Describe how to prepare 100mL of 0.150 acetate buffer at pH=5 from sodium acetate trihydrate and 0.200M HCl

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Answers

Answer 1

The acetate buffer can be prepared by following these steps Calculate the number of moles of NaC2H3O2 · 3H2O required to produce a solution of 100 mL of 0.150 M.

The molar mass of NaC2H3O2 · 3H2O is 136 g/mol, and therefore the number of moles required can be calculated as Moles = Molarity × Volume = 0.150 M × 0.100 L = 0.015 molStep 2: Calculate the mass of NaC2H3O2 · 3H2O required. The mass can be calculated using the following formula:Mass = Moles × Molar Mass = 0.015 mol × 136 g/mol = 2.04 g NaC2H3O2 · 3H2OStep 3: Weigh 2.04 g of NaC2H3O2 · 3H2O and dissolve it in a small volume of water, and then transfer the solution to a 100 mL volumetric flask.

Add distilled water to the volumetric flask to bring the volume up to 100 mL. This results in a 0.150 M solution of sodium acetate.Step 4: To adjust the pH to 5.0, we can add 0.200 M HCl dropwise while monitoring the pH with a pH meter. Once the pH reaches 5.0, the solution is ready. We can add HCl to the sodium acetate solution because the conjugate base, acetate ion (C2H3O2−), can act as a buffer and resist changes in pH when small amounts of acid or base are added to it.

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Related Questions

1. IV DOPamine 200 mg in 500 mL 0.9% NaCl at 1 mcg/kg/min.
2. Titrate by 1 mcg/kg/min every 15 minutes to keep BP above 100/60 and urine output greater than 40 mL/hr.
3. Insert urinary catheter to gravity drainage.

The patient weighs 80 kg. The nurse started the IV at 1400 at the infusion rate of 12 mL/hr. At 1415, the patient’s BP is 90/56 and the output in the urinary catheter bag is 38 mL/hr.

To follow the titration orders, how should the nurse adjust the IV pump?

Answers

The nurse should adjust the IV pump to increase the infusion rate to 12.2 mL/hr. To follow the titration orders and adjust the IV pump, the nurse should:

Calculate the current dose of dopamine being infused:

Dose: 1 mcg/kg/min

Patient's weight: 80 kg

Current infusion rate: 12 mL/hr

Since dopamine is given at a rate of 1 mcg/kg/min, and the patient weighs 80 kg, the current dose being infused is 80 mcg/min.

Assess the patient's blood pressure (BP) and urine output:

BP: 90/56 (below the target of 100/60)

Urine output: 38 mL/hr (below the target of 40 mL/hr)

Determine the required adjustments:

The BP is below the target, so an increase in the dose of dopamine is needed.

The urine output is below the target, so an increase in the dose of dopamine may also help increase urine production.

Calculate the required increase in dopamine dose:

Increase: 1 mcg/kg/min

Patient's weight: 80 kg

The required increase in dopamine dose is 80 mcg/min.

Adjust the IV pump:

Increase the infusion rate by the required increase in dopamine dose.

Since the current infusion rate is 12 mL/hr, convert the required increase in dopamine dose (80 mcg/min) to mL/hr.

To calculate the mL/hr increase, use the concentration of the dopamine solution:

Dopamine concentration: 200 mg in 500 mL

First, convert 200 mg to mcg: 200 mg = 200,000 mcg

Then, calculate the mL/hr increase:

(80 mcg/min * 500 mL) / 200,000 mcg = 0.2 mL/hr

Add the calculated increase to the current infusion rate:

12 mL/hr + 0.2 mL/hr = 12.2 mL/hr

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18. Of the following species, A) PH3 B) CIF3 C)NC13 D) BC3 B) All of these will have bond angles of 120 will have bond angles of 120° 19. The molecular geometry of the left-most carbon atom in the molecule below is A) trigonal planar B) trigonal bipyramidal C) tetrahedral D) octahedral E) T-shaped 20·The central Xe atom in the XeF4 molecule has _ unbonded electron pair(s) and bonded electron pair(s) in its valence shell. A) 1,4 B) 2, 4 C) 4, 0 D) 4,1 E)4, 2 21. What is the molecular shape of H20? A) T-shaped B) tetrahedral C) linear D) trigonal pyramidal E) bent electron domains and a 22. PCIs has A) 6, trigonal bipyramidal B) 6, tetrahedral C) 5, square pyramidal D) 5, trigonal bipyramidal E) 6, scesaw

Answers

18. Among the given species, A) PH3 B) CIF3 C)NC13 D) BC3 B) All of these will have bond angles of 120 will have bond angles of 120° The hybridization of atoms in PH3, CIF3, NC13, and BC3 molecules is sp3. Since there are no lone pairs, all of these molecules have a bond angle of 120°. Hence, the correct option is B.19.

The molecular geometry of the left-most carbon atom in the molecule below is tetrahedral. The given molecule is a pentane with five carbon atoms in it. So, the left-most carbon atom is a tetrahedral-shaped molecule. Hence, the correct option is C.20. The central Xe atom in the XeF4 molecule has 2 unbonded electron pairs and 4 bonded electron pairs in its valence shell. In the XeF4 molecule, the Xenon atom shares a single bond with each of the four Fluorine atoms present in the molecule. This makes up for four bonded electron pairs. Two lone pairs are left unbonded on the Xenon atom, giving a total of six electron pairs. Since there are four bonded pairs and two lone pairs, the answer is 4, 2.

Hence, the correct option is E.21. The molecular shape of H2O is a bent shape. The electron domains and a Bent shape molecule is the one that has two atoms attached to a central atom with one or two lone pairs present on the central atom. The molecular geometry of H2O is bent because the lone pairs exert a greater repulsive force than bonded pairs of electrons, forcing the bonded pairs to be closer to each other. Hence, the correct option is E.22. PCIs has 5, trigonal bipyramidal electron domains. In PCIs, the central Phosphorus atom is bonded to 5 other atoms. This gives a total of 5 electron domains around the Phosphorus atom. Hence, the correct option is D.

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How many protons do all isotopes of Ca have?

2

29

40

4

Answers

Calcium (Ca) is a chemical element with the atomic number 20, indicating that it has 20 protons in its atomic nucleus.

The number of protons in the nucleus determines the element's identity since it determines the number of electrons in the atom. All isotopes of calcium have 20 protons. Isotopes are variants of a particular element that differ in the number of neutrons they contain. Isotopes of the same element have the same number of protons, but different numbers of neutrons.

Calcium has at least 24 known isotopes, with atomic masses ranging from 34 to 57. All isotopes of calcium, however, have 20 protons since that is the element's atomic number. Some isotopes of calcium, such as Ca-40 and Ca-44, are stable and do not emit radiation. Other isotopes, such as Ca-41, Ca-45, and Ca-47, are unstable and may decay into other elements over time. Calcium is an important element for many biological processes, including bone formation, muscle function, and nerve transmission.

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At what pH is glutamate 25% ionized? 2 points At what pH is the side chain of histidine 4/5 ionized? 2 points At what pH is the side chain of cysteine 15% ionized? 2 points At what pH is tyrosine 5/8 ionized?

Answers

Glutamate (Glu) is an anionic amino acid, meaning it carries a negative charge at physiological pH. The question asks at what pH the side chain of histidine is 4/5 ionized.

Glutamic acid (as the ionized form is commonly known) has a pKa of 4.07, which means it exists in two forms in solution: the acidic protonated form and the anionic deprotonated form. The amount of glutamate that is ionized at any given pH can be determined using the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]) Where [A-] is the concentration of the deprotonated form (glutamate) and [HA] is the concentration of the protonated form (glutamic acid).

