A reaction has a specific rate constant of 0.002/hr at 27 C. The initial concentration of 10M will have decreased to 10% of the original value at the end of 230 hrs at 47 C. What is the rate constant at 47 C?

Answers

Answer 1

The rate constant at 47°C is 0.0146/hr.

First, we need to find the activation energy (Ea). We know that after 230 hours at 47°C, the concentration has decreased to 10% of its original value (1M). Now, we can plug this value into the Arrhenius equation to find the rate constant at 47°C. However, we do not have enough information to calculate the activation energy (Ea) or the pre-exponential factor (A) in the equation. Therefore, it is not possible to accurately determine the rate constant at 47°C using the given information alone.

We can use the Arrhenius equation to find the rate constant at 47 C, given the rate constant at 27 C:
k2 = k1 * e^[(Ea/R) * ((1/T2) - (1/T1))]
k2 = k1 * e^[(Ea/R) * ((1/320) - (1/300))]
Now we can plug in the values we know:
k1 = 0.002/hr
T1 = 300 K
T2 = 320 K
k2 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
We still need to find the concentration at the end of 230 hours at 47 C, so we can use the first-order integrated rate law:
ln([A]/[A]0) = -kt

t = ln([A]0/[A]) / k
t = ln(10/100) / k
t = -2.303 / k
t = 230 hours
Now we can plug in the values we know:
[A] = 0.1 [A]0 = 1 M
t = 230 hours
ln(0.1/1) = -k * 230
-2.303 = -k * 230
k = 0.01/23.03
k = 0.000434/hr
Now we can plug in this value for k2 in the Arrhenius equation:
k2 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
0.000434 = 0.002 * e^[(Ea/R) * ((1/320) - (1/300))]
ln(0.000434/0.002) = (Ea/R) * ((1/320) - (1/300))
-1.355 = (Ea/R) * ((1/320) - (1/300))
We can assume that R is constant, so we can solve for Ea:
Ea = (-1.355 * R) / ((1/320) - (1/300))
Ea = 25,620 J/mol
Now we can use this value for Ea to find the rate constant at 47 C:
k2 = k1 * e^[(Ea/R) * ((1/T2) - (1/T1))]
k2 = 0.002 * e^[(25,620 / (8.314 J/mol-K)) * ((1/320) - (1/300))]
k2 = 0.016/hr
Therefore, the rate constant at 47 C is 0.016/hr.

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Related Questions

k3po4 dissolves into ions in water. what ions and how many of each are produced for each formula unit of k3po4?

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When [tex]K_{3}PO_{4}[/tex] dissolves in water, it dissociates into three [tex]K^{+}[/tex] ions and one [tex]PO_{4} ^{3-}[/tex] ion for each formula unit. So, for each formula unit of  [tex]K_{3}PO_{4}[/tex], four ions are produced in total.

What happens when [tex]K _{3}PO_{4}[/tex] dissolved in water?

To determine the ions produced when  [tex]K_{3}PO_{4}[/tex]dissolves into water and how many of each are produced for each formula unit of  [tex]K_{3}PO_{4}[/tex], we need to examine the chemical formula.

[tex]K_{3}PO_{4}[/tex] is potassium phosphate, which consists of 3 potassium (K+) ions and 1 phosphate ([tex]PO_{4} ^{3-}[/tex]) ion. When [tex]K_{3}PO_{4}[/tex]  dissolves in water, it dissociates into its ions.

For each formula unit of  [tex]K_{3}PO_{4}[/tex] , the ions produced are:
- 3 potassium ([tex]K^{+}[/tex]) ions
- 1 phosphate ([tex]PO_{4} ^{3-}[/tex]) ion

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glycogen synthase catalyzes glycogen synthesis. determine whether each example is associated with an increase or decrease in glycogen synthase activity.

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Answer:

1. Phosphorylation by a kinase - decrease

2. Dephosphorylation by a phosphatase - increase

3. Binding of allosteric activator - increase

4. Binding of allosteric inhibitor - decrease

5. Transcriptional upregulation - increase

6. Transcriptional downregulation - decrease

Example 1: The presence of glucose-6-phosphate. This example is associated with an increase in glycogen synthase activity.

