How many moles of NaOH are in 30.85 mL of a 0.110 M NaOH solution?

Answers

Answer 1

0.0034 moles of NaOH are in 30.85 mL of a 0.110 M NaOH solution.

We know that,

Molarity = [tex]\frac{No. of moles of solute}{Volume in liters}[/tex]

molarity = 0.11m

Volume = 30.85ml = 0.03085 Liters

No. of moles of solute = Molarity * volume

No. of moles = 0.11 m * 0.03085 L

No. of moles = 0.00339

                     = 0.0034

The word "molar concentration" refers to the amount of a substance per unit volume of solution and is used to describe the concentration of a chemical species, specifically a solute, in a solution. Molarity, amount, and substance concentration are other names for this term. The number of moles per litre, denoted by the unit symbol mol/L or mol/dm3 in SI units, is the molarity unit that is most frequently used in chemistry. The term "molar," often known as "1 M," refers to a solution with a concentration of 1 mol/L.

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Related Questions

If a gas that occupies 3.00 L has a pressure of 2.85 atm, and the pressure decreases to 0.750 atm, what is the new volume of the gas? (3 SigFigs)

Answers

11.4

Explanation:

Boyle's law:

PV1=PV2

2.85atm × 3.00 L =.750 atm × V

suppose your sample is mixed with other stuff that is not soluble in your recrystallization solvent. when filtering, should you rinse with hot solvent or cold? why?

Answers

When filtering, you should rinse with hot solvent because it can dissolve more solute than cold solvent, effectively removing soluble impurities, and preventing the crystallization of the desired compound on the filter paper.

It is best to rinse with hot solvent when filtering a sample mixed with other stuff that is not soluble in your recrystallization solvent. This is because hot solvent can dissolve more solute than cold solvent, meaning that it will be more effective in rinsing away any soluble impurities from the sample.

Additionally, using hot solvent can help prevent the crystallization of the desired compound on the filter paper, which could lead to a loss of yield. Therefore, it is recommended to use hot solvent when filtering a sample during recrystallization to ensure that the maximum amount of desired compound is recovered and that any soluble impurities are effectively removed.

In summary, rinsing with hot solvent is recommended because it can dissolve more solute than cold solvent, effectively removing soluble impurities, and preventing the crystallization of the desired compound on the filter paper.

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what is the name of cro 3? chromium (iv) oxide chromium (vi) oxide chormium oxide chromium (iii) oxide

Answers

The name of the CrO₃ is Chromium (VI) oxide. Option B is correct.

Chromium (VI) oxide is a chemical compound with the molecular formula CrO₃. It is also known as chromium trioxide or chromic acid anhydride. It is an odorless and dark red or brown colored solid that is highly corrosive and can cause severe burns.

Chromium (VI) oxide is an important industrial chemical used in various applications, including: Production of dyes, pigments, and other chemicals, Electroplating of metals, Manufacturing of chromium catalysts, Surface treatment of metals and plastics and Production of chromium metal and alloys.

It is important to handle chromium (VI) oxide with care, as it is a toxic and carcinogenic substance that can cause respiratory problems, skin irritation, and other health issues. Proper safety precautions should be taken when working with this chemical.

Hence, B. Chromium (VI) oxide is the correct option.

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--The given question is incorrect, the correct question is

"What is the name of CrO₃? A) chromium (iv) oxide B) chromium (vi) oxide C) chromium oxide D) chromium (iii) oxide"--

Which of the following reactions would have a decrease in entropy?
A. 2NO2(g) → N₂04(9)
B. 2SO3(g) →2SO₂(g) + O₂(g)
C. 2NH3(g) → N₂(g) + 3H₂(g)
OD. 2H₂O(g) → 2H₂(g) + O₂(g)

Answers

the  reactions would have a decrease in entropy is 2NO2(g) → N₂04(9).

What is entropy's straightforward definition?

The quantity of thermal energy each unit of temperature in a system that cannot be used to carry out beneficial work is known as entropy. While work is produced by ordered molecular motion, entropy also serves as a proxy for a system's molecular disorder or unpredictability.

In the actual world, what is entropy?

All parts of our daily life are impacted by entropy, which is merely a measure of disorder. In actuality, it can be considered nature's tax. Disorder spreads over time if left uncontrolled. Systems collapse into chaos when energy disperses. Something is considered to be more entropic the more disorganized it is.

