Explain the reason for the change in atomic radii across a period as well as down a group.

Answers

Answer 1

Atomic radii decrease across a period and increase down a group.

How does atomic radii change across periods and groups?

Across a period, atomic radii decrease due to the increase in the number of protons in the nucleus, which leads to a stronger attraction between the nucleus and the electrons in the same energy level. This increased attraction results in a tighter hold on the electrons, making the atomic radius smaller.

Down a group, atomic radii increase due to the addition of more energy levels. As the number of energy levels increases, the outermost electrons are farther away from the nucleus, leading to a weaker attraction between the nucleus and the electrons. The increased distance between the nucleus and the outermost electrons results in a larger atomic radius.

The atomic radius decreases across a period due to increased nuclear charge, and increases down a group due to an increase in the number of energy levels.

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Related Questions

draping at the beginning of a perm service should include a plastic cape and:

Answers

The draping at the beginning of a perm service should include a plastic cape and a towel or neck strip.

During a perm service, draping is an essential step to protect the client's clothing from any chemical spills or solutions. It also helps to ensure the client's comfort during the process. The draping process typically involves placing a plastic cape over the client's clothes and securing it with a clip or collar.

Additionally, a towel or neck strip should be placed around the client's neck to prevent any solution from running down their back. This helps to prevent any discomfort or irritation caused by the solution on the client's skin.

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A current of 3.44 A is passed through a Cr(NO3)2 solution. How long, in hours, would this current have to be applied to plate out 6.60 g of chromium

Answers

A current of 3.44 A is passed through a Cr(NO₃)₂ solution applying to plate out 6.60 g of chromium would need 6.61 hours.

To calculate the time required to plate out 6.60 g of chromium from a Cr(NO₃)₂ solution with a current of 3.44 A, we need to use Faraday's law of electrolysis.

First, we need to determine the number of moles of chromium to be plated out:

molar mass of Cr = 52 g/mol

moles of Cr = 6.60 g ÷ 52 g/mol = 0.127 moles

Next, we need to use the equation:

moles of substance = (current × time) / (n × F)

where:

current = 3.44 An = number of electrons transferred per mole of substance (in this case, it's 2 for Cr)F = Faraday's constant (96,485 C/mol)

Solving for time:

0.127 moles = (3.44 A × time) / (2 × 96,485 C/mol)

time = (0.127 moles × 2 x 96,485 C/mol) / 3.44 A

time = 6.61 hours

Therefore, it would take 6.61 hours of applying a current of 3.44 A to plate out 6.60 g of chromium from the Cr(NO₃)₂ solution.

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produced in one elementary step, consumed in a later elementary step and therefore doesn't appear in overall equation for r x n

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The intermediate is produced and consumed in separate elementary steps, so it does not appear in the overall equation for r x n.

In a reaction mechanism, an intermediate is a species that is formed in one elementary step and consumed in a subsequent elementary step, without appearing in the overall balanced equation for the reaction.

Intermediates are often unstable and reactive, and are difficult to isolate and characterize. While they play a crucial role in the reaction mechanism, they are not included in the overall equation because they are consumed and do not contribute to the net change in the reactants and products.

Therefore, when calculating the rate law for the reaction (r x n), the intermediate is not considered because it does not appear in the overall equation.

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Computer cables create little to no magnetic field because they are comprised of closely spaced wires carrying oppositely directed currents.
True or False

Answers

The statement "Computer cables create little to no magnetic field because they are comprised of closely spaced wires carrying oppositely directed currents" is false.

Computer cables can create a magnetic field even though they are comprised of closely spaced wires carrying oppositely directed currents. This is because any current-carrying conductor generates a magnetic field around it, according to Ampere's Law.

The magnetic field produced by a cable depends on several factors, including the magnitude and direction of the current, the distance from the cable, and the geometry of the cable. However, it is generally true that the magnetic field created by a computer cable is relatively weak and localized to the immediate vicinity of the cable.

Therefore, the statement that computer cables create little to no magnetic field is false.

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True or False: Plant photosystems have a single reaction center of the pheophytin-quinone type

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False. Plant photosystems have multiple reaction centers of the pheophytin-quinone type. The two types of plant photosystems, Photosystem I and Photosystem II.

