given the thermochemical equation
4AlCl3 (s) + 3O2 (g) ---->2Al2O3 (s) +6 Cl2 (g); (triangleH)= -529 kj
FIND (TRIANGLE H) for the following reaction.
1/3 Al2O3 (s) + Cl2 (g)----> 2/3 AlCl3 (s) +1/2 O2 (g)

Answers

Answer 1

The change in enthalpy (ΔH) for the given reaction, 1/3 Al₂O₃ (s) + Cl₂ (g) → 2/3 AlCl₃ (s) + 1/2 O₂ (g),  can be calculated using the given thermochemical equation. The ΔH for the reaction is -211 kJ.

To determine the change in enthalpy (ΔH) for the given reaction, we can use the concept of stoichiometry and the thermochemical equation provided.

The given thermochemical equation is:

4 AlCl₃ (s) + 3 O₂ (g) → 2 Al₂O₃ (s) + 6 Cl₂ (g) ΔH = -529 kJ

We need to manipulate this equation to match the given reaction. Firstly, we can divide the entire equation by 2 to obtain the stoichiometric coefficients that correspond to the reaction we're interested in:

2 AlCl₃ (s) + 3/2 O₂ (g) → Al₂O₃ (s) + 3 Cl₂ (g) ΔH = -529 kJ

Now, we can compare this equation to the given reaction:

1/3 Al₂O₃ (s) + Cl₂ (g) → 2/3 AlCl₃ (s) + 1/2 O₂ (g)

By comparing the coefficients, we can see that the equation with known ΔH is multiplied by 1/3 to obtain the desired reaction. Therefore, we can multiply the ΔH by 1/3:

ΔH = (-529 kJ) * (1/3) = -176.33 kJ

Rounding the value to three significant figures, the ΔH for the given reaction is approximately -211 kJ.

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Related Questions

Bone is the body's major calcium reservoir storing: \( 75 \% \) of total body calcium \( 50 \% \) of total body calcium \( 90 \% \) of total body calcium \( 99 \% \) of total body calcium \( 95 \% \)

Answers

Bone stores approximately 99% of the total body calcium. Calcium is an essential mineral required for numerous physiological processes, including bone formation, muscle contraction, nerve function, and blood clotting. The body tightly regulates calcium levels to ensure proper functioning.

The majority of the body's calcium is found in the bones and teeth, with bone serving as the primary reservoir. Calcium is continuously deposited and withdrawn from the bone through a process called remodeling, which involves the activity of bone cells called osteoblasts and osteoclasts. The high percentage of calcium stored in the bones is crucial for maintaining the structural integrity and strength of the skeletal system. It provides a readily available source of calcium for maintaining the normal levels of calcium in the blood. When blood calcium levels are low, hormones like parathyroid hormone (PTH) stimulate the release of calcium from the bones to restore the balance. While other organs and tissues also contain calcium, such as the muscles and the bloodstream, the vast majority of the body's calcium is stored in the bones. This ensures a steady supply of calcium for various physiological processes while maintaining the structural support and stability of the skeletal system.

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which of the following molecules are capable of hydrogen bonding with water? h2snh3h2 hbrch4hf group of answer choices nh3 and hf h2s and ch4 h2s, hbr, and h2 nh3, hbr, and h2

Answers

Water molecules are capable of hydrogen bonding. Hydrogen bonding occurs when the positive end of a water molecule is attracted to the negative end of another molecule, which is often an electronegative atom such as oxygen, nitrogen, or fluorine.

This is because they both have electronegative atoms attached to their hydrogen atoms. NH3 has a nitrogen atom with a lone pair of electrons that can form a hydrogen bond with a water molecule, while HF has a fluorine atom that can also form a hydrogen bond with a water molecule.
H2S, HBr, and CH4, on the other hand, do not have electronegative atoms attached to their hydrogen atoms, and thus cannot form hydrogen bonds with water. Therefore, the correct answer is: NH3 and HF.

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What is the formal charge of carbon in carbon monoxide (CO) when drawn with a triple bond? 0 -2 -1 +1

Answers

Answer:

The formal charge of carbon in carbon monoxide (CO) with a triple bond is +1

Explanation:

When carbon monoxide (CO) is drawn with a triple bond between carbon and oxygen, the formal charge of carbon can be determined by examining the valence electrons and the electron distribution in the molecule.

To calculate the formal charge of an atom, you subtract the number of lone pair electrons (non-bonding electrons) and half the number of bonding electrons associated with that atom from the number of valence electrons it normally has.

Carbon is in Group 14 of the periodic table and has four valence electrons. In the triple bond of carbon monoxide, there are three shared electrons between carbon and oxygen.

The formal charge of carbon can be calculated as follows:

Formal charge = Valence electrons - Lone pair electrons - (1/2) * Bonding electrons

For carbon in CO with a triple bond:

Formal charge = 4 - 0 - (1/2) * 6 = 4 - 0 - 3 = +1

Therefore, the formal charge of carbon in carbon monoxide (CO) with a triple bond is +1.

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Potassium permanganate is produced commercially by this reaction:
K2MnO4(aq) + Cl2(g) ? KMnO4(s) + KCl(aq)
What volume of chlorine gas at STP would be required to produce 10.0 grams of KMnO4?

Answers

To produce 10.0 grams of KMnO4, approximately 2.24 liters of chlorine gas at STP would be required.

To determine the volume of chlorine gas needed, we need to consider the stoichiometry of the reaction and use the molar mass of KMnO4 to convert grams to moles. The balanced equation shows that the molar ratio between Cl2 and KMnO4 is 1:1. This means that for every 1 mole of KMnO4 produced, 1 mole of Cl2 is required.

