which of the following describes correctly about the regioselectivity and stereospecificity in the bronsted acid-catalyzed addition of water to an alkene reaction? group of answer choices markovnikov orientation with syn-addition markovnikov orientation with anti-addition anti-markovnikov orientation with syn-addition anti-markovnikov orientation with anti-addition markovnikov orientation with both syn- and anti-addition

Answers

Answer 1

The one that best describes the regioselectivity and stereospecificity in the Bronsted acid-catalyzed addition of water to an alkene reaction is Markovnikov orientation with syn-addition. Hence option A.

The preference of E and Y for bonds with carbon atoms an or b is referred to as the Markovnikov orientation. The example below demonstrates how, depending on the reaction conditions, a proton acid HY can add to the -bond of an unsymmetrical alkene with either a Markovnikov or an anti-Markovnikov orientation.

When hydrogen itself forms a double bond with the least-substituted carbon atom in asymmetrical alkenes or alkynes, the Markownikoff or Markovnikov rule determines the orientation of the electrophilic addition of hydrogen halides. (or triple bond). So, as conculsion, option A is correct.

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Complete question - which of the following describes correctly about the regioselectivity and stereospecificity in the bronsted acid-catalyzed addition of water to an alkene reaction?

Group of answer choices

1. markovnikov orientation with syn-addition

2. markovnikov orientation with anti-addition

3. anti-markovnikov orientation with syn-addition

4. anti-markovnikov orientation with anti-addition

5. markovnikov orientation with both syn- and anti-addition


Related Questions

Include units with your answer. Consider the reaction 2A + 3B --> C. If the rate of consumption of A at t=3s is 0.2M/s, the rate of formation of C will be type your answer... and the rate of the reaction will be type your answer... 1 point The average rate of a reaction in a range of t is calculated as the type your answer... of the line connection the two x,y points. Instead the instantaneous rate of a reaction at time t, is the slope of the line type your answer... to the curve. What is the oxidation state of Manganese in KMnO4? Input the answer with the proper sign (+ or -), followed by the roman numeral. Х (no answer) For the reaction of Cu + HCI --> CuCl2 + H2, match the correct compound with its role. Oxidizer H+ Reductant Х H+

Answers

The oxidation state of Manganese in KMnO4 is +7.

For the reaction of Cu + HCl --> CuCl2 + H2, Cu is the reductant and H+ is not a compound but rather a reactant. HCl is the oxidizer.

The rate of formation of C will be (0.2/2) x (1/3) = 0.0333 M/s (since the stoichiometry of A to C is 2:1 and the rate is proportional to the reactant's coefficient).

The rate of the reaction will be the same as the rate of consumption of A or the rate of formation of C, whichever is easier to calculate. In this case, it's the rate of consumption of A, which is 0.2 M/s.

The average rate of a reaction in a range of t is calculated as the slope of the line connecting the two (t, concentration) points.

Instead, the instantaneous rate of a reaction at time t is the slope of the tangent line to the curve at that point.

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Part A (I2(g), Br2(g), Cl2(g), F2(g)): The ranking can best be explained by the trend entropy decreases as _.

Answers

The ranking of I2(g), Br2(g), Cl2(g), and F2(g) can best be explained by the trend that entropy decreases as the size and atomic mass of the halogen increases.

1. Entropy is a measure of the randomness or disorder of a system.
2. In general, larger molecules have higher entropy due to increased molecular complexity and a greater number of possible microstates.
3. For the given molecules (I2(g), Br2(g), Cl2(g), and F2(g)), we can determine their atomic sizes: Iodine (I) is the largest, followed by Bromine (Br), Chlorine (Cl), and Fluorine (F) is the smallest.
4. According to the trend, entropy decreases as atomic size decreases.
5. Therefore, the ranking based on entropy would be: I2(g) > Br2(g) > Cl2(g) > F2(g).

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what is the energy (in kj) of a mole of photons with λ = 720 nm?

Answers

Answer:

The energy of a mole of photons with λ = 720 nm is 2.765 x 10^-22 kJ/mol.

Explanation:

To calculate the energy of a mole of photons with λ = 720 nm, we first need to convert the wavelength to meters.

720 nm = 720 x 10^-9 meters

We can then use the equation:

E = hc/λ

where h is Planck's constant (6.626 x 10^-34 J s), c is the speed of light (2.998 x 10^8 m/s), and λ is the wavelength in meters.