Glycogen synthase requires glucose-6-phosphate (G6P) as a substrate in order to catalyze the synthesis of glycogen.

Therefore, the presence of G6P will increase the activity of glycogen synthase, leading to an increase in glycogen synthesis.

Furthermore, G6P is the product of the enzyme glucokinase, which catalyzes the phosphorylation of glucose, so the presence of G6P indicates that glucose is present, and therefore glycogen synthesis can occur.

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he cathode is the electrode at which reduction takes place. match the words in the left column to the appropriate blanks in the sentences on the right. resethelp . oxidation occurs at the ; reduction occurs at the .target 1 of 3target 2 of 3target 3 of 3

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To match the words in the left column to the appropriate blanks in the sentences on the right, we should match oxidation with the anode, and reduction with the cathode.


The cathode is the electrode at which reduction takes place. In the process of a chemical reaction, there are two types of reactions that occur at the electrodes. One of them is oxidation and the other is reduction. Oxidation occurs at the anode, which is the electrode where oxidation takes place. On the other hand, reduction occurs at the cathode, which is the electrode where reduction takes place.


During oxidation, the anode loses electrons and the oxidation state of the species increases. In contrast, during reduction, the cathode gains electrons and the oxidation state of the species decreases. It is important to understand that oxidation and reduction always occur simultaneously in any electrochemical reaction, and they are always happening at the same time, even if they are not apparent.


It is essential to understand the difference between these two reactions to comprehend any electrochemical reaction. Therefore, knowing the cathode is where reduction takes place, and the anode is where oxidation takes place is crucial for understanding the process of electrochemistry.

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What was the practical effect of not having a legal identity

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The inability to exercise their civil and political rights is hampered by a lack of legal identity.

What is legal identity?

Legal identity is described as the fundamental aspects of an individual's identity, such as name, gender, place of birth, and date of birth, which are conferred through registration and the issue of a certificate by an authorized civil registration body following the occurrence of birth.

The individual's identity includes his or her family name, surname, date of birth, gender, and nationality.

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A Z isomer has its highest priority substituents on {{c1::the same side}} of the double bond

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The Correct, a Z isomer has its highest priority substituents on the same side of the double bond. This means that when the substituents are "loaded" onto the molecule from A to Z, they are on the same side of the double bond.

The important to note that the opposite is true for the E isomer, where the highest priority substituents are on opposite sides of the double bond. A Z isomer has its highest priority substituents on the same side of the double bond. This means that the groups with the highest atomic number (or highest priority) are located on the same side of the molecule, resulting in the Z configuration.

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How many moles are in 1.25 x 1021 molecules of sucrose?
How many moles of aspartame are present in 197 g of aspartame, C14H18N2O5?

Answers

2.08x10^-3 moles Sucrose

6.69x10^-1 moles Aspartame

Take 1.25x10^21 then divide by Avogadro's number (6.02x10^23) and you're left with 0.00208 moles Sucrose. Then use your significant figures (3 in this case) and put it into scientific notation. 2.08x10^-3 moles.

Take the 197g of Aspartame, then divide by the molar mass of it (294.34g), and you're left with 0.669 moles. Use significant figures (3 again) and put into scientific notation, and you're left with 6.69x10^-1 moles.

Phosphorus burns in air to produce a phosphorus oxide (P4O10) in 4​P + 5O2 --> P4O10.
If 0.489 mol of phosphorus burns, what mass in grams of oxygen is used?

Answers

Using the chemical formulas of the reactants and products, a balanced chemical equation represents a chemical reaction. It displays the proportions of each item contributing to the reaction.

The balanced chemical formula for phosphorus combustion in oxygen is:

[tex]4P + 5O_2 --- > P_4O_1_0[/tex]

According to the equation, 4 moles of phosphorus and 5 moles of oxygen combine to form 1 mole of [tex]P_4O_1_0[/tex].

As a result, we require: for 0.489 mol of phosphorus.

0.611 mol [tex]O_2[/tex] is equal to 0.489 mol P x (5 mol [tex]O_2[/tex] / 4 mol P).

Now we can convert the amount of moles to grams using the molar mass of oxygen (O2):

19.6 g from 0.611 mol O2 times 32.00 g/mol.

As a result, when 0.489 moles of phosphorus are burned, 19.6 grams of oxygen are used.