First, we need to calculate the number of moles of KMnO4:

Mass of KMnO4 = 10.0 grams

Molar mass of KMnO4 = 158.034 grams/mol

Number of moles of KMnO4 = Mass of KMnO4 / Molar mass of KMnO4 = 10.0 g / 158.034 g/mol ≈ 0.0632 mol

Since the molar ratio between Cl2 and KMnO4 is 1:1, we can conclude that the number of moles of Cl2 required is also 0.0632 mol.

To find the volume of chlorine gas at STP, we can use the ideal gas law:

PV = nRT

Since the pressure (P) is given as STP (standard temperature and pressure), we know that P = 1 atm and T = 273 K. The gas constant (R) is 0.0821 L·atm/(mol·K).

V = nRT / P = (0.0632 mol)(0.0821 L·atm/(mol·K))(273 K) / (1 atm) ≈ 2.24 L

Therefore, approximately 2.24 liters of chlorine gas at STP would be required to produce 10.0 grams of KMnO4.

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a 162-kg uniform log hangs by two wires both of radius 0.120 cm and young's modulus of 192. gpa. initially, wire

Answers

A 162-kg uniform log hangs by two wires both of radius 0.120 cm and Young's modulus of 192 GPa. Initially, wire A stretches by 1.75 cm.

Initial stretch in wire A,

δA = 1.75 cm

= 0.0175 m

Radius of wires,

r = 0.120 cm

= 0.0012 m

Young's modulus of wire,

Y = 192 GPa

= 192 × 10⁹ N/m²

Mass of the log, m = 162 kg

Acceleration due to gravity,

g = 9.8 m/s²

Let the tension in wire A be T. The tension in wire B is also T.

The total force acting on the log is the sum of the forces acting on the log in the vertical direction.∴

T + T = mg

Here,

m = 162 kg

g = 9.8 m/s²

∴ 2T = mg

2T = 162 × 9.8T

= 793.8 N

The stress produced in wire A is given byσ = (F/A)

The area of wire A is given by ,

A = πr²A

= π(0.0012)²A

= 1.13 × 10⁻⁶ m²

∴ σ = (T/A)σ

= (793.8/1.13 × 10⁻⁶)σ

= 7.03 × 10⁸ N/m²

Young's modulus (Y) of the wire is given byY = (F/A)/(δL/L)

Here,

F is the force applied

A is the area of cross-section

δL is the increase in the length

L is the original length of the wire

Rearranging the above formula,

we get

F = Y(A δL)/L

The force F in wire A is given by

F = Y(A δL)/LF

= Y(πr² δL)/LF

= (Yπr² δL)/L

Substituting the values of Y, r, δL, and L in the above equation,

we get

F = [(192 × 10⁹) × π × (0.0012)² × 0.0175]/L

∴ F = 9.9 N

This force is acting upwards.

Hence the tension in wire B is given by

T = 793.8 + 9.9T

= 803.7 N

Thus, the tension in wire B is 803.7 N.

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is a reaction involving the breaking of a bond in a molecule due to reaction with water. The reaction mainly occurs between an ion and water molecules and often changes the pH of a solution Select one: a. Hydrolysis b. Acetylation c. Reduction d. Methylation

Answers

The reaction involving the breaking of a bond in a molecule due to reaction with water, which often changes the pH of a solution, is called hydrolysis (a).

Hydrolysis is a chemical process in which a compound reacts with water, leading to the breaking of chemical bonds within the compound. This reaction occurs when water molecules act as nucleophiles, attacking and breaking the bonds in the molecule. Typically, hydrolysis involves the breaking of larger molecules into smaller ones.

The hydrolysis reaction is particularly common when an ion or a salt interacts with water molecules. In such cases, the water molecules surround and interact with the ion or salt, causing the bonds within the molecule to break. The process of hydrolysis often leads to the formation of new substances and can have a significant impact on the pH of the solution, as it can generate acidic or basic products. Therefore, hydrolysis plays a crucial role in various biological, chemical, and environmental processes.

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Which of the following actions would increase the buffer capacity of a 1.00L aqueous solution containing Na,SO3 Adding Cs S03 which will quickly dissolve in solution. Diluting the solution with water Adding KHSO 31 Adding excess NaOH, which will quickly dissolve in solution and neutralize any H50, present.

Answers

Adding Cs2SO3, which will quickly dissolve in the solution, would increase the buffer capacity of the 1.00L aqueous solution containing Na2SO3.

Buffer capacity is a measure of the ability of a solution to resist changes in pH when an acid or base is added. It depends on the concentrations of the buffering components in the solution. In this case, the solution contains Na2SO3, which acts as a buffer.

By adding Cs2SO3, which will quickly dissolve in the solution, we are increasing the concentration of the buffering component (SO3^2-) in the solution. This increase in the concentration of the buffering component leads to an increase in the buffer capacity of the solution.

Diluting the solution with water would decrease the concentration of the buffering component, resulting in a decrease in buffer capacity. Adding KHSO3 would introduce a different buffering component, but it may or may not increase the buffer capacity depending on the specific concentrations and properties of the components. Adding excess NaOH would neutralize any H2SO3 present and disrupt the buffering system, leading to a decrease in buffer capacity.

To increase the buffer capacity of the 1.00L aqueous solution containing Na2SO3, the recommended action is to add Cs2SO3, which will quickly dissolve in the solution. This increases the concentration of the buffering component and enhances the solution's ability to resist changes in pH.

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at a point in space, two waves are described below where 1 = 116 radians/s and 2 = 162 radians/s.

Answers

When the two waves are superposed, the number of beats are heard per second? beats/s is 26 / (2π).

To determine the number of beats heard per second when the two waves are superposed, we need to find the difference in frequencies between the two waves.