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why is more atp made from the reoxidation of fadh2 compared to nadh?

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FADH2 generates less ATP than NADH because it enters the electron transport chain at a lower energy level, resulting in fewer proton pumps and less ATP production.

During cellular respiration, the electron transport chain (ETC) transfers electrons from electron donors (NADH and FADH2) to electron acceptors, generating a proton gradient across the inner mitochondrial membrane. This proton gradient drives ATP synthesis through ATP synthase.

However, FADH2 enters the electron transport chain at a lower energy level than NADH, so it bypasses the first complex of the electron transport chain and donates its electrons directly to the second complex. As a result, FADH2 generates fewer proton pumps and therefore less ATP compared to NADH.

Specifically, NADH generates up to 3 ATPs through oxidative phosphorylation, while FADH2 generates only up to 2 ATPs. Therefore, more ATP is made from the reoxidation of NADH than from FADH2.

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when does work have a positive magnitude in the equation for the first law of thermodynamics? when is it negative?

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If energy is leaving the system, the work term will have a positive magnitude. If energy is entering the system, the work term will have a negative magnitude.

Work has a positive magnitude in the equation for the first law of thermodynamics when the system does work on its surroundings. This means that energy is leaving the system and going into the surroundings. In this case, the work term in the equation will have a positive value.


On the other hand, work has a negative magnitude in the equation for the first law of thermodynamics when the surroundings do work on the system. This means that energy is entering the system from the surroundings. In this case, the work term in the equation will have a negative value.


In summary, the sign of the work term in the first law of thermodynamics equation depends on the direction of energy flow between the system and its surroundings.

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Which of the samples most likely had the lowest solubility?

Answers

The samples most probably had the lowest solubility, which is defined as 3 the highest concentration of the a solute that may dissolve in a solvent at a particular temperature.

In its most basic sense, what does "solubility" mean?

The amount of a substance that will dissolve completely in the most amount of solvent at the specified temperature is known as its solubility. The solubility of distinct substances can differ greatly, and it is a defining characteristic of a particular solute-solvent combination.

Describe solubility using an example.

One typical example of such a solution is adding sugar cubes to a coffee or tea beverage. Solubility is a characteristic that makes sugar molecules more soluble. Hence, the ability of a material (solute) can dissolve in a liquid is what is meant by the term "solubility."

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Answer:

C. 3

Explanation:

Took the test, got it right.

why is that in Thompsons model of atom the mass of atom is due to electrons only.​

Answers

Answer:According to the postulates of Thomson's atomic model, an atom resembles a sphere of positive charge with electrons (negatively charged particles) present inside the sphere. The positive and negative charge is equal in magnitude and therefore an atom has no charge as a whole and is electrically neutral.

Explanation:

Answer:

An atom as a whole is electrically neutral because the negative and positive charges are equal in magnitude

How many grams of solid LiCl are needed to make 250. ml of a 0.125 m solution?

Answers

1.325 g of solid LiCl is needed to make 250 ml of a 0.125 m solution.

How do you calculate the mass of solid LiCl are needed to make 250. ml of a 0.125 m solution?

We can use the following formula to determine how many grams of LiCl are needed to create a 0.125 m solution:

Molarity (M) is calculated as moles of solute per liter of solution.

Molarity (M) x liters of solution equals moles of solute.

Inputting the values provided yields:

LiCl moles are equal to 0.125 mol/L times 0.250 L, or 0.03125 mol.

We must utilize the molar mass of LiCl, which is 42.39 g/mol, to convert moles of LiCl to grams. LiCl is therefore needed in the following mass:

LiCl's mass is calculated by multiplying its molar mass (42.39 g/mol) by its molecular weight (0.03125 mol). The result is 1.325 g of LiCl.

Hence, to make 250 mL of a 0.125 m solution we require 1.325 g of solid LiCl.

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When drying an organic solution, start by transferring the solution to _____________or a test tube, depending on the amount.
a. an Erlenmeyer flask
b. a separatory funnel
c. a round bottom flask

Answers

When drying an organic solution, start by transferring the solution to a separatory funnel or a test tube, depending on the amount. The correct answer is option b.

