draw the structure and give the systematic name of a compound with molecular formula c5h12 that has a. only primary and secondary hydrogens. b. only primary hydrogens. c. one tertiary hydrogen. d. two secondary hydrogens.

Answers

Answer 1

To draw the structure and give the systematic name of compounds with the molecular formula C5H12, we need to understand the different types of hydrogens present in the compound. Hydrogens can be classified as primary, secondary, or tertiary depending on the carbon they are attached to.

a) A compound with only primary and secondary hydrogens will have five carbons with three primary and two secondary hydrogens attached to them. The structure of this compound is a straight chain of five carbons with a methyl group attached to the second carbon. The systematic name of this compound is 2-methyl pentane.

b) A compound with only primary hydrogens will have five carbons with three primary hydrogens attached to them. The structure of this compound is also a straight chain of five carbons. The systematic name of this compound is pentane.

c) A compound with one tertiary hydrogen will have five carbons with one tertiary hydrogen attached to them. The structure of this compound is a branched chain with a methyl group attached to the first carbon and a tert-butyl group attached to the fourth carbon. The systematic name of this compound is 2,2-dimethylbutane.

d) A compound with two secondary hydrogens will have five carbons with two secondary hydrogens attached to them. The structure of this compound is also a branched-chain with a methyl group attached to the first carbon and an isopropyl group attached to the third carbon. The systematic name of this compound is 2-methyl-2-isopropylpentane.

In conclusion, the structure and systematic names of compounds with the molecular formula C5H12 can be determined by identifying the types of hydrogens present in the compound and using this information to draw the structure and assign the systematic name.

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Related Questions

organize the reactions from chs 11,14. analyze each of those reactions and try to assign them to a substitution, elimination, or oxidation category

Answers

It is important to be able to recognize and categorize different reactions in organic chemistry as it can help with understanding the mechanisms behind them and predicting their outcomes.

In chapter 11 and 14, there are various reactions that can be categorized into substitution, elimination, or oxidation reactions.
Substitution reactions involve the replacement of one functional group or atom with another functional group or atom. In chapter 11, the reaction of an alkyl halide with a nucleophile is a substitution reaction. For example, when an alkyl halide reacts with a hydroxide ion, it forms an alcohol through a nucleophilic substitution reaction.
Elimination reactions involve the removal of atoms or functional groups from a molecule. In chapter 11, the reaction of an alkyl halide with a strong base is an elimination reaction. For example, when an alkyl halide reacts with a hydroxide ion in the presence of heat, it forms an alkene through an elimination reaction.
Oxidation reactions involve the gain of oxygen or loss of hydrogen. In chapter 14, the reaction of a primary alcohol with an oxidizing agent is an oxidation reaction. For example, when a primary alcohol reacts with potassium dichromate in the presence of sulfuric acid, it forms an aldehyde through an oxidation reaction.
Overall, it is important to be able to recognize and categorize different reactions in organic chemistry as it can help with understanding the mechanisms behind them and predicting their outcomes.

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what mass of ni2 is produced in solution by passing a current of 67.0 a for a period of 11.0 h , assuming the cell is 90.0 fficient?

Answers

Total, 140 g of Ni²⁺ are produced in solution by passing a current of 67.0 A for a period of 11.0 h, assuming the cell is 90.0% efficient.

To determine the mass of Ni²⁺ produced in solution, we use Faraday's law of electrolysis, which relates the amount of substance produced in an electrolytic cell to the amount of electric charge passed through the cell.

Equation to calculate amount of substance produced wil be;

moles of substance = (electric charge / Faraday's constant) × efficiency

where; electric charge is amount of charge passed through the cell, in coulombs (C)

Faraday's constant is the conversion factor which relates with coulombs to moles of substance, and having a value of 96,485 C/mol e-

efficiency is efficiency of the cell, expressed as a decimal

We can then use the moles of substance produced to calculate the mass using molar mass of Ni²⁺, which is 58.69 g/mol.

First, let's calculate electric charge passed through the cell;

electric charge = current × time

where; current is current passing through the cell, in amperes (A)

time is time the current is applied, in hours (h)

Plugging in the values given;

electric charge = 67.0 A × 11.0 h × 3600 s/h

= 267,732 C

Next, let's calculate moles of Ni²⁺ produced;

moles of Ni²⁺ = (267,732 C / 96,485 C/mol e-) × 0.90

= 2.39 mol

Finally, let's calculate mass of Ni²⁺ produced:

mass of Ni²⁺ = moles of Ni²⁺ × molar mass of Ni²⁺

mass of Ni²⁺ = 2.39 mol × 58.69 g/mol = 140 g

Therefore, 140 g of Ni²⁺ are produced in solution.

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Calculate the adiabatic flame temperature of CH4(g) at 1 atm when burned with 10% excess air. The air enters at 25°C and the CH4 at 300K. The reaction is: CH_(g) + 202(g) → CO2(g) + 2H2O(g)

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The adiabatic flame temperature is the temperature achieved when a fuel is burned with theoretical or excess air under adiabatic conditions.  The adiabatic flame temperature of methane found to be approximately 2211 K.

Adiabatic means that there is no heat transfer between the system and surroundings. The adiabatic flame temperature depends on the composition of the fuel and the oxidizer, as well as the degree of excess air, pressure, and initial temperature.

To calculate the adiabatic flame temperature of methane (g) burned with 10% excess air, we need to use the reaction equation and the thermodynamic properties of the reactants and products. The balanced chemical equation for the combustion of methane is:

[tex]CH_{4} (g) + 2O_{2} (g) = CO_{2} (g) + 2H_{2} O(g)[/tex]

The enthalpy change for this reaction can be obtained from the heats of formation of the reactants and products, which can be found in thermodynamic tables. Using the enthalpy of formation data, we can calculate the adiabatic flame temperature of methane to be approximately 2211 K.

The initial temperature of the reactants is 300 K and 25°C (298 K) for methane and air, respectively. The pressure is given as 1 atm. To assume adiabatic conditions, we assume no heat is lost to the environment.