At 25% ionization, the concentration of the deprotonated form is four times the concentration of the protonated form (since the ratio of deprotonated form to protonated form is 1:3). So the pH at which glutamate is 25% ionized is approximately 4.6. The pH at which glutamate is 25% ionized is approximately 4.6 Histidine (His) is an amino acid with a side chain that can be positively charged or neutral depending on the pH of the solution. The pKa of the imidazole group in the side chain is 6.04, which means that at pH values below 6.04, the imidazole group is mostly protonated (positively charged), while at pH values above 6.04, the imidazole group is mostly deprotonated (neutral).The question asks at what pH the side chain of histidine is 4/5 ionized.

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Theoretically, what mass of carbon dioxidé would be released into the atmosphere if 5 kg of toluene reacted with excess oxygen gas? (3 Marks). d) If the percent yield of this reaction is 70%, what mass of water is actually released into the atmosphere by the reaction from part C?

Answers

From the equation, we can see that for every 1 mole of toluene, 7 moles of carbon dioxide are produced. We need to find the number of moles of toluene in 5 kg, and then multiply it by the ratio to find the mass of carbon dioxide.

The molar mass of toluene (C7H8) is approximately 92.14 g/mol. Therefore, the number of moles of toluene in 5 kg can be calculated by dividing 5,000 g by 92.14 g/mol.

Once you have the number of moles of toluene, you can multiply it by the ratio of carbon dioxide to toluene (7 moles of CO2 / 1 mole of toluene) and the molar mass of carbon dioxide (approximately 44.01 g/mol) to find the mass of carbon dioxide released.

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An environmental scientist developed a new analytical method for the determination of cadmium (Cd
2+
) in mussels. To validate the method, the researcher measured the Cd
2+
concentration in standard reference material (SRM) 2976 that is known to contain 0.82±0.16ppmCd
2+
. Five replicate measurements of the SRM were obtained using the new method, giving values of 0.794, 0.763,0.829,0.839, and 0.781ppmCd
2+
Calculate the mean (
x
ˉ
), standard deviation (s
x

), and the 95% confidence interval. A list of t values can be found in the Student's t table.
x
ˉ
= s
x

= 95% confidence interval: ± ppm Does the new method give a result that differs from the known result of the SRM at the 95% confidence level? no yes

Answers

The actual value of the known result of the SRM, it is not possible to determine if the new method gives a result that differs at the 95% confidence level.

To calculate the mean and standard deviation, we use the following formulas:

Mean  = (0.794 + 0.763 + 0.829 + 0.839 + 0.781) / 5 = 0.8016 ppm Cd²⁺

Next, we calculate the standard deviation (sₓ):

Step 1: Calculate the squared differences from the mean for each measurement:

(0.794 - 0.8016)², (0.763 - 0.8016)², (0.829 - 0.8016)², (0.839 - 0.8016)², (0.781 - 0.8016)²

Step 2: Calculate the sum of the squared differences:

Sum = (0.794 - 0.8016)² + (0.763 - 0.8016)² + (0.829 - 0.8016)² + (0.839 - 0.8016)² + (0.781 - 0.8016)²

Step 3: Calculate the variance:

Variance (s²) = Sum / (n - 1), where n is the number of measurements (in this case, 5).

Step 4: Calculate the standard deviation:

Standard Deviation (sₓ) = √(Variance)

Now, we can calculate the 95% confidence interval:

Step 1: Find the t-value corresponding to a 95% confidence level with n-1 degrees of freedom (4 degrees of freedom in this case). Consulting the Student's t-table, the t-value is 2.776.

Step 2: Calculate the standard error of the mean (SEₓ):

SEₓ = sₓ / √n, where n is the number of measurements.

Step 3: Calculate the margin of error:

Margin of Error = t-value * SEₓ

Step 4: Calculate the lower and upper limits of the confidence interval:

Lower Limit =  - Margin of Error

Upper Limit = + Margin of Error

Finally, we can determine if the new method gives a result that differs from the known result of the SRM at the 95% confidence level.

If the known result of the SRM falls within the calculated confidence interval, then the new method does not differ significantly from the known result. If the known result is outside the confidence interval, then the new method does differ significantly.

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In theory, since gases take the volume of their container, in order to collect the largest volume of CO2 possible, why couldn't we just release the CO2 into the room where the experiment is being conducted, and then say that the volume of the gas is the volume of the room. Why can't we do this instead of just measuring the amount of water displaced when bubbling the gas through water?

Answers

In theory, gases do indeed take the volume of their container. However, releasing CO₂ into the room would not allow us to accurately measure the volume of the gas. This is because the CO₂ would quickly mix and disperse throughout the room, making it difficult to collect and measure.



To accurately measure the volume of CO₂, the gas needs to be contained and collected in a specific way. Bubbling the gas through water allows us to collect and measure the amount of CO₂ that is being produced. The CO₂ gas dissolves in the water, causing a displacement of water volume.

By measuring the amount of water displaced, we can determine the volume of CO₂ produced. This method provides a more precise measurement of the gas volume compared to releasing it into the room.

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Chemical Equilibrium: Type Equilibrium Expressions For The Following Equations: 1.) 2BrI3​( g)⇔Br2​(l)+3I2​( g) 2.) 2CO(g)+4Cl2​⇔2CCl4​( g)+O2​( g) 3.) C9​H2​O(l)+14O2​( g)⇔10H2​O(g)+9CO2​( g) Answers Should Be Typed And NOT Handwritten.

Answers

The equilibrium expressions for the given equations are: 1.) K = [Br₂] * [I₂]³ / [BrI₃]². 2.) K = [CCl₄]² * [O₂] / [CO]² * [Cl₂]⁴. 3.) K = [H₂O]¹⁰ * [CO₂]⁹ / [C₉H₂O] * [O2]¹⁴.

Equilibrium expressions are mathematical representations of the concentrations of reactants and products in a chemical reaction. They are determined by considering the stoichiometry of the reaction and the concentrations of the species involved.

The expressions involve raising the concentrations of the substances to the power of their respective stoichiometric coefficients.

Equilibrium expressions are essential for calculating the equilibrium constant (K), which quantifies the extent of the reaction at equilibrium. The three given equilibrium expressions demonstrate this principle for different chemical reactions involving various species.

To write equilibrium expressions for the given equations, we need to consider the stoichiometry of the reactions and the concentrations of the species involved. The equilibrium expression for a reaction is written using the concentrations of the reactants and products raised to the power of their stoichiometric coefficients.

1. For the reaction: 2BrI₃(g) ⇔ Br₂(l) + 3I₂(g)

The equilibrium expression can be written as:

K = [Br₂] * [I₂]³ / [BrI₃]²

where [Br₂], [I₂], and [BrI₃] represent the concentrations of Br₂, I₂, and BrI₃, respectively.

2. For the reaction: 2CO(g) + 4Cl₂ ⇔ 2CCl₄(g) + O₂(g)

The equilibrium expression can be written as:

K = [CCl₄]² * [O₂] / [CO]² * [Cl₂]⁴

where [CCl4], [O₂], [CO], and [Cl₂] represent the concentrations of CCl₄, O₂, CO, and Cl₂, respectively.

3. For the reaction: C₉H₂O(l) + 14O₂(g) ⇔ 10H₂O(g) + 9CO₂(g)

The equilibrium expression can be written as:

K = [H₂O]¹⁰ * [CO₂]⁹ / [C₉H₂O] * [O2]¹⁴

where [H₂O], [CO₂], [C₉H₂O], and [O₂] represent the concentrations of H₂O, CO₂, C₉H₂O, and O₂, respectively.

In these equilibrium expressions, the coefficients of the balanced equation are used as exponents to represent the stoichiometry. The concentrations of the species are written in brackets.

It's important to note that equilibrium expressions are only valid for reactions that occur in the gas or solution phase, and they are temperature-dependent.

