugar solution will be -0.4464 °C.

The freezing point of a solution depends on its concentration. A solution with a higher concentration will have a lower freezing point than a solution with a lower concentration. In this case, the concentration of the sugar solution is 0.24 m. To determine the freezing point, you need to know the freezing point depression constant, which is a property of the solvent (water in this case).
Assuming that the freezing point depression constant of water is 1.86 °C/m, you can use the formula ΔT = Kf * m, where ΔT is the change in freezing point, Kf is the freezing point depression constant, and m is the molality of the solution.
Substituting the values, you get ΔT = 1.86 °C/m * 0.24 m = 0.4464 °C. This means that the freezing point of the sugar solution will be lowered by 0.4464 °C.
To find the new freezing point, you need to subtract this value from the normal freezing point of water, which is 0 °C. Therefore, the freezing point of the sugar solution will be -0.4464 °C.

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when investigating the fate and transport of toxic compounds, which factor should be calculated to estimate the ability of a specific chemical to enter lipid rich tissue? question 5select one: a. koc b. kw c. kd d. kow

Answers

The factor that should be calculated to estimate the ability of a specific chemical to enter lipid-rich tissue is the octanol-water partition coefficient (Kow). Kow is a measure of the relative solubility of a compound in octanol (lipid-like) compared to water.

The higher the Kow value, the more likely a chemical is to accumulate in lipid-rich tissue, such as adipose tissue in animals. This is because the chemical has a greater affinity for lipids than for water, and lipid-rich tissues provide a larger reservoir for storage of lipophilic chemicals.

Kow can be used to estimate the bioaccumulation potential of a chemical and its potential for biomagnification in food chains. Chemicals with high Kow values are more likely to accumulate in the fatty tissues of animals and biomagnify up the food chain, potentially causing adverse effects in top predators.

Other factors such as the octanol-air partition coefficient (Koa), the soil-organic carbon partition coefficient (Koc), and the dissolved organic carbon partition coefficient (Kd) may also be relevant for estimating the fate and transport of toxic compounds, depending on the specific environmental compartment of interest. However, for estimating the potential for accumulation in lipid-rich tissue, Kow is typically the most relevant parameter.

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when titrated with a 0.1191 m solution of sodium hydroxide, a 58.00 ml solution of an unknown polyprotic acid required 20.05 ml to reach the first equivalence point. calculate the molar concentration of the unknown acid.

Answers

The molar concentration of the unknown polyprotic acid is 0.041 M.

To calculate the molar concentration of the unknown polyprotic acid, the equation is:

Molarity of acid x Volume of acid = Molarity of base x Volume of base

At the first equivalence point, the number of moles of base (sodium hydroxide NaOH) is equal to the number of moles of acid in the solution.

Therefore, we can write:

Molarity of acid x 0.05800 L = 0.1191 M x 0.02005 L

Solving for the molarity of acid:

Molarity of acid = (0.1191 M x 0.02005 L) / 0.05800 L

Molarity of acid = 0.041 M

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what is the molarity of a hno3 solution prepared by adding 164.8 ml of water to 350.0 ml of 12.3 m hno3?

Answers

The molarity of an HNO₃ solution is 8.367 M when the solution is prepared by adding 164.8 ml of water to 350.0 ml of 12.3 M  HNO₃.

The number of moles of solute dissolved in one liter of solution is the molarity of a solution and it is denoted by M. In the problem, we are diluting the original HNO₃ solution with the addition of some water so the final volume is given as :

= 164.8 mL + 350.0mL

= 514.8 ml

Therefore, the final volume is 514.8 ml.

We can find how much we are diluting the solution by:

= 514.8 ml / 350.0ml

= 1.470 times

When the original concentration was 12.3M, the final concentration will be:

= 12.3m / 1.470

= 8.367 m

Therefore, the molarity of HNO₃ is 36.72M

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Which of the following statements best explains what happens if you increase the temperature of a gas inside a glass container?
A. As you increase the temperature of the gas the container itself will expand, causing the volume to increase. The larger volume of the
container means the gas particles have more space in which to move, which reduces the number of collisions. Fewer collisions results in a
lower pressure of the gas
B. If the container is rigid the volume of the container does not change (that is, the volume is constant). Since the volume of the gas does not
O change, Boyle's Laww tells us that the pressure of the gas will also not change because the equation P1V1=PZV2 does not depend on
temperature
C. As the temperature increases you are increasing the kinetic energy of the gas particles. As the gas particles move faster, they are more
Sikely to collide with the walls of the container. This increase in the number of collisions causes an increase in the pressure of the gas.
D. As you increase the temperature of the gas, the gas particles expand in size. Since each particle now occupies a larger volume, this means
the total gas also occupies a larger volume, which in tum increases the pressure.