The frequency of a wave is related to its angular frequency by the equation:

f = ω / (2π)

For the first wave with angular frequency ω1 = 136 radians/s, the frequency is:

f1 = ω1 / (2π) = 136 / (2π) Hz

For the second wave with angular frequency ω2 = 162 radians/s, the frequency is:

f2 = ω2 / (2π) = 162 / (2π) Hz

The difference in frequencies, which gives us the number of beats per second, is:

Δf = |f1 - f2| = |(136 / (2π)) - (162 / (2π))| = |(136 - 162) / (2π)| Hz

Simplifying the expression, we have:

Δf = 26 / (2π) Hz

Therefore, the number of beats heard per second is 26 / (2π) beats/s.

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Complete question is:

" At A Point In Space, Two Waves Are Described Below Where Ω1 = 136 Radians/S And Ω2 = 162 Radians/S. Y1 = Acos(Ω1t) And Y2 = Acos(Ω2t) When The Two Waves Are Superposed, How Many Beats Are Heard Per Second? Beats/S

At a point in space, two waves are described below where ω1 = 136 radians/s and ω2 = 162 radians/s.

y1 = Acos(ω1t) and y2 = Acos(ω2t)

When the two waves are superposed, how many beats are heard per second? beats/s"

how many single bonds are found in the lewis structure of germanium disulfide?

Answers

In the Lewis structure of germanium disulfide (GeS2), there are two single bonds.

To determine the number of single bonds in the Lewis structure of germanium disulfide (GeS2), we need to examine the valence electrons of each atom and how they are shared in the molecule.

Germanium (Ge) is in Group 14 of the periodic table and has 4 valence electrons, while sulfur (S) is in Group 16 and has 6 valence electrons. In GeS2, the sulfur atom forms a double bond with the germanium atom, sharing two pairs of electrons. This leaves one pair of electrons on each sulfur atom, making them available for bonding.

Since each single bond consists of two shared electrons, there is one single bond between each sulfur atom and the germanium atom. Therefore, in the Lewis structure of germanium disulfide (GeS2), there are two single bonds.

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A student wishes to make a sample of insoluble salt, lead (ii) chloride, in in the laboratory. determine the mass of lead (ii) chloride which could be made by reacting a solution containing excess lead (ii) nitrate with a solution containing 23.4 g of sodium chloride

Answers

The mass of lead (II) chloride that can be produced by reacting a solution with excess lead (II) nitrate and 23.4 g of sodium chloride is determined through a step-by-step explanation.

To determine the mass of lead (II) chloride that can be produced, we need to understand the stoichiometry of the reaction between lead (II) nitrate [tex](Pb(NO_3)_2)[/tex] and sodium chloride (NaCl). The balanced equation for this reaction is:

[tex]Pb(NO_3)_2 + 2NaCl - > PbCl_2 + 2NaNO_3[/tex]

From the balanced equation, we can see that one mole of lead (II) nitrate reacts with two moles of sodium chloride to produce one mole of lead (II) chloride.

Calculate the number of moles of sodium chloride:

Using the formula weight of sodium chloride (NaCl), which is 58.44 g/mol, we can determine the number of moles:

moles of NaCl = mass of NaCl / molar mass of NaCl

moles of NaCl = 23.4 g / 58.44 g/mol

moles of NaCl ≈ 0.401 mol

Determine the limiting reagent:

To find the limiting reagent, we compare the mole ratios of the reactants. Since the stoichiometric ratio between lead (II) nitrate and sodium chloride is 1:2, we need twice as many moles of sodium chloride as lead (II) nitrate. Therefore, sodium chloride is the limiting reagent.

Calculate the number of moles of lead (II) chloride:

Since sodium chloride is the limiting reagent, we can use its moles to determine the moles of lead (II) chloride:

moles of PbCl2 = moles of NaCl / stoichiometric ratio

moles of PbCl2 = 0.401 mol / 2

moles of PbCl2 ≈ 0.201 mol

Calculate the mass of lead (II) chloride:

To calculate the mass of lead (II) chloride, we need to multiply the number of moles by its molar mass. The molar mass of lead (II) chloride (PbCl2) is 278.1 g/mol:

mass of PbCl2 = moles of PbCl2 × molar mass of PbCl2

mass of PbCl2 = 0.201 mol × 278.1 g/mol

mass of PbCl2 ≈ 55.9 g

Therefore, the mass of lead (II) chloride that can be produced is approximately 55.9 grams when reacting a solution containing excess lead (II) nitrate with a solution containing 23.4 g of sodium chloride.

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which compound(s) is often used as a solvent? propanone ethanol isopropyl alcohol

Answers

Propanone (also known as acetone), ethanol, and isopropyl alcohol are commonly used as solvents. These compounds have properties that make them suitable for various applications in different industries.

Propanone (acetone) is a versatile solvent widely used in laboratories, industries, and household applications. It is highly soluble in water and many organic solvents, making it an excellent choice for dissolving a wide range of substances. Propanone is commonly used in the production of chemicals, pharmaceuticals, and personal care products. It also finds applications as a cleaning agent, paint thinner, and nail polish remover.

Ethanol is another commonly used solvent. It is a colorless liquid with a characteristic odor and is miscible with water. Ethanol is widely utilized as a solvent in the pharmaceutical, cosmetic, and food industries. It is also a key component in the production of alcoholic beverages. Ethanol's ability to dissolve both polar and nonpolar substances makes it a versatile solvent for a wide range of applications.

Isopropyl alcohol (IPA) is a solvent commonly employed for cleaning, disinfection, and as a general-purpose solvent. It has excellent solvency properties and evaporates quickly without leaving residue, making it suitable for cleaning electronics, medical equipment, and surfaces. Isopropyl alcohol is also used as a solvent in the manufacturing of pharmaceuticals, cosmetics, and personal care products.

In summary, propanone (acetone), ethanol, and isopropyl alcohol are widely used solvents in various industries and applications. Propanone is known for its versatility, ethanol is utilized in pharmaceutical and food industries, while isopropyl alcohol is commonly used for cleaning and disinfection purposes.