Additionally, the equilibrium constant, represented by K, is a measure of the extent of the reaction at equilibrium.

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what is the name of the hybrid orbitals used by sulfur in sf4?

Answers

The hybrid orbitals used by sulfur in SF4 are sp3d hybrid orbitals. Let's discuss them in detail below: Sulfur (S) atom in SF4 has a total of six valence electrons: four in the 3p shell and two in the 3s orbital. In order to form bonds with four Fluorine (F) atoms, one electron from 3s shell is excited to the 3d shell, giving rise to five hybrid orbitals.

These hybrid orbitals are then arranged in an octahedral geometry.In addition, the five hybrid orbitals are known as sp3d hybrid orbitals, as they are a mixture of the s, p, and d atomic orbitals. In this hybridization, the central atom utilizes one s, three p, and one d orbitals for hybridization, resulting in five hybrid orbitals with equal energy and shape. The shape of these hybrid orbitals is square pyramidal, with the F atoms occupying the vertices of a square pyramidal shape. Each F atom is bonded to S through one of these hybrid orbitals.

Let's add a few more words to make it 100 words. Therefore, the sulfur in SF4 molecule adopts an sp3d hybridization geometry that produces five sp3d hybrid orbitals that bond with F atoms.

In SF4, the central atom (sulfur) uses the one s, three p, and one d orbitals for hybridization to make a total of five hybrid orbitals that bond with four fluorine atoms through dative covalent bonds, resulting in the square pyramidal shape of the molecule.

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What is the molality of a 10.0% by mass aqueous solution of LiF (molar mass 25.94 g/mol )?

Answers

The molality of the 10.0% by mass aqueous solution of LiF is approximately 4.28 mol/kg.

To calculate the molality of a solution, we need to know the moles of the solute (LiF) and the mass of the solvent (water).

Given:

Mass percentage of LiF in the solution = 10.0%

Molar mass of LiF = 25.94 g/mol

Let's assume we have 100 grams of the solution. This means that 10.0 grams of the solution are LiF, and the remaining 90.0 grams are water (the solvent).

Calculate the moles of LiF:

Moles of LiF = Mass of LiF / Molar mass of LiF

Moles of LiF = 10.0 g / 25.94 g/mol ≈ 0.3856 mol

Calculate the mass of water (solvent):

Mass of water = Total mass of the solution - Mass of LiF

Mass of water = 100.0 g - 10.0 g = 90.0 g

Calculate the moles of water:

Moles of water = Mass of water / Molar mass of water (approximately 18.015 g/mol, which is the molar mass of water)

Moles of water = 90.0 g / 18.015 g/mol ≈ 4.995 mol

Calculate the molality:

Molality (m) = Moles of solute / Mass of solvent in kg

Molality (m) = 0.3856 mol / (90.0 g / 1000 g/kg) ≈ 4.28 mol/kg

The molality of the 10.0% by mass aqueous solution of LiF is approximately 4.28 mol/kg.

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Compare and contrast hydro-cracking, hydro-isomerization, and
catalytic conversion.

Answers

Hydrocracking, hydro-isomerization, and catalytic conversion are all techniques used in refining crude oil into valuable end products. In this context, hydrocracking, hydro-isomerization, and catalytic conversion will be compared and contrasted.

Hydrocracking is the process of breaking down heavy oil fractions to produce more valuable light oils, including gasoline and diesel fuel. It is the most versatile of all refinery processes and is capable of producing an extensive range of lighter, cleaner, and higher-value products from heavy crude oils.

Hydro-isomerization is a refinery process that involves breaking down large hydrocarbon molecules and rearranging them into smaller, branched, and more uniform molecules with lower boiling points. It produces high-quality diesel fuel by isomerizing long chain linear hydrocarbons into shorter chain branched isomers, which have better cold flow properties.

Catalytic conversion refers to a process in which one or more feedstocks are converted into one or more products using a catalyst. Catalysts are used to speed up the reaction and lower the temperature at which the reaction occurs. Catalytic conversion is used for producing fuels such as gasoline, diesel, and jet fuel.

It involves a number of different chemical reactions that take place on a catalyst surface to break down heavy molecules into lighter, more valuable ones.Hydrocracking is a more extensive and flexible process than hydro-isomerization, producing more products.

Catalytic conversion, on the other hand, is a broad term that can refer to any process that uses a catalyst to convert feedstocks into valuable end products. Additionally, catalytic conversion can be used to produce a wide range of products, such as petrochemicals and plastics, whereas hydrocracking and hydro-isomerization are limited to producing fuel products.

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2. What is the best way of limiting exposure to toxic substances?

Answers

The following are the most effective ways of limiting exposure to toxic substances:1. Learn about the substances, .2. Avoid smoking. 3. Proper ventilation, 4. Use personal protective equipment, 5 Wash your hands regularly, 6 Eat a healthy diet

Limiting exposure to toxic substances is a crucial element in ensuring good health. Many harmful substances are present in the environment we live in, such as pollutants, heavy metals, and chemicals, which can cause a variety of health issues. Long-term exposure to these toxins can lead to serious health issues such as cancer, organ damage, developmental issues, and other problems. As a result, it is crucial to take precautions to reduce our exposure to harmful toxins.

Learning about the substances that you are exposed to is one of the most effective ways of limiting exposure to toxic substances. By becoming aware of the harmful substances, you can take action to avoid exposure to these substances.

Avoid smoking: Smoking is one of the most common ways of exposing your body to harmful toxins. It is the leading cause of lung cancer and other health problems.3. Proper ventilation: Proper ventilation can help reduce exposure to harmful toxins in the air.

Proper ventilation helps to circulate air and remove harmful substances from the air.4. Use personal protective equipment: Personal protective equipment such as gloves, face masks, and goggles can help reduce exposure to harmful toxins.

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For the chemical reaction shown here: N
2

( g)+3H
2

( g)→2NH
3

( g) The following data was obtained: at time =0sec[N
2

]=0.70M,[H
2

]=2.0M,[NH
3

]=0.0M at time =25sec[N
2

]=0.30M,[H
2

]=???M,[NH
3

]=???M How much [N
2

] was used? 0.40M used 0.30M used 1.0M used 0.20M

Answers

The balanced chemical equation of the reaction:N₂(g) + 3H₂(g) → 2NH₃(g) . The amount of [N₂] used is 0.40M

Option A is correct .

To determine how much N₂ was used in the chemical reaction, we need to calculate the change in the concentration of N₂ between the initial and final states.

Initial [N₂] = 0.70 M

Final [N₂] = 0.30 M

Change in [N₂] = Final [N₂] - Initial [N₂]

= 0.30 M - 0.70 M

= -0.40 M

The negative sign indicates a decrease in concentration, meaning that 0.40 M of N₂ was used in the reaction.

Therefore, the correct answer is:  0.40M used, Option A is correct

Incomplete question :

For the chemical reaction shown here: N2 ( g)+3H2​ ( g)→2NH3 ( g) The following data was obtained: at time =0 sec[N2]=0.70M,[H2]=2.0M,[NH3 ]=0.0M at time =25sec[N2]=0.30M,[H2]=???M,[NH3]=???M How much [N2] was used?

A. 0.40M used

B. 0.30M used

C. 1.0M used

D. 0.20M

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A solution containing Na
2

SO
4

was treated with 0.117MBaCl
2

solution until all the sulfate ion had reacted to form BaSO 4 . The net reaction Ba
2+
(aq)+SO
4


2−
(aq)→BaSO
4

(s) required 45.4 mL of the BaCl
2

solution. How many grams of Na
2

SO
4

were in the solution? m(Na
2

SO
4

)= g

Answers

To determine the number of grams of Na2SO4 in the solution, we need to use the stoichiometry of the reaction and the volume of the BaCl2 solution required for complete reaction.