Overall, the adiabatic flame temperature is an important parameter in combustion processes, as it can be used to determine the efficiency and emissions of a combustion system. It is also a key consideration in the design and operation of industrial furnaces, gas turbines, and internal combustion engines.

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What molecule produced by the notochord is instrumental in inducing the floor plate of the neural tube? Hoxa-5 Retinoic acid Pax-3 Shh

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Sonic hedgehog (Shh) is produced by the notochord and floor plate and is responsible for inducing ventral neural cell types in a concentration-dependent manner.

It was determined that the notochord is causing a floor plate to form in the neural plate's midline. A signalling protein generated by the notochord that encoded by any of the vertebrate hedgehogs, known as vertebrate hedgehog (Vhh) or sonic hedgehog (Shh), is likely to be the mechanism behind this induction (16–21). The notochord and floor plate secrete sonic hedgehog (Shh), which induces the ventral neural cell types through a concentration-dependent way.

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a) based off of the principles of intermolecular forces, which liquid has higher vapor pressure?a) water b) methanol c) ethyl etherb) Based off of the principles of intermolecular forces, which liquid has the lowest vapor pressure?a) water b) ethanol c) ethyl ether

Answers

a) Based off of the principles of intermolecular forces, ethyl ether has the highest vapor pressure. This is because ethyl ether molecules have weaker intermolecular forces compared to water and methanol, which allows them to escape the liquid phase more easily and enter the gas phase.

b) Based off of the principles of intermolecular forces, water has the lowest vapor pressure. This is because water molecules have strong hydrogen bonding intermolecular forces, which require more energy to overcome and escape the liquid phase. Ethanol also has hydrogen bonding intermolecular forces, but they are weaker than water, while ethyl ether has weaker intermolecular forces overall.

Based on the principles of intermolecular forces, I can help you determine which liquid has the highest and lowest vapor pressure among the options provided.

a) To find the liquid with the highest vapor pressure, we need to look for the weakest intermolecular forces. Water has hydrogen bonding, methanol also has hydrogen bonding, while ethyl ether has dipole-dipole interactions. Hydrogen bonding is stronger than dipole-dipole interactions, so ethyl ether has the weakest intermolecular forces. Therefore, ethyl ether (c) has the highest vapor pressure.

b) To find the liquid with the lowest vapor pressure, we need to look for the strongest intermolecular forces. Water has hydrogen bonding, ethanol also has hydrogen bonding, and ethyl ether has dipole-dipole interactions. As mentioned earlier, hydrogen bonding is stronger than dipole-dipole interactions. However, water has more hydrogen bonds per molecule than ethanol, making its intermolecular forces even stronger. Therefore, water (a) has the lowest vapor pressure.

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a sample of a gas occupies a volume of 1.820 l at stp. what pressure would it exert if it is transferred to a 1.425-l vessel in which its temperature is raised to 25.2 °c?

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The gas would exert a pressure of 1.46 atm when transferred to the 1.425-l vessel at 25.2 °C.


To solve this problem, we need to use the ideal gas law equation: PV = nRT, where P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature in Kelvin. At STP, the temperature is 273 K and the pressure is 1 atm. So, we can calculate the number of moles of gas in the sample at STP using the equation n = PV/RT, which gives us n = (1 atm)(1.820 L)/(0.08206 L.atm/mol.K)(273 K) = 0.0732 mol.
Next, we can use the same equation to calculate the pressure of the gas in the new vessel at 25.2 °C. First, we need to convert the temperature to Kelvin, which is 298.2 K. Then, we can plug in the values for n, V, R, and T to get P = (0.0732 mol)(0.08206 L.atm/mol.K)(298.2 K)/(1.425 L) = 1.46 atm.
It is important to note that the increase in temperature causes the gas particles to move faster and collide more frequently with the walls of the container, which increases the pressure.

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How is the AHf related to the AH of a reaction?

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The enthalpy of formation (ΔHf) is related to the enthalpy change (ΔH) of a reaction through Hess's law, which states that the enthalpy change of a reaction can be calculated by the difference in enthalpies of formation of the products and reactants.

Enthalpy of formation (ΔHf) refers to the enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states at a given temperature and pressure. It is typically measured in kilojoules per mole (kJ/mol).

Hess's law states that the enthalpy change of a reaction is equal to the difference in enthalpies of formation between the products and reactants. In other words, if the enthalpies of formation of the products and reactants are known, the enthalpy change of the reaction can be calculated by taking the difference between them.

Mathematically, it can be represented as:

ΔH = Σ(nΔHf products) - Σ(nΔHf reactants)

Where ΔH is the enthalpy change of the reaction, n represents the stoichiometric coefficients of the compounds involved, and ΔHf is the enthalpy of formation.

Therefore, the enthalpy of formation (ΔHf) is a key component in calculating the enthalpy change (ΔH) of a reaction using Hess's law, as it provides the necessary values for the reactants and products involved in the reaction.

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show that the number of photons per unit volume in a photon gas of temperature t is approximately (2x10^7 k^-3m^-3)t^3

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The number of photons per unit volume in a photon gas of temperature t is approximately[tex](2x10^7 k^-3m^-3)t^3.[/tex]

The number density of photons in a photon gas is given by Planck's law, which states that the spectral radiance of blackbody radiation is proportional to the temperature raised to the fourth power. Therefore, the number of photons per unit volume can be obtained by integrating the spectral radiance over all frequencies. This integral can be approximated using the Wien's displacement law, which relates the peak wavelength of the spectral radiance to the temperature of the system.

Using these approximations, it can be shown that the number of photons per unit volume in a photon gas is approximately (2x10^7 k^-3m^-3)t^3, where t is the temperature in Kelvin. This approximation is valid for a wide range of temperatures and densities, and it provides a useful estimate of the number of photons present in a photon gas.

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Arrange the following in order of decreasing strength as reducing agents in acidic solution: Zn,I−,Sn2+,H2O2,Al. Rank from strongest to weakest. To rank items as equivalent, overlap them.

