What is the pH of a solution of 0.300 M HNO2 containing 0.100 M NaNO2? (Ka of HNO2 is 4.5 x 10-4)

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Answer 1

the pH of the solution of 0.300 M HNO₂ containing 0.100 M NaNO₂ is 3.82.

To solve this problem, we first need to write the chemical equation for the dissociation of HNO₂ in water:

HNO₂ + H₂O ⇌ H₃O+ + NO₂₋

The equilibrium constant expression for this reaction is:

Ka = [H₃O+][NO₂₋]/[HNO₂]

We are given the concentration of HNO2 (0.300 M) and the Ka value (4.5 x 10-4), so we can use this equation to calculate the concentration of H3O+:

Ka = [H₃O+][NO₂₋]/[HNO₂]
4.5 x 10⁻⁴ = [H₃O+][0.100]/[0.300]
[H3O+] = 1.5 x 10⁻⁴M

Now we can use the definition of pH to find the pH of the solution:

pH = -log[H₃O+]
pH = -log(1.5 x 10⁻⁴)
pH = 3.82

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Related Questions

what is s° for a in the reaction 4 a → 3 b if ∆s°(rxn) =-132.0 j/mol ・ k? [s° (b) = (220.0 j/mol ・k)]

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The given problem involves calculating the standard entropy change (ΔS°) for the reactant A in the chemical reaction 4A → 3B, given the value of ΔS° for the reaction and the standard entropy value (S°) for product B.

The standard entropy change is a measure of the disorder or randomness of a system at standard conditions.To calculate the standard entropy change for reactant A, we can use the formula ΔS°(reaction) = ΣS°(products) - ΣS°(reactants), where ΣS° refers to the sum of the standard entropy values for the products or reactants, respectively. Since we are given the value of ΔS°(reaction) and S°(B), we can rearrange the formula to solve for S°(A).Once we have the value of S°(A), we can determine the standard entropy change for A in the reaction.

The standard entropy change for A is equal to the standard entropy change for the reaction multiplied by the stoichiometric coefficient of A in the reaction, which is 4.The final answer will be the value of S°(A) and the standard entropy change for A in the reaction.Overall, the problem involves applying the principles of thermodynamics and entropy to calculate the standard entropy change for a reactant in a chemical reaction. It requires an understanding of the formula for calculating the standard entropy change and the properties of the reactants and products involved.

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For the following chemical equation:
BaBr2(aq)+H2SO4(aq)→BaSO4(s)+2HBr(aq)
which will NOT be involved in the net ionic equation?

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A chemical process in the solution can be described by the net ionic equation, which balances mass and charge while only displaying the particles that are directly involved.

To determine which species will not be involved in the net ionic equation for the chemical reaction: BaBr2(aq) + H2SO4(aq) → BaSO4(s) + 2HBr(aq),

One first needs to write the full ionic equation. This involves breaking down the soluble ionic compounds into their respective ions: Ba²⁺(aq) + 2Br⁻(aq) + 2H⁺(aq) + SO₄²⁻(aq) → BaSO4(s) + 2H⁺(aq) + 2Br⁻(aq)

Now, we can identify the spectator ions, which are ions that appear on both sides of the equation and do not participate in the reaction. In this case, the spectator ions are: 2H⁺(aq) and 2Br⁻(aq)

So, the net ionic equation will not include these spectator ions. Therefore, the net ionic equation is: Ba²⁺(aq) + SO₄²⁻(aq) → BaSO4(s)

So, 2H⁺(aq) and 2Br⁻(aq) will NOT be involved in the net ionic equation for the chemical reaction between BaBr2(aq) and H2SO4(aq).

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what accounts for the light yellow color of trans-p-anisalacetophenone? does the color indicate an impurity?

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The light yellow color of trans-p-anisalacetophenone can be attributed to the presence of conjugated double bonds in its structure, which absorb light in the blue region of the spectrum and appear yellow. This color is a characteristic feature of this compound and is not necessarily indicative of impurities.

The color of a compound can provide information about its structure and purity, but it is important to consider other factors as well, such as the method of preparation and storage conditions.

In general, if a compound has a consistent color across different batches and its purity has been verified using analytical techniques, then the color is unlikely to be a sign of impurities. However, if the color varies significantly or there are other signs of impurities, then further analysis may be necessary to identify and remove any contaminants.

The light yellow color of trans-p-anisalacetophenone is likely due to the presence of impurities or a byproduct from the synthesis process. While it is possible that the color could be indicative of an impurity, further analysis would be necessary to confirm this.

It is important to note that the color of a compound alone is not enough to determine the purity or identity of a sample.

