given 1 amp of current for 1 hour, which solution would c,of''e'9 deposit the smallest mass of metal?a) Fe found in FeCl2 (aq) b) Ni found in NiCl2 (aq) c) Cu found in CuSO4 (aq) d) Ag found in AgNO3 (aq)

Answers

Answer 1

The amount of metal deposited on an electrode during electrolysis is directly proportional to number of moles of electrons transferred to the electrode. Option d is correct.

The metal that requires the fewest number of electrons to be reduced will be deposited with smallest mass of metal for a given amount of current and time.

The reduction half-reactions for Fe, Ni, Cu, and Ag are:

[tex]Fe_2+(aq)[/tex] + 2e- → Fe(s) (2 electrons transferred)

[tex]Ni_2+(aq)[/tex] + 2e- → Ni(s) (2 electrons transferred)

[tex]Cu_2+(aq)[/tex] + 2e- → Cu(s) (2 electrons transferred)

Ag+(aq) + e- → Ag(s) (1 electron transferred)

Since Ag+ requires only one electron for reduction, it would deposit the smallest mass of metal.

Therefore, correct answer is option d Ag found in [tex]AgNO_3(aq)[/tex].

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Related Questions

Austin is on a fishing trip. At first he rides his boat 15 km east. He doesn’t catch anything, so he turns the boat around and rides 5 km west to find a better spot. A. His distance traveled is. B. His displacement is

Answers

A. The distance traveled by Austin is the total length of the path he covered. In this case, he rode 15 km east and then 5 km west. The total distance traveled is the sum of these distances:

Distance traveled = 15 km + 5 km = 20 km

Therefore, Austin traveled a total distance of 20 kilometers.

B. The displacement of Austin is the straight-line distance from the starting point to the ending point, regardless of the path taken. Displacement takes into account both the distance and the direction. In this case, Austin initially traveled 15 km east and then 5 km west. The displacement is the difference between these two distances, considering the direction:

Displacement = 15 km east - 5 km west = 10 km east

Therefore, the displacement of Austin is 10 kilometers east.

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Given 1 Coulomb = 1 A •s, and F = 96500 C/mol. 100.0 mL of an Pb2+ containing waste water sample was analyzed by using coulometry based on the Pb2+ + Pb process. 620 seconds with constant direct current 5.0 mA were used to completely drain lead(II) from this sample. Assume Pb2+ is the only electrolyzable species in the sample, what was the original molar concentration Pb2+ ?

Answers

To calculate the original molar concentration of Pb2+, we need to use the formula:

mol Pb2+ = (I * t) / (n * F)

where I is the current in amperes, t is the time in seconds, n is the number of electrons involved in the reaction (in this case, 2 electrons for the Pb2+ + Pb process), and F is the Faraday constant (96500 C/mol).

First, we need to convert the current from milliamperes to amperes:

5.0 mA = 0.005 A

Next, we can plug in the values we have:

mol Pb2+ = (0.005 A * 620 s) / (2 * 96500 C/mol)

mol Pb2+ = 0.000016 mol

Finally, we need to convert from moles to molarity (mol/L) using the volume of the sample:

100.0 mL = 0.100 L

Molarity Pb2+ = 0.000016 mol / 0.100 L

Molarity Pb2+ = 0.00016 M

Therefore, the original molar concentration of Pb2+ in the waste water sample was 0.00016 M.

The question gives us the information that the waste water sample was analyzed using coulometry based on the Pb2+ + Pb process. Coulometry is a method of chemical analysis that measures the amount of charge (in coulombs) that passes through a solution during an electrolysis reaction. In this case, the electrolysis of the Pb2+ + Pb process involves the reduction of Pb2+ ions to metallic lead (Pb), which means that the number of coulombs passed through the solution is proportional to the number of moles of Pb2+ present in the sample. By using the current and time values given in the question, we can calculate the number of moles of Pb2+ that were present in the sample, and then convert this to the original molar concentration (M) using the volume of the sample. The original molar concentration of Pb2+ in the waste water sample is 0.00032 M.

First, we need to calculate the total charge passed through the sample using the formula Q = I × t, where Q is the charge, I is the current (5.0 mA), and t is the time (620 s).

Q = 5.0 mA × 620 s = 3100 mC (1C/1000mC) = 3.1 C

Next, we can find the moles of Pb2+ reduced using the Faraday's constant (F = 96500 C/mol):

moles of Pb2+ = Q / F = 3.1 C / 96500 C/mol = 3.21 x 10^-5 mol

Now, we can determine the molar concentration of Pb2+ in the original 100.0 mL sample:

molar concentration = moles of Pb2+ / volume of the sample (in L) = 3.21 x 10^-5 mol / 0.1 L = 0.00032 M

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Derive an expression for the reaction half-time of the irreversible second-order ki reaction 2A - B in terms of k, and the starting concentration A. Show that the rate predicted by the reaction mechanism 6-12a-c, with the second step assumed to be rate-limiting and the first step assumed to be at equilibrium, is rate = k,K, 1/2[CL][CO].

Answers

The rate law for the overall reaction is: Rate = k[A][B]².  Option c is correct.