A separatory funnel is a piece of laboratory glassware used in liquid-liquid extractions to separate the components of a mixture into two immiscible solvent phases of different densities. The separatory funnel has a conical shape and a stopcock at the bottom to control the flow of liquids.

In the process of drying an organic solution, the solution is transferred to the separatory funnel, and a drying agent is added to absorb any water present in the solution. The stopcock is then opened to allow the water to drain out, leaving the dried organic solution in the separatory funnel.

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How many molecules of oxygen are produced when 6.54 g of potassium chlorite decompose?

Answers

Answer:

3.24× 10^22 molecules of oxygen gas.

Explanation:

The decomposition of potassium chlorite produces oxygen gas according to the following equation:

2KClO2(s) → 2KCl(s) + 3O2(g)

From the equation, we can see that for every 2 moles of KClO2 that decompose, 3 moles of O2 are produced.

To determine the number of moles of KClO2 in 6.54 g, we need to divide the mass by the molar mass of KClO2. The molar mass of KClO2 is

121.56 g/mol (39.10 g/mol for potassium + 35.45 g/mol for chlorine + 47.01 g/mol for oxygen).

moles of KClO2 = 6.54 g / 121.56 g/mol = 0.0538 mol

Since 2 moles of KClO2 produce 3 moles of O2, we can use this ratio to find the number of moles of O2 produced:

moles of O2 = 0.0538 mol KClO2 × (3 mol O2 / 2 mol KClO2) = 0.08mol O2

Finally, we can use Avogadro's number, which is 6.022 × 10^23 molecules/mol, to convert the number of moles of O2 to the number of molecules of O2:

number of molecules of O2 = 0.0538mol O2 × 6.022 × 10^23 molecules/mol = 3.24× 10^22 molecules of O2

Therefore, 6.54 g of potassium chlorite produces approximately 3.24× 10^22 molecules of oxygen gas.

Describe the method by which hydrogen bromide is prepared for use in this experiment: synthesis of 1-bromobutane from 1-butanol.

Answers

Hydrogen Bromide is a reagent used in the synthesis of 1-bromobutane from 1-butanol by reacting sodium bromide with the sulphuric acid. This further reacts with the corresponding alcohol.

Alcohols and hydrogen bromide (HBr) react to generate bromo-alkanes. Sodium bromide or potassium bromide and H2SO4 combine to produce hydrogen bromide in the reaction (sulphuric acid). The reaction between NaBr and H2SO4 in the following example produces HBr, which then reacts with alcohol.

HBr produced in the above reaction now reacts with the butanol and undergoes SN2 reaction by producing an intermediate called bromide ion. When this intermediate is reacted with the alcohol further, it yields the corresponding haloalkane called bromobutane.

The reaction can be depicted as:

CH3CH2CH2CH2OH + HBr → CH3CH2CH2CH2Br + H2O

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What forest has the largest carbon sink?

Answers

Answer:

I'm pretty sure it's the Amazon rainforest

5. what is the maximum amount of trimyristin recoverable from your sample of nutmeg?

Answers

The maximum amount of trimyristin recoverable from your sample of nutmeg is 18 - 29%.

The Trimyristin is found in fixed oil of the nutmeg. The fixed oil will comprises the approximately about 24 - 40% of the seed of the nutmeg. The Trimyristin is the comprises of the 73% of the fixed oil. The Overall, trimyristin should be have the percent recovery of 18-29%.

The extraction of the nutmeg seed to be isolate the trimyristin is, however the exception, and it can easily be done in the one lab period. The Ground nutmeg seeds can be extracted with the tert -butyl methyl ether and it is the resulting solid recrystallized from the acetone to yield the pure trimyristin.

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construct the routh array for the system to determine the gain kcr for which the closedloop system exhibits sustained oscillations. what is the value of kcr?

Answers

The Bode plot is given in the image and from the graph it is known that the value of Kcr is 0.924 rad/sec.

Generally a Bode plot is simply defined as a plot of magnitude and phase of a transfer function as frequency varies. However, we will want to be able to display always a large range of frequencies and magnitudes, so we will plot the logarithm of frequency, and use a logarithmic (dB, or decibel) scale for the magnitude as well.

Basically, the Bode plot is a very popular tool with control system engineers as it lets them to achieve desired closed-loop system performance by graphically shaping the open-loop frequency response using clear and easy-to-understand rules.