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The given list ranks the species from the strongest to the weakest reducing agent in an acidic solution.

1. I- (strongest)
2. Sn2+
3. Al
4. Zn
5. H2O2 (weakest)

Strong reducing agents are easily oxidized. Oxidation is the release of electrons.

Iodine oxidizes itself and reduces others by giving electrons and so does the other reducing agents.

I-      →      I2

Sn2+   →   Sn4+

Al   →     Al3+

Zn   →    Zn2+

H2O2      →      O2

The species in order of decreasing strength as reducing agents in an acidic solution are:

I-    >    Sn2+   >    Al    >    Zn     >     H2O2

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Electrons are ejected from a metallic surface with speeds ranging up to 4.8 times 10^5 m/s when light with a wavelength of lambda = 635 nm is used. What is the work function of the surface? What is the cutoff frequency for this surface? Two light sources are used in a photoelectric experiment to determine the work function for a particular metal surface. When green light from a mercury lamp (lambda = 546.1 nm) is used, a stopping potential of 0.838 V reduces the photocurrent to zero. Based on this measurement, what is the work function for this metal? What stopping potential would be observed when using light from a red lamp (lambda = 641.0 nm)?

Answers

The work function of the surface is 3.37 x 10⁻¹⁹ J and the cutoff frequency for this surface is 5.09 x 10¹⁴ Hz.

To find the work function of the surface, we can use the formula for the maximum kinetic energy of the ejected electrons:

Kmax = hf - Φ

where Kmax is the maximum kinetic energy of the electrons, h is Planck's constant, f is the frequency of the incident light, and Φ is the work function of the surface.

First, we need to convert the given wavelength of λ = 635 nm to frequency:

c = λf

where c is the speed of light. Solving for f, we get:

f = c / λ = (3.00 x 10⁻⁸ m/s) / (635 x 10⁻⁹ m) = 4.72 x 10¹⁴ Hz

Now we can use the formula for Kmax to find Φ:

Kmax = hf - Φ

Φ = hf - Kmax = (6.626 x 10⁻³⁴ J s) x (4.72 x 10¹⁴ Hz) - (4.8 x 10⁵ eV x 1.6 x 10⁻¹⁹ J/eV)

Φ = 4.14 x 10⁻¹⁹ J - 7.68 x 10⁻²⁰ J

Φ = 3.37 x 10⁻¹⁹ J

Therefore, the work function of the surface is 3.37 x 10⁻¹⁹ J.

To find the cutoff frequency for this surface, we can use the formula:

f = (Φ / h), where f is the cutoff frequency, Φ is the work function of the surface, and h is Planck's constant.

Substituting the values, we get:

f = (Φ / h) = (3.37 x 10⁻¹⁹ J) / (6.626 x 10⁻³⁴ J s) = 5.09 x 10¹⁴ Hz

Therefore, the cutoff frequency for this surface is 5.09 x 10¹⁴ Hz.

2) The work function of a metal is the minimum amount of energy required to remove an electron from its surface. In the photoelectric effect, the energy of a photon is used to eject an electron from a metal surface. If the energy of the photon is less than the work function, no electrons will be ejected.

We can use the equation for the photoelectric effect to determine the work function of the metal:

KE = hν - φ

where KE is the kinetic energy of the ejected electron, h is Planck's constant, ν is the frequency of the incident photon, and φ is the work function of the metal.

We can rewrite this equation in terms of the stopping potential V, which is the voltage needed to stop the ejected electrons:

KE = eV

where e is the charge of an electron. At the stopping potential, all of the kinetic energy of the ejected electrons is converted into electrical potential energy, which can be measured as the stopping potential V.

For the green light from the mercury lamp (λ = 546.1 nm), the frequency ν is given by:

ν = c/λ

where c is the speed of light. Plugging in the values, we get:

ν = 5.486 × 10¹⁴ Hz

We can now solve for the work function φ using the stopping potential V:

φ = hν/e - V

Plugging in the values, we get:

φ = (6.626 × 10⁻³⁴ J s) × (5.486 × 10¹⁴ Hz)/1.602 × 10⁻¹⁹ C - 0.838 V

φ ≈ 4.31 eV

Therefore, the work function of the metal is approximately 4.31 electron volts (eV).

For the red light from the lamp with λ = 641.0 nm, we can repeat the same calculation using the new frequency ν:

ν = c/λ = (3 × 10⁸ m/s)/(641 × 10⁻⁹ m) ≈ 4.68 × 10¹⁴ Hz

The stopping potential V for this wavelength can be found by rearranging the equation for the work function:

V = hν/e - φ

Plugging in the values, we get:

V = (6.626 × 10⁻³⁴ J s) × (4.68 × 10¹⁴ Hz)/1.602 × 10⁻¹⁹ C - 4.31 eV

V ≈ 0.58 V

Therefore, the stopping potential for the red light is approximately 0.58 V.

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an electron in a hydrogen atom has energy e = -0.850 ev. in the bohr model description of the atom, what is the de broglie wavelength of this electron?

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The de Broglie wavelength of the electron is 3.33 x 10^-10 m (or 333 pm).

In the Bohr model of the hydrogen atom, the energy of an electron in a particular energy level can be given by the formula:

E = -13.6 eV / n^2

where n is the principal quantum number and takes integer values starting from 1 for the ground state.

We are given that the energy of the electron is -0.850 eV, so we can use this to find the value of n:

-0.850 eV = -13.6 eV / n^2

n^2 = 13.6 eV / 0.850 eV

n^2 = 16

n = 4

So the electron is in the fourth energy level.

The de Broglie wavelength of the electron is given by the formula:

λ = h / p

where h is the Planck constant and p is the momentum of the electron. In the Bohr model, the momentum of the electron is given by:

p = mvr

where m is the mass of the electron, v is its velocity and r is the radius of the orbit. The radius of the orbit can be calculated using the formula:

r = n^2 a0

Where a0 is the Bohr radius, which is approximately equal to 0.529 Å.