Plugging in the values, we get:

E = (6.626 x 10^-34 J s) x (2.998 x 10^8 m/s) / (720 x 10^-9 m)
E = 2.765 x 10^-19 J

To convert joules to kilojoules, we divide by 1000:

E = 2.765 x 10^-19 J / 1000
E = 2.765 x 10^-22 kJ

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what type of system uses diesel exhaust fluid and a catalyst to break nitrogen oxides into nitrogen and water?

Answers

Answer:

SELECTIVE CATALYTIC REDUCTION (SCR)

Explanation:

This catalytic system uses the DEF to break down the dangerous NOx emissions produced during combustion into nitrogen (N2) and water (H2O).

how reduction is characterized in organic chemistry how to recognize reduction, oxidation and substitution why nabh4 used instead of lialh4

Answers

Reduction is a process in organic chemistry where a molecule gains electrons or hydrogen atoms, resulting in a decrease in oxidation state. This process can be characterized by the addition of hydrogen, the removal of oxygen, or the addition of electrons.

Oxidation, on the other hand, is the opposite process where a molecule loses electrons or hydrogen atoms, resulting in an increase in oxidation state. This process can be characterized by the removal of hydrogen, the addition of oxygen, or the loss of electrons.

Substitution is a reaction in which one atom or group is replaced by another atom or group. This process can be characterized by the replacement of a halogen with another halogen or the replacement of a functional group with another functional group.

To recognize reduction, oxidation, and substitution reactions, it is important to look for changes in oxidation state, the addition or removal of atoms or groups, and changes in the number of electrons. These changes can be identified by using chemical tests or by analyzing the chemical structure of the reactants and products.

NaBH4 is often used instead of LiAlH4 in reduction reactions because it is less reactive and less likely to react with other functional groups present in the reaction mixture. NaBH4 is also less expensive and easier to handle than LiAlH4. However, LiAlH4 is more powerful and can be used for more complex reduction reactions.

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The standard entropy of vaporization of acetone is approximately 85 J/K⋅mol
at its boiling point.
(a) Estimate the standard enthalpy of vaporization a acetone at its normal boiling point of 56.2∘ C
.
(b) What is the entropy change of the surroundings when 10.0 g
of acetone, CH3COCH3, condenses at its normal boiling point?

Answers

(a)  The estimated standard enthalpy of vaporization of acetone is  31.3 kJ/mol

The estimated standard enthalpy of vaporization of acetone at its normal boiling point of 56.2∘ C can be calculated using the Clausius-Clapeyron equation:

ΔHvap = -R*(Tb^2/T)*ln(P1/P2)

where R is the gas constant, Tb is the boiling point in Kelvin, T is the temperature in Kelvin, P1 is the vapor pressure at the initial temperature, and P2 is the vapor pressure at the final temperature.

Using the given standard entropy of vaporization and the boiling point of acetone, we can calculate the initial vapor pressure of acetone, which is 31.1 kPa. Substituting the values into the equation, we get:

ΔHvap = 31.3 kJ/mol

Tthe entropy change of the surroundings when t0.0 g of acetone condenses at its normal boiling point is -95.0 J/K.

(b) The entropy change of the surroundings can be calculated using the equation:

ΔSsurroundings = -ΔHvap/T

Substituting the values, we get:

ΔSsurroundings = -31.3 kJ/mol / (329.35 K)

ΔSsurroundings = -95.0 J/K

Therefore, the entropy change of the surroundings when t0.0 g of acetone condenses at its normal boiling point is -95.0 J/K.

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A sample of HI was placed in a container and the following reaction was allowed to come to equilibrium.
H₂(g) + I₂(g) ⇌ 2 HI(g)
The equilibrium concentrations were found to be [HI] = 3.88 M and [H₂] = [I₂] = 0.556.
Calculate the equilibrium constant, Kc, for the reaction. Note Kc is often called K.

Answers

the equilibrium constant (Kc) for the reaction is 57.2. This value indicates that the reaction strongly favors the formation of HI at equilibrium.


H₂(g) + I₂(g) ⇌ 2 HI(g)

First, let's write the equilibrium expression for the reaction:

Kc = [HI]^2 / ([H₂] * [I₂])

Now, we can plug in the equilibrium concentrations given:

[HI] = 3.88 M
[H₂] = [I₂] = 0.556 M

Next, substitute the concentrations into the equilibrium expression:

Kc = (3.88)^2 / (0.556 * 0.556)

Now, calculate the equilibrium constant:

Kc = 15.0544 / 0.309136

Kc = 48.7 (rounded to one decimal place)

So, the equilibrium constant Kc for this reaction is 48.7.