First, let's convert the volume of BaCl2 solution to liters:

45.4 mL = 45.4 mL * (1 L / 1000 mL) = 0.0454 L

Now, we can use the molarity (M) and volume (V) of the BaCl2 solution to calculate the moles of BaCl2 used:

moles of BaCl2 = M * V = 0.117 M * 0.0454 L = 0.00531 moles

Since the stoichiometry of the reaction is 1:1 between BaCl2 and Na2SO4, the moles of Na2SO4 present in the solution is also 0.00531 moles.

The molar mass of Na2SO4 is:

Na = 22.99 g/mol

S = 32.07 g/mol

O4 = 4 * 16.00 g/mol = 64.00 g/mol

So, the molar mass of Na2SO4 is:

2 * Na + S + 4 * O = 2 * 22.99 g/mol + 32.07 g/mol + 4 * 16.00 g/mol = 142.06 g/mol

Finally, we can calculate the mass of Na2SO4 in grams:

m(Na2SO4) = moles of Na2SO4 * molar mass of Na2SO4

= 0.00531 moles * 142.06 g/mol

= 0.752 g

Therefore, there were approximately 0.752 grams of Na2SO4 in the solution.

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Citric acid has three pKa values, roughly 3,1,4.8 and 6.4 Why is pKa (2) so much larger than pKa(1) and why is pKa(3) so much larger than pKa(2) ?

Answers

pKa(2) is more substantial than pKa(1) because the proton removed in the second ionization is more difficult to remove than the first one, which makes it harder to deprotonate, pKa(2) is higher than pKa(1) because the hydrogen ion is attached to a carboxylic acid group.

Citric acid is a weak organic acid that has three pKa values, roughly 3.1, 4.8, and 6.4. The pKa values of the acid provide information regarding its tendency to lose a proton. These pKa values allow us to determine which protons in the citric acid molecule will be most likely to dissociate when exposed to a basic environment.

pKa(1) has a value of 3.1, while pKa(2) has a value of 4.8, and pKa(3) has a value of 6.4.Furthermore, pKa(2) is higher than pKa(1) because the hydrogen ion is attached to a carboxylic acid group, which is an electron-withdrawing group that withdraws electrons from the adjacent carbon-oxygen double bond.

The double bond is, therefore, more electronegative, which decreases the strength of the O-H bond and makes it harder to remove a proton.pKa(3) is larger than pKa(2) because the hydrogen ion is now connected to a carboxylate anion that is electron-rich and so can withdraw even more electrons from the adjacent carbon-oxygen bond, making it even harder to remove the hydrogen ion.

Thus, the greater the electron-withdrawing capacity of the functional group connected to the proton, the greater the pKa of the proton would be.

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Find Δ
r

H for the combustion of naphthalene at 298 K. When considering phase, assume all reactants and products are at 298 K Express your answer using four significant figures.

Answers

ΔrH for the combustion of naphthalene at 298 K is to use the heat of formation values for naphthalene and the combustion products, which are carbon dioxide and water.

you need to know the standard enthalpy of formation (ΔfH) for each compound. The given values at 298 K are:ΔfH(C10H8) = 79.2 kJ/molΔfH(CO2) = -393.5 kJ/molΔfH(H2O) = -285.8 kJ/mol

Plugging in the values, we have:ΔrH = (10 * -393.5 kJ/mol) + (4 * -285.8 kJ/mol) - (1 * 79.2 kJ/mol) - (12.5 * 0 kJ/mol)Simplifying, we get:the heat of formation values for naphthalene and the combustion products, which are carbon dioxide and water.

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the change in enthalpy (ΔH) for the combustion of naphthalene at 298 K is -5152.3 kJ/mol.

The change in enthalpy (ΔH) for the combustion of naphthalene at 298 K can be determined using Hess's Law and the enthalpy of formation values.

First, let's write the balanced equation for the combustion of naphthalene:
C10H8 + 12.5O2 → 10CO2 + 4H2O

To find ΔH, we need to consider the enthalpies of formation (ΔHf) for each compound involved. The ΔHf values are given as follows:
ΔHf(C10H8) = 78.0 kJ/mol
ΔHf(CO2) = -393.5 kJ/mol
ΔHf(H2O) = -285.8 kJ/mol

Now, we can calculate ΔH for the combustion reaction:
ΔH = Σ(ΔHf(products)) - Σ(ΔHf(reactants))

ΔH = [10 × ΔHf(CO2) + 4 × ΔHf(H2O)] - [ΔHf(C10H8) + 12.5 × ΔHf(O2)]

Substituting the given values, we get:
ΔH = [10 × (-393.5 kJ/mol) + 4 × (-285.8 kJ/mol)] - [78.0 kJ/mol + 12.5 × 0 kJ/mol]

Calculating this expression, we find:
ΔH = -5152.3 kJ/mol

Therefore, the change in enthalpy (ΔH) for the combustion of naphthalene at 298 K is -5152.3 kJ/mol.

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Carry out the given conversions from one metric unit of length to another. 65.5Mm= 7.03 nm=

Answers

65.5 megameters (Mm) is equal to 6.55 × 10²⁰ nanometers (nm).

7.03 nanometers (nm) is equal to 7.03 × 10⁻³⁰ megameters (Mm).

To convert between metric units of length, we use the prefixes and conversion factors associated with those units.

For the first conversion:

65.5 Mm to nm

1 megameter (Mm) is equal to 1 × 10¹⁸ nanometers (nm).

Therefore, to convert Mm to nm, we multiply the given value by the conversion factor:

65.5 Mm * (1 × 10¹⁸ nm / 1 Mm) = 65.5 × 10¹⁸ nm = 6.55 × 10²⁰ nm

Hence, 65.5 Mm is equal to 6.55 × 10²⁰ nm.

For the second conversion:

7.03 nm to Mm

To convert nm to Mm, we divide the given value by the conversion factor:

7.03 nm / (1 × 10¹⁸ nm / 1 Mm) = 7.03 × 10⁻³⁰ Mm

Therefore, 7.03 nm is equal to 7.03 × 10⁻³⁰ Mm.

In summary, 65.5 Mm is equivalent to 6.55 × 10²⁰ nm, and 7.03 nm is equivalent to 7.03 × 10⁻³⁰ Mm.

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Calculate the equilibrium conversion and concentrations for each of the following reactions: a) The liquid phase reaction: A+B⇄C with CA0=CB0=2 mol/dm3 and KC=10dm3/mol b) The gas phase reaction: A⇄3C is carried out in a flow reactor with no pressure drop. Pure A enters at T=400 K and P=10 atm. At this temperature, Kc=0.25( mol/dm3)2. c) The gas phase reaction in part b) carried out in a constant-volume batch reactor. d) The gas phase reaction in part b) carried out in a constant-pressure batch reactor. e) Write a list and description of the typical errors that you think a student may likely commit when solving this problem (e.g. sign in a particular place, units, incorrect equation, assumptions, etc.). The more specific and detailed the best.

Answers

(a)CC = 0.4 mol/dm³. (b)  The reaction is reversible, the conversion cannot exceed 1. (c) In a constant-volume batch reactor, the volume remains constant, and the reaction proceeds until equilibrium is reached. (d) In a constant-pressure batch reactor, the pressure remains constant, and the reaction proceeds until equilibrium is reached.(e) Possible errors a student may commit when solving can errors, misinterpreting.

a) The liquid phase reaction: A + B ⇄ C with CA0 = CB0 = 2 mol/dm³ and KC = 10 dm³/mol.

Let x be the extent of reaction (conversion), then the equilibrium concentrations are given by:

CA = CA0 - x

CB = CB0 - x

CC = x

From the equilibrium constant expression:

KC = CC / (CA × CB)

Substituting the equilibrium concentrations:

10 = x / ((2 - x) × (2 - x))

Simplifying the equation:

10(4 - 4x + x²) = x

40 - 40x + 10x² = x

10x² - 41x + 40 = 0

Solving the quadratic equation, we find two roots: x = 0.4 and x = 4.