The rate-determining step in this mechanism is the slow step, which involves the collision of A and B to form AB. Therefore, the rate law for this step is Rate = k[A][B]. However, we still need to express the rate of the overall reaction in terms of the concentrations of the reactants. The first step, A₂ → 2A, is fast and does not affect the overall rate law. Thus, we can use the steady-state approximation to express the concentration of A in terms of [A₂] and [AB].

Since A₂ is consumed twice as fast as B in the overall reaction, we can assume that [A₂] = 2[AB]. Substituting this expression into the rate law for the slow step gives Rate = k[2AB][B] = 2k[AB][B] = k[A][B]², which is the rate law for the overall reaction.

C is the correct option.

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The complete question is

Given the following proposed mechanism, predict the rate law for the overall reaction.

A2 + 2B ? 2AB (overall reaction)

Mechanism A2 →2A fast A + B ? AB slow

Possible Answers: A. Rate = k[A2][B]

B. Rate = k[A2][B]1/2

C. Rate = k[A][B]

D. Rate = k [A2]1/2[B]

E. Rate = k[A2]

To calculate how many grams NH3 will be formed from 6. 0 g H2, the first step you need



A) information about chemical reaction is balanced or not.


B) set up given mole ratio of reactant vs products.


C) information about the mass of N2 reacting.


D) Set up mole ratios of reactants vs products from balanced chemical equation.



N2 + H2 → NH3

Answers

The correct answer is D) Set up mole ratios of reactants vs products from balanced chemical equation.

In order to calculate how many grams of NH3 will be formed from 6.0 g of H2, we need to set up the appropriate mole ratios from the balanced chemical equation. The balanced equation given is:

N2 + H2 → NH3

From this equation, we can determine the stoichiometric relationship between the reactants (N2 and H2) and the product (NH3). The coefficients in the balanced equation represent the mole ratios.

In this case, we see that the coefficient of H2 is 3, indicating that 3 moles of H2 react with 1 mole of NH3. Therefore, we can set up the mole ratio:

3 moles H2 : 1 mole NH3

Since we are given the mass of H2 (6.0 g), we would then convert this mass to moles using the molar mass of H2. Once we have the moles of H2, we can use the mole ratio to calculate the moles of NH3 formed. Finally, we can convert the moles of NH3 to grams using the molar mass of NH3.

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what would happen to the ag and cl− concentrations if nacl(s) was added to a saturated solution of agcl in water?

Answers

Answer to the question would be that the addition of NaCl(s) to a saturated solution of AgCl in water would not affect the Ag+ concentration but would increase the Cl- concentration.

When NaCl(s) is added to the saturated solution of AgCl, the Na+ and Cl- ions dissociate from the solid and enter the solution. However, since AgCl is already saturated, the addition of more Ag+ ions from the NaCl(s) will not dissolve and instead remain as a solid. Therefore, the Ag+ concentration remains the same.

On the other hand, since Cl- is the anion of both AgCl and NaCl, the addition of NaCl(s) increases the concentration of Cl- ions in the solution. This can cause more AgCl to dissolve until the solution reaches a new equilibrium where the concentration of Ag+ and Cl- ions is once again equal to the solubility product constant.

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A mixture of three gases has a total pressure of 94. 5 kPa. If the partial pressure of


the 1st gas is 65. 4 kPa and the partial pressure of the 2nd gas is 22. 4 kPa, what is the


partial pressure of the 3rd gas of the mixture?

Answers

The partial pressure of the 3rd gas in the mixture can be calculated by subtracting the sum of the partial pressures of the 1st and 2nd gases from the total pressure of the mixture, resulting in 6.7 kPa.

The total pressure of a gas mixture is equal to the sum of the partial pressures of each individual gas component. In this case, the total pressure of the mixture is given as 94.5 kPa. The partial pressure of the 1st gas is 65.4 kPa, and the partial pressure of the 2nd gas is 22.4 kPa. To find the partial pressure of the 3rd gas, we subtract the sum of the partial pressures of the 1st and 2nd gases from the total pressure of the mixture:

Partial pressure of 3rd gas = Total pressure - (Partial pressure of 1st gas + Partial pressure of 2nd gas)

= 94.5 kPa - (65.4 kPa + 22.4 kPa)

= 94.5 kPa - 87.8 kPa

≈ 6.7 kPa

Therefore, the partial pressure of the 3rd gas in the mixture is approximately 6.7 kPa. This calculation is based on the assumption that the partial pressures of the three gases are the only contributors to the total pressure of the mixture and that there are no other gases present.

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how many grams of water are needed to prepare 255g of 4.25 lcl3 solution

Answers

a) The percent composition of SrCl₂ in 95.0 g of water cannot be calculated without additional information.

b) To prepare 255 g of a 4.25% AlCl₃ solution, 10.84 g of AlCl₃ and 244.16 g of water are needed.

c) 13.1 mL of 0.842 M NaOH is required to react with 30.0 mL of 0.635 M H₃PO₄ solution in the given reaction: 3 NaOH + H₃PO₄ → Na₃PO₄ + 3 H₂O.

b) To find the mass of AlCl₃ and water needed to prepare a 255 g of 4.25% AlCl₃ solution, we can use the formula for mass percent:

mass percent = (mass of solute / mass of solution) x 100%

Substituting the given values, we get:

4.25% = (mass of AlCl₃ / 255 g) x 100%

Solving for the mass of AlCl₃, we get:

mass of AlCl₃ = (4.25 / 100) x 255 g = 10.84 g

To find the mass of water needed, we subtract the mass of AlCl₃ from the total mass of the solution:

mass of water = 255 g - 10.84 g = 244.16 g

Therefore, 10.84 g of AlCl₃ and 244.16 g of water are needed to prepare a 255 g of 4.25% AlCl₃ solution.

c) To determine the amount of NaOH needed to react with a given amount of H₃PO₄, we use the balanced chemical equation and stoichiometry. According to the balanced equation, 3 moles of NaOH react with 1 mole of H₃PO₄.