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Jupiter is 7.8x108 km from the Sun. Its albedo is 0.73. Calculate the effective temperature of Jupiter assuming that the Sun is the only energy source. (note: The solar "constant" follows an inverse square law, meaning that for a distance d from the Sun it’s equal to FS(d)= 1370 W m-2 (1.5E8 km/d)2

Answers

Assuming that the Sun is the only energy source, the effective temperature of Jupiter is approximately 109.96 K.

To calculate the effective temperature of Jupiter, we will use the following formula:

Te = [(FS(d) * (1 - albedo)) / (4 * σ)]^(1/4)

where:
- Te is the effective temperature of Jupiter
- FS(d) is the solar constant at the distance d from the Sun
- albedo is the reflectivity of Jupiter
- σ is the Stefan-Boltzmann constant (5.67 × 10⁻⁸ W m⁻² K⁻⁴)

First, let's find the solar constant at Jupiter's distance:

FS(d) = 1370 W m⁻² * (1.5E8 km / 7.8 x 10⁻⁸ km)²
FS(d) = 1370 W m⁻² * (1.5E8 / 7.8E8)²
FS(d) ≈ 50.66 W m⁻²

Now, we can calculate Jupiter's effective temperature:

Te = [(50.66 * (1 - 0.73)) / (4 * 5.67 × 10⁻⁸)]^(1/4)
Te = [(50.66 * 0.27) / (4 * 5.67 × 10⁻⁸)]^(1/4)
Te ≈ 109.96 K

Therefore, the effective temperature of Jupiter, assuming the Sun is the only energy source, is approximately 109.96 K.

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25.0 ml of a 0.100 m solution of nh3 is titrated with 0.150 m hcl. after 10.0 ml of the hcl has been added, the resultant solution is: a) basic and before the equivalence point. b) basic and after the equivalence point. c) acidic and before the equivalence point. d) acidic and after the equivalence point. e) neutral and at the equivalence point

Answers

When 25.0 ml of a 0.100 m solution of nh3 is a titration with 0.150 m HCL After 10.0 ml of the HCL has been added, the resultant solution is basic and before the equivalence point.

At the start of the titration, we have a solution of NH3, which is a weak base, and we add HCl, which is a strong acid. As we add HCl, it reacts with NH3 to form NH4Cl, which is a salt.

The balanced equation for the reaction is: NH3 + HCl → NH4Cl

We can see that for every mole of HCl added, one mole of NH3 is consumed. Therefore, at the equivalence point, all the NH3 will be consumed and the solution will contain only NH4Cl, which is a neutral salt.

Since only 10.0 ml of the 0.150 M HCl has been added to 25.0 ml of 0.100 M NH3, the solution is still before the equivalence point. The pH of the solution will be basic because NH3 is a weak base and has not been completely neutralized by the HCl.

Therefore, the correct answer is (a) basic and before the equivalence point.

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The reaction has an initial rate of 0.0300 M/s.A+B YIELDS C+D rate=k[A][B]^2What will the initial rate be if [A] is halved and [B] is tripled? (answer) _________ M/s

Answers

The new rate will be 0.135 M/s.

The new rate can be calculated using the rate law equation: rate=k[A][B]^2.

If [A] is halved and [B] is tripled, the new concentrations are: [A]/2 and 3[B].

Plugging in these new concentrations into the rate law equation, we get:

new rate = k * ([A]/2) * (3[B])^2

Simplifying:

new rate = (9/2) * k * [A] * [B]^2

Therefore, the new rate will be (9/2) times the initial rate:

new rate = (9/2) * 0.0300 M/s = 0.135 M/s

Hence, the new rate will be 0.135 M/s.

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An infant dose of acetaminophen (C8H9NO2) is 0.080 g. How many moles of acetaminophen are in each infant dose?

Answers

There are approximately 0.00053 moles of acetaminophen in each infant dose.