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The term mole concept is used here to determine the mass of oxygen. The mass of oxygen produced when 0.489 mol of phosphorus burns is 19.56 g.

One mole of a substance is defined as that quantity of it which contains as many entities as there are atoms exactly in 12 g of carbon - 12. The formula used to calculate the number of moles is:

Number of moles = Given mass / Molar mass

Here 4 moles of 'P' burns in the presence of 5 moles of 'O'.

So 0.489 moles of 'P' burn in, 5/4 × 0.489 = 0.61 moles 'O'

Molar mass of oxygen = 32 g / mol

Mass of 'O' =  0.61  × 32 = 19.56 g

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A compound was found to have a Ka value of 1.2 after calculation. Identify this compound
A weak base
B strong base
C string acid
D weak acid

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The given Ka value of 1.2 indicates that the compound is a weak acid.

What is Ka value ?

Ka value is the acid dissociation constant which represents the strength of an acid in solution.

The strength of an acid in solution is represented by the acid dissociation constant, or Ka. A stronger acid is one with a higher Ka value, whereas a weaker acid is one with a lower Ka value. A weak acid is indicated by a comparatively low Ka value of 1.2.

Therefore, the correct option is D weak acid.

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Write an equation explaining why H2 gas is evolved when HCl is added during the work-up.

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When HCl is added during the work-up, it reacts with any remaining metal present in the reaction mixture, producing hydrogen gas (H2 gas). The equation for this reaction is:

2HCl + 2M → 2MCl + H2

When HCl is added during the work-up, it reacts with a metal, such as magnesium (Mg), to produce H₂ gas. The equation for this reaction is:

Mg (s) + 2 HCl (aq) → MgCl₂ (aq) + H₂ (g)


Where M represents the metal present in the reaction mixture. This reaction is an example of a single displacement reaction, in which the more reactive hydrogen replaces the less reactive metal in the compound. As a result, H2 gas is evolved during the work-up process.

In this equation, magnesium reacts with hydrochloric acid (HCl) to form magnesium chloride (MgCl₂) and hydrogen gas (H₂). The hydrogen gas is evolved as a result of this reaction.

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ultiple qualitative tests can be used to determine the properties of carbohydrate samples. identify the test that provides the given information about carbohydrates. identify reducing sugars choose... distinguish between monosaccharides and disaccharides choose... distinguish between a pentose and a hexose choose... determine whether starch is present

Answers

1. To identify reducing sugars, use the Benedict's test.
2. To distinguish between monosaccharides and disaccharides, use the Barfoed's test.
3. To distinguish between a pentose and a hexose, use the Seliwanoff's test.
4. To determine whether starch is present, use the Iodine test.

1. Benedict's test: This test detects the presence of reducing sugars, which have free aldehyde or ketone groups. When heated with Benedict's reagent, reducing sugars react and produce a color change ranging from green to red-orange, depending on the sugar concentration.
2. Barfoed's test: This test differentiates monosaccharides from disaccharides. When heated with Barfoed's reagent, monosaccharides react quickly and form a red precipitate, while disaccharides react more slowly or not at all.
3. Seliwanoff's test: This test is used to distinguish between pentoses and hexoses. When heated with Seliwanoff's reagent, pentoses produce a red color, while hexoses produce a yellow color.
4. Iodine test: This test detects the presence of starch. When iodine solution is added to a sample containing starch, the solution turns a blue-black color.
By using the Benedict's, Barfoed's, Seliwanoff's, and Iodine tests, you can identify reducing sugars, distinguish between monosaccharides and disaccharides, differentiate between pentoses and hexoses, and determine the presence of starch in carbohydrate samples.

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use th tabulated electrode potentials to calculate delta g for the reactionwhat is the formula for the relationship between Ecell and G

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∆ G in thermodynamics denotes the change in Gibbs Free energy of a chemical reaction. Gibbs free energy is the amount of total energy present in a thermodynamic system that is used in doing work.

Delta G = -nFEcell, where n is the number of electrons transferred in the reaction, F is the Faraday constant (96,485 C/mol), and Ecell is the cell potential calculated from the difference between the standard reduction potentials of the half-reactions involved in the reaction.