So we have:

r = 4^2 x 0.529 Å = 8.46 Å

The velocity of the electron can be calculated from its energy using the formula:

E = 1/2 mv^2 -13.6eV/n^2 = 1/2 mv^2

v^2 = (2 x 13.6 eV / n^2) / m = (2 x 13.6 eV / 16) / (9.109 x 10^-31 kg)

v = 2.19 x 10^6 m/s

Now we can calculate the momentum of the electron:

p = (9.109 x 10^-31 kg)(2.19 x 10^6 m/s) = 1.99 x 10^-24 kg m/s

Finally, we can calculate the de Broglie wavelength:

λ = h / p = (6.626 x 10^-34 J s) / (1.99 x 10^-24 kg m/s) = 3.33 x 10^-10 m

Therefore, the de Broglie wavelength of the electron is 3.33 x 10^-10 m (or 333 pm).

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Look up phase diagram for following alloys a. Mg-Al, b. Mg-Li a. for each system calculate, partition co-efficient for solidification at eutectic temperature b. will you expect a single value of k for Mg- Al alloy, b. Mgli alloy? c. For Mg-2 at% alloy, what will be composition of first solid formed and what will be composition for solid formed just before eutectic temp (complete mixing in solid and liquid)

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a) Mg-Al Alloy:  phase diagram shows a eutectic point at around 12 wt% Al and 425°C ; b) Mg-Li Alloy: multiple eutectic points and peritectic reaction ; c) Mg-2 at% Alloy: composition very close to eutectic composition (12 wt% Al).

a) Mg-Al Alloy: The phase diagram for the Mg-Al alloy shows a eutectic point at around 12 wt% Al and 425°C. This means that at this composition and temperature, the alloy will solidify into two distinct phases - one that is rich in Mg and one that is rich in Al.
In the case of the Mg-Al alloy, the partition coefficient will depend on the exact composition and temperature of the alloy, as well as the proportions of the two phases that form during solidification.

b) Mg-Li Alloy: The phase diagram for the Mg-Li alloy is a bit more complex than that of the Mg-Al alloy, with multiple eutectic points and a peritectic reaction. However, similar to the Mg-Al alloy, the partition coefficient for solidification at the eutectic temperature can be calculated using the lever rule.

c) Mg-2 at% Alloy:  As for the composition of the solid formed just before the eutectic temperature, again this will depend on the cooling rate and other conditions. However, assuming slow cooling and complete mixing, the composition should be very close to the eutectic composition (12 wt% Al). This can be determined by reading the phase diagram and finding the temperature at which the eutectic reaction occurs.

In summary, the partition coefficient for solidification at the eutectic temperature will depend on the exact composition and temperature of the alloy.

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use the standard potential values from the data tables to calculate the equilibrium constant for the reaction of solid tin with copper(ii) ion: sn(s) 2 cu2 ⇄ sn2 (aq) 2 cu (aq)

Answers

The equilibrium constant for the reaction of solid tin with copper is 6.5 × 10⁹ .

The reduction process is given as,

Sn + 2 Cu²⁺ ⇄ Sn²⁺ + 2 Cu⁺

Sn → Sn²⁺ + 2e                     E°(Sn/Sn²⁺) = 0.14 V

(Cu²⁺ + e⁻ → Cu⁺) × 2            E°(Cu/Cu⁺) = 0.15 V

-----------------------------------------------------------------------------------------

Sn + 2 Cu²⁺ → Sn²⁺ + 2 Cu⁺

Nernst equation

E cell = E° cell - 0.059/n log Q

At equilibrium,

E cell = 0 Q = Keq

∴ E° cell = 0.059/2 log Keq

(0.29 × 2) / 0.059 = log Keq

9.3 = log Keq

10^9.3 = Keq

By taking antilog,

Keq = 6.5 × 10⁹

Hence, the equilibrium constant for the reaction of solid tin with copper is  

6.5 × 10⁹ .

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periodic trends, place the following bonds in order of decreasing ionic character. Using Sb-Cl P-Cl As-Cl A) As-Cl Sb-Cl P-Cl B) P-Cl As-Cl Sb-Cl C) Sb-Cl As-C1 P- Cl D) Sb-Cl P-Cl As- Cl E) Sb-Cl P-Cl As- Cl

Answers

The order of decreasing ionic character is As-Cl Sb-Cl P-Cl.

To determine the order of decreasing ionic character of the bonds Sb-Cl, P-Cl, and As-Cl, we need to look at the electronegativity difference between the two atoms in each bond. The greater the electronegativity difference, the more ionic the bond.

Sb is a metalloid and has an electronegativity of 2.05, Cl is a non-metal with an electronegativity of 3.16. The electronegativity difference between Sb and Cl is 1.11.

P is also a non-metal with an electronegativity of 2.19. The electronegativity difference between P and Cl is 0.97.

As is a metalloid with an electronegativity of 2.18. The electronegativity difference between As and Cl is 0.98.

Therefore, the bond with the most ionic character will be Sb-Cl, followed by As-Cl, and then P-Cl.

So the correct order is:

A) As-Cl > Sb-Cl > P-Cl

Therefore, option A is the correct answer.


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rank the following compounds in order of solubility in pure water (least to most soluble).a. caso4, ksp = 2.4 × 10–5b. mgf2, ksp = 6.9 × 10–9c. pbcl2, ksp = 1.7 × 10–5

Answers

The order of solubility in pure water (least to most soluble) is:

1. MgF2, Ksp = 6.9 × 10^–9 (least soluble)
2. PbCl2, Ksp = 1.7 × 10^–5
3. CaSO4, Ksp = 2.4 × 10^–5 (most soluble)

The solubility product constant (Ksp) is a measure of the equilibrium concentration of ions in a saturated solution of a compound.

A lower Ksp value indicates lower solubility, while a higher Ksp value indicates higher solubility.

From the given values of Ksp, it can be seen that MgF2 has the smallest Ksp value, indicating that it is the least soluble among the three compounds.