To calculate the moles of acetaminophen (C8H9NO2) in each infant dose, you'll need to use the formula:

moles = mass (g) / molar mass (g/mol)

First, determine the molar mass of acetaminophen:
C: 8 atoms × 12.01 g/mol = 96.08 g/mol
H: 9 atoms × 1.01 g/mol = 9.09 g/mol
N: 1 atom × 14.01 g/mol = 14.01 g/mol
O: 2 atoms × 16.00 g/mol = 32.00 g/mol

Total molar mass = 96.08 + 9.09 + 14.01 + 32.00 = 151.18 g/mol

Now, divide the mass of the infant dose (0.080 g) by the molar mass (151.18 g/mol):

moles = 0.080 g / 151.18 g/mol ≈ 0.00053 moles

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what is the molarity of 25 ml an acetic acid solution that contains 0.024 moles? report your answer to three decimal places.

Answers

The molarity of the acetic acid solution is 0.96 M, rounded to three decimal places.

It is calculated by dividing the number of moles of acetic acid by the volume of the solution in liters.
First, convert the volume from milliliters to liters by dividing by 1000:
25 ml = 25/1000 L = 0.025 L
Then, divide the number of moles (0.024) by the volume in liters (0.025):
Molarity = 0.024 moles / 0.025 L = 0.96 M

The density of acetic acid is 1.05 g/ml, and its molecular weight is 60 g/mol. Acetic acid CH3COOH (C2H4O2) has a molecular weight of 60 grams. One litre of water and one mole of acetic acid combine to form a molar solution.

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Compare the average speed of gas phase H2 molecules to the average speed of gas phase krypton atoms: a. Argon atoms have greater average speed than H2 because argon is smaller than H2. b. Argon atoms have greater average speed than H2 because atoms move faster than molecules. c. H2 has greater average speed than argon because H2 is more reactive than noble gases d. H2 and argon have the same average speeds. e. H2 has greater average speed than argon because it has lower molar mass.

Answers

e. H2 has greater average speed than argon because it has lower molar mass.

The average speed of gas particles is directly proportional to the square root of their temperature and inversely proportional to the square root of their molar mass. Since hydrogen gas (H2) has a lower molar mass than krypton (Kr) or argon (Ar), it will have a higher average speed at the same temperature.

The statement that argon atoms have a greater average speed than H2 because argon is smaller than H2 is incorrect because the size of the atom or molecule is not the determining factor in average speed. Statement b is also incorrect, as it implies that all atoms move faster than all molecules, which is not true. Statement c is also incorrect as reactivity is not related to average speed. Statement d is incorrect because H2 and argon have different molar masses and therefore different average speeds.

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4.25×10−3mol of the weak base pyridine, C5H5N, is added to water to make up 25.0mL of solution. The Kb of pyridine is 1.7×10−9. What is the pH of the solution?
round to two decimal places

Answers

The pH of the pyridine solution is approximately 9.23, rounded to two decimal places.

When 4.25×10⁻³ mol of pyridine (C₅H₅N), a weak base, is added to 25.0 mL of water, we need to determine the pH of the resulting solution. The Kb of pyridine is given as 1.7×10⁻⁹.

First, we need to calculate the initial concentration of pyridine:

[Pyridine] = (4.25×10⁻³ mol) / (25.0 mL × 10⁻³ L/mL) = 0.17 M

Next, we'll set up an equilibrium expression using the Kb:

Kb = [C₅H₅NH⁺][OH⁻] / [C₅H₅N]

Let x be the change in concentration of the species:

1.7×10⁻⁹ = (x)(x) / (0.17 - x)

Since Kb is very small, we can assume x is much smaller than 0.17, so:

1.7×10⁻⁹ ≈ x² / 0.17

x² ≈ 2.89×10⁻¹⁰
x ≈ 1.7×10⁻⁵

x represents the concentration of OH⁻ ions:

[OH⁻] = 1.7×10⁻⁵ M

Now, we'll find the pOH:

pOH = -log([OH⁻]) = -log(1.7×10⁻⁵) ≈ 4.77

Finally, we can calculate the pH:

pH = 14 - pOH ≈ 14 - 4.77 ≈ 9.23

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determine the rate constant k from the slope of the linear regression line for your linear curve (k=1 slope for zero and first order and k=slope for the second order). Be sure to include correct units for the rate constant. Note: This constant is sometimes referred to as the pseudo constant, because it does not take into account the effect of the other reactant, OH-

Answers

To determine the rate constant (k) from the slope of the linear regression line, you will need to plot a graph of concentration versus time for the reaction. Once you have this graph, you can perform a linear regression analysis to find the slope of the line. The slope of the line will give you the value of the rate constant (k) for the reaction.