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when properly balanced, what is the sum of the stoichiometric coefficients for the reaction of nahco 3 with hcl?

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When properly balanced, the sum of the stoichiometric coefficients for the reaction of nahco3 with hcl is 5.

To determine the sum of the stoichiometric coefficients for the reaction of NaHCO3 with HCl, we first need to write and balance the chemical equation. The reaction is as follows:

NaHCO3 (s) + HCl (aq) → NaCl (aq) + H2O (l) + CO2 (g)

The balanced equation has the stoichiometric coefficients:

1 NaHCO3 + 1 HCl → 1 NaCl + 1 H2O + 1 CO2

The sum of the stoichiometric coefficients is 1 + 1 + 1 + 1 + 1 = 5.

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) describe the process of glycogen breakdown in muscle. include a description of the structure of glycogen, the nature of the breakdown reaction and the breakdown product, and the required enzyme(s).

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Glycogen is a branched polymer of glucose that serves as the main energy storage molecule in animals, including humans. It is primarily stored in the liver and muscle tissue, where it can be quickly broken down to release glucose for use by the body.

In muscle tissue, glycogen breakdown is initiated by the hormone adrenaline, which signals the muscle cells to activate an enzyme called glycogen phosphorylase. This enzyme cleaves glucose molecules from the glycogen polymer by breaking the alpha-1,4 glycosidic bonds that link them together. The resulting product is glucose-1-phosphate, which can be further processed to release free glucose.

The structure of glycogen is highly branched, with many short chains of glucose linked together by alpha-1,4 glycosidic bonds, and occasional branching points created by alpha-1,6 glycosidic bonds. This branching structure allows for rapid and efficient breakdown of glycogen, since glycogen phosphorylase can work simultaneously on many different chains.

Overall, the breakdown of glycogen in muscle is an important process for providing energy to the body during physical activity. By breaking down glycogen into glucose-1-phosphate and ultimately glucose, the body can generate ATP, the primary source of energy for cellular processes.

Glycogen breakdown in muscle, also known as glycogenolysis, is a process where glycogen, a branched polymer of glucose, is broken down into glucose molecules to provide energy. The structure of glycogen consists of glucose units connected by α-1,4-glycosidic bonds, with branches formed by α-1,6-glycosidic bonds.

The nature of the breakdown reaction involves cleaving the α-1,4-glycosidic bonds, releasing glucose-1-phosphate as the main breakdown product. This is then converted to glucose-6-phosphate, which can enter glycolysis for energy production.

The key enzymes involved in glycogenolysis are glycogen phosphorylase, which cleaves the α-1,4-glycosidic bonds, and debranching enzyme, which helps remove the α-1,6-glycosidic branch points. These enzymes work together to efficiently break down glycogen and provide energy for muscle activity.

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the concentration of hydroxide ion is an aqueous solution at 25 degrees celsius is 1.9 * 10^-4 m. what is the concentration of the hydronium ion?

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The concentration of the hydronium ion is
5.3 x 10^-11

The concentration of the hydronium ion (H3O+) in the aqueous solution at 25 degrees Celsius is approximately 5.26 × 10^-11 M.

To find the concentration of the hydronium ion, we will use the relationship between hydroxide ion (OH-) concentration, hydronium ion (H3O+) concentration, and the ion product of water (Kw) at 25 degrees Celsius.

Given:
OH- concentration = 1.9 × 10^-4 M
Kw (ion product of water at 25°C) = 1.0 × 10^-14

The relationship between OH- concentration, H3O+ concentration, and Kw is:

Kw = [OH-] × [H3O+]

Now, we need to solve for the H3O+ concentration:

[H3O+] = Kw / [OH-]

Plug in the values:

[H3O+] = (1.0 × 10^-14) / (1.9 × 10^-4)

[H3O+] ≈ 5.26 × 10^-11 M

Therefore the concentration of the hydronium ion (H3O+) in the aqueous solution at 25 degrees Celsius is approximately 5.26 × 10^-11 M.

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Please I need help not understanding this

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To confirm the hypothesis, we have to compare the chemical properties of the reactants and the products.

What is a chemical change?

A chemical change, also known as a chemical reaction, is a process that involves the transformation of one or more substances into new substances with different chemical properties.

In a chemical change, the chemical composition of the substances involved is altered, resulting in the formation of one or more new substances with different physical and chemical properties.

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How many atoms are in 6 moles of lead?

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Answer:

Explanation:

To determine the number of atoms in 6 moles of lead, we can use Avogadro's number, which is the number of atoms or molecules in one mole of a substance. Avogadro's number is approximately 6.022 x 10^23.