From the above bode plot, we can see the 3-dB bandwidth of the system = 0.924 rad/sec.

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What is the mass percent of a 0.20 M solution of KF? The 1.02 g/mL Answer to 1 decimal place; density of the solution is ______.

Answers

The mass percent of the 0.20 M solution of KF is 1139.2% rounding to one decimal place, while the density of the solution is 1.02 g/mL.

To find the mass percent of a solution, we need to use the formula:

mass percent = (mass of solute/mass of solution) x 100%

First, we need to find the mass of the solute.

Since we are given the molarity (0.20 M) and the density of the solution (1.02 g/mL),

we can use the formula:

mass of solute = molarity x volume x molar mass

We can rearrange this formula to find the volume:

volume = mass of solute / (molarity x molar mass)

Since we are given the density of the solution (1.02 g/mL),

we can use the formula:

mass of solution = volume x density

Substituting the equation for volume into this formula gives us:

mass of solution = (mass of solute / (molarity x molar mass)) x density

We can rearrange this formula to solve for the mass of solute:

mass of solute = (mass of solution x molarity x molar mass) / density

Plugging in the given values:

mass of solute = (1.02 g/mL x 0.20 M x 58.10 g/mol) / 1.02 g/mL

mass of solute = 11.62 g/mol

Now we can plug this value back into the formula for mass percent:

mass percent = (11.62 g/mol / 1.02 g/mL) x 100%

mass percent = 1139.2%

Rounding to one decimal place, the mass percent of the 0.20 M solution of KF is 1139.2%.

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what is the mechanism for the reaction of ammonia with acetyl chloride

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The reaction of ammonia with acetyl chloride is a nucleophilic substitution reaction that occurs via an addition-elimination mechanism. The mechanism can be described in the following steps:

Step 1: Addition of ammonia to acetyl chloride

The lone pair of electrons on the nitrogen atom in ammonia (NH3) attacks the electrophilic carbon atom in acetyl chloride (CH3COCl), forming a tetrahedral intermediate. This step is the rate-determining step of the reaction and is exothermic.

Step 2: Proton transfer

In this step, a proton is transferred from the ammonium ion intermediate (NH4+) to the chloride ion (Cl-) to form ammonium chloride (NH4Cl). This step is an acid-base reaction.

Step 3: Elimination of HCl

In this step, a chloride ion (Cl-) acts as a nucleophile and attacks the carbon atom in the tetrahedral intermediate, leading to the elimination of a hydrogen chloride (HCl) molecule. This step is also exothermic.

Step 4: Deprotonation

The final step involves deprotonation of the remaining ammonium ion (NH4+) by the solvent or by another molecule of ammonia. This step regenerates the ammonia catalyst and completes the reaction.

Overall, the reaction can be represented by the following equation:

CH3COCl + NH3 → CH3CONH2 + HCl

where CH3CONH2 is the amide product and HCl is the byproduct.

In summary, the mechanism for the reaction of ammonia with acetyl chloride involves the addition of ammonia to the acyl chloride, followed by proton transfer, elimination of HCl, and deprotonation to form the amide product.

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what do scientists use multiple tests to determine the characteristics of an unknown compound?

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A compound has a wide range of properties. So, the scientist tests the same unknown substance numerous times in order to precisely identify it.

Compounds can be classified as ionic, covalent (simple molecular and large atomic), or metallic. So, a number of tests and studies must be performed in order for scientists to determine what features a substance possesses before classifying it as one of these compounds.

From its characteristics, including colour, weight, smell, taste, and whether it is safe to consume it, as well as through testing.

The melting point, spectroscopy, chromatography, titration, electron spin resonance, and other techniques are all available to scientists.

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How much heat is required to convert 5.88 g of ice at -12.0°C to water at 25.0°C, if the heat capacity of ice is 2.09 J/°C?

Answers

The heat required to convert 5.88 g of ice at -12.0°C to water at 25.0°C is 2721.99 J.