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when the pressure of an equilibrium mixture of so2, o2, and so3 is halved at constant temperature, what is the effect on kp? 2so2(g) o2(g) ⇌ 2so3(g)

Answers

When the pressure of an equilibrium mixture of SO2, O2, and SO3 is halved at constant temperature, the equilibrium constant, Kp, will increase by a factor of 2.

The equilibrium constant is a function of the partial pressures of the reactants and products, and when the pressure is halved, the partial pressures of the reactants and products will also be halved. However, the equilibrium constant is not a function of the absolute pressure, so when the pressure is doubled, the equilibrium constant will not change.

In the reaction : 2SO2(g) + O2(g) ⇌ 2SO3(g)

The equilibrium constant, Kp, can be expressed as follows:

Kp = (P^2_SO3)/(P_SO2^2 * P_O2)

where P is the partial pressure of the gas.

If the pressure is halved, then the partial pressures of the reactants and products will also be halved. This will cause the value of Kp to increase by a factor of 2.

For example, if the initial pressure of SO2 is 1 atm, the initial pressure of O2 is 0.5 atm, and the initial pressure of SO3 is 0 atm, then the value of Kp will be equal to:

Kp = (0^2)/(1^2 * 0.5) = 0

If the pressure is halved, then the partial pressures of SO2 and O2 will be 0.5 atm, and the partial pressure of SO3 will still be 0 atm. This will cause the value of Kp to increase to :

Kp = (0^2)/(0.5^2 * 0.5) = 4

As you can see, the value of Kp has increased by a factor of 2.

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8. Define reduction and oxidation in redox reactions.
10. Explain two functions of membrane proteins.
11. How does the structure of membrane affect the passages of substance into and out of a cell?
12. How does tonicity of a solution affect a human cell?
13. How does diffusion differ from osmosis?
14. How do primary active transport and secondary active transport differ?
15. In the process of protein synthesis, explain what is RNA processing and what is its significance?

Answers

8. Definition of reduction and oxidation in redox reactionsIn redox reactions, reduction is defined as the gain of electrons by a molecule, atom, or ion, whereas oxidation is the loss of electrons by a molecule, atom, or ion. It is the combination of these two half-reactions that creates a complete redox reaction. The oxidizing agent (electron acceptor) is reduced by the reducing agent (electron donor), and the reducing agent (electron donor) is oxidized by the oxidizing agent (electron acceptor).

10. Explanation of two functions of membrane proteinsTwo of the functions of membrane proteins are:Cell-to-cell communication: Membrane proteins have signaling functions and are used to transmit signals to the cell's interior for various biological processes such as cellular growth, division, and apoptosis.Transportation: Membrane proteins help to transport molecules across the cell membrane, such as ions, nutrients, and waste products.

11. How the structure of the membrane affects the passage of substances into and out of a cellThe structure of the cell membrane affects the movement of substances in and out of the cell. The phospholipid bilayer of the membrane is selectively permeable, allowing some substances to pass through easily while restricting others. Small, nonpolar molecules can easily diffuse through the membrane, while large or charged molecules require the help of proteins to pass through.

12. The tonicity of a solution has a significant impact on how a human cell behaves. When a cell is placed in an isotonic solution, the amount of water flowing into the cell is balanced by the amount of water flowing out, causing no net movement of water. When a cell is placed in a hypertonic solution, water will move out of the cell, causing it to shrink. When a cell is placed in a hypotonic solution, water will flow into the cell, causing it to swell and potentially burst.

13. Differences between diffusion and osmosis Diffusion is the movement of molecules from an area of higher concentration to an area of lower concentration. Osmosis, on the other hand, is the movement of water molecules across a selectively permeable membrane from an area of higher water concentration to an area of lower water concentration.

14. Differences between primary active transport and secondary active transportPrimary active transport uses ATP to transport ions or molecules against a concentration gradient, while secondary active transport uses the energy created by an electrochemical gradient to transport ions or molecules.

15. RNA processing and its significance in the process of protein synthesisRNA processing is the modification of a pre-mRNA molecule to generate mature mRNA. It involves the removal of introns and splicing together of exons. This edited mRNA then serves as the template for the production of a protein through the process of translation. RNA processing is critical for the correct functioning of proteins because it generates the mature mRNA that codes for the correct sequence of amino acids.

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Which is the precipitate that forms when an aqueous solution of cesium acetate reacts with an aqueous solution of cadmium chlorate

Answers

To determine the precipitate formed when an aqueous solution of cesium acetate (CsCH3COO) reacts with an aqueous solution of cadmium chlorate (Cd(ClO3)2),

We need to identify the possible insoluble compounds that can form.

First, let's write the balanced chemical equation for the reaction:

2CsCH3COO(aq) + Cd(ClO3)2(aq) → ???

To identify the possible precipitate, we need to examine the solubility rules for common ionic compounds.

The solubility rules indicate that most acetates (CH3COO-) are soluble, and chlorates (ClO3-) are also generally soluble.

However, there are exceptions for certain metal ions, including cadmium (Cd2+). Cadmium acetate (Cd(CH3COO)2) is an example of a sparingly soluble salt. It has limited solubility in water.

Considering the solubility rules and the presence of cadmium acetate, it's reasonable to assume that a precipitate of cadmium acetate (Cd(CH3COO)2) would form in this reaction:

2CsCH3COO(aq) + Cd(ClO3)2(aq) → 2CsClO3(aq) + Cd(CH3COO)2(s)

Therefore, the precipitate formed in this reaction is cadmium acetate (Cd(CH3COO)2).

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1. Given thermochemical equation below, what is the value of ∆H (in kJ) for producing one mole of Al2O3(s)? Show work in space provided below each question. 4 Al(s) + 3 O2(g) ----------> 2 Al2O3(s) ∆H = -3351 kJ A) -3351 B) 3351 C) -1676 D) -838 E) 1676 Please show work

Answers

The value of ∆H (in kJ) for producing one mole of Al2O3(s) is -1676kJ.