First, we need to determine the molar mass of lead. The atomic mass of lead is 207.2 g/mol, so the molar mass of lead is:

207.2 g/mol x 6 mol = 1243.2 g

Next, we can use the molar mass of lead to convert grams to atoms, as follows:

1243.2 g / 207.2 g/mol = 6 moles of lead

6 moles of lead x 6.022 x 10^23 atoms/mol = 3.6132 x 10^24 atoms of lead

Therefore, there are approximately 3.6132 x 10^24 atoms in 6 moles of lead.

A (C4H8) reacts with peroxyacetic acid to give B (C4H8O). B reacts with cold concentrated HCl to give 2-chloro-2-methyl-1-propanol. Draw the structure of A.

Answers

The structure of A is 2-methylpropene (also known as isobutene).

To determine the structure of A (C4H8),  follow these steps:

Step 1:  Identify the reaction between A (C4H8) and peroxyacetic acid to give B (C4H8O): The reaction between A (C4H8) and peroxyacetic acid is an epoxidation reaction that converts an alkene to an epoxide (B, C4H8O).

Step 2: Determine the structure of B (C4H8O): Since B (C4H8O) reacts with cold concentrated HCl to give 2-chloro-2-methyl-1-propanol, B must be an epoxide with the same carbon skeleton as 2-chloro-2-methyl-1-propanol. Therefore, B's structure is 2,3-epoxy-2-methylpropane.



Step 3: The reaction between B (C4H8O, 2,3-epoxy-2-methylpropane) and cold concentrated HCl opens the epoxide ring, resulting in the formation of 2-chloro-2-methyl-1-propanol.

Step 4: To deduce the structure of A (C4H8), we need to reverse the epoxidation reaction. Since the epoxide ring in B (2,3-epoxy-2-methylpropane) was formed from an alkene, the structure of A must be the alkene with the same carbon skeleton as B which is 2-methylpropene (also known as isobutene).

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consider a reaction with an activation energy of 11186.5 j/mol run at 298.15 k and at 2226 k. how many times larger is the rate constant, k k , for the reaction at 2226 k than at 298 k?

Answers

The question pertains to reaction kinetics and involves the calculation of the ratio of rate constants for a chemical reaction at two different temperatures.

The rate constant is a proportionality constant that relates the rate of a chemical reaction to the concentration of reactants. The activation energy is the minimum amount of energy required for a reaction to occur, and it determines the rate at which the reaction occurs. The rate constant increases with increasing temperature due to the increase in the number of collisions between reactant molecules and the increase in the energy of these collisions.

The ratio of the rate constants at two different temperatures can be calculated using the Arrhenius equation, which relates the rate constant to the activation energy and temperature. Understanding reaction kinetics is important in many areas of chemistry, including materials science, biochemistry, and environmental chemistry. It allows for the optimization of reaction conditions and the prediction of reaction rates under different conditions.

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A water solution of one of these substances will conduct electricity because of either a small or large amount of dissociation into ions.a) solutionb) solutec) solventd) hydrogen bonde) electrolytef) nonelectrolyteg) strong electrolyteh) weak electrolytei) solubilityj) unsaturated solutionk) saturated solutionl) molaritym) indicator

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"Electrolyte" is the word that best describes the situation.  A substance is considered an electrolyte if it dissolves in water and forms conductor ions.

The term that best fits the given statement is "electrolyte". An electrolyte is a substance that, when dissolved in water, produces ions that can conduct electricity. The amount of dissociation of an electrolyte determines whether it is a strong or weak electrolyte. In contrast, a nonelectrolyte is a substance that does not produce ions when dissolved in water and therefore does not conduct electricity. The solubility of a substance refers to its ability to dissolve in a solvent, such as water, to form a solution. A solution is a homogeneous mixture of a solute and a solvent, and it can be classified as unsaturated or saturated depending on the amount of solute dissolved in the solvent. The concentration of a solution can be expressed in various ways, such as molarity, which measures the number of moles of solute per liter of solution. An indicator is a substance that changes color in response to a change in pH or the presence of a specific substance in a solution.

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when a weak acid (ha) is titrated with a strong base, such as naoh what species are present in the weak acid solution before the titration is started?

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Before the titration begins, the weak acid solution (HA) consists of molecules of the weak acid and a small number of H+ ions, which are the result of the weak acid's partial dissociation.

In other words, only a fraction of the weak acid molecules have lost a proton and formed H+ ions. This means that the solution has a low concentration of H+ ions, and therefore has a high pH value.

When the strong base, such as NaOH, is added to the weak acid solution during the titration, it reacts with the H+ ions and forms water. As more and more NaOH is added, the number of H+ ions decreases, and the pH of the solution increases.