The formula for the relationship between Ecell and G is: delta G = -nFEcell, which relates the free energy change of a reaction to the cell potential and the number of electrons transferred in the reaction. This formula is based on the concept that the free energy change of a reaction is proportional to the work done by the electrical energy produced by the reaction.

To find ΔG for the reaction, follow these steps:

1. Determine the standard reduction potentials for the cathode and anode from the provided table.
2. Calculate the standard cell potential, E°cell, using the equation: E°cell = E°cathode - E°anode
3. Determine the number of moles of electrons transferred, n, in the redox reaction.
4. Use the formula ΔG = -nFE°cell to find the change in Gibbs free energy for the reaction.


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what is the stereochemical outcome for a cis alkene in a halogenation reaction?

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When a cis alkene undergoes halogenation, the halogen atoms add to the same face of the double bond, resulting in the formation of a chiral compound.

When a cis alkene undergoes halogenation, the halogen atoms add to the same face of the double bond, resulting in the formation of a chiral compound. In a halogenation reaction, the halogen molecule (X₂) is polarized by the addition of a Lewis acid catalyst, such as FeBr₃, forming a reactive electrophilic halonium ion (X⁺). This halonium ion can then be attacked by a nucleophile, such as a halide ion, which results in the formation of a bridged halonium ion intermediate. For a cis alkene, the two halogen atoms add to the same face of the double bond, resulting in the formation of a bridged halonium ion with a non-planar arrangement of atoms. The subsequent attack by the nucleophile on one face of the intermediate results in the formation of a chiral compound, as the two halogen substituents are on the same side of the molecule.

In conclusion, the stereochemical outcome for a cis alkene in a halogenation reaction is the formation of a chiral compound due to the same addition of the halogen atoms to the same face of the double bond.

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What is the relation between electron rich and electron deficient species?

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Electron rich species are those that have an excess of electrons in their outer shell. These species are typically negatively charged and have a high electron density.


The relationship between electron rich and electron deficient species is one of attraction and repulsion. Electron rich species are attracted to electron deficient species because they have a surplus of electrons that they can donate to the electron deficient species. This is known as a nucleophilic reaction.

                                             On the other hand, electron deficient species are those that have a shortage of electrons in their outer shell. These species are typically positively charged and have a low electron density.


On the other hand, electron deficient species are attracted to electron rich species because they have a shortage of electrons that they can accept from the electron rich species. This is known as an electrophilic reaction.

Overall, the relationship between electron rich and electron deficient species is one of balance. They work together to maintain a stable electronic configuration and to achieve chemical equilibrium.

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you are performing a titration of 25.00 ml of 0.0100 m sn2 in 1 m hcl with 0.0200 m fe3 resulting in the formation of sn4 and fe2 . a pt indicator electrode and a saturated calomel electrode (sce) reference electrode are used to monitor the titration. write the balanced titration reaction.

Answers

The balanced titration reaction for the given scenario is:
Sn2+ (aq) + 2Fe3+ (aq) + 2H2O (l) → Sn4+ (aq) + 2Fe2+ (aq) + 4H+ (aq)

In this reaction, Sn2+ from the tin solution reacts with 2 Fe3+ from the iron solution and 2 H2O molecules. This results in the formation of Sn4+ ions, 2 Fe2+ ions, and 4 H+ ions. The indicator electrode and SCE reference electrode are used to monitor the potential difference between the two electrodes during the titration, which helps to determine the endpoint of the reaction and the concentration of the tin solution. A solution of the iron solution is used to titrate the tin solution to the endpoint.
Now, let's write the balanced titration reaction:
Step 1: Write the half-reactions for the species involved in the redox reaction.
Sn2+ → Sn4+ + 2e- (Oxidation half-reaction)
Fe3+ + e- → Fe2+ (Reduction half-reaction)
Step 2: Balance the electrons in both half-reactions.
To balance the electrons, multiply the reduction half-reaction by 2 to match the number of electrons in the oxidation half-reaction:
2(Sn2+ → Sn4+ + 2e-)
2(Fe3+ + e- → Fe2+)
Step 3: Combine the half-reactions to form the balanced redox reaction.
2Sn2+ + 2Fe3+ → 2Sn4+ + 2Fe2+
So, the balanced titration reaction is:
2Sn2+ + 2Fe3+ → 2Sn4+ + 2Fe2+

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What changes have occurred in the last 20-50 years in the temperate deciduous forest in the united kingdom

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There have been several changes that have occurred in the temperate deciduous forest of the United Kingdom over the last 20-50 years. Some of these changes include:

1. Increase in temperature: The average temperature in the UK has increased over the last few decades, which has resulted in changes in the timing of seasonal events in the forest. For example, the leafing-out of trees has advanced by several days.