First, we calculate the number of moles of H₃PO₄ in 30.0 mL of 0.635 M solution:

moles of H₃PO₄ = Molarity x volume in liters = 0.635 M x (30.0 / 1000) L = 0.01905 moles

Since 3 moles of NaOH react with 1 mole of H₃PO₄, we need:

moles of NaOH = 3 x moles of H₃PO₄ = 3 x 0.01905 moles = 0.05715 moles

Now, we can use the molarity and the number of moles of NaOH to calculate the volume of NaOH needed:

Molarity = moles of solute / volume of solution in liters

Volume of NaOH = moles of solute / Molarity = 0.05715 moles / 0.842 M = 0.0679 L = 67.9 mL

Therefore, 13.1 mL of 0.842 M NaOH is required to react with 30.0 mL of 0.635 M H₃PO₄ solution.

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Complete Question:

Calculate the percent composition by SrCl2 in 95.0 g of water. hposition by mass of a solution prepared by dissolving 5.57 g of b). How many grams of water are needed to prepare 255 g of 4.25% AlCl3 solution? c) For the reaction; 3 NaOH + H3PO4 - Na3PO4 + 3H20 How many milliliters of 0.842 M sodium hydroxide are required to react with 30.0 mL of 0.635 M phosphoric acid solution?

draw the beta anomer of the sugar in its furanose form.

Answers

The cyclic form known as furanose, which consists of a five-membered ring structure with four carbon atoms and one oxygen atom, is one that sugars can take on.

The hydroxyl group (-OH) connected to the anomeric carbon of the sugar molecule in the beta anomer is angled downward with respect to the plane of the ring. In other words, the hydroxyl group is below the ring in this structure.

In this structure, the oxygen atom represents the oxygen in the furanose ring, and the anomeric carbon is labeled as "C". The hydroxyl group on the anomeric carbon is oriented downwards (beta configuration) relative to the plane of the ring. The CH2OH group is attached to the other carbon atom in the ring.

It's important to note that the beta and alpha anomers of a sugar differ in the orientation of the hydroxyl group attached to the anomeric carbon. In the alpha anomer, the hydroxyl group is oriented in an upward direction relative to the plane of the ring.

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a force f = bx3 acts in the x direction, where the value of b is 3.9 n/m3. how much work is done by this force in moving an object from x = 0.0 m to x = 2.5 m?

Answers

The work done by the force F = b * x³ in moving an object from x = 0.0 m to x = 2.5 m is 15.36 J.

To calculate the work done, we need to integrate the force over the displacement.

The formula for work done in one dimension is given by:

W = ∫(F dx)

Substituting the given force, F = b * x³, we have:

W = ∫(b * x³ dx)

Integrating with respect to x, we get:

W = (b/4) * x⁴ + C

Evaluating the limits of integration, from x = 0.0 m to x = 2.5 m, we have:

W = (b/4) * (2.5)⁴ - (b/4) * (0.0)⁴

Since the initial position is x = 0.0 m, the term (b/4) * (0.0)⁴ becomes zero. Therefore, we are left with:

W = (b/4) * (2.5)⁴

Substituting the value of b = 3.9 N/m³, we get:

W = (3.9/4) * (2.5)⁴

 = 15.36 J

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which qtable will you compare your qcalculated to? 0.76 0.64 0.56 can the questionable value be discarded based on your q-test results?

Answers

The main answer to your question is that you should compare your qcalculated value to the qtable value for your desired level of significance (typically 0.05).

If your qcalculated value is greater than the qtable value, then you can reject the null hypothesis and conclude that there is a significant difference between your data sets.

As for the values you provided (0.76, 0.64, 0.56), it is unclear what these values represent and how they are related to your q-test. Without additional information, it is difficult to determine whether the questionable value can be discarded based on your q-test results.
you will need to compare your calculated Q-value (Qcalculated) to the appropriate Q-table value (Qcritical) based on your given data points (0.76, 0.64, 0.56).

Step 1: Calculate the range and questionable value
First, find the range of your data points by subtracting the smallest value from the largest value (0.76 - 0.56 = 0.20). Next, identify the questionable value; in this case, it is 0.76.

Step 2: Calculate the Qcalculated value
Now, calculate the Qcalculated value by dividing the difference between the questionable value and the next closest value by the range. In this example, (0.76 - 0.64) / 0.20 = 0.6.

Step 3: Compare Qcalculated to Qcritical
You will need to compare your Qcalculated value (0.6) to the Qcritical value from a Q-table based on your dataset's sample size and a desired confidence level (usually 90%, 95%, or 99%). In this example, let's assume a 90% confidence level and a sample size of 3. The Qcritical value from the table would be approximately 0.94.