At some point, all of the H+ ions are neutralized by the NaOH, and the solution reaches the equivalence point, where the number of moles of NaOH added is equal to the number of moles of weak acid present.

At this point, the solution consists of the salt of the weak acid (NaA) and water. The pH of the solution is determined by the salt's acidity or basicity. If the salt is acidic, the pH of the solution will be less than 7, and if it is basic, the pH will be greater than 7.

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Qualitative Analysis: Cations, Anions and Complex Ions Post-Lab 1. Which anion or anions are not present in a solution that forms no precipitate upon addition of BaCl(aq)

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The anion or anions that are not present in a solution that forms no precipitate upon the addition of BaCl(aq) are chlorides ([tex]Cl^{-}[/tex]), nitrate ([tex]NO_{3}^{-}[/tex]), and sulfate ([tex]SO_{4}^{-2}[/tex]).

Barium chloride ([tex]BaCl_{2}[/tex]) is a soluble salt, and when it is added to a solution that contains these anions, no precipitate will form.

However, when [tex]BaCl_{2}[/tex] is added to a solution that contains carbonate ([tex]CO_{3}^{-2}[/tex]), phosphate ([tex]PO_{4}^{-3}[/tex]), or sulfite ([tex]SO_{3}^{-2}[/tex]) ions, a precipitate will form. This is because barium forms insoluble salts with these anions.

Therefore, the absence of a precipitate upon the addition of [tex]BaCl_{2}[/tex] indicates the absence of these anions in the solution.

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Specific volume for air at 300 k 100 kpa.

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The specific volume for air at 300 K and 100 kPa will be approximately 0.8612 m³/kg.

The specific volume can be calculated using the ideal gas law. At standard temperature and pressure (STP), which is 0 degrees Celsius and 101.325 kPa, the specific volume of air is approximately 0.831 m³/kg. However, at 300 K and 100 kPa, the specific volume of air will be different. To calculate it, we need to use the ideal gas law:

PV = nRT

where P is the pressure, V is the volume, n is the number of moles of gas, R is the gas constant, and T is the temperature in Kelvin.

Rearranging the equation, we can solve for the specific volume (V/n):

V/n = RT/P

Plugging in the values for air at 300 K and 100 kPa (kilopascal), we get:

V/n = (8.314 J/mol*K)(300 K)/(100,000 Pa) = 0.024942 m³/mol

To convert from mol to kg, we need to use the molar mass of air, which is approximately 28.97 g/mol:

0.024942 m³/mol * (1 kg / 28.97 g) = 0.8612 m³/kg

Therefore, the specific volume for air is approximately 0.8612 m³/kg.

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how many moles of hcl need to be added to 150.0 ml of 0.50 m naz to have a solution with a ph of 6.50? (ka of hz is 2.3 x 10-5) assume a negligible volume of the hcl

Answers

0.063 moles of HCl need to be added to 150.0 mL of 0.50 M NaZ to have a solution with a pH of 6.50.

First, find the pKa of HZ by taking the negative logarithm of its Ka value: pKa = -log(Ka) = 4.64.

To calculate the amount of HCl needed to achieve a pH of 6.50, we need to use the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]). Rearranging the equation, we get [A-]/[HA] = 10^(pH - pKa).

Substituting the given values, we get [A-]/[HA] = 10^(6.50 - 4.64) = 70.79. Since the initial solution has 0.50 M NaZ, the concentration of the conjugate base (A-) is 0.50 M. Solving for the concentration of the acid (HA), we get [HA] = [A-]/70.79 = 0.50/70.79 = 0.00706 M.

The volume of the solution is 150.0 mL or 0.150 L. Thus, the number of moles of HA needed is 0.00706 M x 0.150 L = 0.001059 moles.

Since HCl is a strong acid, it will completely dissociate into H+ and Cl-. Therefore, the number of moles of H+ needed is also 0.001059 moles. The concentration of HCl can be calculated using its volume, which is assumed to be negligible: [HCl] = 0.001059 moles / 0.0001 L = 10.59 M.

Finally, we need to dilute this solution to a concentration that will yield the desired pH. Using the equation pH = -log[H+], we get [H+] = 10^(-pH) = 3.16 x 10^(-7) M. The final volume of the solution can be calculated using the equation [H+][Cl-]/[HZ] = 10^(-pKa).

Rearranging this equation, we get [Cl-] = [HZ][10^(-pKa)]/[H+]. Substituting the given values, we get [Cl-] = (0.50 - 0.00706) x [10^(-4.64)] / (3.16 x 10^(-7)) = 0.4927 M.