To find the heat required to convert 5.88 g of ice at -12.0°C to water at 25.0°C, we will use the following formula:

Q = m × C × ΔT

Where,
Q = Heat required
m = Mass of substance
C = Heat capacity
ΔT = Change in temperature

First, we will calculate the heat required to raise the temperature of ice from -12.0°C to 0.0°C:

Q₁ = m × C × ΔT
Q₁ = 5.88 g × 2.09 J/°C × (0.0°C - (-12.0°C))
Q₁ = 147.37 J

Next, we will calculate the heat required to convert the ice at 0.0°C to water at 0.0°C using the heat of fusion (ΔHfus) of water, which is 334 J/g:

Q₂ = m × ΔHfus
Q₂ = 5.88 g × 334 J/g
Q₂ = 1963.92 J

Finally, we will calculate the heat required to raise the temperature of water from 0.0°C to 25.0°C using the heat capacity of water, which is 4.18 J/°C:

Q₃ = m × C × ΔT
Q₃ = 5.88 g × 4.18 J/°C × (25.0°C - 0.0°C)
Q₃ = 610.70 J

Adding all the heat values together, we get the total heat required:

Q = Q₁ + Q₂ + Q₃
Q = 147.37 J + 1963.92 J + 610.70 J
Q = 2721.99 J

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How many molecules are equal to 90.3 grams of water?​

Answers

Answer:

5.02 mol

Explanation:

number of mole =given mass/molar mass

What volume of O2 at 0.750 atm and 313 K is generated by the thermolysis of 10.0 g of HgO?

Answers

0.568 L of O2 is generated by the thermolysis of 10.0 g of HgO at 0.750 atm and 313 K.

The thermolysis of HgO results in the production of mercury and oxygen gas. The balanced chemical equation for the reaction is:

2HgO(s) -> 2Hg(l) + O2(g)

The molar mass of HgO is 216.59 g/mol, so 10.0 g of HgO is equivalent to 0.0461 moles. From the balanced chemical equation, we can see that for every 2 moles of HgO, 1 mole of O2 is produced. Therefore, 0.023 moles of O2 will be produced by the thermolysis of 10.0 g of HgO.

The ideal gas law, PV = nRT, can be used to calculate the volume of the O2 produced. Rearranging the equation to solve for volume, we get:

V = nRT/P

where n is the number of moles of gas, R is the gas constant (0.08206 L atm/mol K), T is the temperature in Kelvin, and P is the pressure in atm.

Plugging in the values, we get:

V = (0.023 mol) x (0.08206 L atm/mol K) x (313 K) / (0.750 atm) = 0.568 L

Therefore, the volume of O2 produced by the thermolysis of 10.0 g of HgO at 0.750 atm and 313 K is 0.568 L.

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Based on the pKa of benzoic acid and the pKa of HCl, what do you hypothesize will happen in terms of reaction equilibrium? a) the equilibrium will favor the starting materials (sodium benzoate and HCl) because HCl has a lower pKa b) the equilibrium will favor the starting materials (sodium benzoate and HCl) because benzoic acid has a lower pKa c) the equilibrium will favor the products (benzoic acid and NaCl) because benzoic acid has a lower pKa d) the equilibrium will favor the products ( benzoic acid and NaCl) because HCl has a lower pKa

Answers

The equilibrium will favor the products (benzoic acid and NaCl) because HCl has a lower pKa. The correct answer is (d).

The pKa of HCl is -7, while the pKa of benzoic acid is 4.2. This means that HCl is a much stronger acid than benzoic acid.

When benzoic acid reacts with sodium hydroxide (NaOH), it forms sodium benzoate and water. This reaction is a type of acid-base reaction, where benzoic acid acts as an acid and NaOH acts as a base.

When sodium benzoate is treated with hydrochloric acid (HCl), it reacts to form benzoic acid and sodium chloride (NaCl). This reaction is also a type of acid-base reaction, where sodium benzoate acts as a base and HCl acts as an acid.

The equilibrium of the reaction between sodium benzoate and HCl will depend on the relative strengths of the two acids. Since HCl is a much stronger acid than benzoic acid, it will be more likely to react with sodium benzoate than benzoic acid will be to react with NaOH.

Therefore, the equilibrium will favor the products (benzoic acid and NaCl) because HCl has a lower pKa. The correct answer is (d).

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A laser having a wavelength of 457 nm emits 7.11 x 10¹⁷ photons of light per second. how much energy, in joules, does this laser emit in 2 seconds?

Answers

The laser emits 6.15 J of energy in 2 seconds.