Step 4: Determine if the questionable value can be discarded
Since the Qcalculated value (0.6) is less than the Qcritical value (0.94), the questionable value (0.76) cannot be discarded based on the Q-test results.

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if a noble gas is compressed from 0.5 atm to 2 atm what is itz phase change

Answers

If a noble gas is compressed from 0.5 atm to 2 atm and its temperature is below its boiling point at 2 atm, it will likely remain in the gaseous state. However, if its temperature is above its boiling point at 2 atm, it may undergo a phase change and condense into a liquid or solid state.

If a noble gas is compressed from 0.5 atm to 2 atm, its phase change will depend on its initial state and the temperature at which the compression occurs.

Noble gases such as helium, neon, argon, krypton, and xenon are typically found in the gaseous state at room temperature and atmospheric pressure. At low temperatures and/or high pressures, these gases may undergo a phase change and condense into a liquid or solid state.

For example, helium has a boiling point of -268.9°C at atmospheric pressure, and can be liquified at temperatures below this point and pressures above about 25 atm. Neon has a similar boiling point of -246.1°C, and can be liquified at pressures above about 27 atm.

Therefore, if a noble gas is compressed from 0.5 atm to 2 atm and its temperature is below its boiling point at 2 atm, it will likely remain in the gaseous state. However, if its temperature is above its boiling point at 2 atm, it may undergo a phase change and condense into a liquid or solid state.

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how is specifit heat defined? how will you find the specific heat capacity of water in activity 2-2

Answers

Specific heat is defined as the amount of heat energy required to raise the temperature of one unit of mass of a substance by one degree Celsius (or Kelvin). It is denoted by the symbol c and has units of J/(g·°C) or J/(g·K).

To find the specific heat capacity of water in Activity 2-2, you can perform an experiment where a known mass of water is heated to a known temperature and then allowed to cool down.

The amount of heat energy gained by the water can be calculated using the equation Q = mcΔT, where Q is the heat energy gained, m is the mass of water, c is the specific heat capacity of water, and ΔT is the change in temperature of the water.

Using the known values of Q, m, and ΔT, you can rearrange the equation to solve for c, which will give you the specific heat capacity of water. The value of c for water is approximately 4.184 J/(g·°C) at room temperature, but may vary slightly with temperature.

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a periodic karman vortex street is formed when

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A periodic Karman vortex street is formed when a fluid flow, such as air or water, encounters an obstacle, typically a cylindrical or bluff body.

This phenomenon occurs due to the separation of fluid layers around the object, which creates alternating low-pressure regions on each side. The fluid flow begins to shed vortices in a periodic manner, generating a pattern known as a Karman vortex street, these vortices are formed at regular intervals, creating a distinct street-like pattern downstream of the obstacle. The shedding of vortices is influenced by the Reynolds number, which determines the fluid flow regime. In low Reynolds number conditions, the flow is laminar, and no vortex street is formed. However, as the Reynolds number increases, the flow transitions to a turbulent regime, leading to the formation of the Karman vortex street.

The presence of a Karman vortex street can have various consequences on structures, such as increased vibrations and dynamic loads. In engineering applications, understanding and mitigating the effects of vortex shedding is crucial to ensure structural stability and prevent failures. To reduce the impact of a Karman vortex street, engineers may implement design modifications or use devices such as vortex breakers or flow control techniques to alter the flow characteristics around the object. So therefore when a fluid flow, such as air or water, encounters an obstacle, typically a cylindrical or bluff body, a periodic Karman vortex street is formed.

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The industrial synthesis of H_2 begins with the steam-reforming reaction, in which methane reacts with high-temperature steam: CH_4(g) + H_2O (g) rightarrow CO (g) + 3 H_2(g) What is the percent yield when a reaction vessel that initially contains 67.0kg CH_4 and excess steam yields 16.8kg H_2?

Answers

The percent yield of the reaction is 66.4%.

To calculate the percent yield of H₂, we need to first determine the theoretical yield and then compare it to the actual yield (16.8 kg H₂).

1. Determine the moles of CH₄ (molar mass = 16.04 g/mol):
67.0 kg CH₄ × (1000 g/kg) / 16.04 g/mol = 4180.3 mol CH₄

2. From the balanced equation, 1 mol CH₄ produces 3 mol H₂:
4180.3 mol CH₄ × (3 mol H₂ / 1 mol CH₄) = 12540.9 mol H₂

3. Determine the theoretical yield of H₂ (molar mass = 2.02 g/mol):
12540.9 mol H₂ × 2.02 g/mol = 25332.6 g = 25.3 kg H₂

4. Calculate the percent yield:
Percent Yield = (Actual Yield / Theoretical Yield) × 100
Percent Yield = (16.8 kg H₂ / 25.3 kg H₂) × 100 = 66.4%

The percent yield of the reaction is 66.4%.

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What is the boiling point elevation of a solution that is 651 g ethylene glycol (MW=62.01) in 2,505 g of water? Ko (H20)=0.52 "Cim) O 10.1 °C 04.19°C 2.18 °C O 7.79°C 0.218 °C QUESTION 28 What is the molality for the solution in problem #272 10.5 m 0.4.19 m 4.19 x 103 m 1.86 m 0.419 m

Answers

The boiling point elevation of the solution is 4.36 "C" and the molality is 4.19 m.