Therefore, the final volume of the solution is [HCl] / [Cl-] = 0.001059 moles / 0.4927 M = 0.00215 L or 2.15 mL. Subtracting this volume from the initial volume, we get the volume of HCl that needs to be added: 150.0 mL - 2.15 mL = 147.85 mL.

Finally, we can calculate the number of moles of HCl needed: 10.59 M x 0.14785 L = 0.06261 moles, or approximately 0.063 moles.

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the pressure 35.0 m under water is 445 kpa. what is this pressure in atmospheres (atm)?P = ______What is this pressure in millimeters of mercury (mmHg)? P = ______

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The pressure 35.0 m under water 445kPa is approximately 4.39 atmospheres (atm) and 3337.78 mmHg.

To convert the pressure 35.0 m under water from kPa to atmospheres (atm) and mmHg, we need to follow these steps:
1. Convert the given pressure in kPa to atmospheres (atm):
The pressure given is 445 kPa. We will use the conversion factor:

1 atm = 101325 Pa = 101.325 kPa
P(atm) = P(kPa) / 101.325 = 445 / 101.325 ≈ 4.39 atm

2. Convert the given pressure in kPa to mmHg:
The pressure given is 445 kPa. We will use the conversion factor:

1 kPa = 7.50062 mmHg.
P(mmHg) = P(kPa) *7.50062 = 445 * 7.50062 ≈ 3337.78 mmHg

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Based on periodic trends, which one of the following elements do you expect to be most easily reduced: Ca, Sr. P. or Cl? a) Cab) sr c) P d) СІ

Answers

Chlorine, being a halogen, has a high electron affinity and is more likely to be reduced compared to Ca, Sr, and P.

Based on periodic trends, we can expect element (d) Cl (chlorine) to be most easily reduced. This is because, as we move across a period from left to right, elements tend to have an increasing affinity for electrons (due to increasing nuclear charge), making them more likely to be reduced (gain electrons). Chlorine, being a halogen, has a high electron affinity and is more likely to be reduced compared to Ca, Sr, and P.

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Metal ions in aqueous solutions are solvated, or hydrated by water molecules. Typically this primary hydration sphere is composed of six water molecules. The hydrated metal ion acts as a weak acid, undergoing a stepwise hydrolysis in which it donates an H* ion from its water ligands to the surrounding free water molecules. Shown below is the hydrolysis of Al(H20s3 (pka 4.85) in water. calculate the ph of a 0.00339 m alcl3 solution and determine what fraction of the aluminum is in the form al(h2o)5oh2.

Answers

The pH of a 0.00339 M AlCl3 solution is 2.59, and approximately 87% of the aluminum is in the form of Al(H2O)5OH2.

The hydrolysis reaction of Al(H2O)63+ is:

Al(H2O)63+ + H2O ⇌ Al(H2O)5OH2+ + H3O+

The equilibrium constant for this reaction is given by:

Ka = [Al(H2O)5OH2+][H3O+]/[Al(H2O)63+]

At equilibrium, the sum of [Al(H2O)5OH2+] and [Al(H2O)63+] is equal to the initial concentration of Al(H2O)63+, which is 0.00339 M. Using the expression for Ka and the equation for the conservation of mass, we can calculate that the pH of the solution is 2.59 and that approximately 87% of the aluminum is in the form of Al(H2O)5OH2+.

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1) Do the following processes produce an increase or decrease in entropy? Justify A) H2O(1) - H2O(g) B) N(g) + O(g) - NO(g) C) N2(g) + 3H2(g) - 2NH3(g) D) C&His(g) + 2502(g) 16CO2(g) + 18H20(g) E) CaO(s) + CO2(g) → CaCO3(s) F) MgCl2(s) + H2O(1) ► Mg(s) + 2HCl()

Answers

Three reaction result in Increase in entropy and three result in decrease in entropy.

How we determine entropy  for different reactions?

A) H2O(1) - H2O(g): Increase in entropy.

This is because when water goes from a liquid to a gas, the number of available microstates increases, which leads to an increase in entropy.

B) N(g) + O(g) - NO(g): Increase in entropy.

This is because the formation of NO from N and O involves an increase in the number of particles, which leads to an increase in the number of microstates and hence an increase in entropy.

C) N2(g) + 3H2(g) - 2NH3(g): Decrease in entropy.

This is because the reactants have higher entropy than the products. The formation of NH3 involves a decrease in the number of particles and an increase in order, which leads to a decrease in entropy.

D) C&His(g) + 2502(g) 16CO2(g) + 18H20(g): Decrease in entropy.

This is because the reactants have higher entropy than the products. The combustion of carbon and hydrogen with oxygen involves a decrease in the number of particles and an increase in order, which leads to a decrease in entropy.

E) CaO(s) + CO2(g) → CaCO3(s): Decrease in entropy.