Each have their own reaction center composed of a primary electron acceptor, a special pair of chlorophyll molecules, and several accessory pigments. These reaction centers are linked together by electron transport chains that pass electrons from one reaction center to the next, generating energy in the form of ATP and reducing power in the form of NADPH. While pheophytin and quinone molecules are involved in the electron transfer process, they are not the only types of molecules involved. Other pigments, proteins, and cofactors also play important roles in the photosynthetic process. Overall, the complex interplay between these molecules allows plants to harness the energy of sunlight and convert it into usable forms of energy.

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During _______________________, operation gas oil enters the reactor and is mixed with a superheated powdered catalyst. The term cracking is applied to the process because during vaporization the molecules literally split and are sent to a fractionation tower for further processing.

Answers

During catalytic cracking, operation gas oil enters the reactor and is mixed with a superheated powdered catalyst. The term "cracking" is applied to this process because, during vaporization, the molecules literally split apart and are sent to a fractionation tower for further processing.

Catalytic cracking is an essential method in the petroleum refining industry, as it helps convert heavy oils into more useful products such as gasoline, diesel, and jet fuel. The superheated powdered catalyst promotes the breaking of carbon-carbon bonds within the hydrocarbon molecules, which allows them to recombine into different structures.

Once the cracking process is complete, the resulting mixture is sent to a fractionation tower for further processing. In the fractionation tower, the cracked products are separated based on their boiling points. Lighter fractions, like gasoline and diesel, have lower boiling points and rise to the top of the tower, while heavier fractions with higher boiling points settle at the bottom.

The catalyst used in the process becomes deactivated over time due to the build-up of coke, a byproduct of the cracking reaction. Therefore, it needs to be regenerated periodically by burning off the coke to restore its activity.

Overall, catalytic cracking is a crucial process in the petroleum industry, enabling the conversion of less valuable heavy oils into a range of useful products that power our modern society.

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Heat + NHâCl (s) â NHâ (g) + HCl (g)
if pressure is increased, will the reaction shift to the right, left, or no change

Answers

If the pressure is increased, the reaction will shift to the left

The given chemical equation represents the thermal decomposition of ammonium chloride (NH4Cl) into ammonia gas (NH3) and hydrogen chloride gas (HCl) at high temperatures. According to Le Chatelier's principle, if a system at equilibrium is subjected to a stress, it will respond by shifting in a way that tends to counteract the stress and re-establish equilibrium.

In this case, if the pressure is increased, the reaction will shift to the side with fewer moles of gas to reduce the total number of gas molecules and lower the pressure.

As we can see, the reactant side has one mole of solid NH4Cl, whereas the product side has one mole of gaseous NH3 and one mole of gaseous HCl. Therefore, the reaction will shift to the left, which is the side with fewer moles of gas, to decrease the pressure. This means that more NH4Cl will be formed at the expense of NH3 and HCl, and the concentration of NH3 and HCl will decrease.

In summary, if the pressure is increased, the reaction will shift to the left, resulting in more solid NH4Cl being formed and less NH3 and HCl being produced.

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unsaturated compounds with ____________ as the functional group usually undergo __________ reactions with electrophiles, but ________ and related aromatic compounds don't, they usually undergo _______ instead.

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Unsaturated compounds with carbon-carbon double bonds as the functional group usually undergo addition reactions with electrophiles. Electrophiles are electron-deficient species that are attracted to the electron-rich double bond. During the addition reaction, the electrophile attacks the double bond, breaking it and forming a new single bond with one of the carbons.

The other carbon becomes positively charged and attracts a nucleophile to neutralize the charge. This results in the formation of a new compound with a single bond and a new functional group.
However, benzene and related aromatic compounds don't undergo addition reactions with electrophiles. Instead, they usually undergo substitution reactions. Substitution reactions occur when a substituent group replaces a hydrogen atom on the benzene ring. The substituent group can be either an electron-donating group or an electron-withdrawing group, which affects the reactivity of the benzene ring. Substitution reactions are named based on the type of group that is substituted, such as nitration, halogenation, sulfonation, and acylation.
The reason for this difference in reactivity between unsaturated compounds and aromatic compounds is due to the stability of the double bond and the aromatic ring. The double bond is easily broken and reformed during addition reactions, while the aromatic ring is more stable and requires a stronger force, such as a substituent group, to be replaced. Overall, understanding the reactivity of unsaturated and aromatic compounds is important for predicting and controlling chemical reactions in organic chemistry.

