Nickel is not an essential trace mineral because it is required by the body in proper amount.
A silver-white metal called nickel is present in soil, water, and a variety of foods, such as almonds, dried beans, and chocolate. Only tiny amounts of nickel are necessary for the body.
For various bodily chemical processes, nickel is necessary. Its precise functions within the body aren't known. Vitamin supplements frequently contain the trace metal nickel.
When there is insufficient nickel in the blood, nickel insufficiency results. In order to avoid Nickel deficiency, people use Nickel. A good strategy to prevent nickel insufficiency is to take a supplement containing modest levels of nickel.
On the other hand, the essential trace minerals are chromium, copper, selenium, and molybdenum, which are needed by the body in small amounts for various physiological functions.
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classify thf (tetrahydrofolate), sam (s‑adenosyl methionine), cys (cysteine), and glu (glutamate) as methyl group, formyl group, amino group, or thiol group donors in biological reactions.
THF (tetrahydrofolate) is a methyl group donor in biological reactions.
SAM (s‑adenosyl methionine) is a methyl group donor in biological reactions.
Cys (cysteine) is a thiol group donor in biological reactions.
Glu (glutamate) is an amino group donor in biological reactions.
It is important to note that formyl groups are not mentioned in this question, but they are typically involved in reactions that add a formyl group to a molecule.
The following classify these molecules based on their roles as donors in biological reactions:
1. THF (Tetrahydrofolate) - Formyl group donor
2. SAM (S-Adenosyl methionine) - Methyl group donor
3. CYS (Cysteine) - Thiol group donor
4. GLU (Glutamate) - Amino group donor
These classifications are based on the functional groups these molecules typically donate during biological reactions.
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Include units with your answer. Consider the reaction 2A + 3B --> C. If the rate of consumption of A at t=3s is 0.2M/s, the rate of formation of C will be type your answer... and the rate of the reaction will be type your answer... 1 point The average rate of a reaction in a range of t is calculated as the type your answer... of the line connection the two x,y points. Instead the instantaneous rate of a reaction at time t, is the slope of the line type your answer... to the curve. What is the oxidation state of Manganese in KMnO4? Input the answer with the proper sign (+ or -), followed by the roman numeral. Х (no answer) For the reaction of Cu + HCI --> CuCl2 + H2, match the correct compound with its role. Oxidizer H+ Reductant Х H+
The oxidation state of Manganese in KMnO4 is +7.
For the reaction of Cu + HCl --> CuCl2 + H2, Cu is the reductant and H+ is not a compound but rather a reactant. HCl is the oxidizer.
The rate of formation of C will be (0.2/2) x (1/3) = 0.0333 M/s (since the stoichiometry of A to C is 2:1 and the rate is proportional to the reactant's coefficient).
The rate of the reaction will be the same as the rate of consumption of A or the rate of formation of C, whichever is easier to calculate. In this case, it's the rate of consumption of A, which is 0.2 M/s.
The average rate of a reaction in a range of t is calculated as the slope of the line connecting the two (t, concentration) points.
Instead, the instantaneous rate of a reaction at time t is the slope of the tangent line to the curve at that point.
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4.25×10−3mol of the weak base pyridine, C5H5N, is added to water to make up 25.0mL of solution. The Kb of pyridine is 1.7×10−9. What is the pH of the solution?
round to two decimal places
The pH of the pyridine solution is approximately 9.23, rounded to two decimal places.
When 4.25×10⁻³ mol of pyridine (C₅H₅N), a weak base, is added to 25.0 mL of water, we need to determine the pH of the resulting solution. The Kb of pyridine is given as 1.7×10⁻⁹.
First, we need to calculate the initial concentration of pyridine:
[Pyridine] = (4.25×10⁻³ mol) / (25.0 mL × 10⁻³ L/mL) = 0.17 M
Next, we'll set up an equilibrium expression using the Kb:
Kb = [C₅H₅NH⁺][OH⁻] / [C₅H₅N]
Let x be the change in concentration of the species:
1.7×10⁻⁹ = (x)(x) / (0.17 - x)
Since Kb is very small, we can assume x is much smaller than 0.17, so:
1.7×10⁻⁹ ≈ x² / 0.17
x² ≈ 2.89×10⁻¹⁰
x ≈ 1.7×10⁻⁵
x represents the concentration of OH⁻ ions:
[OH⁻] = 1.7×10⁻⁵ M
Now, we'll find the pOH:
pOH = -log([OH⁻]) = -log(1.7×10⁻⁵) ≈ 4.77
Finally, we can calculate the pH:
pH = 14 - pOH ≈ 14 - 4.77 ≈ 9.23
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determine the rate constant k from the slope of the linear regression line for your linear curve (k=1 slope for zero and first order and k=slope for the second order). Be sure to include correct units for the rate constant. Note: This constant is sometimes referred to as the pseudo constant, because it does not take into account the effect of the other reactant, OH-
To determine the rate constant (k) from the slope of the linear regression line, you will need to plot a graph of concentration versus time for the reaction. Once you have this graph, you can perform a linear regression analysis to find the slope of the line. The slope of the line will give you the value of the rate constant (k) for the reaction.