2. Changes in vegetation: There has been a shift in the composition of the forest towards more shade-tolerant species, which has led to changes in the understory vegetation.

3. Changes in wildlife: Changes in the forest structure and composition have led to changes in the wildlife that inhabit the forest. For example, some bird species have increased in abundance, while others have declined.

4. Increase in invasive species: The UK has seen an increase in invasive plant species, such as Japanese knotweed, which can outcompete native species and alter the composition of the forest.

5. Changes in land use: Forests in the UK are increasingly being managed for multiple uses, such as recreation and timber production. This has led to changes in forest structure and composition.

calculate the volume of 5.00 mol of helium at 120.°c and 1520 mm hg.

Answers

The volume of 5.00 mol of helium at 120°C and 1520 mm Hg is 102.13 L.

To calculate the volume of 5.00 mol of helium at 120°C and 1520 mm Hg, we will use the ideal gas law equation PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin. First, we need to convert the given temperature of 120°C to Kelvin by adding 273.15 to it, which gives us 393.15 K.Next, we need to convert the given pressure of 1520 mm Hg to atm by dividing it by 760, which gives us 2 atm. The gas constant R is 0.0821 L.atm/mol.K.Now, we can substitute these values into the ideal gas law equation and solve for V:
V = nRT/P
V = 5.00 mol x 0.0821 L.atm/mol.K x 393.15 K/2 atm
V = 102.13 LTherefore, the volume of 5.00 mol of helium at 120°C and 1520 mm Hg is 102.13 L.

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The Lewis Structure for the cyanide ion is shown. The formal charge on the C atom is equal to ______ and the formal charge on the N atom is equal to ________.

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The Lewis Structure for the cyanide ion is shown. The formal charge on the C atom is equal to 0 and the formal charge on the N atom is equal to -1.

In order to determine the formal charges on the C and N atoms in the cyanide ion, we must first draw its Lewis structure.
Draw the Lewis structure for the cyanide ion (CN-).
C is triple bonded to N, with an additional lone pair of electrons on N. Since it is an ion, there is a negative charge on the molecule.
Calculate the formal charge on the C atom.
The formula for formal charge is: (number of valence electrons) - (number of lone pair electrons) - 0.5*(number of bonding electrons). Carbon has 4 valence electrons, no lone pair electrons, and 6 bonding electrons (from the triple bond). Therefore, the formal charge on the C atom is 4 - 0 - 0.5*6 = 0.
Calculate the formal charge on the N atom.
Nitrogen has 5 valence electrons, 2 lone pair electrons, and 6 bonding electrons (from the triple bond). The formal charge on the N atom is 5 - 2 - 0.5*6 = -1.

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Rank the following ions in order of increasing first ionization energy: O²⁻, Mg²⁺, F⁻, Na⁺

Answers

According to first ionization energy, the ions are as follows:
O²⁻ < F⁻ < Na⁺ < Mg²⁺

This is because as you move from left to right across a period in the periodic table, the atomic radius decreases while the nuclear charge increases. As a result, it takes more energy to remove an electron from a smaller atom with a greater nuclear charge. Therefore, the ion with the smallest atomic radius and highest nuclear charge (Mg2+) will have the highest first ionization energy, while the ion with the largest atomic radius and lowest nuclear charge (O2) will have the lowest first ionization energy.

Ionization energy increases as you move from left to right across a period and decreases as you move down a group in the periodic table. Ions with the same electron configurations will have different ionization energies based on their effective nuclear charge, which increases with atomic number.

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Why do aldehydes more readily form hydrates than ketones?

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Aldehydes more readily form hydrates than ketones due to the differences in their molecular structure and the relative electron-withdrawing effect of the substituents attached to the carbonyl group.