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The human toxicity of a pesticide is indicated on the label by the

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Human toxicity of a pesticide. The human toxicity of a pesticide is indicated on the label by the Signal Word.

This word reflects the product's potential hazard to humans and can be found on the pesticide's label. There are four Signal Words:

Danger-Poison: These products are highly toxic and can cause severe injury or death.
Danger: Indicates that the pesticide can cause severe skin or eye irritation, or can be highly toxic if ingested or inhaled.
Warning: Represents products that are moderately toxic or can cause moderate irritation.
Caution: Indicates that the pesticide is slightly toxic or can cause slight irritation.

Always read the label carefully to determine the human toxicity of a pesticide, and follow all safety precautions and guidelines provided.

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what is the structure and color of the oxidized and unoxidized version of indigo

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Indigo is a natural dye that is derived from the leaves of certain plants, and its color can vary depending on the method of extraction and processing.

In its unoxidized form, indigo is a yellow-green powder that is insoluble in water. When indigo is exposed to oxygen, it undergoes a chemical reaction and becomes oxidized, resulting in a blue color. The oxidized version of indigo is commonly used as a dye for textiles, and its blue color can range from a deep navy to a lighter sky blue depending on the concentration and method of application. The structure of both the oxidized and unoxidized versions of indigo is characterized by a complex organic compound known as indigotin, which gives the dye its distinctive color and chemical properties.

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Does the value of the equilibrium constant depend on the initial concentrations of the reactants and products? Do the equilibrium concentrations of the reactants and products depend on their initial concentrations? Explain.

Answers

The value of the equilibrium constant, represented by K, is a constant value that depends only on the temperature and the chemical reaction being studied. Therefore, it does not depend on the initial concentrations of the reactants and products.

However, the equilibrium concentrations of the reactants and products do depend on their initial concentrations. This is because the position of the equilibrium is determined by the relative amounts of reactants and products at the time the reaction reaches equilibrium. If the initial concentrations are changed, the reaction will shift to restore equilibrium according to Le Chatelier's principle. For example, if the concentration of reactants is increased, the reaction will shift towards the products to restore equilibrium.

In summary, the equilibrium constant does not depend on the initial concentrations, but the equilibrium concentrations of the reactants and products do depend on their initial concentrations due to the effect of Le Chatelier's principle.

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Which two Archaeal replication initiator proteins are thought to be same as in eukaryotes?
SeqA/DnaA
Cdc6/Cdt1
DnaA/Orc1
Orc1/Cdc6

Answers

The two Archaeal replication initiator proteins that are thought to be the same as in eukaryotes are Cdc6/Cdt1 and Orc1.

In Archaea, Cdc6 (Cell Division Cycle 6) and Cdt1 (Chromatin licensing and DNA replication factor 1) are involved in the initiation of DNA replication, functioning similarly to their eukaryotic counterparts. They both help in the recruitment and assembly of the replicative helicase onto the origin of replication.

Similarly, Orc1 (Origin Recognition Complex 1) is a crucial protein in both Archaea and eukaryotes for recognizing and binding to the origin of replication. In eukaryotes, the ORC complex consists of six subunits (Orc1-6), whereas in Archaea, it is simplified and usually represented by a single Orc1 protein or a few homologs.

Both Cdc6/Cdt1 and Orc1 proteins in Archaea exhibit homology and functional similarity with their eukaryotic counterparts, supporting the idea of a conserved mechanism in the initiation of DNA replication across these domains of life.

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28) How many moles of oxygen are required in the complete combustion of 1 mole of acetylene?A) 1
B) 1.5
C) 2
D) 2.5
E) 3

Answers

2 moles of oxygen are required in the complete combustion of 1 mole of acetylene.