For zero and first order reactions, k=1. For second order reactions, k=slope. The units of the rate constant will depend on the order of the reaction. For zero order reactions, the units are mol/L/s. For first order reactions, the units are s^-1. For second order reactions, the units are L/mol/s.

It is important to note that the rate constant obtained from the linear regression analysis is sometimes referred to as the pseudo constant. This is because it only takes into account the effect of one reactant, and does not consider the effect of other reactants present in the reaction mixture.

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a relation is in 2nf if and only if it is in 1nf and some non-key attributes are not determined by the entire primary key. (True or False)

Answers

True. In second normal form (2NF), a relation must first be in first normal form (1NF), which means it has no repeating groups and each attribute contains atomic values.

In addition, for a relation to be in 2NF, all relation non-key attributes must be dependent on the entire primary key. If some non-key attributes are not determined by the entire primary key, then the relation is not in 2NF.
False. A relation is in 2NF (Second Normal Form) if and only if it is in 1NF (First Normal Form) and all non-key attributes are fully functionally dependent on the entire primary key, not just a part of it. This means that no non-key attributes are determined by a subset of the primary key.A relational table is in third normal form (3NF) if it is already in 2NF and every non-key column is non transitively dependent upon its primary key. In other words, all nonkey attributes are functionally dependent only upon the primary key.

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(a) What sign for ∆ S do you expect when the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm? (b) If the final pressure on the gas is 1.20 atm, calculate the entropy change for the process. (c) Do you need to specify the temperature to calcu-late the entropy change? Explain.

Answers

(a) When the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm, we expect a negative sign for ∆S. This is because increasing pressure causes the molecules to become more ordered, which results in a decrease in entropy.

(b) To calculate the entropy change for the process, we can use the formula:

∆S = nR ln(Vf/Vi)

where n is the number of moles of gas, R is the gas constant, and Vf and Vi are the final and initial volumes of the gas, respectively.

Since the process is isothermal, we can use the ideal gas law to relate pressure and volume:

PV = nRT

Solving for V, we get:

V = nRT/P

Using this expression for V in the entropy formula, we get:

∆S = nR ln(Pi/Pf)

Substituting the given values, we get:

∆S = (0.600 mol)(8.314 J/mol K) ln(0.750 atm/1.20 atm) = -5.6 J/K

Therefore, the entropy change for the process is -5.6 J/K.

(c) No, we do not need to specify the temperature to calculate the entropy change. This is because the process is isothermal, which means that the temperature remains constant throughout. The entropy change only depends on the initial and final pressures of the gas.

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Determine the relative acidity of two species, and explain why they're ranked that way. Choose one: O Compounds A and B are equally acidio O Compound B is mc tre sci ld than compound O Compound A is more acidic than compound B

Answers

Compound B is more acidic than Compound A because it is stated that "Compound B is more acidic than Compound A".

The relative acidity of Compound A and Compound B can be determined by comparing their ability to donate a proton (H+ ion). The compound that can donate a proton more easily is more acidic. In this case, it can be assumed that both compounds are organic acids.

If Compound A has a stronger electron-withdrawing group than Compound B, it will be more acidic because the electron-withdrawing group makes the proton more easily removable. Therefore, if Compound A has a higher electronegativity or more electron-withdrawing groups than Compound B, it will be more acidic.

Without knowing the structures of the two compounds, it is difficult to make a definite determination. However, based on the information given, we can conclude that Compound B is more acidic than Compound A because it is stated that "Compound B is more acidic than Compound A".

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what products are formed when benzene is treated with each alkyl chloride and alcl3?

Answers

When benzene is treated with an alkyl chloride and AlCl3, the products formed are an alkylbenzene and aluminum chloride.


This reaction is called the Friedel-Crafts alkylation and proceeds in the following steps:

1. The alkyl chloride (R-Cl) reacts with AlCl3 to form a complex, in which the AlCl3 acts as a Lewis acid, accepting a lone pair from the chloride ion.

2. This complex dissociates to generate an alkyl carbocation (R+) and an AlCl4- ion.

3. The alkyl carbocation (R+) then attacks the benzene ring, forming a bond with one of the carbon atoms and creating a cyclohexadienyl cation.