The energy emitted by the laser can be calculated using the formula E=hf, where E is energy, h is Planck's constant, and f is frequency. Frequency is related to wavelength by the equation c=λf, where c is the speed of light. Solving for frequency, we get f=c/λ.

Using these equations, we can find the frequency of the laser to be f=c/λ= (3x10⁸ m/s)/(457x10⁻⁹ m)= 6.57x10¹⁴ Hz.

We know that the number of photons emitted per second is 7.11 x 10¹⁷ photons/s. To find the energy emitted per photon, we can use the equation E=hf. Plugging in the frequency we just found and Planck's constant (6.626 x 10⁻³⁴ J·s), we find that the energy per photon is 4.33 x 10⁻¹⁹ J.

To find the total energy emitted in 2 seconds, we can multiply the energy per photon by the number of photons emitted per second and the duration of emission. Thus, the energy emitted in 2 seconds is:

E = (7.11 x 10¹⁷ photons/s) x (4.33 x 10⁻¹⁹ J/photon) x (2 s) = 6.15 J.

Therefore, the laser emits 6.15 J of energy in 2 seconds.

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1. How many moles of Fe₂O, can be formed by reacting 3.2 moles of iron?

Answers

Answer:



Explanation:

To determine the number of moles of Fe2O3 that can be formed by reacting 3.2 moles of iron (Fe), we need to first write and balance the chemical equation for the reaction between iron and oxygen (O2) to form Fe2O3:

4Fe + 3O2 → 2Fe2O3

From the balanced equation, we see that 4 moles of Fe react with 3 moles of O2 to produce 2 moles of Fe2O3. This means that the mole ratio of Fe to Fe2O3 is 4:2, or simply 2:1.

To find the number of moles of Fe2O3 formed from 3.2 moles of Fe, we can use the mole ratio from the balanced equation:

moles of Fe2O3 = 2/4 x 3.2 moles

moles of Fe2O3 = 1.6 moles

Therefore, 1.6 moles of Fe2O3 can be formed by reacting 3.2 moles of iron.

what is the solubility in g l of calcium sulfate at 25 c?

Answers

The solubility of calcium sulfate at 25°C is 2.4 g/L.

This means that at 25°C, a maximum of 2.4 grams of calcium sulfate can dissolve in one liter of water before the solution becomes saturated and no more solute can dissolve.

It is important to note that the solubility of a substance is affected by temperature. As temperature increases, the solubility of most solid solutes in water also increases. However, the solubility of gases in water typically decreases as temperature increases.

In the case of calcium sulfate, its solubility at 25°C is 2.4 g/L, but at higher or lower temperatures, its solubility may be different.

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how many grams of carbon atoms are present in c4h8 if there are 5.50 moles of hydrogen atoms in the samoke

Answers

There are 33.0275 grams of carbon atoms present in C4H8 if there are 5.50 moles of hydrogen atoms in the same molecule.

There are 44 grams of carbon atoms present in C4H8 if there are 5.50 moles of hydrogen atoms in the same molecule.
Explanation:
1. First, we need to determine the number of moles of C4H8 that are present. Since there are 8 hydrogen atoms in each molecule of C4H8, we can divide the number of moles of hydrogen atoms by 8 to find the number of moles of C4H8:
5.50 moles of H / 8 = 0.6875 moles of C4H8
2. Next, we need to determine the mass of carbon atoms in one mole of C4H8. Since there are 4 carbon atoms in each molecule of C4H8, and the molar mass of carbon is 12.01 grams per mole, we can multiply these values to find the mass of carbon atoms in one mole of C4H8:
4 x 12.01 g/mol = 48.04 g/mol of C
3. Finally, we can multiply the number of moles of C4H8 by the mass of carbon atoms in one mole of C4H8 to find the total mass of carbon atoms:
0.6875 moles of C4H8 x 48.04 g/mol of C = 33.0275 g of C

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15.) The vapor pressure (at 25 °C) of benzene and toluene are 103.4 and 46.9 torr respectively. In a solution of 45.0 g of benzene and 55.0 g toluene what is the applied pressure? (benzene = C6H6 = 78g/mol, toluene = C,Hg = 92 g/mol) a) 102.7 b) 36.3 c) 16.4 d) 169.0 e) 174.6 f) none

Answers

The partial pressure of benzene and toluene is 74.11 torr.