The balanced chemical equation for the complete combustion of acetylene (C2H2) is:

C2H2 + 2.5O2 → 2CO2 + H2O

From the equation, we can see that 2.5 moles of oxygen are required to react with 1 mole of acetylene. However, since we cannot have half a mole of oxygen, we need to multiply everything by 2 to get whole numbers:

2C2H2 + 5O2 → 4CO2 + 2H2O

Now we can see that 5 moles of oxygen are required to react with 2 moles of acetylene. Simplifying further, we get that 2 moles of oxygen are required to react with 1 mole of acetylene.

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Determine the actual yield of oxygen gas if 15g of barium choléate decompose according to the chemical equation shown below. The percent yield of this reaction is 92%

Answers

The actual yield of the oxygen in the reaction is 4.32 g.

What is the decomposition?

The equation of the reaction is;

Ba(ClO3)2 → BaCl2 + 3O2

Now we have that ;

Number of moles of the barium chlorate is;

Number of moles = mass/Molar mass

= 15 g/304 g/mol

= 0.049 moles

If 1 mole of barium chlorate produced 3 moles of oxygen

0.049 moles of barium chlortae will produce 0.049 * 3/1

= 0.147 moles

Mass of the oxygen produced = 0.147 moles * 32 g/mol

= 4.7 g

Then we have that;

Percent yield = Actual/Theoretical * 100/1

92 = x/4.7 * 100/1

92 * 4.7 = 100x

x = 92 * 4.7/100

x = 4.32 g

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acids and bases worksheet
give the chemical name for each of the following acids in water solution.
HCl
HNO3
H2SO4
H2S

Answers

The chemical names for the following acids in water solution are:

HCl: Hydrochloric acidHNO₃: Nitric acidH₂SO₄: Sulfuric acidH₂S: Hydrosulfuric acid

Chemical name means the scientific designation of a chemical substance in accordance with the nomenclature system developed by the International Union of Pure and Applied Chemistry or the Chemical Abstracts Service's rules of nomenclature, or a name which will clearly identify a chemical substance for the purpose of conducting a hazard evaluation.

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Which atom in each set has the most exothermic electron affinity?
i) N, O, Ne
ii) Al, Si, Cl

Answers

In each set, the atom with the most exothermic electron affinity is i) Among N, O, and Ne, oxygen (O) has the most exothermic electron affinity. ii) In the set of Al, Si, and Cl, chlorine (Cl) has the most exothermic electron affinity.

These atoms have a stronger attraction for an additional electron, releasing more energy when the electron is added.In the first set, Ne has the most exothermic electron affinity. This is because Ne has a completely filled outermost shell, and adding an electron to this shell would result in a stable, full configuration. In contrast, N and O both have partially filled outermost shells, so adding an electron would result in an unstable configuration.

In the second set, Cl has the most exothermic electron affinity. This is because Cl has a higher electronegativity than Al and Si, meaning that it has a stronger attraction for electrons. Additionally, Cl has a partially filled outermost shell, so adding an electron would result in a more stable configuration.

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Which process is used to produce beer and wine?
Select one:
a. lactic acid fermentation
b. glycolysis
c. alcoholic fermentation
d. the Krebs cycle

Answers

c. Alcoholic fermentation is the process used to produce beer and wine. This process does not involve the Krebs cycle or lactic acid fermentation.

Your answer is "c. alcoholic fermentation." This process is used to produce beer and wine, as it involves the conversion of sugars into alcohol (ethanol) and carbon dioxide by yeast. Lactic acid fermentation, glycolysis, and the Krebs cycle are not directly responsible for the production of alcohol in beer and wine. During alcoholic fermentation, yeast consumes sugar and converts it into ethanol (alcohol) and carbon dioxide.

Alcoholic fermentation is the anaerobic conversion of fructose and glucose (sugar) into ethanol and carbon dioxide. The process is done by yeast and some bacteria (Zymomonas mobilis).

The alcoholic fermentation process regenerates the NAD+ absorbed during glycolysis and gives the yeast an energy boost of 2 ATP molecules from the metabolized hexose sugar.