The boiling point elevation of a solution can be calculated using the formula: ΔTb = Kb * molality * i, where ΔTb is the boiling point elevation, Kb is the boiling point elevation constant (0.52 "C/m" for water), molality is the concentration of the solution in moles of solute per kilogram of solvent, and i is the van't Hoff factor which represents the number of particles the solute breaks into when it dissolves.

First, we need to calculate the molality for the solution. To calculate the boiling point elevation, we first need to determine the molality of the solution. Molality (m) is defined as the moles of solute (ethylene glycol) per kilogram of solvent (water).

1. Calculate moles of ethylene glycol:
moles = mass / molecular weight = 651 g / 62.01 g/mol ≈ 10.5 moles
2. Convert the mass of water to kilograms:
mass = 2505 g / 1000 g/kg = 2.505 kg
3. Calculate molality:
molality = moles of solute / kg of solvent = 10.5 moles / 2.505 kg ≈ 4.19 m


Next, we can calculate the boiling point elevation using the formula: ΔTb = Kb * molality * i. The van't Hoff factor for ethylene glycol is 2 because it dissociates into two particles in water. Thus, ΔTb = 0.52 "C/m" * 4.19 m * 2 = 4.36 "C".

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We have a container of unknown size. It's pressure is 30 atm, with 1. 5


moles at 2000K. What is the volume of this container?

Answers

The volume of the container is approximately 82.65 liters.To determine the volume of the container, we can use the ideal gas law equation:

PV = nRT

Where:

P is the pressure (in atm),

V is the volume (in liters),

n is the number of moles,

R is the ideal gas constant (0.0821 L·atm/(mol·K)),

T is the temperature (in Kelvin).

Given:

P = 30 atm,

n = 1.5 moles,

T = 2000 K.

Rearranging the equation, we have:

V = (nRT) / P

Substituting the given values:

V = (1.5 moles * 0.0821 L·atm/(mol·K) * 2000 K) / 30 atm

V = 82.65 L

Therefore, the volume of the container is approximately 82.65 liters.

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A solution is prepared at 25°C that is initially 0.098M in acetic acid HCH3CO2 , a weak acid with =Ka×1.810−5 , and 0.30M in potassium acetate KCH3CO2 . Calculate the pH of the solution. Round your answer to 2 decimal places.

Answers

The pH of the solution is approximately 5.98 (rounded to 2 decimal places).To calculate the pH of the solution, we need to use the equilibrium expression for the dissociation of acetic acid: HCH3CO2 + H2O ⇌ H3O+ + CH3CO2- .The equilibrium constant, Ka, is given as 1.81 × 10^-5. We can use the Ka value to calculate the concentration of H3O+ ions in the solution at equilibrium.

First, we need to calculate the initial concentration of HCH3CO2 and CH3CO2- ions using the given molarity and stoichiometry:
[HCH3CO2] = 0.098 M
[KCH3CO2] = 0.30 M
Ka = [H3O+][CH3CO2-] / [HCH3CO2]
[HCH3CO2] = 0.098 M
[CH3CO2-] = 0.30 M
Ka = 1.81 × 10^-5
[H3O+] = sqrt(Ka × [HCH3CO2] / [CH3CO2-]) = sqrt(1.81 × 10^-5 × 0.098 / 0.30) = 0.0082 M
pH = -log[H3O+] = -log(0.0082) = 2.09
pH = pKa + log([A-]/[HA])
pH = 4.74 + log(0.30/0.098)
pH ≈ 4.74 + 1.24
pH ≈ 5.98

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1.) What is the purpose of the sodium carbonate in step 2? In what form is the sulfanilic acid? 2. What is the purpose of the hydrochloric acid in step 4? 3. Why must the diazonium salt be kept cold? What would happen if you allowed the diazonium salt to warm to room temperature? 4 What would happen if you rinsed your precipitates in step 11 with water? 5. If you attempt to purify your products, why do you use sodium chloride along with the water? 6 Which of your prepared dyes behaved as acid/base indicators? Which dye exhibited fluorescence? Why will coupling only occur between diazonium salts and activated rings? Why is it desirable to use purified starting materials to prepare dyes?

Answers

The purpose of sodium carbonate in step 2 is to create a basic environment that will convert the sulfanilic acid into its sodium salt form, making it more soluble in water and easier to work with.


The hydrochloric acid in step 4 is used to create an acidic environment that will protonate the diazonium salt and help it react with the coupling reagent in step 5.
The diazonium salt must be kept cold to prevent premature coupling reactions from occurring, which would decrease the yield and purity of the final product. If it were allowed to warm to room temperature, it would become more reactive and could couple with impurities or other undesired compounds.
Rinsing the precipitates in step 11 with water could dissolve or wash away some of the product, decreasing the yield and purity.
Sodium chloride is added to the water in the purification process to increase the solubility of the dye in water and improve the separation of impurities.
The dye that behaved as an acid/base indicator was the one that changed color in response to changes in pH. The dye that exhibited fluorescence was the one that emitted light when excited by UV radiation. Coupling only occurs between diazonium salts and activated rings because these reactions require the formation of a highly reactive electrophilic intermediate. Using purified starting materials is desirable to prepare dyes because impurities can interfere with the reaction and decrease the yield and purity of the product.