This is because the reactants have higher entropy than the products. The formation of CaCO3 from CaO and CO2 involves a decrease in the number of particles and an increase in order, which leads to a decrease in entropy.

F) MgCl2(s) + H2O(1) ► Mg(s) + 2HCl(): Increase in entropy.

This is because the reaction involves an increase in the number of particles and an increase in the number of microstates, which leads to an increase in entropy.

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what gas has a solubility of 26 g per 100 g of water at 56 °c

Answers

The gas that has a solubility of 26 g per 100 g of water at 56°C is ammonia (NH3).

Ammonia is a colorless gas with a pungent odor and is commonly used in fertilizer production, refrigeration, and as a cleaning agent. It dissolves in water to form ammonium hydroxide, and its solubility increases with increasing temperature. At 56°C, the solubility of ammonia in water is 26 g per 100 g of water.

Ammonia (NH3) is a versatile compound that has many uses in industry, agriculture, and households. Some of its common uses include:

Fertilizer production: Ammonia is used to produce nitrogen-based fertilizers,

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Identify the element that has a ground state electronic configuration of [Ar] 4s^23d^104p^3. a) As b) Sb c) N d) P

Answers

The element that has a ground state electronic configuration of [Ar] 4s^2 3d^10 4p^3 is a) As (Arsenic)


As (Arsenic) has a ground state electronic configuration of [Ar] 4s^2 3d^10 4p^3.

Sb (Antimony) has a ground state electronic configuration of [Kr] 5s^2 4d^10 5p^3.

N (Nitrogen) has a ground state electronic configuration of 1s^2 2s^2 2p^3.

P (Phosphorus) has a ground state electronic configuration of [Ne] 3s^2 3p^3.

Arsenic is an element which is widely used in pharmaceuticals, wood preservatives, agricultural chemicals, and applications in the mining, metallurgical, glass-making, and semiconductor industries.



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Need help calculating the H

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2AlBr₃ + 3Ca → 2Al + 3CaBr₂. The heat of reaction (ΔHf) of the following reaction is 1002.44 kJ/mol.

What is Heat of Reaction (ΔHrxn)?

The change in the enthalpy of a chemical reaction that takes place at constant pressure is known as the Heat of Reaction (also known as the Enthalpy of Reaction). It is a thermodynamic unit of measurement that can be used to determine how much energy is released or created per mole during a reaction. Enthalpy is a state function since it is derived from state functions, such as pressure, volume, and internal energy.

As it became too challenging to determine the U, or change in internal energy of a system, by concurrently measuring the quantity of heat and work exchanged, the H, or the change in enthalpy, emerged as a unit of measurement intended to compute the change in energy of a system.

What is Internal Energy?

The amount of energy required to move a thermodynamic system from its initial internal state to the current internal state of interest, accounting for energy gains and losses resulting from changes in the internal state, including factors like magnetization, is the amount of internal energy in the system. It contains the thermal energy but excludes the kinetic energy of motion and the potential energy of position of the system as a whole in relation to its surroundings and external force fields (i.e. internal kinetic energy). According to the first law of thermodynamics, which is based on the concept of conservation of energy, an isolated system's internal energy cannot change.

Using the formula:

ΔHrxn = ∑n ΔH(products) − ∑nΔH(reactants)

ΔHrxn = 3 × (-675.0) - 2 × (-511.28)

ΔHrxn =  1002.44 kJ/mol

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A current of 5.31 A is passed through a Ni(NO3)2 solution for 1.60 hours . How much nickel is plated out of the solution?

Answers

9.29 grams of nickel is plated out of the Ni(NO3)2 solution when a current of 5.31 A is passed through a Ni(NO3)2 solution for 1.60 hours.

Calculate the charge (in coulombs) passed through the solution:
Charge (Q) = Current (I) × Time (t)
I = 5.31 A (amps)
t = 1.60 hours × 3600 seconds/hour = 5760 seconds
Q = 5.31 A × 5760 s = 30576 coulombs

Determine the mole ratio of electrons to nickel in the balanced redox reaction:
Ni(NO3)2 → Ni + 2NO3-
For every one mole of Ni, there are 2 moles of electrons involved.

Convert the charge to moles of electrons:
1 Faraday = 96485 coulombs/mol of electrons
Moles of electrons = Q / 1 Faraday
Moles of electrons = 30576 coulombs / 96485 coulombs/mol = 0.3168 mol

Convert moles of electrons to moles of nickel using the mole ratio:
Moles of Ni = Moles of electrons / 2 (from step 2)
Moles of Ni = 0.3168 mol / 2 = 0.1584 mol

Calculate the mass of nickel plated out using the molar mass of nickel:
Molar mass of Ni = 58.69 g/mol
Mass of Ni = Moles of Ni × Molar mass of Ni
Mass of Ni = 0.1584 mol × 58.69 g/mol = 9.29 g

So, 9.29 grams of nickel is plated out of the Ni(NO3)2 solution.