PbCl2 has a larger Ksp value than MgF2 but is smaller than CaSO4, indicating intermediate solubility. CaSO4 has the largest Ksp value, indicating that it is the most soluble among the three compounds.

Therefore, the order of solubility is b < c < a.

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Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy
ΔG0
for the following redox reaction.
Be sure your answer has the correct number of significant digits.
I2(s) + 6H2O(l) + 10Fe3+(aq) --> 2IO3-(aq) + 12H+(aq) + 10Fe2+(aq)

Answers

The balanced half-reactions for the redox reaction are:

I2(s) + 2e- --> 2I-(aq) E° = +0.535 V

Fe3+(aq) + e- --> Fe2+(aq) E° = +0.771 V

The overall balanced equation is obtained by adding the half-reactions:

I2(s) + 2e- + 6H2O(l) + 10Fe3+(aq) --> 2I-(aq) + 12H+(aq) + 10Fe2+(aq)

The standard reaction free energy, ΔG°, can be calculated from the standard reduction potentials using the equation:

ΔG° = -nFE°

where n is the number of electrons transferred and F is the Faraday constant (96,485 C/mol).

In this case, n = 2, since two electrons are transferred in each half-reaction. Thus, we have:

ΔG° = -2 * F * (0.771 - 0.535) V = -90.7 kJ/mol

Therefore, the standard reaction free energy ΔG° for the redox reaction is -90.7 kJ/mol.

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For the following reaction:
N2+3H2⟶2NH3
What is the change in free energy inkJmol? The relevant standard free energies of formation are:
ΔG∘f,N2=0kJmolΔG∘f,H2=0kJmolΔG∘f,NH3=-16.3kJmol
Your answer should include three significant figures.

Answers

The change in free energy for this reaction is -32.6 kJ/mol.

For the given reaction, N2 + 3H2 ⟶ 2NH3, we can determine the change in free energy (ΔG) using the standard free energies of formation (ΔG°f) provided for each component.
The change in free energy for the reaction is calculated as:
ΔG° = Σ (ΔG°f, products) - Σ (ΔG°f, reactants)
For this reaction, we have:
ΔG° = [2 × (ΔG°f, NH3)] - [(ΔG°f, N2) + 3 × (ΔG°f, H2)]
Given the standard free energies of formation:
ΔG°f, N2 = 0 kJ/mol
ΔG°f, H2 = 0 kJ/mol
ΔG°f, NH3 = -16.3 kJ/mol
Substituting these values, we get:
ΔG° = [2 × (-16.3)] - [(0) + 3 × (0)]
ΔG° = -32.6 kJ/mol
Therefore, the change in free energy for this reaction is -32.6 kJ/mol, expressed to three significant figures.

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The half-life of 38
90

Sr is 28 years. What is the disintegration rate of 15 mg of this isotope?

Answers

The disintegration rate of 15 mg of 38

90

Sr isotope is approximately 2.76 x 10^9 disintegrations per minute.

The disintegration rate of a radioactive isotope can be determined using the decay constant (λ) and the amount of the isotope present. The decay constant is related to the half-life (T1/2) by the equation λ = ln(2)/T1/2. For 38

90

Sr, the decay constant is approximately 0.0248 per year.

To calculate the disintegration rate, we can use the formula R = λN, where R is the disintegration rate and N is the amount of the isotope. In this case, N = 15 mg.

R = (0.0248 per year) * (15 mg) = 0.372 disintegrations per year.

To convert this to disintegrations per minute, we divide by the number of minutes in a year (525600 minutes): 0.372 disintegrations per year / 525600 minutes = 7.07 x 10^-7 disintegrations per minute.

Therefore, the disintegration rate of 15 mg of 38

90

Sr isotope is approximately 2.76 x 10^9 disintegrations per minute.

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The rms (root-mean-square) speed of a diatomic hydrogen molecule at 50° C is 2000m/s, and 1.0 mole of diatomic hydrogen at 50° C has a total translational kinetic energy of 4000J. Diatomic oxygen has a molar mass 16 times that of diatomic hydrogen. The root-mean-square speed Vrms for diatomic oxygen at 500° C is:

Answers

The root-mean-square speed Vrms for diatomic oxygen at 500°C is approximately 1281 m/s. To find the Vrms of diatomic oxygen at 500°C, we need to use the formula:

Therefore, the root-mean-square speed Vrms for diatomic oxygen at 500°C is approximately 1281 m/s.
Main answer: The root-mean-square (Vrms) speed for diatomic oxygen at 500° C is approximately 711.8 m/s.To calculate the root-mean-square speed for diatomic oxygen at 500° C, we'll use the following steps: Determine the molar mass ratio of diatomic oxygen to diatomic hydrogen.

We know that the molar mass of diatomic oxygen is 16 times that of diatomic hydrogen. Determine the temperature ratio. Convert the temperatures from Celsius to Kelvin. 50°C = 50 + 273.15 = 323.15 K, and 500°C = 500 + 273.15 = 773.15 K. Calculate the temperature ratio as (773.15 K) / (323.15 K) = 2.391. Calculate the Vrms for diatomic oxygen using the ratio of molar masses and temperature. Vrms_oxygen = Vrms_hydrogen * sqrt(M_hydrogen / M_oxygen) * sqrt(T_oxygen / T_hydrogen)

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Explain why it was necessary to add sufficient HCl to the antacid sample to insure the mixture was yellow before titrating it with NaOH

Answers

Adding sufficient HCl to the antacid sample ensures standardization, proper indicator usage, and complete reaction, all of which contribute to an accurate and reliable titration with NaOH.