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What is the role of the filter paper in the salt bridge? Do you think the bridge would work as well without the filter paper?

Answers

The filter paper acts as a barrier to prevent the mixing of solutions in the salt bridge.

The filter paper is a crucial component in the salt bridge as it separates the two half-cells and prevents the mixing of their respective solutions.

It allows ions to pass through it and establish a connection between the half-cells, enabling the flow of electrons in the external circuit.

Without the filter paper, the solutions in the two half-cells would mix, causing an irreversible chemical reaction that would render the salt bridge useless.

Therefore, the filter paper is necessary for the proper functioning of the salt bridge and the overall electrochemical cell.

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The filter paper in a salt bridge is used to prevent mixing of the two half-cells while allowing the ions to pass through.

The bridge would not work as effectively without the filter paper, as it would allow unwanted mixing and potentially interfere with the flow of ions. The filter paper in a salt bridge serves as a barrier that prevents the two half-cells from mixing while allowing the ions to pass through. It is essential to maintain the integrity of the two half-cells, as any unwanted mixing can interfere with the redox reaction and affect the accuracy of the results. The filter paper is typically made of a porous material, such as cellulose or glass fiber, that allows the ions to move freely but prevents any physical mixing of the solutions. Without the filter paper, the salt bridge would not work as effectively as it would allow unwanted mixing and interfere with the flow of ions. This could result in a slower reaction or an incomplete reaction, leading to inaccurate results. Therefore, the filter paper is an essential component of the salt bridge and plays a crucial role in ensuring the success of the redox reaction.

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phosphate buffer with a ph of 7.40 using phosphoric acid (h3po4) or its conjugate bases. which acid and conjugate base would you use? the pka values for phosphoric acid are 2.16. 7.21, and 12.32.

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To make a phosphate buffer with a pH of 7.40, we need to choose an acid and its conjugate base from the phosphoric acid system, whose pKa values are 2.16, 7.21, and 12.32.

The buffer solution should contain equal amounts of acid and its conjugate base, and their respective pKa values should differ by 1 unit from the desired pH of the buffer solution.

Therefore, we need to choose the acid and its conjugate base that have pKa values close to 7.40. In this case, we would choose the acid [tex]H_{2}PO_{4-}[/tex] and its conjugate base [tex]HPO_{42-}[/tex], whose pKa values are 7.21 and 12.32, respectively.

By mixing these two components in equal amounts, we can create a phosphate buffer with a pH of 7.40.

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A 0.033M solution of a weak acid (HA) has a pH of 4.11. What is the Ka of the acid

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The concentration of hydrogen ions, conjugate base, and weak acid must be taken into account, as well as the degree of dissociation of the acid. In this case, the Ka of the weak acid is [tex]1.89 \times 10^{-6.[/tex]

To determine the Ka of a weak acid from its pH, it is necessary to use the equation for the acid dissociation constant:

Ka = [H+][A-]/[HA]

where [H+] is the concentration of the hydrogen ions, [A-] is the concentration of the conjugate base, and [HA] is the concentration of the weak acid.

In this problem, the pH of the solution is 4.11, which means that the concentration of [H+] can be calculated as follows:

pH = -log[H+]

4.11 = -log[H+]

[tex][H+] = 7.94 \times 10^{-5} M[/tex]

Since the acid is weak, it does not completely dissociate, so the concentration of [A-] can be assumed to be equal to [H+], and the concentration of [HA] is given as 0.033 M. Thus, the equation for Ka can be simplified as:

[tex]Ka = [H+]^2 / [HA]\\Ka = (7.94 \times 10^{-5})^{2} / 0.033\\Ka = 1.89 \times 10^{-6[/tex]

Therefore, the Ka of the weak acid is [tex]1.89 \times 10^{-6.[/tex]

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Predict the major product for the reaction. The starting material is an alkene where carbon 1 has a cyclohexyl and methyl substituent, and carbon 2 has a methyl and hydrogen substituent. This reacts with C l 2 in the presence of ethanol. Draw the major product.

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The major product of the reaction will be the 1,2-dichloroalkane .

The reaction is likely a halogenation reaction, where the alkene reacts with [tex]Cl_2[/tex] in the presence of ethanol as a solvent. Specifically, the double bond in the starting material will undergo electrophilic addition to one of the chlorine atoms, forming a carbocation intermediate. This intermediate can then undergo a nucleophilic attack by the chloride ion, resulting in substitution of the original double bond with a new carbon-chlorine bond.

In this case, the major product of the reaction will be the 1,2-dichloroalkane, where both carbons of the original double bond have been replaced with chlorine atoms.  

The reaction can be represented as follows:

[tex]CH_3[/tex]
  |
[tex]CH_3C[/tex] -- [tex]CH(C_6H_1_1)Cl[/tex] + [tex]Cl_2[/tex] + EtOH → [tex]CH_3C[/tex] --[tex]CH(C_6H_1_1)Cl_2[/tex] + HCl + EtOH
  |
 H

Therefore, The cyclohexyl and methyl substituents on carbon 1 and the methyl and hydrogen substituents on carbon 2 will remain unchanged in the final product. Hence, the major product of the reaction will be the 1,2-dichloroalkane .