Answers

Answer:D. As you increase the temperature of the gas, the gas particles expand in size. Since each particle now occupies a larger volume, this means the total gas also occupies a larger volume, which in tum increases the pressure.

Explanation:

which of the following is a weak acid?select one:a.chloric acid, hclo3b.hydrocyanic acid, hcnc.sulfuric acid, h2so4d.nitric acid, hno3e.hydrochloric acid, hcl

Answers

The weak acid among the options given is hydrocyanic acid, HCn.

The weak acid among these options is hydrocyanic acid, HCN. The other options, chloric acid (HClO3), sulfuric acid (H2SO4), nitric acid (HNO3), and hydrochloric acid (HCl), are all considered strong acids.

a. Chloric acid, HClO3
b. Hydrocyanic acid, HCN
c. Sulfuric acid, H2SO4
d. Nitric acid, HNO3
e. Hydrochloric acid, HCl

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How many kilojoules of heat are produced when 34. 0 g of Fe2O3 reacts with an excess of

CO according to the following reaction?

Answers

The heat released by the reaction is approximately 271.9 kJ.

The balanced chemical equation for the reaction is:

Fe₂O₃ + 3CO → 2Fe + 3CO₂

From the equation, we see that 1 mole of Fe₂O₃ reacts with 3 moles of CO, producing 2 moles of Fe and 3 moles of CO₂.

To determine the amount of heat released by the reaction, we need to use the enthalpy of formation values for the reactants and products. Assuming standard conditions, we can use the following values:

ΔHf°(Fe₂O₃ ) = -824.2 kJ/mol

ΔHf°(CO) = -110.5 kJ/mol

ΔHf°(Fe) = 0 kJ/mol

ΔHf°(CO₂) = -393.5 kJ/mol

Using these values and the stoichiometry of the reaction, we can calculate the heat released by the reaction to be:

ΔH°rxn = (2 mol Fe × 0 kJ/mol) + (3 mol CO2 × -393.5 kJ/mol) - (1 mol Fe₂O₃  × -824.2 kJ/mol) - (3 mol CO × -110.5 kJ/mol)

ΔH°rxn = -1139.8 kJ/mol

To calculate the heat released for 34.0 g of Fe₂O₃ , we need to convert the mass of Fe₂O₃  to moles, and then multiply by the heat released per mole:

34.0 g Fe₂O₃  × (1 mol Fe₂O₃ /159.69 g) × (-1139.8 kJ/mol) = -271.9 kJ

As a result, the heat produced by the reaction is roughly 271.9 kJ.


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how many stereocenters does sucrose, also known as table sugar, have?

Answers

Sucrose, also known as table sugar, has a total of 16 stereocenters.

Sucrose is a disaccharide made up of glucose and fructose units, which are joined by a glycosidic bond. Each glucose and fructose unit has four stereocenters, making a total of 8 stereocenters in each unit.

Therefore, sucrose has a total of 16 stereocenters.


It is important to note that sucrose does not exhibit any optical activity, despite the presence of multiple stereocenters, because the molecule has a plane of symmetry that bisects the glycosidic bond, which leads to the cancellation of the optical activity of the stereocenters.


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What is the pH of a solution with a [OH-] of 4.1 x 10-3 M?

Answers

The pH of the solution is 11.61.

We know that the concentration of hydroxide ions and the concentration of hydrogen ions in any aqueous solution are related by the equation:

[tex][OH-] * [H+] = 1.0 *10^-14[/tex]

Taking the negative logarithm of both sides of this equation, we get:

[tex]-pOH + pH = 14.00[/tex]

where pOH is the negative logarithm of the hydroxide ion concentration, and pH is the negative logarithm of the hydrogen ion concentration.