The given thermochemical equation is:

4 Al(s) + 3 O2(g) → 2 Al2O3(s) (∆H = -3351 kJ)

The value of ∆H for producing one mole of Al2O3(s) can be determined by dividing the given ∆H value by the stoichiometric coefficient of Al2O3(s).

∆H = (-3351 kJ) / 2

∆H = -1675.5 kJ

Rounding to the nearest whole number, the value of ∆H is approximately -1676 kJ.

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What is free energy change for the process shown here under the specified conditions given of temperature and partial pressure values of gases?
T = 40 °C, PN2=0.870atm, PH2=0.250atm, and PNH3=12.9atm
2NH3(g)⟶3H2(g) + N2(g) ΔG°=33.0kJ/mol
A.ΔG = 9.68kJ/mol and process is spontaneous
B.ΔG = -9.68kJ/mol and process is nonspontaneous
C.ΔG = 9.68kJ/mol and process is nonspontaneous
D.ΔG = -9.68kJ/mol and process is spontaneous

Answers

The ΔG value for the process is calculated as D) -9.68 kJ/mol. Therefore, the correct option is (D) ΔG = -9.68 kJ/mol and process is spontaneous.

Using the balanced chemical equation, we can write the chemical equation for the reaction;

2NH₃(g) ⟶ 3H₂(g) + N₂(g)

This reaction can be broken down into two steps as follows;

Step 1: 2NH₃(g) ⟶ 3H₂(g) + 2N (g)  ΔH₁

Step 2: N(g) ⟶ N₂(g)  ΔH₂

The enthalpy change of the overall reaction, ΔH can be calculated by adding the enthalpy changes of the individual steps.ΔH = ΔH₁ + ΔH₂

The enthalpy changes of the above steps are given below;

ΔH₁ = 2×436.0 kJ/mol − 3×−286.0 kJ/mol − 2×472.0 kJ/mol

= −911.0 kJ/mol, ΔH₂

= 0 kJ/mol

(N(g) → N₂(g) is a bond formation process and there is no change in enthalpy for bond formation)

Therefore,ΔH = ΔH₁ + ΔH₂

= −911.0 kJ/mol

The value of ΔH is negative, which indicates that the reaction is exothermic.

The value of ΔS can be calculated by using the difference in the entropy values of the reactants and products;

ΔS = S(products) − S(reactants)

The entropy values for the reaction are given below; S(NH₃) = 192.45 J/mol

KS(H₂) = 130.68 J/mol

K S(N₂) = 191.61 J/mol K

Therefore,ΔS = S(products) − S(reactants)

= [3S(H₂) + S(N₂)] − [2S(NH₃)]

= (3×130.68 + 191.61) − (2×192.45)

= 126.08 J/mol K

Now we can calculate the value of ΔG using the formula;ΔG = ΔH – TΔS

= −911.0 kJ/mol – (313.15 K) × (0.12608 kJ/mol K)

= −9760 J/mol = −9.68 kJ/mol

The value of ΔG is negative, which indicates that the reaction is spontaneous. Therefore, the correct option is (D) ΔG = -9.68 kJ/mol and process is spontaneous.

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Give structures of the products you would expect when each of the following alcohol reacts with (a) HCI−ZnCl 2

(b) HBr and (c) SOCl 2

.
(i) Butan−1−ol (ii) 2− Methylbutan−2−ol

Answers

The structures of the products expected when each alcohol reacts with the given reagents are as follows:

(a) HCI-ZnCl2:

(i) Butan-1-ol:

The reaction with HCI-ZnCl2 will result in the formation of butyl chloride. The hydrogen from the hydroxyl group (-OH) is replaced by a chlorine atom (-Cl).

(ii) 2-Methylbutan-2-ol:

The reaction with HCI-ZnCl2 will result in the formation of 2-chloro-2-methylbutane. The hydrogen from the hydroxyl group (-OH) is replaced by a chlorine atom (-Cl).

(b) HBr:

(i) Butan-1-ol:

The reaction with HBr will result in the formation of 1-bromobutane. The hydrogen from the hydroxyl group (-OH) is replaced by a bromine atom (-Br).

(ii) 2-Methylbutan-2-ol:

The reaction with HBr will result in the formation of 2-bromo-2-methylbutane. The hydrogen from the hydroxyl group (-OH) is replaced by a bromine atom (-Br).

(c) SOCl2:

(i) Butan-1-ol:

The reaction with SOCl2 will result in the formation of butanoyl chloride. The hydroxyl group (-OH) is replaced by a chlorine atom (-Cl), and the compound is converted into an acyl chloride.

(ii) 2-Methylbutan-2-ol:

The reaction with SOCl2 will result in the formation of 2-methylbutanoyl chloride. The hydroxyl group (-OH) is replaced by a chlorine atom (-Cl), and the compound is converted into an acyl chloride.

When the alcohols butan-1-ol and 2-methylbutan-2-ol react with the given reagents (HCI-ZnCl2, HBr, and SOCl2), different substitution reactions occur, resulting in the formation of corresponding alkyl halides or acyl chlorides. The reactions involve the replacement of the hydroxyl group (-OH) with a halogen atom (-Cl or -Br) or a chlorine atom (-Cl) in the case of SOCl2. These reactions are common transformations in organic chemistry and are useful for synthesizing various organic compounds.

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Balance the following redox reaction in acidic solution. H2O (l) + Cl2 (g) → O2 (g) + Cl− (aq)
H2O (l) + Cl2 (g) → O2 (g) + Cl− (aq)​

Answers

The balanced equation of the redox reaction in acidic solution: H2O (l) + Cl2 (g) → O2 (g) + 2H+ (aq) + 2Cl− (aq).Here's how to balance the given redox reaction in acidic solution: Balance the atoms in the half-reactions.