4. Finally, the cyclohexadienyl cation loses a proton, regenerating the aromaticity of the benzene ring, and yielding the alkylbenzene and  HCl molecule as products.

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How many different elements are in the compound C6H12O6?A) 3B) 6C) 24D) All of the elements are the same.

Answers

There are three different elements present in the compound C₆H₁₂O₆. Option (A) is correct.

The molecular formula C₆H₁₂O₆ represents a carbohydrate known as glucose, a simple sugar. The elements that are present in the compound C₆H₁₂O₆ are Carbon (C), Hydrogen (H), and Oxygen (O). Glucose is a monosaccharide, i.e., a single sugar molecule that cannot be further broken down by hydrolysis.

C₆H₁₂O₆ consists of six carbon atoms, twelve hydrogen atoms, and six oxygen atoms. The carbon atoms form a six-carbon chain, which serves as the backbone of the molecule. Each carbon atom is also bonded to a hydrogen atom, except for the first and last carbons, which are each bonded to a hydroxyl group (-OH).

The hydroxyl groups of glucose make it a polar molecule, meaning it can form hydrogen bonds with other polar molecules, such as water. So, the correct option is (A) 3 different elements are present in C₆H₁₂O₆.

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which chemical used in rocket fuel affects the thyroid gland?

Answers

Perchlorate is used in rocket fuel affects the thyroid gland.

Perchlorate, a chemical substance used in rocket fuel, fireworks, fertilisers, and other products, is one such contaminant.

Since it prevents the sodium/iodide symporter (NIS), a protein that transports iodide into the thyroid and other tissues, perchlorate is associated with thyroid disorders. Hypothyroidism, which can be brought on by decreased iodide uptake, can be extremely harmful for infants since it directly impacts how they develop in numerous ways.

Thyroxine (also known as T4), a relatively inactive prohormone, and triiodothyronine, a highly active hormone, are both produced by the thyroid gland (referred to as T3). The thyroid hormones are thyroxine and triiodothyronine taken together.

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The complete question is

Which chemical used in rocket fuel affects the thyroid gland?

A. Reproductive hormones

B. DDT

C. PCBs

D. PBDEs

E. Perchlorates

) Complete the reactions to form a series of equations describing the oxidation of 2 mol of glutamate to 2 mol of α‑ketoglutarate and 1 mol of urea.H2O + __________ + NAD+ ⟶ α‑ketoglutarate + NH4+ + NADH + H+NH4+ + 2 ATP + H2O + CO2 ⟶ __________ + 2 ADP + Pi + 3H+Carbamoyl phosphate + _________ ⟶ citrulline + Pi + H+Citrulline + aspartate + ATP ⟶ argininosuccinate + AMP + PPi + H+Argininosuccinate ⟶ ________ + fumarateFumarate + H2O ⟶ malateMalate + NAD + ⟶ oxaloacetate + NADH + H+Oxaloacetate + glutamate ⟶ aspartate + _________Arginine + H2O ⟶ _________ + ornithine

Answers

Here are the completed reactions for the oxidation of 2 mol of glutamate to 2 mol of α‑ketoglutarate and 1 mol of urea, with the missing terms filled in:

1. H2O + glutamate dehydrogenase + NAD+ ⟶ α‑ketoglutarate + NH4+ + NADH + H+
2. NH4+ + 2 ATP + H2O + CO2 ⟶ carbamoyl phosphate + 2 ADP + Pi + 3H+
3. Carbamoyl phosphate + ornithine ⟶ citrulline + Pi + H+
4. Citrulline + aspartate + ATP ⟶ argininosuccinate + AMP + PPi + H+
5. Argininosuccinate ⟶ arginine + fumarate
6. Fumarate + H2O ⟶ malate
7. Malate + NAD + ⟶ oxaloacetate + NADH + H+
8. Oxaloacetate + glutamate ⟶ aspartate + α-ketoglutarate
9. Arginine + H2O ⟶ urea + ornithine

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Consider the following equilibrium:2H2(g) + S2(g) <=> 2H2S(g) Kc=1.08 x 10^7 at 700oCa) Calculate Kpb) Does the equilibrium mixture containmostly H2 and S2 or mostlyH2S?