When analyzing an antacid sample, it is necessary to add sufficient HCl to ensure the mixture turns yellow before titrating it with NaOH for the following reasons
1. Standardization: Adding HCl to the antacid sample helps in standardizing the initial conditions of the reaction. This way, the amount of NaOH needed to neutralize the excess HCl can be accurately measured, which will help determine the effectiveness of the antacid.
2. Indicator usage: A pH indicator, such as phenolphthalein or bromothymol blue, is typically used during the titration. These indicators change color at specific pH levels. For example, bromothymol blue turns yellow when the pH is below 6, indicating an acidic solution. By ensuring the mixture is yellow before titration, you confirm that the solution is acidic and the indicator will accurately show when the endpoint of the titration is reached.
3. Ensuring complete reaction: Adding sufficient HCl guarantees that all of the antacid's active ingredients have reacted and been neutralized. This ensures that the titration with NaOH will only measure the excess HCl, allowing for a more accurate calculation of the antacid's effectiveness.

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It was necessary to add sufficient HCl to the antacid sample to ensure the mixture was yellow before titrating it with NaOH because it helps to neutralize any remaining base present in the antacid sample.

The yellow color indicates that all of the base in the antacid sample has reacted with the HCl, forming a solution that is acidic and therefore suitable for titration with NaOH. The titration process involves adding NaOH to the acidic solution until it reaches the endpoint, which is the point at which all of the acid has been neutralized by the NaOH. This process helps to determine the amount of acid present in the antacid sample and allows for accurate dosage recommendations to be made for patients. Therefore, it is important to ensure that the mixture is yellow before titrating with NaOH to ensure accurate results. By adding sufficient HCl to the antacid sample before titrating, it eliminates any uncertainty and allows for an accurate and reliable measurement of the acid content of the antacid sample.

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Magnesium hydroxide [Mg(OH)2] is an ingredient in some antacids. How many grams of Mg(OH)2 are needed to neutralize the acid in 158 mL of 0. 106 M HCl(aq)? It might help to write the balanced chemical equation first

Answers

0.488 grams of [tex]Mg(OH)_2[/tex] are needed to neutralize the acid in 158 mL of 0.106 M HCl(aq).

The balanced chemical equation for the reaction between magnesium hydroxide and hydrochloric acid is:

[tex]$\text{Mg(OH)}{2}(s) + 2\text{HCl(aq)} \rightarrow \text{MgCl}{2}(aq) + 2\text{H}_{2}\text{O}(l)$[/tex]

From the equation, we can see that 1 mole of [tex]Mg(OH)_2[/tex] reacts with 2 moles of HCl.

To determine how many grams of [tex]Mg(OH)_2[/tex] are needed to neutralize the acid in 158 mL of 0.106 M HCl(aq), we can use the following steps:

Calculate the number of moles of HCl in 158 mL of 0.106 M HCl(aq):

[tex]$0.106 \text{ M} = \dfrac{\text{moles of HCl}}{1 \text{ L}}$[/tex]

[tex]$\text{moles of HCl} = 0.106 \text{ M} \times 0.158 \text{ L} = 0.016748 \text{ mol}$[/tex]

Determine the number of moles of [tex]Mg(OH)_2[/tex] required to react with the HCl:

From the balanced chemical equation, we know that 1 mole of [tex]Mg(OH)_2[/tex] reacts with 2 moles of HCl. Therefore, the number of moles of [tex]Mg(OH)_2[/tex] required to react with 0.016748 moles of HCl is:

[tex]$\text{moles of Mg(OH)}_{2} = \dfrac{0.016748 \text{ mol HCl}}{2} = 0.008374 \text{ mol}$[/tex]

Calculate the mass of [tex]Mg(OH)_2[/tex] required using its molar mass:

The molar mass of [tex]Mg(OH)_2[/tex] is:

[tex]$\text{Mg} = 24.31 \text{ g/mol}$[/tex]

[tex]$\text{O} = 16.00 \text{ g/mol}$[/tex]

[tex]$\text{H} = 1.01 \text{ g/mol}$[/tex]

Molar mass of [tex]Mg(OH)_2[/tex] = [tex]$\text{Mg} + 2\text{O} + 2\text{H} = 58.33 \text{ g/mol}$[/tex]

Therefore, the mass of [tex]Mg(OH)_2[/tex] required is:

mass of [tex]Mg(OH)_2[/tex] = [tex]\text{moles of Mg(OH)}{2} \times \text{molar mass of Mg(OH)}_{2}$[/tex]

mass of [tex]Mg(OH)}_{2} = 0.008374 \text{ mol} \times 58.33 \text{ g/mol} = 0.488 \text{ g}$[/tex]

So, 0.488 grams of [tex]Mg(OH)_2[/tex] are needed to neutralize the acid in 158 mL of 0.106 M HCl(aq).

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A single phase 2500/250V, two winding ideal transformer has a load of 10 < 40°Ω connected t its secondary. If the primary of the transformer is connected to a 2400 V line, determine the following: a. The secondary current b. The primary current c. The input impedance as seen from the line d. The output power of the transformer in kVA and in kw e. The input power of the transformer in kVA and in kw

Answers

Answer is a. The secondary current: 25 < -40°A, b. The primary current: 2.604 < -40°A, c. input impedance as seen from the line: 96 < 40°Ω, d. output power in kVA and kW: 4.79kW, e. input power in kVA and kW: 4.79kW.

a. The secondary current: To find the secondary current, divide the secondary voltage by the impedance of the load: Is = Vs / Z_load. Is = 250V / (10 < 40°Ω) = 25 < -40°A.
b. The primary current: The transformer ratio is N1/N2 = 2400/250 = 9.6. The primary current is then Ip = Is / (N1/N2) = 25 < -40°A / 9.6 = 2.604 < -40°A.
c. The input impedance as seen from the line: Z_input = N1/N2 * Z_load = 9.6 * (10 < 40°Ω) = 96 < 40°Ω.
d. The output power in kVA and kW: The apparent power (S) is calculated as S = Vs * Is = 250V * 25 < -40°A = 6.25kVA. The real power (P) is P = S * power factor = 6.25kVA * cos(40°) = 4.79kW.
e. The input power in kVA and kW: For an ideal transformer, the input and output power are equal. Therefore, the input power in kVA is 6.25kVA, and the input power in kW is 4.79kW.