Since the reaction is reversible, the conversion cannot exceed 1. Therefore, the equilibrium conversion is x = 0.4. The equilibrium concentrations are:

CA = 2 - 0.4 = 1.6 mol/dm³

CB = 2 - 0.4 = 1.6 mol/dm³

CC = 0.4 mol/dm³

b) The gas phase reaction: A ⇄ 3C is carried out in a flow reactor with no pressure drop. Pure A enters at T = 400 K and P = 10 atm. At this temperature, Kc = 0.25 (mol/dm³)².

Let CA0 be the initial concentration of A. At equilibrium, the concentrations are given by:

CA = CA0 - 3x

CC = 3x

From the equilibrium constant expression:

KC = (CC)³ / CA

Substituting the equilibrium concentrations:

0.25 = (3x)³ / (CA0 - 3x)

0.25(CA0 - 3x) = 27x³

0.25CA0 - 0.75x = 27x³

Since the reaction is reversible, the conversion cannot exceed 1. Therefore, we solve for x numerically or graphically to find the equilibrium conversion and concentrations.

c) The gas phase reaction in part b) carried out in a constant-volume batch reactor:

In a constant-volume batch reactor, the volume remains constant, and the reaction proceeds until equilibrium is reached. The equilibrium conversion and concentrations will be the same as in part b) once equilibrium is attained.

d) The gas phase reaction in part b) carried out in a constant-pressure batch reactor:

In a constant-pressure batch reactor, the pressure remains constant, and the reaction proceeds until equilibrium is reached. The equilibrium conversion and concentrations will be the same as in part b) once equilibrium is attained.

e) Possible errors a student may commit when solving this problem:

Incorrectly applying the equilibrium constant expression or misinterpreting its meaning.

Errors in solving the quadratic equation to find the equilibrium conversion.

Failing to consider the limitations on conversion (it cannot exceed 1).

Using the wrong equation or approach for different reactor types (flow reactor, constant-volume batch reactor, constant-pressure batch reactor).

Misinterpreting or using incorrect units for concentrations, equilibrium constants, or other parameters.

Overlooking the fact that the reaction is reversible and assuming it goes to completion.

Failing to account for the initial conditions and concentrations given in the problem.

Mistakes in numerical calculations or rounding errors.

Forgetting to consider the effect of temperature and pressure on equilibrium and the equilibrium constant.

Making assumptions or approximations that are not justified in the problem statement or neglecting important factors such as pressure drop or reaction kinetics.

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the tube additive that is responsible for the most carryover problems is

Answers

The tube additive that is responsible for most carryover problems in laboratory settings is the anticoagulant ethylenediaminetetraacetic acid (EDTA). EDTA is commonly used in blood collection tubes to prevent clotting by chelating calcium ions, thus inhibiting coagulation cascade.

Carryover refers to the phenomenon where traces of a substance from a previous sample contaminate subsequent samples, leading to inaccurate test results. EDTA can contribute to carryover issues due to its ability to bind with metal ions, including calcium, which is essential for proper clotting. When residual EDTA remains in the collection tube or the analytical system, it can interfere with subsequent tests, leading to erroneous results.

EDTA carryover can be particularly problematic in sensitive laboratory assays that require precise measurements or low detection limits. It can result in falsely elevated or reduced analyte concentrations, affecting patient diagnosis and treatment decisions. Additionally, carryover can lead to increased analytical variability, requiring additional sample analysis and causing delays in reporting results.

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What is the entropy of mixing in J/K if 5.3 molO
2

and 7.9 mol N
2

are mixed at 298 K ? Express your answer with no decimals.

Answers

The entropy of mixing for 5.3 mol O2 and 7.9 mol N2 at 298 K is 129 J/K. We can use the ideal gas law to solve this question.

To calculate the entropy of mixing, we use the formula:

ΔS_mix = n_R gas × R × ln(V_f / V_i)

where n_R gas is the number of moles of gas, R is the gas constant (8.314 J/(mol·K)), V_f is the final volume, and V_i is the initial volume.

Since the gases are being mixed, their volumes are additive:

V_f = V_O2 + V_N2

Using the ideal gas law, we can express the volumes in terms of moles and molar volumes:

V_f = (n_O2 × RT) / P + (n_N2 × RT) / P

Substituting the given values, we get:

V_f = (5.3 × 8.314 × 298) / P + (7.9 × 8.314 × 298) / P

Simplifying the equation and calculating the natural logarithm, we find:

V_f = 0.0728 + 0.1089 = 0.1817

Substituting the values into the entropy of the mixing equation, we have:

ΔS_mix = (5.3 + 7.9) × 8.314 × ln(0.1817 / 0) = 129 J/K

Therefore, the entropy of mixing is 129 J/K.

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Given that you have access to Tris Base, sodium chloride, and a 2.0 M solution of HCl determine how you would prepare a 1.0 L of a 25 mM Tris buffer at pH 7.4 with 150 mM NaCl.

Write a bullet point style protocol for the preparation of your Tris buffer. Include all of the steps that would be required to make this buffer.

· Assume you start with solid reagents and have access to a balance, standard glassware, pH probe, 2.0 M HCl solution, and water.

· Be specific about how much of each reagent you need based on your Excel calculations.

· Be clear about when you add water and how much.

· Give an approximate amount of HCl you would expect to titrate with to reach the desired pH

· Be specific with what glassware you would choose for each step.

Answers

Here is the stepwise protocol for the preparation of a 1.0 L of a 25 mM Tris buffer at pH 7.4 with 150 mM NaCl. Calculation of amount of reagents required:Calculate the amount of Tris base required to prepare 1.0 L of 25 mM .

Where, MW (Tris) = 121.14 g/mol (molecular weight of Tris),

V (buffer) = 1.0

L (volume of buffer required),

C (buffer) = 25 mM (concentration of buffer required)

Substituting the values, we get mass of Tris = 3.0285 gSimilarly, calculate the amount of NaCl required using the formula: MW (NaCl) * V (buffer) * C (buffer) = mass of NaClWhere, MW (NaCl) = 58.44 g/mol (molecular weight of NaCl), V (buffer) = 1.0 L (volume of buffer required), C (buffer) = 150 mM (concentration of buffer required)Substituting the values, we get mass of NaCl = 8.766 g.

Weigh out the required amounts of Tris Base and NaCl on a balance. Transfer each of these to a 1.0 L volumetric flask using a funnel. The 1.0 L volumetric flask should have enough space for additional solid and liquid.Step 3: Add some water to the flask to dissolve the solids. Then, add more water to the flask until the total volume of the solution is 750 mL. The amount of water required is calculated as follows:Volume of water = Total volume of buffer – volume occupied by the solid reagents .

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charge on one side and a charge on the other side. Where the two types of silicon meet, the N/P junction, electrons can wander across creating a positive; negative neutral; positive negative; positive positive; neutral In spite of these limitations, it is still possible to supply the world's needs with solar technology. We need to have to build the infrastructure and the to put it all. people; homes none of the answers here funding; space machinery; rooftops

Answers

The N/P junction in solar cells is formed where two types of silicon, N-type and P-type, meet. Electrons can wander across this junction, creating a charge imbalance. On one side, there will be an excess of electrons (negative charge), while on the other side, there will be a deficiency of electrons (positive charge).


In order to meet the world's needs with solar technology, we need to build the necessary infrastructure and put it all into action. This includes securing funding and space for solar installations, as well as deploying the necessary machinery on rooftops of homes and other suitable locations. By overcoming these challenges, we can harness solar energy to meet our energy demands.