Answers

The equilibrium mixture contains mostly H2S, as the reaction strongly favors the formation of H2S.

a) To calculate Kp, we need to use the equation Kp = Kc(RT)Δn, where Δn is the change in the number of moles of gas between the products and reactants. In this case, Δn = (2 + 1) - (2) = 1 (since there are 2 moles of H2 and 1 mole of S2 on the left side, and 2 moles of H2S on the right side). We also need to convert the temperature from Celsius to Kelvin by adding 273.15: T = 700 + 273.15 = 973.15 K. Finally, we need to use the value of R in the correct units: R = 0.08206 L·atm/K·mol. Putting it all together, we get:

Kp = Kc(RT)Δn
Kp = (1.08 x 10^7)(0.08206 L·atm/K·mol)(973.15 K)^1
Kp = 9.10 x 10^5 atm

b) To determine which gases are present in the equilibrium mixture, we can compare the reaction quotient Qc (which is the same as Kc when the system is at equilibrium) to Kc. If Qc < Kc, then the forward reaction (to form H2S) is favored, and the mixture will contain mostly H2S. If Qc > Kc, then the reverse reaction (to form H2 and S2) is favored, and the mixture will contain mostly H2 and S2.

Let's assume that we start with equal initial concentrations of H2 and S2 (we don't know the actual concentrations, but this is a reasonable assumption to make). Then, at equilibrium, we have:

Kc = [H2S]^2 / ([H2]^2 [S2])
Kc = (2x)^2 / (x^2 x)
Kc = 4 / x

where x is the equilibrium concentration of either H2 or S2 (since they are equal initially). We can rearrange this equation to solve for x:

x = sqrt(4/Kc) = 6.14 x 10^-4 M

Now we can calculate Qc using this value of x:

Qc = [H2S]^2 / ([H2]^2 [S2])
Qc = (2x)^2 / (x^2 x)
Qc = 4 / x
Qc = 6.51 x 10^6

Since Qc > Kc, the reverse reaction is favored, and the equilibrium mixture will contain mostly H2 and S2.

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How many moles of H2 are needed to react with 5.0 mol of O2 ?

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Therefore, 10.0 moles of [tex]H_2[/tex] are needed to react with 5.0 moles of [tex]O_2[/tex].

5 moles of [tex]O_2[/tex] may make how many moles of [tex]H_2O[/tex]?

There is nothing in front of this by chemical composition, thus we may place a one. I get three moles of [tex]CO_2[/tex] and four moles of [tex]H_2O[/tex] from one mole of this and five moles of [tex]O_2[/tex].

The balanced chemical equation for the reaction between hydrogen gas ([tex]H_2[/tex]) and oxygen gas ([tex]O_2[/tex]) to form water ([tex]H_2O[/tex]) is:

[tex]2H_2 + O_2 - > 2H_2O[/tex]

According to the equation, 1 mole of [tex]O_2[/tex] reacts with 2 moles of . So, to determine how many moles of [tex]H_2[/tex] are needed to react with 5.0 mol of [tex]O_2[/tex], we need to use the mole ratio:

5.0 mol [tex]O_2[/tex] x (2 mol H2 / 1 mol [tex]O_2[/tex]) = 10.0 mol hydrogen

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classify thf (tetrahydrofolate), sam (s‑adenosyl methionine), cys (cysteine), and glu (glutamate) as methyl group, formyl group, amino group, or thiol group donors in biological reactions.

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THF (tetrahydrofolate) is a methyl group donor in biological reactions.
SAM (s‑adenosyl methionine) is a methyl group donor in biological reactions.
Cys (cysteine) is a thiol group donor in biological reactions.
Glu (glutamate) is an amino group donor in biological reactions.

It is important to note that formyl groups are not mentioned in this question, but they are typically involved in reactions that add a formyl group to a molecule.

The following classify these molecules based on their roles as donors in biological reactions:

1. THF (Tetrahydrofolate) - Formyl group donor
2. SAM (S-Adenosyl methionine) - Methyl group donor
3. CYS (Cysteine) - Thiol group donor
4. GLU (Glutamate) - Amino group donor

These classifications are based on the functional groups these molecules typically donate during biological reactions.

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what is the advantage of decreasing monochromator slit width in spectroscopic techniques? what is the disadvantage?

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The decision to decrease the monochromator slit width should be balanced between the desired resolution and the sensitivity of the detector.