In both aldehydes and ketones, the carbonyl group consists of a carbon atom double-bonded to an oxygen atom. In aldehydes, one of the groups attached to the carbonyl carbon is a hydrogen atom, while in ketones, both groups are alkyl or aryl groups. The presence of the hydrogen atom in aldehydes makes the carbonyl carbon more electrophilic, meaning it is more prone to attracting nucleophiles, such as water molecules, to form hydrates. In ketones, the alkyl or aryl groups exhibit an electron-donating effect, which reduces the electrophilicity of the carbonyl carbon, making them less likely to form hydrates as compared to aldehydes.

Additionally, aldehydes are typically less sterically hindered than ketones, which allows water molecules to access and react with the carbonyl group more easily. The increased steric hindrance in ketones, due to the presence of larger substituents, creates a barrier that reduces the likelihood of hydrate formation. In summary, aldehydes more readily form hydrates than ketones because their carbonyl carbon is more electrophilic and less sterically hindered, making it easier for water molecules to react and form hydrates.

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which of the following is isomeric with ch3 ch2 cho ? a ch3 ch2 ch2 ch3 b ch3 ch2 ch2 oh c ch3 coch3 d ch3 cooh e ch3 ch2 ch2 nh2

Answers

CH3COCH3 is the compound that is isomeric with CH3CH2CHO.

An isomer is a molecule with the same molecular formula but a different structural arrangement of atoms.

In the context of your question, you are asked to determine which compound is isomeric with CH3CH2CHO.

The molecular formula of CH3CH2CHO is C3H6O. Now, let's analyze the given options:

a) CH3CH2CH2CH3: This has the molecular formula C4H10, which is not the same as C3H6O. Therefore, it is not isomeric.

b) CH3CH2CH2OH: This has the molecular formula C3H8O, which is not the same as C3H6O. Thus, it is not isomeric.

c) CH3COCH3: This has the molecular formula C3H6O, which is the same as that of CH3CH2CHO. The structural arrangement is different, so the isomeric compound is CH3CH2CHO.

d) CH3COOH: This has the molecular formula C2H4O2, which is not the same as C3H6O. It is not isomeric.

e) CH3CH2CH2NH2: This has the molecular formula C3H9N, which is not the same as C3H6O. Therefore, it is not isomeric.

In conclusion, option c) CH3COCH3 is the compound that is isomeric with CH3CH2CHO, as it has the same molecular formula but a different structural arrangement of atoms.

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Which sentence from the section "Blue Eyes Are Recessive" explains why some people have blue eyes? A The genes for eye color produce proteins. B The proteins give the eye pigment, or color. C When the alleles for eye color are both recessive, the protein is turned off. D The sky has no color, yet it looks blue.

Answers

When the alleles for eye color are both recessive, the protein is turned off. Therefore, option (C) is correct.

This means that if a person inherits two copies of the recessive allele for blue eyes from both parents, their body will not produce the proteins that give color to the eyes, resulting in blue eyes.

In contrast, if a person inherits at least one dominant allele for brown eyes, their body will produce the proteins, resulting in brown or other darker eye colors.

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the pKa of EtOCONH2 (ethyl carbamate) is?

Answers

The pKa of EtOCONH2 (ethyl carbamate) is approximately 0.2. The pKa of EtOCONH2 (ethyl carbamate) is 0.2, which reflects its weak acidity due to the amide nitrogen's hydrogen's ability to dissociate and form a resonance-stabilized conjugate base.


1. pKa refers to the acid dissociation constant, which measures the acidity of a compound by quantifying how easily a proton (H+) can be released from the compound in a solution.
2. EtOCONH2, or ethyl carbamate, is a compound with the molecular formula C3H7NO2. It has both an ester group (EtO-) and an amide group (CONH2).
3. The acidic proton in ethyl carbamate is the amide nitrogen's hydrogen (NH2). When this proton dissociates, it forms a conjugate base, which is stabilized by resonance with the carbonyl group (C=O).
4. The pKa value of 0.2 for ethyl carbamate indicates that it is a weak acid, as lower pKa values correspond to stronger acids.

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The electron transport chain takes electrons from ___ and ultimately uses them to reduce ___ into ____

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The electron transport chain takes electrons from NADH and FADH2 and ultimately uses them to reduce oxygen into water.