Substituting the given value of [OH-] into the above equation, we can calculate the pOH:

[tex][OH-] = 4.1 x 10^-3 M\\pOH = -log[OH-] = -log(4.1 * 10^-3) = 2.39[/tex]

Using the relationship between pH and pOH, we can then calculate the pH of the solution:

pH = 14.00 - pOH = 14.00 - 2.39 = 11.61

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- Describe the relationship between a chemical

reaction's equilibrium and an inflated balloon

when pressure is increased for both

Answers

The relationship between a chemical reaction's equilibrium and an inflated balloon when pressure is increased is that, in both cases, the system will try to balance the pressure by shifting to the side with fewer moles of gas.

In a chemical reaction, the equilibrium state is achieved when the rates of the forward and reverse reactions are equal. At this point, the concentrations of the reactants and products remain constant, and there is no further change in the composition of the system. The equilibrium constant (K) is a measure of the extent to which the reaction has proceeded towards the products or the reactants.

When pressure is increased in a system at equilibrium, the system will try to balance the pressure by shifting to the side with fewer moles of gas. This is known as Le Chatelier's principle. For example, if the reaction involves the production of gas molecules, such as in the reaction of calcium carbonate with hydrochloric acid:

[tex]CaCO3(s) + 2HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)[/tex]

Similarly, when an inflated balloon is subjected to an increased pressure, the balloon will try to balance the pressure by decreasing its volume. This is because the pressure inside the balloon is higher than the pressure outside, and the balloon will try to reach equilibrium by decreasing its volume to reduce the pressure.

Therefore, both in a chemical reaction's equilibrium and an inflated balloon, the system will respond to an increase in pressure by shifting to the side with fewer moles of gas to balance the pressure.

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. a 750 g copper calorimeter can containing 200 g of water is in equilibrium at a temperature 20 c. one places 30 g of ice at 0c in the calorimeter and encloses the latter with a heatinsulating shield. when all the ice has melted and equilibrium has been reached a) what will be the temperature of the water? the specific heat of copper is 0.418 j/(deg g) and the specific heat of water is 4.18 j/(deg g). ice has a heat of fusion 333 j/g, i.e. its requires 333 j of heat to convert 1g of ice to water at 0 c. b) how much work (in j) must be supplied to the system (e.g. by stirring) to restore all the water to 20 c?

Answers

Therefore, the final equilibrium temperature of the water is 13.9°C. Therefore, the work required is 14686 J.

a) First, we need to calculate the heat absorbed by the ice to melt it, and then the heat released by the water and calorimeter to lower their temperature to the final equilibrium temperature.

Heat absorbed by ice to melt = (30 g) x (333 J/g) = 9990 J

Heat released by water and calorimeter = (750 g + 200 g) x (4.18 J/(g·°C)) x (20°C - T)

where T is the final equilibrium temperature.

9990 J = (750 g + 200 g) x (4.18 J/(g·°C)) x (20°C - T)

T = 13.9°C

b) To restore all the water to 20°C, we need to add heat to the system equal to the heat capacity of the water and calorimeter multiplied by the change in temperature:

Heat required = (750 g + 200 g) x (4.18 J/(g·°C)) x (20°C - 13.9°C)

Heat required = 14686 J

This is the amount of heat we need to supply to the system.

ΔU = Q - W

Assuming that the internal energy of the system is constant (i.e. ΔU = 0), we can rearrange the equation to solve for W:

W = Q

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a(n) ____ is an element’s numeric position within an array.

Answers

According to the question, a(n) index is an element’s numeric position within an array.

What is numeric position?

Numeric position is a system of referencing locations using numerical coordinates. It is often used in geography, engineering, and mathematics. Numeric position is most commonly expressed using two or three numbers, which identify the location in a two- or three-dimensional space, respectively. The first number usually represents the location on a horizontal plane, while the second number represents the location on a vertical plane. In some cases, a third number may be used to represent the location on a depth plane.

An array index is the numeric position of an element within an array. It is used to identify and access elements within an array. The first element in an array has an index of 0, the second element has an index of 1, and so on.

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