During fermentation, Saccharomyces cerevisiae (a type of yeast) often takes pyruvate to produce ethanol to produce NAD+, which is consumed during glycolysis. This phenomenon is called "alcoholic fermentation."

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PLEASE HELP! VERY STUCK!

Answers

The heat that is evolved in the process is 29.2 kJ of heat.

What is the heat evolved?

The first step in the process would be to obtain the limiting reactant of the system and then we would have that;

Number of moles of the SO2 = 0.5 * 15/0.082 * 310

= 0.295 moles

Number of moles of oxygen = masa/molar mass = 16 g/32 g/mol = 0.5 moles

If 2 moles of SO2 reacts with 1 mole of O2

0.295 moles of SO2 will react with 0.295 moles * 1/2

= 0.1475 moles

Hence the SO2 is the limiting reactant.

If 2 moles of SO2 produced 198 kJ .of heat

0.295 moles of SO2 will produce 0.295 moles * 198 kJ/2 moles

= 29.2 kJ of heat

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Consider Endothermic reaction:
PCl5 <--> PCl3 + Cl2
At a certain temp., the equilibrium mixture contains 1.5atm PCl5, 0.10atm PCl3, and 7.50atm Cl2. What is equilibrium constant, Kp, for reaction?

Answers

If at a certain temp., the equilibrium mixture contains 1.5atm PCl5, 0.10atm PCl3, and 7.50atm Cl2, the equilibrium constant, Kp, for the given endothermic reaction is 0.5 atm.

The equilibrium constant, Kp, for the endothermic reaction PCl5 <--> PCl3 + Cl2 can be calculated using the following formula:

Kp = (PCl3 x Cl2) / PCl5

Where PCl3, Cl2, and PCl5 are the partial pressures of the respective gases at equilibrium. Substituting the given values into the formula, we get:

Kp = (0.10 atm x 7.50 atm) / 1.5 atm
Kp = 0.5 atm

Therefore, the equilibrium constant, Kp, for the given endothermic reaction is 0.5 atm.

Alternatively, in order to calculate the equilibrium constant Kp for the reaction PCl5 ↔ PCl3 + Cl2, we can use the following equation:

Kp = [PCl3] * [Cl2] / [PCl5]

Given the partial pressures at equilibrium: PCl5 = 1.5 atm, PCl3 = 0.10 atm, and Cl2 = 7.50 atm, we can plug these values into the equation:

Kp = (0.10 atm) * (7.50 atm) / (1.5 atm)

Kp ≈ 0.50

So, the equilibrium constant Kp for the reaction is approximately 0.50.

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why would it be difficult to observe a positive ceric nitrate test on an old bottle of a diet cola drink [ex. diet coke it if contained a hydrolyzed aspartame]? hint: what indicates a positive test and what color is the starting solution from cola drinks?

Answers

A positive ceric nitrate test would be difficult to observe on an old bottle of diet cola drink, such as Diet Coke, if it contained hydrolyzed aspartame. The positive ceric nitrate test indicates the presence of a reducing sugar, which causes the solution to change from an orange-yellow color to a pale or colorless solution.

However, the starting solution of cola drinks is typically dark brown, making it challenging to observe the color change associated with a positive test. Additionally, the hydrolyzed aspartame may have degraded over time, reducing the likelihood of a positive test result.

A positive ceric nitrate test indicates the presence of free formaldehyde in a sample. Hydrolyzed aspartame in an old bottle of diet cola can potentially break down into its components, one of which is free formaldehyde. However, over time, formaldehyde can react with other compounds present in the drink or evaporate, which can make it difficult to detect using a ceric nitrate test. Additionally, the starting solution of cola drinks is typically brown, which can make it harder to observe color changes indicating a positive test.

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In preparation for a helium dilution study, a respiratory therapist is calibrating the helium analyzer. While exposing the analyzer to ambient room air, what will the analyzer read for helium concentration?
A. 2%
B. 21%
C. 79%
D. 0%

Answers

The correct answer is: D. 0% While conducting the helium dilution study, it's essential for the respiratory therapist to properly

In preparation for a helium dilution study, a respiratory therapist calibrates the helium analyzer by exposing it to ambient room air. The analyzer measures the helium concentration in the air. Ambient room air does not typically contain helium as a primary component. The primary components of room air are nitrogen (approximately 78%) and oxygen (approximately 21%), with trace amounts of other gases like argon, carbon dioxide, and neon.
Therefore, the helium concentration in ambient room air would be extremely low or negligible. Calibrate the helium analyzer to ensure accurate measurements of helium concentration within the patient's lungs.