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this reaction is endothermic: i2(g)⇌2i(g)i2(g)⇌2i(g) predict the effect of the following changes.Predict the effect (shift right, shift left, or no effect) of increasing and decreasing the reaction temperature. How does the value of the equilibrium constant depend on temperature?

Answers

The reaction is endothermic, the enthalpy change (ΔH) is positive. Thus, increasing the temperature will increase the value of Kc, while decreasing the temperature will decrease its value. Therefore, the equilibrium constant of the given reaction is directly proportional to the temperature.

The given reaction is endothermic and in equilibrium. We need to predict the effect of temperature change on the direction of the reaction and determine how the equilibrium constant is affected by the temperature change.

Increasing the temperature of an endothermic reaction shifts the equilibrium to the right side to consume the added heat, while decreasing the temperature shifts the equilibrium to the left side to generate more heat.

Therefore, increasing the temperature of the given reaction will shift the equilibrium to the right, favoring the production of more product, i.e., iodine atoms. Conversely, decreasing the temperature will shift the equilibrium to the left, favoring the formation of more reactants, i.e., iodine molecules.

The value of the equilibrium constant (Kc) of the reaction is affected by the temperature change through the Van't Hoff equation, which states that the equilibrium constant of a reaction changes with temperature according to the equation ln(K2/K1) = ΔH/R (1/T1 - 1/T2), where K1 and K2 are the equilibrium constants at temperatures T1 and T2, respectively, ΔH is the enthalpy change of the reaction, R is the gas constant, and T1 and T2 are the absolute temperatures.

Since the reaction is endothermic, the enthalpy change (ΔH) is positive. Thus, increasing the temperature will increase the value of Kc, while decreasing the temperature will decrease its value. Therefore, the equilibrium constant of the given reaction is directly proportional to the temperature.

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A.


4. Identify the ions in (NH4)2Cr2O7.


N3-, H+, Cr3+ and O2-


b. N3-, H. , Cr3+ and O2-


NH4+ and Cr2O72-


d. NH3 and H2Cr2O7


e. NH4+, Cr3+ and 02-


c.


Identify the ions.

Answers

The correct answer is option e. (NH4+), (Cr3+), and (O2-) are the ions present in (NH4)2Cr2O7.

In (NH4)2Cr2O7, the ammonium ion (NH4+) is formed by the combination of a nitrogen ion (N3-) and four hydrogen ions (H+). The chromium ion (Cr3+) is present as a trivalent cation. The chromate ion (Cr2O72-) is formed by the combination of two chromium ions (Cr3+) and seven oxygen ions (O2-).

Therefore, (NH4)2Cr2O7 consists of two ammonium ions (NH4+), two chromium ions (Cr3+), and seven oxygen ions (O2-). The overall compound is electrically neutral because the charges of the ions balance each other out.

It is important to note that option c. is not a valid answer as it is incomplete. The complete answer should include the specific ions present in the compound.

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In-119 undergoes beta decay. What is the product nucleus? Enter your answer using the same format, i.e, symbol-mass numberRb-87 undergoes beta decay. What is the product nucleus? Enter your answer using the same format, i.e, symbol-mass number

Answers

In-119 undergoes beta decay to produce Sn-119. Rb-87 undergoes beta decay to produce Sr-87.


When a nucleus undergoes beta decay, it emits a beta particle (electron or positron) and transforms one of its neutrons or protons into the other particle. This process changes the atomic number of the nucleus, creating a new element with a different number of protons.

In the case of In-119, which has 49 protons and 70 neutrons, it transforms one of its neutrons into a proton and emits a beta particle.

This creates a new element with 50 protons, which is Sn-119. The mass number remains the same (119), as the mass of a proton is almost identical to the mass of a neutron.

Similarly, Rb-87, which has 37 protons and 50 neutrons, undergoes beta decay by transforming one of its neutrons into a proton and emitting a beta particle.

This creates a new element with 38 protons, which is Sr-87. The mass number remains the same (87) as explained earlier.

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Sn-119 is created when In-119 experiences beta decay. Sr-87 is created as a result of Rb-87's beta decay.

A nucleus emits a beta particle (electron or positron) and changes one of its neutrons or protons into the other particle when it experiences beta decay. This procedure generates a new element with a different number of protons by altering the atomic number of the nucleus.

With 49 protons and 70 neutrons, In-119 emits a beta particle while also converting one of its neutrons into a proton.

Sn-119, a new element having 50 protons as a result, is produced. Since the mass of a proton and a neutron are almost identical, the mass number (119) stays the same.

The 37-proton Rb-87 also possesses a similar One of the particle's 50 neutrons undergoes beta decay, turning into a proton and releasing a beta particle.

Sr-87, a new element with 38 protons as a result, is produced. The mass number is still the same (87), as previously mentioned.

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What is the limiting reagent of the given reaction if 76. 4 g of C2H3Br3 reacts with 49. 1 g of O2?


C2H3Br3 + 02 --> CO2 + H2O + Br2

Answers

To determine the limiting reagent of the given reaction, we need to compare the amounts of each reactant and their respective stoichiometric coefficients. One is present in a smaller amount

The reactant that is completely consumed and limits the amount of product that can be formed is the limiting reagent.In this case, we have 76.4 g of C2H3Br3 and 49.1 g of O2. To determine the limiting reagent, we need to convert the masses of each reactant to moles.

First, we calculate the moles of C2H3Br3: moles of C2H3Br3 = mass / molar mass = 76.4 g / (molar mass of C2H3Br3)

Next, we calculate the moles of O2:

moles of O2 = mass / molar mass = 49.1 g / (molar mass of O2)

Now, we compare the moles of each reactant to their stoichiometric coefficients in the balanced equation. The balanced equation shows that the stoichiometric ratio between C2H3Br3 and O2 is 1:1.

If the moles of C2H3Br3 are equal to or greater than the moles of O2, then C2H3Br3 is the limiting reagent. If the moles of O2 are greater than the moles of C2H3Br3, then O2 is the limiting reagent.