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The pOH of Windex window cleaner is 2.40. Calculate the hydrogen ion concentration. Report the concentration using Molar concentration. make sure your answer has 15 decimal digits Type your answer... 1 point The pH of Shiner Bock Beer is 4.60. Calculate the hydrogen ion concentration. Report your answer using Molar concentration units. Type your answer... 1 point The pH of Shiner Bock Beer is 4.60. Calculate the hydroxide ion concentration. Report your answer using Molar concentration units. Make sure your answer has 13 decimal digits.

Answers

The hydrogen ion concentration of Windex window cleaner is 3.98 × 10^–13 M. The hydrogen ion concentration of Shiner Bock Beer is 2.51 × 10^–5 M.

The hydroxide ion concentration of Shiner Bock Beer is 3.98 × 10^–10 M. To calculate the hydrogen ion concentration from the pOH of Windex window cleaner, we use the following formula: pOH + pH = 14. To get the pH, we rearrange the equation as follows: pH = 14 - pOH

PH = 14 - 2.40

= 11.60

Now that we have the pH, we can calculate the hydrogen ion concentration using the formula: pH = - log [H+]11.60

= - log [H+] [H+]

= 10^–11.60

= 3.98 × 10^–12 M.

To report the concentration using Molar concentration units, we need to convert the value to Molar concentration by dividing by 1000. Thus, the hydrogen ion concentration of Windex window cleaner is 3.98 × 10^–13 M.To calculate the hydrogen ion concentration of Shiner Bock Beer.

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What Is The Mass Of 467 Ml Of Liquid Oxygen Given That Its Density Is 1.141g G/Cm^3 ?

Answers

The mass of 467 mL of liquid oxygen is 532.147 g. Given, the volume of liquid oxygen = 467 mL The density of liquid oxygen = 1.141 g/cm³.

The formula to calculate mass is given by, Mass = Density × VolumeVolume is given in mL, and density is given in g/cm³. So, we need to convert the volume to cm³ to get the mass.

1 mL = 1 cm³Mass = Density × Volume= 1.141 g/cm³ × 467 mL= 1.141 g/cm³ × 467 cm³= 532.147 g Hence, the mass of 467 mL of liquid oxygen is 532.147 g. The density of liquid oxygen = 1.141 g/cm³.

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4. Vacuum distillation is widely used to produce catalytic cracking plant teed stocks of low carbon content. List and specify the major specifications for the most common products.

Answers

Vacuum distillation is widely used to produce catalytic cracking plant teed stocks of low carbon content.

The major specifications for the most common products are:

Low Sulphur Content: The carbon materials produced during the vacuum distillation process contain very low levels of sulfur.

The sulfur content of the carbon material is one of the major factors that influences its performance.

The low sulfur content of the carbon material produced by vacuum distillation is one of the key reasons why it is used to produce feedstocks for catalytic cracking plants.

Low Metal Content: Another important specification for carbon materials produced by vacuum distillation is low metal content.

The presence of metal contaminants in the carbon material can significantly reduce its effectiveness as a feedstock for catalytic cracking plants. The vacuum distillation process is able to produce carbon materials with low metal content.

High Purity: Finally, carbon materials produced by vacuum distillation are typically very pure. They contain very few impurities and are often used as feedstocks for the production of high-purity products such as specialty chemicals and pharmaceuticals.

The high-purity of the carbon material is one of the key reasons why it is so valuable in these applications.

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what will be the formula of a compound formed by magnesium and nitrogen?

Answers

Magnesium and Nitrogen react to form Magnesium nitride. The formula of the compound formed by magnesium and nitrogen is Mg3N2.

In the formation of magnesium nitride, two atoms of nitrogen will be required to combine with three atoms of magnesium to form the ionic compound Mg3N2.

                                When magnesium reacts with nitrogen, the nitrogen atom will gain electrons from magnesium atoms, resulting in a magnesium ion (Mg2+) and two nitride ions (N3-).

                                          The chemical equation for the reaction between magnesium and nitrogen will be:Mg + N2 → Mg3N2The balanced equation shows that three magnesium atoms react with one molecule of nitrogen gas to produce one magnesium nitride molecule.

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At 2257 K and 1.00 atm total pressure, water is 1.77% decomposed at equilibrium by way of the reaction 2 H2O(g) ↔ 2 H2(g) + O2(g). Calculate K, ΔGo, and ΔG at 2257 K and 4050 K.

Answers

The value of Kc at 4050 K is 0.1356.

The value of ΔGo at 4050 K is -44.24 kJ/mol.

The expression for the equilibrium constant for a reaction is given as:

[tex]Kc = {products}/{reactants}[/tex]

The expression for ΔGo for a reaction is given as:

ΔGo = - RT ln Kc

Where,

R is the gas constant (8.31 J/K.mol)

T is the temperature in Kelvin

Kc is the equilibrium constant for the reaction given.

For the reaction 2H2O(g) ⇌ 2H2(g) + O2(g)At equilibrium, water is 1.77% decomposed.

Moles of water, H2, and O2 before reaction:

Starting Moles = 2 moles, 0 moles, 0 moles

After Reaction Moles = (2 - 0.0177) moles, (2 x 0.0177) moles, (0.0177) moles

Therefore, moles of water left at equilibrium = 2 - 0.0177 = 1.9823 moles

Moles of hydrogen gas at equilibrium = 0.0354 moles

Moles of oxygen gas at equilibrium = 0.0177 moles

The total moles at equilibrium = 1.0354 + 0.0177 + 1.9823 = 3 moles

The concentration of H2O(g) = 1.9823/3 = 0.66077

The concentration of H2(g) = 0.0354/3 = 0.0118

The concentration of O2(g) = 0.0177/3 = 0.0059

Now, we will calculate the equilibrium constant at

[tex]2257K.Kc = {H2}^2{O2}/{H2O}^2[/tex]

[tex]Kc = (0.0118)^2 x (0.0059)/0.66077)^2[/tex]

Kc = 0.00011915

So, Kc at 2257K is 0.00011915.

The value of ΔGo is given as:

ΔGo = - RT ln Kc

ΔGo = - 8.31 x 2257 x ln(0.00011915)

ΔGo = 68.17 kJ/mol

The change in free energy for the reaction is 68.17 kJ/mol.

At 4050 K, we can calculate the equilibrium constant and ΔGo in the same way as above.

The value of Kc at 4050 K is 0.1356.

The value of ΔGo at 4050 K is -44.24 kJ/mol.

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i)The value of Kc(equilbrium) at 4050 K is 0.1356.

ii)The value of ΔGo at 4050 K is -44.24 kJ/mol.

The expression for the equilibrium constant for a reaction is given as

The expression for ΔGo for a reaction is given as

ΔGo = - RT ln Kc

Where,

R is the gas constant (8.31 J/K.mol)

T is the temperature in Kelvin

Kc is the equilibrium constant for the reaction given.

For the reaction 2H2O(g) ⇌ 2H2(g) + O2(g)At equilibrium, water is 1.77% decomposed.

Moles of water, H2, and O2 before reaction:

Starting Moles = 2 moles, 0 moles, 0 moles

After Reaction Moles = (2 - 0.0177) moles, (2 x 0.0177) moles, (0.0177) moles

Therefore, moles of water left at equilibrium = 2 - 0.0177 = 1.9823 moles

Moles of hydrogen gas at equilibrium = 0.0354 moles

Moles of oxygen gas at equilibrium = 0.0177 moles

The total moles at equilibrium = 1.0354 + 0.0177 + 1.9823 = 3 moles

The concentration of H2O(g) = 1.9823/3 = 0.66077

The concentration of H2(g) = 0.0354/3 = 0.0118

The concentration of O2(g) = 0.0177/3 = 0.0059

Now, we will calculate the equilibrium constant a

Kc = 0.00011915

So, Kc at 2257K is 0.00011915.