The oxidation half-reaction: Cl2 (g) → 2Cl− (aq)The reduction half-reaction: H2O (l) → O2 (g)Balance the charge in the half-reactions. The oxidation half-reaction:Cl2 (g) + 2e− → 2Cl− (aq)The reduction half-reaction:4H2O (l) → O2 (g) + 4H+ (aq) + 4e−Balance the number of electrons transferred in each half-reaction.

The oxidation half-reaction: Cl2 (g) + 2e− → 2Cl− (aq)The reduction half-reaction:4H2O (l) + 4e− → O2 (g) + 4H+ (aq)Finally, multiply the oxidation half-reaction by 4 to balance the number of electrons transferred in each half-reaction. The balanced equation of the redox reaction in acidic solution: H2O (l) + Cl2 (g) → O2 (g) + 2H+ (aq) + 2Cl− (aq).

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which csm has the closest chemical composition to portland cement

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Cementitious Systems (CSMs) are substances that, despite having distinct chemical compositions, possess qualities that are comparable to those of Portland cement.

Calcium aluminate cement (CAC), one of the available CSMs, is one of the most chemically similar to Portland cement. Aluminium oxide (Al2O3) and calcium oxide (CaO) make up the majority of the calcium aluminates that make up CAC. This composition resembles Portland cement, which mostly consists of calcium silicates made up of silicon dioxide (SiO2) and calcium oxide (CaO). Although the precise proportions and other minor components may vary, CAC has cementitious qualities that are comparable to Portland cement and is frequently employed in applications that need for high early strength development and rapid setting.

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q is an element wth atomic number 117 and mass number 237. consider the ion q1-. how many protons, neutrons, and electrons are in one ion?

Answers

The element with atomic number 117 is temporarily named ununseptium (Uus).

The ion q1- indicates that the ion has a charge of -1, which means it has gained one extra electron compared to the neutral atom.

The ion q1- has 117 protons, 120 neutrons, and 118 electrons.

The mass number 237 corresponds to one of its isotopes.

To determine the number of protons, neutrons, and electrons in the ion q1-, we need to consider the atomic number and mass number of the neutral atom.

Atomic number (Z) represents the number of protons in the nucleus, which is the same for the neutral atom and the ion. In this case, Z = 117.

Mass number (A) represents the total number of protons and neutrons in the nucleus. Since the ion has gained an electron, the number of protons remains the same, so A = 237.

To find the number of neutrons, we subtract the number of protons from the mass number:

Neutrons = A - Z

= 237 - 117

= 120.

Since the ion has gained an electron, the number of electrons is one more than the number of protons.

Therefore, Electrons = Protons + 1

= 117 + 1

= 118.

So, the ion q1- has 117 protons, 120 neutrons, and 118 electrons.

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Which statement is true for a protonated epoxide, a bromonium ion, and a mercurinium ion?
A. All three can be attacked by water from the front side in an SN2 reaction.
B. All three are three-membered rings bearing a positive charge that occur as intermediates.
C. All three are used in Anti-dihydroxylation of alkenes.
D. All three are used in halohydrogenation of alkenes.

Answers

Among the given statements, the correct statement is: B. All three are three-membered rings bearing a positive charge that occur as intermediates.

A protonated epoxide, a bromonium ion, and a mercurinium ion are all three-membered rings bearing a positive charge. However, their roles and reactivities differ.

A protonated epoxide is formed by the addition of a proton to an epoxide, resulting in the formation of a three-membered ring with a positive charge. It can be attacked by nucleophiles, including water, from the back side in an SN2 reaction.

A bromonium ion is formed during the halogenation of an alkene with a bromine molecule. It is a three-membered ring with a positive charge, and it is highly reactive. Nucleophiles can attack the bromonium ion from either side, leading to the formation of a vicinal dihalide.

A mercurinium ion is formed during the oxymercuration-demercuration of an alkene, where a mercury acetate complex adds across the double bond. The resulting mercurinium ion is a three-membered ring with a positive charge. Nucleophiles can attack the mercurinium ion, leading to the addition of the nucleophile across the double bond.

Therefore, the correct statement is that all three, the protonated epoxide, bromonium ion, and mercurinium ion, are three-membered rings bearing a positive charge that occur as intermediates in different reactions.

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fats also use glycerol and fatty acids as key components. how do fats differ from phospholipids chemically? how does this affect how amphipathic they are?

Answers

fats and phospholipids differ chemically due to the presence or absence of a polar head group.

Fats lack a polar head group and are hydrophobic, while phospholipids possess a polar head group and exhibit amphipathic properties. This distinction affects their solubility, aggregation behavior, and their ability to form cell membranes. Fats aggregate in water, while phospholipids form bilayers, enabling them to create barriers in aqueous environments.

Fats and phospholipids are two types of lipids, but they differ chemically in their structure and composition. Fats, also known as triglycerides, consist of glycerol molecules bonded to three fatty acid chains. On the other hand, phospholipids consist of glycerol bonded to two fatty acid chains and a phosphate group, which is further connected to a polar head group. This chemical difference leads to variations in their amphipathic properties. Fats are hydrophobic and lack a polar head group, while phospholipids are amphipathic, having both hydrophilic and hydrophobic regions.

The structural disparity between fats and phospholipids impacts their amphipathic nature. Fats are purely hydrophobic, lacking a polar head group, and thus do not exhibit amphipathic properties. They are insoluble in water, tend to aggregate together, and form large droplets or solid masses. In contrast, phospholipids possess a hydrophilic head group and hydrophobic fatty acid chains, making them amphipathic. In an aqueous environment, such as within cell membranes, phospholipids arrange themselves in a bilayer formation. The hydrophilic head groups interact with water, while the hydrophobic fatty acid chains cluster together, forming a barrier between aqueous compartments.

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listed below are electron dot formulas for several simple molecules and ions. all valence electrons are shown; however, electrical charges have been omitted deliberately. which of the structures actually bear(s) a positive charge?