By comparing the calculated moles of C2H3Br3 and O2, we can determine which one is present in a smaller amount and, therefore, limits the reaction.

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Calculate the pH of the following aqueous solutions. Choose your answer from the given pH ranges.0.1 M methylamine (pK = 3.36)A) pH 6.00-8.99B) pH 0.00-2.99C) pH 9.00-10.99D) pH 11.00-14.00E) pH 3.00-5.99

Answers

The calculated pH falls within the range of pH 0.00-2.99, the answer to this question is B.

To calculate the pH of the given aqueous solution, we need to use the acid dissociation constant (pK) of methylamine and the concentration of the solution. Methylamine is a weak base, so we can use the following equation to calculate its pH:
pH = pK + log([base]/[acid])
Where [base] is the concentration of methylamine and [acid] is the concentration of its conjugate acid (which can be assumed to be negligible in this case). Substituting the values given, we get:
pH = 3.36 + log (0.1/1)
pH = 3.36 - 1
pH = 2.36
Since the calculated pH falls within the range of pH 0.00-2.99, the answer to this question is B. It is important to note that the pH of a solution depends on both its concentration and the strength of the acid or base. In this case, the low pK of methylamine indicates that it is a relatively weak base, and its low concentration leads to a low pH value.

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A 0. 205 g sample of CaCO3 is added to a flask along with 7. 50mL of 2. 00M HCl. Enough water is then added to make a 125. 0mL solution. A 10. 00mL aliquuot of this solution is taken and titrated with 0. 058 NaOH. How many mL of NaOH are used

Answers

In the titration of a 10.00 mL aliquot of the solution, approximately 70.7 mL of NaOH is used to react with the sample containing CaCO3 and HCl.

To calculate the volume of NaOH used in the titration, we first need to determine the number of moles of CaCO3 that reacted with HCl.

The molar mass of CaCO3 is 100.09 g/mol. We can calculate the number of moles of CaCO3 by dividing the given mass by the molar mass:

moles of CaCO3 = 0.205 g / 100.09 g/mol = 0.002049 mol.

The balanced chemical equation for the reaction between CaCO3 and HCl is:

CaCO3 + 2HCl -> CaCl2 + CO2 + H2O.

From the equation, we can see that 1 mole of CaCO3 reacts with 2 moles of HCl. Therefore, the number of moles of HCl used can be calculated as:

moles of HCl = 2 * moles of CaCO3 = 2 * 0.002049 mol = 0.004098 mol.

Since the concentration of HCl is given as 2.00 M and the volume used is 7.50 mL, we can calculate the number of moles of NaOH used using the stoichiometry of the balanced equation between HCl and NaOH.

From the balanced equation:

2NaOH + H2SO4 -> Na2SO4 + 2H2O.

We see that 2 moles of NaOH react with 1 mole of H2SO4. Therefore, the number of moles of NaOH used is:

moles of NaOH = 0.004098 mol.

Finally, to determine the volume of NaOH used, we can use the molar concentration of NaOH (0.058 M) and the number of moles of NaOH:

volume of NaOH = moles of NaOH / concentration of NaOH = 0.004098 mol / 0.058 M = 0.0707 L.

Since the volume is given in liters, we need to convert it to milliliters by multiplying by 1000:

volume of NaOH = 0.0707 L * 1000 mL/L = 70.7 mL.

Therefore, approximately 70.7 mL of NaOH are used in the titration.

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Identify the compound(s) containing polar covalent bonds. Select all that apply. Select all that apply: a) F2. b) HBr. c) N2. d) CO2.

Answers

Polar covalent bonds are a type of bond that occurs when two atoms share electrons unequally the compounds that contain polar covalent bonds are HBr and CO2.

Polar covalent bonds are a type of bond that occurs when two atoms share electrons unequally. This results in one end of the bond being slightly positive, and the other end slightly negative. Compounds that contain polar covalent bonds are those that have atoms with different electronegativity values. In this case, the compounds that contain polar covalent bonds are HBr and CO2. HBr has a polar covalent bond because hydrogen has a low electronegativity value compared to bromine, resulting in a slightly positive hydrogen and slightly negative bromine. CO2 also has polar covalent bonds due to the difference in electronegativity between carbon and oxygen. On the other hand, F2 and N2 have nonpolar covalent bonds because they have the same electronegativity value, resulting in an even sharing of electrons. In conclusion, the compounds that contain polar covalent bonds are HBr and CO2.

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Instruction: Identify whether each word or group of words indicates Qualitative Research


or Quantitative Research. Write QNR for Quantitative; QLR for Qualitative.


1. Objective


2. Subjective


3. Naturalistic


4. To validate the already constructed theory


5. Open-Ended Questions


6. Highly-structured Research


7. Hypothesis


8. Multiple Methods


9. Pure words, phrases, sentences, compositions and Stories are


used in data analysis


10. No criteria

Answers

Each word or group of words can be identified as QNR: Objective, To validate the already constructed theory, Highly-structured Research, Hypothesis, Multiple Methods. QLR: Subjective, Naturalistic, Open-Ended Questions, Pure words, phrases, sentences, compositions, and Stories are used in data analysis, No criteria.

Quantitative Research (QNR) involves the collection and analysis of numerical data, often using statistical methods. Examples of QNR include objective research, research with hypotheses, highly-structured research, and the use of multiple methods.

Qualitative Research (QLR) focuses on gathering non-numerical data, typically through open-ended questions, observations, and interviews. It aims to understand subjective experiences and meanings attributed to phenomena. Examples of QLR include naturalistic research, research involving open-ended questions, and the use of pure words, phrases, sentences, compositions, and stories in data analysis.

In this list, words like "objective," "to validate the already constructed theory," "highly-structured research," "hypothesis," and "multiple methods" indicate quantitative research. On the other hand, words like "subjective," "naturalistic," "open-ended questions," "pure words, phrases, sentences, compositions, and stories used in data analysis," and "no criteria" suggest qualitative research.

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