The value of ΔGo is given as:

ΔGo = - RT ln Kc

ΔGo = - 8.31 x 2257 x ln(0.00011915)

ΔGo = 68.17 kJ/mol

The change in free energy for the reaction is 68.17 kJ/mol.

At 4050 K, we can calculate the equilibrium constant and ΔGo in the same way as above.

The value of Kc at 4050 K is 0.1356.    

The value of ΔGo at 4050 K is -44.24 kJ/mol.

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Determine the number of molocules in a 296mg dose of aspirin, molecular formula C
2

H
8

O
4

.

Answers

There are approximately 9.87 x 10^20 molecules in a 296 mg dose of aspirin (C2H8O4).

To determine the number of molecules in a 296 mg dose of aspirin, we need to use the molar mass of aspirin and Avogadro's number.

The molar mass of aspirin (acetylsalicylic acid) is calculated by adding the atomic masses of its constituent elements:

C: 12.01 g/mol

H: 1.008 g/mol

O: 16.00 g/mol

Molar mass of aspirin (C9H8O4) = (9 * 12.01 g/mol) + (8 * 1.008 g/mol) + (4 * 16.00 g/mol) = 180.16 g/mol

Now, we can calculate the number of moles in the given dose of aspirin:

Number of moles = Mass (g) / Molar mass (g/mol)

Number of moles = 0.296 g / 180.16 g/mol ≈ 0.00164 mol

Avogadro's number tells us the number of molecules in one mole of a substance, which is approximately 6.022 x 10^23 molecules/mol.

Number of molecules = Number of moles * Avogadro's number

Number of molecules = 0.00164 mol * (6.022 x 10^23 molecules/mol) ≈ 9.87 x 10^20 molecules

Therefore, there are approximately 9.87 x 10^20 molecules in a 296 mg dose of aspirin (C2H8O4).

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Hydrogen fluoride is produced industrially by the action of sulphuric acid on CaF Ca
2

. Suppose 486 kg of CaF
2

is treated with an excess of sulphuric acid and 233 kg of HF is produced. What is the percent yield of HF? percent eTextbook and Media How much CaF
2

remains unreacted?

Answers

The percent yield of HF can be calculated using the formula: percent yield = (actual yield/theoretical yield) * 100.

First, we need to determine the theoretical yield of HF. To do this, we can assume that the reaction between CaF2 and sulfuric acid is a one-to-one ratio. This means that for every 1 mole of CaF2, we should get 1 mole of HF.

To find the number of moles of CaF2, we can use the molar mass of CaF2. Ca has a molar mass of 40.08 g/mol, and F has a molar mass of 19.00 g/mol. So the molar mass of CaF2 is 40.08 + (2 * 19.00) = 78.08 g/mol.

The given mass of CaF2 is 486 kg, which is equal to 486,000 grams. We can convert this mass to moles by dividing by the molar mass: moles of CaF2 = 486,000 g / 78.08 g/mol = 6227.24 mol.

Since the reaction is a one-to-one ratio, the theoretical yield of HF is also 6227.24 mol.

The actual yield of HF is given as 233 kg, which is equal to 233,000 grams. To convert this mass to moles, we divide by the molar mass of HF. The molar mass of HF is 1 * 19.00 = 19.00 g/mol. Moles of HF = 233,000 g / 19.00 g/mol = 12263.16 mol.

Now we can calculate the percent yield using the formula: percent yield = (actual yield/theoretical yield) * 100.

percent yield = (12263.16 mol / 6227.24 mol) * 100 = 197.15%

So the percent yield of HF is 197.15%.

To find the amount of CaF2 that remains unreacted, we can subtract the moles of HF produced from the moles of CaF2 used.

moles of CaF2 remaining = moles of CaF2 used - moles of HF produced
moles of CaF2 remaining = 6227.24 mol - 12263.16 mol = -6035.92 mol

Since we cannot have a negative number of moles, it means that all of the CaF2 has been completely consumed in the reaction. Therefore, there is no CaF2 remaining unreacted.

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Calculate Keq given standard free energy change of 0.2 kJ/mol at 298 K.

Round the answer to the nearest tenths place.

Answers

The calculated value of Keq, rounded to the nearest tenths place, is approximately 0.4. The equilibrium constant (Keq) is a measure of the ratio of product concentrations to reactant concentrations at equilibrium for a given chemical reaction under specific conditions.


The equilibrium constant (Keq) can be calculated using the standard free energy change (∆G°) and the temperature (T).

The formula to calculate Keq is:

Keq = exp(-∆G° / (R * T))

Where:

∆G° = standard free energy change

R = gas constant (8.314 J/(mol·K))

T = temperature in Kelvin

Using the given values, with ∆G° = 0.2 kJ/mol and T = 298 K, we can calculate Keq.

Keq = exp(-0.2 kJ/mol / (8.314 J/(mol·K) * 298 K))

Keq ≈ 0.4

Therefore, the calculated value of Keq, rounded to the nearest tenths place, is approximately 0.4.


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The following formula can be used to compute the equilibrium constant (Keq):

Keq equals. [tex]e(-G°/RT).\\[/tex]

Keq is equal to e(-0.2 kJ/mol / (8.314 J/K/mol * 298 K)) = 1.8.

Keq = 1.8 is the result of rounding to the nearest tenths place.

As a result, Keq is around 1.8.

The product and reactant concentrations in an equilibrium state of a chemical reaction are related by the equilibrium constant, Keq. The ratio of the concentrations of the reactants to the products, each raised to the power of its own stoichiometric coefficient, is what determines the ratio.

The direction in which a reaction will spontaneously continue is indicated by the sign of G°, the standard Gibbs free energy change. An exergonic reaction releases energy and favours the creation of products when the G-factor is negative. An endergonic reaction, on the other hand, is indicated by a positive G° and calls for energy intake to continue.