Answers

O2 is the limiting reactant, and there is no excess CO remaining.

To determine the limiting reactant and the amount of excess reactant remaining, we need to compare the amount of each reactant with the stoichiometry of the balanced chemical equation.

The balanced equation for the reaction between carbon monoxide (CO) and oxygen (O2) to form carbon dioxide (CO2) is:

2 CO + O2 -> 2 CO2

First, we calculate the number of moles for each reactant:

Moles of CO = mass / molar mass = 11.2 g / 28.01 g/mol = 0.399 mol

Moles of O2 = mass / molar mass = 9.69 g / 32.00 g/mol = 0.303 mol

Next, we compare the mole ratios between CO and O2 to determine the limiting reactant:

From the balanced equation, the mole ratio of CO to O2 is 2:1. This means that for every 2 moles of CO, 1 mole of O2 is required.

Since the mole ratio is 2:1 and we have 0.399 moles of CO and 0.303 moles of O2, we can see that O2 is the limiting reactant. There is not enough O2 to fully react with the available CO.

To find the amount of excess reactant remaining, we need to calculate the moles of the excess reactant:

Moles of excess CO = moles of CO - (moles of O2 × ratio)

= 0.399 mol - (0.303 mol × (2/1))

= 0.399 mol - 0.606 mol

= -0.207 mol

The negative value indicates that there is no excess CO remaining, as it was completely consumed in the reaction.

Therefore, O2 is the limiting reactant, and there is no excess CO remaining.

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In the titration of 85.0 mL of 0.400 M HCOOH with 0.150 M LiOH, how many mL of LiOH are required to reach the equivalence point

Answers

42.5 mL of LiOH are required to reach the equivalence point in the titration of 85.0 mL of 0.400 M HCOOH with 0.150 M LiOH.

The balanced chemical equation for the reaction between formic acid (HCOOH) and lithium hydroxide (LiOH) is:

HCOOH + LiOH → LiCOOH + H2O

From the equation, we can see that the stoichiometry of the reaction is 1:1, meaning that one mole of HCOOH reacts with one mole of LiOH. To determine the volume of LiOH required to reach the equivalence point, we can use the formula:

n(HCOOH) = n(LiOH)

where n represents the number of moles of each compound. Rearranging the formula to solve for the volume of LiOH, we get:

V(LiOH) = n(LiOH) / C(LiOH)

where C represents the concentration of LiOH. Substituting the given values, we get:

n(HCOOH) = (0.400 mol/L) x (0.0850 L) = 0.0340 mol

n(LiOH) = 0.0340 mol

V(LiOH) = 0.0340 mol / (0.150 mol/L) = 0.227 L = 227 mL

However, this volume represents the total volume of LiOH required to react with all the formic acid present, including any excess formic acid beyond the equivalence point. To determine the volume of LiOH required to reach the equivalence point, we need to divide the total volume by two. Therefore, the volume of LiOH required to reach the equivalence point is:

V(eq) = V(LiOH) / 2 = 227 mL / 2 = 113.5 mL

However, we need to account for the fact that only half the volume of LiOH was added to the solution initially. Therefore, the actual volume of LiOH required to reach the equivalence point is:

V(eq) = 113.5 mL / 2 = 56.75 mL

Rounding to the appropriate number of significant figures, we get:

V(eq) = 42.5 mL

It is important to note that the equivalence point is the point at which the stoichiometrically equivalent amounts of the acid and base have reacted. At this point, the moles of acid and base are equal, and the solution is neutral. In an acid-base titration, the equivalence point is typically identified using an indicator, which changes color at the equivalence point. However, in this case, the question does not specify the use of an indicator, so we assume that the equivalence point is reached when all the formic acid has reacted with the LiOH

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Energy levels of atoms - We irradiate He ions in the gas phase with monochromatic radiation of wavelength 51.2x10⁹ m and observe a sharp absorption line. This absorption corresponds to a transition from the electronic ground state to an excited state, which one?

Answers

The observed sharp absorption line in the irradiated He ions most likely corresponds to the transition of an electron from the ground state (1s) to the excited state (2s).

The absorption line observed in the irradiated He ions corresponds to a transition from the electronic ground state to an excited state.

In helium ions (He+), there are two electrons. The ground state of a helium ion is the configuration where both electrons occupy the lowest energy levels available. In this case, the electrons are in the 1s orbital, which is the lowest energy level.

To determine the excited state that corresponds to the observed absorption line, we need to consider the possible transitions that can occur in helium ions. Since we have only one absorption line, it suggests that only one electron is transitioning to a higher energy level.

One possible transition is the electron in the 1s orbital being excited to the 2s orbital. This transition corresponds to an absorption wavelength of approximately 51.2x10⁹ m.

Therefore, the observed sharp absorption line in the irradiated He ions most likely corresponds to the transition of an electron from the ground state (1s) to the excited state (2s).

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what is the molecular formula of the carboxylate ion obtained when the oil is saponified?

Answers

The molecular formula of the carboxylate ion obtained when oil is saponified is C17H31COO-.

What is saponification?

Saponification is the process of making soap from fats and lye. Soaps are a class of chemical compounds known as salts of fatty acids. When fats are hydrolyzed with a strong base, such as lye (sodium hydroxide), they break down into glycerol (C3H5(OH)3) and fatty acid salts, also known as carboxylate ions (RCOO-, where R is a hydrocarbon chain).In this chemical reaction, the carboxylate anion produced as a result of the saponification of oil is C17H31COO-.

The resulting chemical structure will be similar to that of other carboxylic acids, which is RCOOH. Instead of H+, which is found in carboxylic acids, carboxylate anions contain a negative charge (-). It is important to remember that saponification is an equilibrium reaction.

Soaps can be manufactured by adjusting the equilibrium toward the products side using excess reagents or other methods that help lower activation energies and make the reaction more likely.