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QUESTION 9 Compare the proton NMR spectra between the starting material biphenyl, and the product 4-acetylbiphenyl. (a) What does the peak at 2.58 ppm in the product's 1H-NMR spectrum represent? (b) Briefly describe the difference in the aromatic region between the starting material and product. How many hydrogen atoms should be integrated for in the spectrum of biphenyl? (

Answers

The comparison of proton NMR spectra between biphenyl and 4-acetylbiphenyl can be done as follows:

(a) The peak at 2.58 ppm in the product's 1H-NMR spectrum represents the protons of the methyl group (CH3) that is part of the acetyl group (COCH3) in the 4-acetylbiphenyl molecule. This is due to the deshielding effect of the carbonyl group (C=O) adjacent to the methyl protons.

(b) The difference in the aromatic region between the starting material (biphenyl) and the product (4-acetylbiphenyl) can be observed in their respective proton NMR spectra. In the biphenyl molecule, there are two sets of equivalent aromatic protons, resulting in two peaks in the aromatic region. However, in the 4-acetylbiphenyl molecule, the introduction of the acetyl group causes a change in the chemical environment of the aromatic protons, resulting in three peaks in the aromatic region due to the three sets of non-equivalent protons.

For the biphenyl molecule, there are a total of 10 hydrogen atoms in the aromatic region (5 on each phenyl ring). Therefore, the spectrum of biphenyl should show an integration of 10 hydrogen atoms in the aromatic region.

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A solution is made by mixing 3.5x10-4M Sr2+ and 0.0010M F-. Will a precipitate from? (ksp of SrF is 4.3x10-9)a. YEs because QKspc.No, because QKsp

Answers

Q Ksp denotes that there won't be any precipitate formation because the solution is not saturated.  Consequently, the response is: No, since QKsp.

To determine whether a precipitate will form, we need to compare the ion product (Q) to the solubility product (Ksp).

The balanced chemical equation for the dissolution of [tex]SrF_2[/tex] is:

[tex]SrF_2(s)[/tex] ⇌ [tex]Sr_2+(aq) + 2F^-(aq)[/tex]

The Ksp expression is:

Ksp = [tex][Sr^2^+][F^-]^2[/tex]

Substituting the given values:

Ksp = [tex](4.3x10^-^9) = (3.5x10^-^4)(0.0010)^2[/tex]

Ksp is greater than Q, which is calculated by multiplying the concentrations of the ions in the solution:

[tex]Q = [Sr^2^+][F^-]^2 = (3.5x10^-^4)(0.0010)^2[/tex]

Therefore, Q < Ksp, which means the solution is not saturated and no precipitate will form.

Therefore, the answer is: No, because QKsp.

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The 'H NMR spectrum shown in the figure corresponds to the products isolated from the same Wittig reaction that you performed in lab. Figure Table ppa 95.5 4.5 Using this NMR, answer the following questions. (a) The peaks labeled a-d correspond to the alkene protons in the cis & trans alkene isomers. Which peaks correspond to the trans product: a & cor b & d? og (b) In the structure drawing window: • Draw the structure that corresponds to signals a & c. (Draw in all hydrogen atoms in your answer. Include lone pairs where appropriate.) • Assign the two alkene signals (a & c) to the corresponding alkene protons in the molecule. Use the built-in Atom Map function to assign atom map numbers to these two protons. Assign "1" to the alkene proton corresponding to signal a. Assign "2" to the alkene proton corresponding to signal c. If you do not know how to map a number to an atom, click the "Atom Map link shown above! Marvin JS Help D = E 5 C x 6 6 8 28 29 30 0 0 10 ZIL Marvin JS

Answers

In order to determine which peaks correspond to the trans product, we need to look at the chemical shift values. The peak at 4.5 ppm corresponds to the trans product, as it is closer to the typical chemical shift for trans alkene protons.

Moving on to part (b), we need to draw the structure that corresponds to signals a and c, and assign the two alkene signals to the corresponding alkene protons in the molecule using the Atom Map function. Signal a corresponds to the proton on the carbon adjacent to the oxygen atom, and signal c corresponds to the proton on the carbon adjacent to the phenyl group. Therefore, we can draw the structure as follows:
H3C-CH=CH-CH=CH-Ph
| |
O H
We can assign the atom map numbers to the two protons as follows: the alkene proton corresponding to signal a is assigned the number 1, and the alkene proton corresponding to signal c is assigned the number 2. Overall, the 'H NMR spectrum provides valuable information about the structure of the product obtained from the Wittig reaction.