According to Henry's Law, the partial pressure of a gas above a liquid determines how much gas is dissolved in the liquid. Henry's constant (kH), which affects the relationship between a gas and a liquid as well as temperature and pressure, is the proportionality constant.

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Increasing the temperature of a system in dynamic equilibrium favours the endothermic reaction. The system counteracts the change you have made by absorbing the extra heat.

Answers

Increasing the temperature of a system in dynamic equilibrium favors the endothermic reaction because the system counteracts the change by absorbing the extra heat.

This means that the reaction shifts towards the endothermic direction to maintain equilibrium and minimize the effect of the increased temperature. When a system is in dynamic equilibrium, the rate of the forward reaction is equal to the rate of the backward reaction. If the temperature is increased, it will cause the rate of both reactions to increase. However, since the endothermic reaction absorbs heat, it will be favored as the extra heat is absorbed by the reaction.

This will cause the equilibrium to shift to the right, favoring the formation of more products. The system will counteract the change in temperature by absorbing the extra heat, which will help maintain the equilibrium. It is important to note that the equilibrium constant remains the same, but the position of equilibrium will shift in favor of the endothermic reaction.

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The passage of the Clean Air Act Amendments that marked an overall change in the federal approach to air pollution was:

Answers

The passage of the Clean Air Act Amendments marked an overall change in the federal approach to air pollution regulation.

The Clean Air Act Amendments refer to the revisions made to the Clean Air Act, which is a comprehensive federal law aimed at addressing and controlling air pollution in the United States. The amendments, passed by the U.S. Congress, brought significant changes to the way air pollution was regulated and managed at the federal level. These changes included the establishment of stricter air quality standards, increased regulatory authority for the Environmental Protection Agency (EPA), implementation of emission control programs, and provisions for addressing specific types of pollutants and sources.

The amendments signaled a shift towards a more comprehensive and proactive approach to reducing and controlling air pollution, leading to improvements in air quality and environmental protection across the country.

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Radiation with enough energy to knock electrons off atoms or molecules is known as

Answers

The type of radiation with enough energy to knock electrons off atoms or molecules is known as ionizing radiation.

Ionizing radiation has enough energy to create ions (charged particles) by removing electrons from atoms or molecules. This type of radiation includes alpha particles, beta particles, gamma rays, X-rays, and ultraviolet radiation. Ionizing radiation can cause damage to living cells and increase the risk of cancer and other health problems. It is important to take precautions and limit exposure to ionizing radiation whenever possible.
                                 Radiation with enough energy to knock electrons off atoms or molecules is known as ionizing radiation. This type of radiation includes alpha particles, beta particles, gamma rays, and X-rays, which can cause atoms or molecules to lose electrons and become positively charged ions.

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13. A solid that comes out of solution as a result of an ion exchange reaction is called a a. precipitate. b. contaminant. c. base. d. metal.

Answers

When two ions in a solution exchange places, it is known as an ion exchange reaction. Sometimes, this reaction causes a solid to form and separate from the solution. This solid is called a precipitate.

Precipitates can be either desirable or undesirable, depending on the circumstances. In some cases, they may be a sign that a chemical reaction has taken place or that a certain process is occurring. In other cases, they may indicate that there is a problem with the solution or that it has been contaminated in some way. Overall, a precipitate is simply a solid that comes out of a solution as a result of an ion exchange reaction. It is not necessarily a contaminant, base, or metal, although it may contain one or more of these substances. The important thing to remember is that a precipitate is a sign that a chemical reaction has occurred, and it may have implications for the properties and behavior of the solution going forward. To prevent precipitates from forming, it is important to carefully control the conditions of the solution and to monitor it closely for any signs of change.

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In salt hydrolysis, the conjugate bases of weak acids yield what type of soln? What about the conjugate acids of weak bases?