The electron transport chain is a series of proteins and enzymes located in the inner mitochondrial membrane that plays a key role in oxidative phosphorylation, the process by which ATP is synthesized from ADP and inorganic phosphate.

The electron transport chain receives electrons from NADH and FADH2, which are produced during the breakdown of glucose and other nutrients, and uses them to pump protons from the mitochondrial matrix to the intermembrane space, creating an electrochemical gradient. This gradient is used by ATP synthase to drive the synthesis of ATP.

The final electron acceptor in the electron transport chain is oxygen, which is reduced to water by the transfer of electrons and protons. This process generates a large amount of energy that is used to power cellular processes.

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Why are internal standards commonly used forGC?

Answers

They help to control for any variation that may occur during sample preparation and analysis. This can be due to factors such as changes in temperature, pressure, or humidity.

Internal standards are compounds that are added to a sample prior to GC analysis. These standards are chosen for their similarity to the analyte of interest and are used to correct for any variability in sample preparation, injection, and analysis. Internal standards provide a reliable way to ensure the accuracy and precision of GC results.


There are several reasons why internal standards are commonly used in GC analysis. Firstly, they help to control for any variation that may occur during sample preparation and analysis. This can be due to factors such as changes in temperature, pressure, or humidity. By adding an internal standard to the sample, it is possible to ensure that any changes in the sample are reflected in the standard. This allows for more accurate and precise measurements of the analyte of interest.


Secondly, internal standards help to correct for any losses or gains that may occur during sample preparation and injection. This can be due to factors such as sample adsorption onto the injection port or column, or changes in the sample volume during injection. By adding an internal standard, it is possible to calculate the amount of analyte that was lost or gained during sample preparation and injection. This allows for more accurate and precise measurements of the analyte of interest.


Finally, internal standards can also be used to monitor the performance of the GC system over time. By analyzing the same internal standard over a period of time, it is possible to detect any changes in the system performance. This can include changes in column performance, injector performance, or detector performance. By monitoring the internal standard, it is possible to ensure that the GC system is operating within acceptable limits and that the results obtained are reliable and accurate.

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ompletely decomposes, producing no2(g) and no(g). calculate the final pressure of the gas mixture, assuming that the container volume does not change.

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The balanced chemical equation for the reaction. In this case, we don't have the complete equation, but let's assume it is a decomposition reaction involving a compound X, producing [tax]N_{2} [/tax] and[tax]N_{ g}[/tax] The balanced equation should look like this the problem can be solved using the ideal gas law equation PV=north where P is pressure, V is volume, n is number of moles of gas, R is the gas constant and T is temperature in Kelvin.

The initial pressure of [tax]N_{23}g[/tax] is given as 0.270 atm. When the absolute temperature of [tax]N_ {23}g [/tax]is tripled, it completely decomposes into [tax]N_{2}g[/tax] and [tax]N_{O} g[/tax]. Since the volume of the container does not change, we can assume that the number of moles of gas remains constant. Let’s assume that there are n moles of [tax]N_{23} g[/tex] initially in the container. Then after complete decomposition, there will be n moles of[tax]N_ {2} g[/tax] and n moles of [tax]N_ {g}[/tax]. Since we know that P1V1/T1 = P2V2/T2 for an ideal gas, we can use this equation to calculate the final pressure of the gas mixture. Let’s assume that T1 is the initial temperature and T2 is the final temperature after complete decomposition. Then we have P1V/nor = T1 P2V/nor = T2 Since V/nor is constant for a given amount of gas at a constant temperature and pressure, we can write: P1/T1 = P2/T2 Substituting values 0.270 atm / T1 = P2 / (3 * T P2 = 0.810 atm Therefore, the final pressure of the gas mixture after complete decomposition is 0.810 atm.

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UPLC has better performance than the HPLC. What is the mechanism?

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The mechanism behind UPLC's better performance compared to HPLC lies in the use of smaller particle sizes in the columns and the ability to operate at higher pressures. These factors contribute to improved resolution, speed, and sensitivity in UPLC

UPLC (Ultra Performance Liquid Chromatography) has better performance than HPLC (High Performance Liquid Chromatography) primarily due to its increased resolution, speed, and sensitivity. This improved performance is a result of the use of smaller particle sizes in UPLC columns, leading to a higher efficiency in separation.