In spectroscopic techniques, the monochromator is an important component that selects a narrow range of wavelengths from the incident light in spectroscopic techniques. By decreasing the monochromator slit width, the advantage is that the resolution of the spectrum is improved. This means that the spectrum will have more defined peaks and troughs, which can aid in identifying and characterizing the sample being studied. However, the disadvantage of decreasing the monochromator slit width is that the intensity of the light reaching the detector will decrease, which may result in a lower signal-to-noise ratio. This means that the spectrum may be more difficult to interpret or may require longer exposure times to obtain a clear signal.

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determine the volume in ml of 0.141 m koh(aq) needed to reach the equivalence (stoichiometric) point in the titration of 44.29 ml of 0.153 m c6h5oh(aq). the ka of phenol is 1.0 x 10-10.

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The volume of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 mL of 0.153 M C6H5OH(aq) is 48.06 mL.

To determine the volume in ml of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 ml of 0.153 M C6H5OH(aq) with the Ka of phenol being 1.0 x 10^-10, follow these steps:

1. Write the balanced chemical equation for the reaction between phenol (C6H5OH) and potassium hydroxide (KOH):
  C6H5OH + KOH → C6H5O⁻ + H2O

2. Calculate the moles of phenol (C6H5OH) using the given concentration and volume:
  moles of C6H5OH = 0.153 M × 0.04429 L = 0.006777 moles

3. At the equivalence point, the moles of phenol and hydroxide ions (from KOH) will be equal. Therefore, the moles of KOH required are also 0.006777 moles.

4. Calculate the volume of 0.141 M KOH(aq) needed using the moles and concentration:
  Volume (L) = moles of KOH / concentration of KOH
  Volume (L) = 0.006777 moles / 0.141 M = 0.04806 L

5. Convert the volume from liters to milliliters:
  Volume (mL) = 0.04806 L × 1000 mL/L = 48.06 mL

So, the volume of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 mL of 0.153 M C6H5OH(aq) is 48.06 mL.

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bongkrekic acid is a toxic compound producted by pseudomonas cocovenenans, and isolated from a mold that grows on bongkrek, a fermented indonesian coconut dish. in bongkrekic acid, abel each double bond as e or z and each tetrahedral stereogenic center as r or s.

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Bongkrekic acid is a toxic compound produced by the bacterium Pseudomonas cocovenenans, and it is isolated from a mold that grows on bongkrek, a fermented Indonesian coconut dish.

To determine the configurations of double bonds as E or Z and tetrahedral stereogenic centers as R or S, one would need to examine the molecular structure of bongkrekic acid. Unfortunately, without providing the specific structure of bongkrekic acid, I am unable to assign the E/Z and R/S configurations. However, I can give you a brief explanation of these terms:

1. E/Z configuration: In chemistry, E/Z notation is used to describe the spatial arrangement of atoms or groups around a double bond. The E configuration indicates that the two largest substituents are on opposite sides of the double bond, while the Z configuration means they are on the same side.

2. R/S configuration: This is used to describe the configuration of a tetrahedral stereogenic center. The R (rectus) and S (sinister) designations are determined by the priority of the substituent groups around the chiral center following the Cahn-Ingold-Prelog priority rules.
If you provide the molecular structure of bongkrekic acid, I can help you assign the E/Z and R/S configurations for this compound.

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Na+ is actively transported into the tubule cells of the ascending limb of the Loop of Henle from the tubular lumen.
F/T

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The ascending limb of loop of Henle is a segment of the nephron in the kidney divided into a thin and thick ascending limb. The thin ascending limb is impermeable to water and ions, except sodium and chloride, which cross by diffusion.

True. Na+ is actively transported from the tubular lumen into the tubule cells of the ascending limb of the Loop of Henle
True, Na+ is actively transported into the tubule cells of the ascending limb of the Loop of Henle from the tubular lumen. This process helps in maintaining the concentration gradient and is important for the regulation of water and electrolyte balance in the body.

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compost experts recommend a carbon to nitrogen level of _______ in order to optimize the decomposition process of composting.

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Compost experts recommend a carbon-to-nitrogen (C:N) ratio of around 30:1 in order to optimize the decomposition process of composting.

This proportion offers a healthy balance of nitrogen- and carbon-rich materials, such as grass clippings or dried leaves, which are required for the development of microorganisms that break down organic matter in the compost pile.

A C:N ratio that is too high in nitrogen may result in an offensive odor or the attraction of pests, while a C:N ratio that is too high in carbon may cause slow decomposition.

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