Generally, vapor pressure is defined as a measure of the tendency of a material to change into the gaseous or vapor state, and it basically increases with temperature. Basically the temperature at which the vapor pressure at the surface of a liquid becomes equal to the pressure exerted by the surroundings is known as the boiling point of the liquid.

Pa denotes the Vapor pressure of benzene = 103.4 torr

Pb denotes the Vapor pressure of toluene = 46.9 torr

Moles of benzene can be calculated by the formula,

Number of moles of benzene = Given mass of benzene / Molar mass of benzene = 45/78 = 0.57 moles

Number of moles of toluene = Given mass of toluene/ Molar mass of toluene = 55/92 = 0.59 moles

Mole fraction of benzene (Xa) = 0.57/(0.57+0.59) = 0.57 / 1.16 = 0.49

Mole fraction of toluene (Xb) = 0.59/(0.57+0.59) = 0.50

Partial pressure = (XaPa + XbPb)

                          = 0.49 × 103.4 + 0.50 × 46.9

                          = 50.666 + 23.45 = 74.11 torr

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Which ylide is needed to prepare 3-ethyl-3-heptene from 3-pentanone using a Wittig reaction? A) Ph_₃P = CH (CH₂CH₃)₂ B) Ph_₃P = CHCH₂CH₃ C) Ph_₃P = CHCH₂CH₂CH₃
D) Ph_₃P = CH₂

Answers

The ylide needed to prepare 3-ethyl-3-heptene from 3-pentanone using a Wittig reaction is option B) Ph_₃P = CHCH₂CH₃.

The Wittig reaction is a method for the synthesis of alkenes from aldehydes or ketones using a phosphonium ylide. The ylide is a compound that has a negatively charged carbon atom bonded to a positively charged phosphorus atom. The ylide reacts with the carbonyl group of the aldehyde or ketone to form a new carbon-carbon double bond, resulting in the formation of an alkene.

In this case, the starting material is 3-pentanone, which has a carbonyl group at the third carbon atom. The ylide needed to prepare 3-ethyl-3-heptene should have a carbon chain that can attach to the carbonyl group and form the desired product. Option B) Ph_₃P = CHCH₂CH₃ has the correct carbon chain to form 3-ethyl-3-heptene.

Therefore, the correct answer is option B) Ph_₃P = CHCH₂CH₃.

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What is electrophilic acylium cation? How does it form and affect Friedel-Crafts acylation reaction?

Answers

The electrophilic acylium cation is an intermediate species that forms during the Friedel-Crafts acylation reaction. This reaction involves the addition of an acyl group (R-C=O) to an aromatic ring using a Lewis acid catalyst, typically aluminum chloride (AlCl3).

The complexation of the acyl chloride (or anhydride) with the Lewis acid catalyst is the first step in the production of the electrophilic acylium cation. As a result, a highly reactive intermediate known as the "acyl cation" or "acylium ion" is formed. This acylium ion is extremely electrophilic, which means it is drawn to electron-rich areas of other molecules.

The electrophilic acylium cation then interacts with the aromatic ring, acting as a nucleophile. This causes a carbon-carbon bond to form between the acyl group and the aromatic ring, resulting in the desired product.

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which starting material in the reaction is the limiting reactant and which material is present in the excess. show calculations and all work for your determination of this

Answers

In order to determine the limiting reactant and the excess reactant in a chemical reaction, you need to compare the stoichiometric ratios of the reactants and the actual amounts used in the reaction.

To determine the limiting reactant and the excess reactant in a chemical reaction, we need to use the stoichiometry of the reaction and the amounts of the starting materials given. Here is how to do it:

1. Write the balanced chemical equation for the reaction.
2. Convert the given amounts of the starting materials to moles using their molar masses.
3. Use the stoichiometry of the reaction to determine how many moles of each reactant are required to completely react with the other reactant.
4. Compare the required amounts of the reactants with the given amounts to determine which reactant is limiting and which is in excess.
5. Calculate the amount of the excess reactant remaining after the reaction is complete.

For example, consider the reaction between aluminum and oxygen to form aluminum oxide:
4Al + 3O2 → 2Al2O3
If we have 6.0 moles of Al and 4.0 moles of O2, we can determine the limiting reactant and the excess reactant as follows:
Convert the given amounts of the starting materials to moles:
Al: 6.0 moles
O2: 4.0 moles
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