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Does a reaction occur when aqueous solutions of calcium chloride and nickel(II) sulfate are combined?
yes or no
If a reaction does occur, write the net ionic equation.

Answers

A reaction occurs when aqueous solutions of calcium chloride and nickel(II) sulfate are surely combined.

The net ionic equation for the reaction is:

Ca₂⁺(aq) + NiSO₄(aq) → CaSO₄(s) + Ni₂⁺(aq)

In this reaction, the calcium ions (Ca₂⁺) and sulfate ions (SO4) from calcium chloride (CaCl₂) react with nickel ions (Ni₂⁺) from nickel(II) sulfate (NiSO₄) to form solid calcium sulfate (CaSO₄) and aqueous nickel ions (Ni2+). The chloride ions (Cl⁻) from CaCl2 do not participate in the reaction and remain in solution as spectator ions.

The net ionic equation only includes the reactants and products that participate in the reaction, which are the ions that change their oxidation state or form a precipitate.

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The solubility data for another compound
is given below. What is the concentration
in g solute / mL solvent at 50.9 °C?
(see photo)

Answers

According to the question the concentration of the solute in the solvent is 0.116 g/mL.

What is concentration?

Concentration is the act of focusing one's mental energy and attention on a particular object, subject, activity, or goal. It is a key mental skill that can be developed and improved through practice and repetition.

The solubility of a compound is the mass of solute that will dissolve in a given amount of solvent at a given temperature. To calculate the concentration of a solute in a solvent, you need to know the mass of solute, the mass of solvent, and the temperature.
In this case, the mass of solute is 0.72 g, the mass of solvent is 0.934 g - 0.836 g = 0.098 g, and the temperature is 50.9°C. The concentration of the solute in the solvent is then calculated as follows:
Concentration = (Mass of Solute) / (Mass of Solvent)
= 0.72 g / 0.098 g
= 0.116 g/mL.

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Answer:

Thats wrong the answer is C. 1.18g/mL

Explanation:

What species has the electron configuration [Kr]4d5? A) Zr2+ B) Ru3+ C) V3+ D) Fe3+ E) K+ 2. What is the electron configuration for the Cu2+ ion? A) [Ar]4s13d10 B) [Ar]4s03d10 C) [Ar]4s03d9 D) [Ar]4s23d9 E) [Ar]4s03d11

Answers

1. The species with the electron configuration [Kr]4d5 is B) Ru3+.
2. The electron configuration for the Cu2+ ion is D) [Ar]4s23d9.

1. The species with the electron configuration [Kr]4d5 is Ru3+. The electron configuration for the neutral ruthenium atom (Ru) is [Kr]4d7 5s1. When it loses 3 electrons, it becomes Ru3+ with the electron configuration [Kr]4d5.
2. The electron configuration for the Cu2+ ion is [Ar]4s0 3d9. The electron configuration for the neutral copper atom (Cu) is [Ar]4s1 3d10. When it loses 2 electrons, it becomes Cu2+ with the electron configuration [Ar]4s0 3d9.

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sodium hypochlorite, naocl, is the active ingredient in household bleach. what is the concentration of hypochorite ion if 20.00 ml of bleach requires 28.30 ml of 0.500 m hcl to reach the equivalence point?

Answers

The concentration of hypochlorite ion (OCl-) in the bleach solution is 0.710 M.

The balanced chemical equation for the reaction between sodium hypochlorite and hydrochloric acid is:

NaOCl + HCl → NaCl + H2O + Cl2

From the equation, we can see that one mole of HCl reacts with one mole of NaOCl. Therefore, the number of moles of NaOCl in the 20.00 mL of bleach can be calculated from the volume and concentration of HCl required to reach the equivalence point:

moles of HCl = volume of HCl (in L) × molarity of HCl

moles of NaOCl = moles of HCl

Converting the volume of HCl to liters and plugging in the values, we get:

moles of HCl = 28.30 mL × 0.500 mol/L / 1000 mL/L = 0.0142 mol

moles of NaOCl = 0.0142 mol

The concentration of hypochlorite ion (OCl-) can be calculated from the number of moles of NaOCl and the volume of bleach used:

moles of NaOCl = concentration of NaOCl (in mol/L) × volume of NaOCl (in L)

the concentration of OCl- = moles of NaOCl / volume of NaOCl (in L)

Converting the volume of bleach to liters and plugging in the values, we get:

0.0142 mol / (20.00 mL / 1000 mL/L) = 0.710 M

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