Answers

In salt hydrolysis, the conjugate bases of weak acids yield basic solutions, while the conjugate acids of weak bases yield acidic solutions. This phenomenon occurs because the hydrolysis of a salt produces either hydroxide ions or hydronium ions, depending on the nature of the salt.

For example, when the salt of a weak acid and a strong base is hydrolyzed, the conjugate base of the weak acid is formed, which acts as a weak base. This weak base can then react with water to produce hydroxide ions, leading to an increase in the pH of the solution and a basic solution. Conversely, when the salt of a weak base and a strong acid is hydrolyzed, the conjugate acid of the weak base is formed, which acts as a weak acid. This weak acid can then react with water to produce hydronium ions, leading to a decrease in the pH of the solution and an acidic solution.

It is important to note that the strength of the acid or base will also influence the pH of the solution, as stronger acids and bases will have a greater impact on the pH. Additionally, the concentration of the salt and the water will also impact the degree of hydrolysis and the resulting pH of the solution.

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T/F: L-sugars are epimers of their D-configuration counterparts

Answers

True. L-sugars are epimers of their D-configuration counterparts.

Epimers are a type of stereoisomers that differ in the configuration at only one stereogenic center. L-sugars and D-sugars are mirror images of each other, and they differ in their configuration at the highest numbered chiral carbon. Therefore, L-sugars are epimers of their D-configuration counterparts.
                                           True, L-sugars are epimers of their D-configuration counterparts. An epimer is a stereoisomer that differs in the configuration at only one chiral center. L-sugars and D-sugars have the same molecular formula but differ in the spatial arrangement of their atoms, specifically at the chiral center farthest from the carbonyl group.

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Phosphate, diphosphate, and triphosphate make good leaving groups in biological substitutions because they are ______.

Answers

Phosphate, diphosphate, and triphosphate make good leaving groups in biological substitutions because they are negatively charged and relatively stable.

The substitution reaction involves the replacement of one functional group by another, and a leaving group is required to leave the molecule during this process. Phosphate groups have a negative charge, which makes them good leaving groups because they can stabilize the transition state of the reaction. Additionally, phosphates are relatively stable due to their resonance stabilization, making them less likely to undergo unwanted reactions or hydrolysis. These properties make them suitable leaving groups for many biological substitutions, such as nucleophilic substitutions in DNA and RNA synthesis.

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In which pair do both compounds exhibit predominantly ionic bonding?
A) PCl5 and HF
B) Na2SO3 and BH3
C) KI and O3
D) NaF and H2O
E) RbCl and CaO

Answers

Both NaF and H2O exhibit predominantly ionic bonding. The correct answer is D) NaF and H2O.

NaF is an ionic compound consisting of a metal (Na) and a nonmetal (F), and H2O is a polar molecule with an electronegative oxygen atom and two electropositive hydrogen atoms, resulting in an ionic-like attraction between the two. PCl5 and HF do not exhibit predominantly ionic bonding, as they both have covalent bonds. Na2SO3 and BH3 have some ionic character, but it is not predominant. KI and O3 are both covalent compounds, and RbCl and CaO both have predominantly ionic bonding, but they are not a pair.
E) RbCl and CaO
RbCl (rubidium chloride) involves ionic bonding between the metal Rb and the non-metal Cl. CaO (calcium oxide) also involves ionic bonding between the metal Ca and the non-metal O. Both compounds exhibit predominantly ionic bonding in this pair.

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Post 10: Synthesis of t-Butyl Chloride
Why do tertiary alcohols react faster with concentrated hydrochloric acid than do
secondary or primary alcohols?

Answers

Tertiary alcohols react faster due to steric hindrance and stabilization.

How does the reaction rate vary with alcohol type?

Tertiary alcohols react faster with concentrated hydrochloric acid than secondary or primary alcohols due to their higher degree of substitution. The increased steric hindrance around the carbon atom in tertiary alcohols makes it more susceptible to nucleophilic attack, allowing for faster and more efficient conversion to the corresponding alkyl halide. Additionally, the tertiary carbocation intermediate formed during the reaction is stabilized by the surrounding alkyl groups, which further promotes the reaction rate.

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