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why is butter a solid at room temperature ,while vegetable oil is liquid? Does Wayne Little seem too focused on detention fees as an issue? List some logistics costs and factors that were not discussed specifically in the case. What are the trade-offs that might come into play were these to be considered by Mr. Little? Which of the following is not a fundamental subatomic particle that forms elements?protonselectronsneutronsnucleus 4. A lumber store stocks dowels in one standard length of 150 cm. Each dowel costs $20. A customer wants the store to cut him at minimal cost twenty dowels of length 67 cm, eighty dowels of length 51 cm, sixty dowels of length 28 cm, and forty dowels of length 15 cm. You might wish to use Excel to help create a list of patterns when beginning part (a). Make a formula to be copied for all patterns which will calculate the waste. The pattern must be discarded if this calculated number is negative or if it's greater than the smallest dowel size sought by the customer ( 15 cm in this example). how can brain waves produced during rem sleep be described Which statement best characterizes the hearing process of a formal bill?a. A formal bill receives a hearing and goes to the floor when the vice president requests it.b. A formal bill receives a hearing or floor time only when extensively marked up.c. Few formal bills receive a hearing, but many are marked up and sent to the floor. -- Consider This: Hearings are often the first step for the few bills that have some chance of approval by committee. They cannot be marked up or sent to the floor without this initial step.d. Most formal bills receive a hearing, but few are marked up and sent to the floor. (3 points) Each of the following choices lists three steps from the accounting cycle. Which of these sets of steps correctly follows the order we discussed for one fiscal period? (AC 7) Identify transactions, create the financial statements, make the trial balance. Make closing entries, make an adjusted trial balance, identify transactions. Make journal entries, post journal entries to the ledger, make closing entries. (3 points) Kaiser Co. counted inventory on December 31, 2019 and had $2,490,000 worth of inventory on their books. Their records indicate that they purchased $18,675,000 worth of inventory during the year and that they sold $20,542,500 worth of inventory during the year. How much inventory did they have on January 1 , 2019? (AC 8) $2,490,000 $4,357,500 $622,500 $18,675,000 (3 points) Which of the following is the primary benefit of using the worksheet method we discussed in the videos for converting cash to accruals? (AC 29) To match expenses and revenues. To calculate the correct value of cash flow from investing activities. To change from cash to accruals or from accruals to cash. To determine the correct value of cost of good sold during the period. one way that we can view someone's personality is to assess his or her Use TjMaxx as the retail store and describe and discuss theirlocation, transition zone, and traffic flow relating to bothConsumer Behavior and Why We Buy Use an ICE table to determine Kc. For the reaction: 2H 2 S( g)2H 2 ( g)+S 2 ( g) When 0.200 molH 2 S was put into a 5.0 L vessel and heated to 1132 C, it gave an equilibrium mixture containing 0.0345 mol S 2 . What is the value of Kc at this temp? Question 2 Use an ICE table to determine Kc for the following balanced general reaction: 2X( g)3Y( g)+4Z( g) A sample consisting of 0.500 mol of x is placed into a system with a volume of 0.750 liters. At equilibrium, the amount of sample x is known to be 0.350 mol. An example of a gliding/plane type synovial joint would be?Select one: a. the elbow joint. b. the posterior intervertebral joints c. the superior radio-ulnar joint. d. the shoulder joint. e. the metacarpophalangeal joints. Distinguish between the locations and tissues of the periosteum and those of the endosteum. How are these structural differences related to the locations and functions of these two types of bone? From your observations, how does the marrow in the medullary cavity compare with the marrow in the spaces of the spongy bone? Suppose you will travel to Switzerland and need CHF10,000 foryour stay. Your bank quotes you .7640-.90/CHF. How many USD willyou need? As the financial advisor to All Star Manufacturing you are evaluating the following new investment in a manufacturing project: - The project has a useful life of 8 years. Land costs $10m and is estimated to have a resale value of $20m at the completion of the project. Buildings cost $12m, with allowable depreciation of 6% pa reducing balance and a salvage value of $10m. Equipment costs $5m, with allowable depreciation of 10% pa reducing balance and a salvage value of $1m. An investment allowance of 20% of the equipment cost is available. Revenues are expected to be $15m in year one and rise at 5% pa. Cash variable costs are estimated at 30% of revenue. Cash fixed costs are estimated at $3m pa. Managerial salaries of $800,000 will be allocated to the project, but these managerial positions will be unaffected by the acceptance of the project. An amount of $200,000 has been spent on a feasibility study for the new project. The project is to be partially financed with a loan of $13.5m to be repaid annually with equal instalments at a rate of 5% pa over 8 years. Except for initial outlays, assume cash flows occur at the end of each year. The tax rate is 30% and is payable in the year in which profit is earned. The after-tax required return for the project is 11% pa. Required Calculate the NPV. Is the project acceptable? Why or why not? Explain and defend your processes, answer, and calculations clearly. Conduct a sensitivity analysis showing how sensitive the project is to revenues, fixed costs and to the required rate of return. Your client took a $750,500 mortgage with ABC lender Inc. The mortgage now has an outstanding balance of 600,500 . Down payment must show 1.5% of purchase price fore closing cost in bank account. Based on this how much of lump sum preparment can client make? a) $120,100 b) $150,100 c) $120,000 d) $150,00 John is a mortgage agent whose brother has recently run into some finandal dificaliy tecause he has bog his job. His brother has no savings and needs money to pay his monthly bills buy food, etc. He oners tos own home with approximately 35% equity and is asking john to refinance his house john televes touthe can afford to make his brother's payments until his brother finds another job, but also hons taktewem qualify if he goes on the mortgage with his brother. John feels that he can get this mortgso aperoed by lender using the lender's stated income program because the lender will not require proof di hane Gien this scenario which of the following statements is correct? Select one; a. John's brother has enough equity to be able to afford the payments so pohn should arrange this mortgage b. Because this mortgage doesn't require proof of income john should arrange ths moregse c. Because john will make the payments for his brother he should arrange this mortage d. Arranging this mortgage will require john to commit fraud so he should not arrange tis moregse how would an increase in extracellular k+ affect repolarization? Jenny is a consumer who likes to drink juice and seltzer. The price of liters of juice and the price of liters of seltzer are each $2 per liter. Suppose her budget for drinks for the month is $60. (Assume that Jenny believes that juice and seltzer are neither perfect complements nor perfect substitutes.) If you are unable to upload this answer, then please email it to me as soon as you finish the exam. 1. On a well labeled diagram, plot Jenny's initial budget constraint and her utility maximizing indifference curve. Place juice on the vertical axis and seltzer on the horizontal axis. Label the initial budget constraint as BC1 and the initial indifference curve as U1. 2. Suppose the price of seltzer increases by 50%. Plot the new budget constraint as BC2. 3. Now, suppose Jenny believes that juice and seltzer are complementary goods. Draw a utility maximizing indifference curve for the new budget constraint that reflects this fact, and label it U2. Declining FCF Growth Valuation Brushy Mountain Mining Company's coal reserves are being depleted, so its sales are falling. Also, environmental costs increase each year, so its costs are rising. As a result, the company's free cash flows are declining at the constant rate of 7% per year. If its current free cash flow (FCF0) is $6 million and its weighted average cost of capital (WACC)) is 10%, what is the estimated value of Brushy Mountain's value of operations? Do not round intermediate calculations. Enter your answer in millions. For example, an answer of $1 million should be entered as 1, not 1,000,000. Round your answer to two decimal places $ million Determine the number of significant figures for the following: 0.098200 has significant figure(s). 1.6810 4 has significant figures(s). 78,000,120 has significant figure(s). 1.008 has significant figure(s). The theoretical mass percent of water in a hydrate is calculated as follows: molar mass hydrate n molar mass H 2 O 100%= mass % water in hydrate - Calculate the mass % of water in the first hydrate, show work and round answer to 2 decimal places: 117.3+3097+64.00+126.112 126.112 = 338.382 126.112 100%=34.269121.88=37.27% - Calculate the mass \% of water in the second hydrate, show work and round answer to 2 decimal places: - Calculate the mass % of water in third hydrate, show work and round answer to 2 decimal places: 18.016 2(22.99)+1201+3(1600)+(18.016) 18.016 + 45.98+12.01+48+18.016 100% = 124.006 18.016 =0.1452832927100%=14.53% Calculations: Verify the mole-to-mole ratio of water to anhydrate for your first unknown. To get full credit: show units all through calculations and track significant figures by underlining them. Use an extra 3 digits beyond the proper number of significant figures in all calculations. Numbers recorded in tables should be rounded to the proper number of significant figures. m. mass of H 2 O=10.052 g/m 1. Determine the identity of your unknown based on the mass percent of water and write it below. Include H 2 O. K 3 PO 4 FH 2 O= Patassium Phospate Heptahydrate 2. What is the mass of water that evaporated? 58.069 g57.345=0.724 g 3. Use the periodic table to find the molar mass of water? Include units: g/mol. H 2 O molar mass = 18,01528 g/mol 4. Divide mass of water by molar mass of water. Show work and include units. Do NOT round at this point. 5. What is the mass of the anhydrate? This is the substance with no water, so subtract the mass of the water from the unknown. Unkenoun mass-water mass - was - 1.507=0.724g= 0.78 g.78 g 6. What is the molar mass of the anhydrate? Use the periodic table. 7. Divide mass of anhydrate by molar mass of anhydrate. Show work and include units. Do NOT round at this point. 8. Divide the moles of water by the moles of anhydrate. 9. Round off X to a whole number and write the chemical reaction for the hydrate. Table 3: Waters of Coystallization Summary