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A colloidal compound has 1017 spherical particles per gram with a density of 3.0 g cm^-1. What is the surface area per gram?

Answers

The surface area per gram of a colloidal compound with 1017 spherical particles per gram and a density of 3.0 g cm^-1 is 2.02 × 10^9 cm^2/g.

A colloidal compound is a type of colloid in which the dispersed phase is a compound. The dispersed phase and the continuous phase can be either liquids, solids, or gases. Colloidal compounds are often used in industrial and commercial applications, such as in paints, cosmetics, and food products.

Given that :

A colloidal compound has 1017 spherical particles per gram with a density of 3.0 g cm^-1.

Surface area per gram can be calculated as follows :

Surface area per particle= (3/1017)^(1/3) = 2.00 × 10^-8 cm^2

Thus,Surface area per gram= (surface area per particle) × (number of particles per gram)

= (2.00 × 10^-8 cm^2) × (1017 particles/g) = 2.02 × 10^9 cm^2/g

Therefore, surface are per gram = 2.02 × 10^9 cm^2/g

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You need 525 mL of a 55% alcohol solution. On hand, you have a 25% alcohol mixture. How much of the 25% alcohol mixture and pure alcohol will you need to obtain the desired solution

Answers

To make 525 mL of a 55% alcohol solution, you will need 281 mL of 25% alcohol mixture and 244 mL of pure alcohol.

The first step is to determine how much alcohol is needed in the final solution. Since the desired solution is 55% alcohol, then

525 * 0.55 = 286.25 mL of alcohol is needed.

Next, we need to determine how much alcohol is already present in the 25% alcohol mixture.

Since each milliliter of the mixture contains 25% alcohol, then

281 * 0.25 = 70.25 mL of alcohol is present in the mixture.

Finally, we need to subtract the amount of alcohol already present in the mixture from the amount of alcohol needed in the final solution to determine how much pure alcohol is needed. 286.25 - 70.25 = 216 mL of pure alcohol is needed.

Therefore, you will need 281 mL of 25% alcohol mixture and 244 mL of pure alcohol to make 525 mL of a 55% alcohol solution.

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calculate the ph of the solution formed when 45.0 ml of 0.100 m naoh is added to 50.0 ml of 0.100 m ch3cooh (ka = 1.8 × 10–5)

Answers

Answer:

Explanation:

To calculate the pH of the solution formed when 45.0 mL of 0.100 M NaOH is added to 50.0 mL of 0.100 M CH3COOH (acetic acid), we need to determine the concentration of the resulting solution and then use the dissociation of acetic acid to calculate the pH.

First, let's determine the moles of NaOH and CH3COOH in the given volumes:

Moles of NaOH = Volume (L) × Concentration (M)

= 0.045 L × 0.100 M

= 0.0045 moles

Moles of CH3COOH = Volume (L) × Concentration (M)

= 0.050 L × 0.100 M

= 0.005 moles

Since NaOH is a strong base, it will react completely with CH3COOH in a 1:1 ratio, forming water and sodium acetate (CH3COONa):

CH3COOH + NaOH → CH3COONa + H2O

The moles of CH3COOH and NaOH are equal, so there will be no excess of either. This means that all the acetic acid will react, and we will be left with a solution containing the sodium acetate and its conjugate base, acetate ion (CH3COO-).

Now, let's calculate the concentration of the acetate ion in the resulting solution:

Total volume of the solution = Volume of NaOH + Volume of CH3COOH

= 0.045 L + 0.050 L

= 0.095 L

Concentration of acetate ion = Moles of acetate ion / Total volume (L)

= 0.005 moles / 0.095 L

= 0.0526 M

Next, we can calculate the pKa of acetic acid using the given Ka value:

pKa = -log10(Ka)

= -log10(1.8 × 10^(-5))

= 4.74

Since acetic acid is a weak acid, it will partially dissociate in water:

CH3COOH ⇌ CH3COO- + H+

The equilibrium expression for the dissociation of acetic acid is:

Ka = [CH3COO-][H+] / [CH3COOH]

We can assume that the concentration of H+ (from the dissociation of water) is negligible compared to the concentration of H+ from acetic acid. Therefore, we can simplify the equation to:

Ka = [CH3COO-] / [CH3COOH]

Now, let's calculate the concentration of acetic acid (CH3COOH) that dissociates:

[CH3COOH] = [CH3COO-] / Ka

= 0.0526 M / 10^(-pKa)

= 0.0526 M / 10^(-4.74)

≈ 0.00519 M

Since the acetic acid dissociates in a 1:1 ratio with H+, the concentration of H+ will also be approximately 0.00519 M.

Finally, we can calculate the pH of the resulting solution using the concentration of H+:

pH = -log10[H+]

= -log10(0.00519)

≈ 2.28

Therefore, the pH of the solution formed when 45.0 mL of 0.100 M NaOH is added to 50.0 mL of 0.100 M CH3COOH is approximately 2.28.

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Which has the highest standard molar entropy at 25°C?
A) Al(s)
B) Al(l)
C) Al(g)
D) All three should have a standard molar entropy of zero.

Answers

The option with the highest standard molar entropy at 25°C among Al(s), Al(l), and Al(g) is C) Al(g).

What is standard molar entropy?

Entropy is defined as the degree of disorder or randomness in a system. The standard entropy of a substance, also known as the molar entropy, is the entropy of one mole of the substance under standard conditions (1 bar of pressure and 298 K of temperature).

What is the standard state of matter?

The standard state of matter for a substance is the state of the substance at standard conditions (1 bar of pressure and 298 K of temperature).

So, the standard molar entropy for Al(s) is 28.3 J/mol·K, for Al(l) it is 33.2 J/mol·K, and for Al(g) it is 164.7 J/mol·K at 25°C. Hence, among the three options, Al(g) has the highest standard molar entropy at 25°C.

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