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Which of the following monosaccharides is not a carboxylic acid? A) 6-phospho-gluconate. B) gluconate. C) glucose. D) glucuronate. E) muramic acid.

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Among the following monosaccharides, the one that is not a carboxylic acid is C) glucose.

Carboxylic acid refers to a group of organic compounds that contain a carboxyl group (-COOH) attached to a carbon atom.


A) 6-phospho-gluconate is a derivative of gluconic acid, which is a carboxylic acid.

B) gluconate is a salt or ester of gluconic acid, which is also a carboxylic acid.

D) glucuronate is a salt or ester of glucuronic acid, a carboxylic acid.

E) muramic acid is a modified sugar containing both a carboxylic acid and an amino group.

C) glucose is an aldohexose sugar, which means it has an aldehyde functional group rather than a carboxylic acid functional group. It is an essential source of energy for cellular metabolism but does not have a carboxylic acid group.

Therefore, glucose is a monosaccharide that is not an acid.

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calcium hydroxide, ca(oh)2, is a strong base that has a low solubility in water. what is the ph of a solution of 2.3×10−4m calcium hydroxide at 25.0∘c?

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The pH of a solution of 2.3×10⁻⁴ M calcium hydroxide (Ca(OH)₂) at 25.0°C is approximately 10.66.

To determine the pH of a solution of 2.3×10⁻⁴ M calcium hydroxide (Ca(OH)₂) at 25.0°C, we can calculate it using the fact that it is a strong base, despite its low solubility in water. Since Ca(OH)₂ dissociates into two OH⁻ ions, the concentration of OH⁻ ions in the solution will be 2 × 2.3×10⁻⁴ M = 4.6×10⁻⁴ M. To find the pH, we first calculate the pOH using the formula:

pOH = -log₁₀[OH⁻]

pOH = -log₁₀(4.6×10⁻⁴) ≈ 3.34

Next, we find the pH using the relationship between pH and pOH at 25°C:

pH + pOH = 14

pH = 14 - pOH = 14 - 3.34 ≈ 10.66

Therefore, the pH of the 2.3×10⁻⁴ M calcium hydroxide solution at 25.0°C is approximately 10.66.

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if, by mistake, a chemist used 100thanol rather than diethyl ether as the reaction solvent, would the grignard synthesis still proceed as expected?

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No, the Grignard synthesis would not proceed as expected if a chemist used 100% ethanol rather than diethyl ether as the reaction solvent.

Would using 100% ethanol instead of diethyl ether affect the outcome of the Grignard synthesis?

The Grignard synthesis is a powerful tool used in organic chemistry for creating carbon-carbon bonds. The reaction involves the reaction of an organomagnesium halide (Grignard reagent) with a carbonyl compound, such as an aldehyde or ketone. The reaction takes place in an anhydrous environment, typically using diethyl ether as the solvent.

However, if a chemist were to mistakenly use 100% ethanol instead of diethyl ether as the reaction solvent, the Grignard synthesis would not proceed as expected. This is because ethanol is a polar solvent, unlike diethyl ether, which is a nonpolar solvent. As a result, the Grignard reagent would be significantly less soluble in ethanol, and the reaction may not even take place at all.

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____________ type of reaction undergoes a concerted cycloaddition.

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The Diels-Alder reaction undergoes a concerted cycloaddition. It is a type of organic chemical reaction that involves the addition of a diene and a dienophile to form a cyclic compound.

In a Diels-Alder reaction, a conjugated diene reacts with a dienophile to form a cyclic product, which occurs in a single, concerted step. The reaction involves a 4π-electron diene and a 2π-electron dienophile, creating a new six-membered ring with a double bond.

The concerted mechanism ensures that all bond-making and bond-breaking processes occur simultaneously, leading to high regioselectivity and stereoselectivity. The Diels-Alder reaction is a valuable synthetic tool in organic chemistry, as it allows for the formation of complex cyclic compounds from relatively simple starting materials, and has applications in pharmaceuticals, natural products synthesis, and material science.

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Use the Ksp values to calculate the molar solubility of each of the following compounds in pure water.MX (Ksp = 2.31×10−11)Ag2CrO4 (Ksp = 1.12×10−12)Ni(OH)2 (Ksp = 5.48×10−16)

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The molar solubility of MX in pure water is approximately 4.81×10^−6 M, the molar solubility of silver chromate is approximately 1.09×10^−4 micro Moles, and the molar solubility of nickel hydroxide is approximately 5.70 micro Moles.

The molar solubility of a compound is the number of moles of the compound that can dissolve per liter of solution before reaching saturation.