In UPLC, the column particle size is typically around 1.7 to 2 µm, whereas HPLC columns have particle sizes around 3 to 5 µm. The smaller particles in UPLC columns create a larger surface area for interactions between the sample molecules and the stationary phase, resulting in better separation of analytes.

Additionally, UPLC operates at higher pressure (up to 15,000 psi) compared to HPLC (up to 6,000 psi). The increased pressure allows for faster flow rates, which in turn reduces analysis time without compromising the separation quality. Lastly, UPLC's increased sensitivity means lower limits of detection and quantification, making it ideal for analyzing trace-level components in complex samples.

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A tablet containing 500.0 mg of aspirin (acetylsalicylic acid or HC9H7O4) was dissolved in enough water to make 100 mL of solution. Given that Ka = 3.0 × 10

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The concentration of the aspirin solution is approximately 0.0277 M.


Convert the mass of aspirin to moles:
The molecular weight of acetylsalicylic acid (HC9H7O4) is approximately 180.16 g/mol. To find the moles of aspirin, use the following formula:
moles = mass (mg) / (molecular weight * 1000)
moles = 500.0 mg / (180.16 g/mol * 1000)
moles ≈ 0.00277 mol
Find the concentration of the solution:
To get the concentration, divide the moles of aspirin by the volume of the solution (in liters).
concentration = moles / volume
concentration = 0.00277 mol / 0.1 L
concentration ≈ 0.0277 M
Now, we have the concentration of the aspirin solution, which is approximately 0.0277 M.

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log K = amount on one side. (when calculating K). how to get rid of K?

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To get rid of K in the equation log K = amount on one side, you can use the property of logarithms which states that if log a = b, then a = 10^b.

In this case, if you apply this property to the equation, you will get K = 10^(amount on one side).

This will allow you to calculate the value of K in a detailed manner.


You can follow these steps:

1. Repeat the question: We want to solve for K when given log K = amount on one side.
2. Use the properties of logarithms to solve for K: To get rid of the log and isolate K, we can use the inverse of the logarithm function, which is the exponentiation function with the base of the logarithm.
3. Apply exponentiation: If you have log K = amount on one side, you can rewrite this as an exponential equation. Assuming it's a common logarithm (base 10), the equation becomes 10^(amount on one side) = K.

Now, you have isolated K and removed the log from the equation.

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What happens if any of the dyes in the ink are insoluble (won't dissolve)?

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If any of the dyes used in the ink are insoluble, they will not dissolve in the liquid components of the ink and will remain as separate particles.

These particles will not be evenly distributed throughout the ink and can cause the ink to appear blotchy or streaky when printed on paper. Additionally, these insoluble particles can clog the print nozzle, leading to poor print quality and frequent clogs.

To prevent this, manufacturers must use dyes that are soluble in the liquid components of the ink, as well as ensure that the dyes are of a high enough quality to ensure uniform color and good print quality.

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R stereocenters have a substituent priority that rotates {{c1::clockwise}}

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When looking at R stereocenters, it is important to consider the priority of substituents. This is because the priority of substituents can affect the direction of rotation.

Specifically, if the highest priority substituent is oriented to the right (as determined by the Cahn-Ingold-Prelog priority rules), the rotation will be clockwise, or R. This is because the molecule will rotate in a direction that allows the highest priority substituent to move away from the viewer.

On the other hand, if the highest priority substituent is oriented to the left, the rotation will be counterclockwise, or S. Understanding the priority of substituents is crucial in determining the stereochemistry of a molecule.


R stereocenters have a substituent priority that rotates clockwise. In order to determine this, follow these steps:

1. Assign priority to the substituents around the stereocenter based on their atomic number (higher atomic number gets higher priority).
2. Temporarily orient the molecule so that the lowest priority substituent (usually hydrogen) is pointing away from you.
3. Observe the order of the remaining substituents in terms of priority.
4. If the order of the remaining substituents (highest to lowest) rotates clockwise, then the stereocenter is labeled as R; if it rotates counterclockwise, it is labeled as S.

By following this procedure, you can accurately identify R and S stereocenters in a chiral molecule.

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