To calculate the molar solubility, we need to use the equilibrium expression for the dissolution of the compound, as well as the given Ksp value. For the compound MX, the dissolution equilibrium can be written as:[tex]MX(s) = M^+(aq) + X^-(aq)[/tex]

The Ksp value of[tex]2.31×10^{-11}[/tex] is the product of the concentrations of the ions in solution at equilibrium, and can be written as: [tex]Ksp = [M^+][X^-][/tex]

Since MX dissociates completely, we can assume that the concentration of MX at equilibrium is equal to the molar solubility, s. Therefore:

Ksp = [tex][M^+][X^-] = s^2[/tex]

[tex]s = sqrt(Ksp) = sqrt(2.31×10^−11) ≈ 4.81×10^−6 M[/tex]

The Ksp value of 1.12 is the product of the concentrations of the ions in the solution at equilibrium, and can be written as:

[tex]Ksp = [Ag^+]^2[CrO4^2-][/tex] Assuming that the molar solubility of Silver chromate is s, we can write: [tex][Ag^+] = 2s, [CrO4^2-] = s[/tex]

Substituting into the Ksp expression, we get: Ksp = (2s)^2 * s = 4s^3 Solving for s, we get: s = (Ksp/4)^(1/3) = (1.12×10^−12/4)^(1/3) ≈ 1.09×10^−4 M

Assuming that the molar solubility of nickel hydroxide is s, we can write:

[tex][Ni^2+] = s [OH^-] = 2s[/tex]. Substituting into the Ksp expression, we get: Ksp =[tex]s * (2s)^2 = 4s^3[/tex] Solving for s, we get: [tex]s = (Ksp/4)^(1/3) = (5.48×10^−16/4)^(1/3) ≈ 5.70×10^−6 M[/tex]

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calculate the molar solubility (mol/l) of pbcro4. Ksp = 1.8 X 10^-14

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The molar solubility of PbCrO4 is 1.34 x 10^-7 mol/L.

To calculate the molar solubility of PbCrO4, we need to use the Ksp value given, which is 1.8 x 10^-14. The equation for the dissociation of PbCrO4 is: PbCrO4 (s) ↔ Pb2+ (aq) + CrO42- (aq)

Let x be the molar solubility of PbCrO4 in moles per liter. Then, the equilibrium concentrations of Pb2+ and CrO42- are also x.

Using the Ksp expression for PbCrO4, we can write:
Ksp = [Pb2+][CrO42-] = x^2
Substituting the given Ksp value, we get:
1.8 x 10^-14 = x^2
Taking the square root of both sides, we get:
x = sqrt(1.8 x 10^-14) = 1.34 x 10^-7 mol/L
Therefore, the molar solubility of PbCrO4 is 1.34 x 10^-7 mol/L.

Here is a step by step explanation to calculate the molar solubility (mol/L) of PbCrO4 with Ksp = 1.8 x 10^-14

1. Write the balanced chemical equation for the dissolution of PbCrO4:
PbCrO4 (s) ⇌ Pb²⁺ (aq) + CrO₄²⁻ (aq)

2. Let the molar solubility of PbCrO4 be 'x'. At equilibrium, the concentration of Pb²⁺ and CrO₄²⁻ will also be 'x'.

3. Write the expression for Ksp:
Ksp = [Pb²⁺] * [CrO₄²⁻]

4. Substitute the equilibrium concentrations and Ksp value into the equation:
1.8 x 10^-14 = (x) * (x)

5. Solve for 'x':
x² = 1.8 x 10^-14
x = √(1.8 x 10^-14)
x ≈ 1.34 x 10^-7 mol/L

So, the molar solubility of PbCrO4 is approximately 1.34 x 10^-7 mol/L.


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You have an electrostatic force of 100 N. If you triple the charges of q1 and q2 , and you double the distance, how will the electrostatic force change?

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If the charges of q1 and q2 are tripled, and the distance is doubled, the electrostatic force between them will change by a factor of 9. The electrostatic force is directly proportional to the product of the charges and inversely proportional to the square of the distance between them, as stated by Coulomb's Law.

According to Coulomb's Law, the electrostatic force (F) between two charges (q1 and q2) is given by the equation F = k * (q1 * q2) / r^2, where k is the electrostatic constant and r is the distance between the charges.

If we triple the charges of both q1 and q2, the new force (F') can be calculated as F' = k * (3q1 * 3q2) / r^2 = 9 * (k * (q1 * q2) / r^2) = 9F.

Additionally, if the distance is doubled (2r), the new force (F'') can be calculated as F'' = k * (3q1 * 3q2) / (2r)^2 = 9 * (k * (q1 * q2) / 4r^2) = (9/4)F.

Therefore, the electrostatic force will change by a factor of 9 when the charges are tripled and the distance is doubled.

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will the following alcohol be likely to undergo rearrangement during a dehydration reaction? Yes, it will undergo rearrangement. Rearrangement is possible, but usually will not occur. Rearrangement will occur about half of the time. Rearrangement will not occur. It is impossible to determine without more information.

Answers

The following alcohol be likely to undergo rearrangement during a dehydration is a. Yes, it will undergo rearrangement

During dehydration reactions, alcohols can rearrange to form more stable intermediates, such as carbocations, this rearrangement usually involves the movement of a hydrogen atom or an alkyl group to a neighboring carbon atom, resulting in a more stable, substituted carbocation. The likelihood of rearrangement depends on the structure of the alcohol and the stability of the carbocation formed. Rearrangements are more likely to occur if the resulting carbocation is significantly more stable than the initial one. Generally, rearrangement will not occur if the starting carbocation is already highly substituted or stable.

However, without more information about the specific alcohol, it is impossible to determine the exact probability of rearrangement occurring during the dehydration reaction. In some cases, rearrangement may not occur, while in others, it may occur about half of the time or even more frequently, it is essential to know the alcohol's structure and the reaction conditions to predict the rearrangement probability accurately. So therefore the following alcohol be likely to undergo rearrangement is a. Yes, it will undergo rearrangement during a dehydration reactions.

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