For zero and first order reactions, k=1. For second order reactions, k=slope. The units of the rate constant will depend on the order of the reaction. For zero order reactions, the units are mol/L/s. For first order reactions, the units are s^-1. For second order reactions, the units are L/mol/s.
It is important to note that the rate constant obtained from the linear regression analysis is sometimes referred to as the pseudo constant. This is because it only takes into account the effect of one reactant, and does not consider the effect of other reactants present in the reaction mixture.
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HELP PLEASE WILL GIVE BADGE
H₂CO₃ is an acid that gives a proton to H₂O, which accepts the proton as a base. H₂O's conjugate acid is H₃O⁺, and H₂CO₃'s conjugate base is HCO₃⁻. H₂O/H₃O⁺ and H₂CO₃/HCO₃⁻are the conjugate acid-base pair in this process.
What is acid-base pairs?Two chemical species are referred to as an acid-base pair when a proton (H+) from one species is transferred to the other. The species that accepts a proton is known as the base, while the species that provides a proton is known as the acid.
b. H₂O functions as an acid by giving a proton to a different H₂O molecule, which accepts the proton and functions as a base. H₃O⁺ is the conjugate acid of H₂O, whereas OH⁻ is the conjugate base of H₂O. H₂O/H₃O⁺ and H₂O/OH⁻ are the conjugate acid-base pair in this process.
c. H₂S functions as an acid by giving a proton to NH₃, which accepts the proton and functions as a base. NH₄⁺ is the conjugate base of H₂S, whereas NH₃'s conjugate acid is NH₄⁺. NH₃/NH₄⁺ and H₂S/HS⁻ are the conjugate acid-base pair in this reaction, respectively.
d. H₂PO₄⁻ functions as an acid by giving a proton to H₂O, while H₂O functions as a base by taking the proton. H₂O's conjugate acid is H₃O⁺, and H₂PO₄⁻'s conjugate base is HPO₄²⁻. H₂O/H₃O⁺ and H₂PO₄⁻/HPO₄²⁻ are thus the conjugate acid-base pair in this process.
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Part A (I2(g), Br2(g), Cl2(g), F2(g)): The ranking can best be explained by the trend entropy decreases as _.
The ranking of I2(g), Br2(g), Cl2(g), and F2(g) can best be explained by the trend that entropy decreases as the size and atomic mass of the halogen increases.
1. Entropy is a measure of the randomness or disorder of a system.
2. In general, larger molecules have higher entropy due to increased molecular complexity and a greater number of possible microstates.
3. For the given molecules (I2(g), Br2(g), Cl2(g), and F2(g)), we can determine their atomic sizes: Iodine (I) is the largest, followed by Bromine (Br), Chlorine (Cl), and Fluorine (F) is the smallest.
4. According to the trend, entropy decreases as atomic size decreases.
5. Therefore, the ranking based on entropy would be: I2(g) > Br2(g) > Cl2(g) > F2(g).
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Aluminum forms a layer of aluminum oxide when exposed to air which protects the bulk metal from further corrosion.
4Al(s) + 3O2(g) → 2Al2O3(s)
Calculate ΔG° for this reaction, given that ΔG°f of aluminum oxide is –1576.4 kJ/mol.
Calculate ΔG° for the reaction: ΔG° = -3152.8 kJ/mol.
The standard free energy change for the reaction of aluminum with oxygen to form aluminum oxide is -3152.8 kJ/mol.
The equation for the formation of aluminum oxide from aluminum is:
4Al(s) + 3O2(g) → 2Al2O3(s)
The standard free energy change for this reaction, ΔG°, can be calculated using the following equation:
ΔG° = ΣΔG°f(products) - ΣΔG°f(reactants)
where ΔG°f is the standard free energy of formation for each compound.
Using the given value of ΔG°f for aluminum oxide (-1576.4 kJ/mol), we can calculate ΔG° for the reaction:
ΔG° = (2 mol × -1576.4 kJ/mol) - (4 mol × 0 kJ/mol + 3 mol × 0 kJ/mol)
ΔG° = -3152.8 kJ/mol
Therefore, the standard free energy change for the reaction of aluminum with oxygen to form aluminum oxide is -3152.8 kJ/mol. This negative value indicates that the reaction is spontaneous under standard conditions (25°C, 1 atm pressure, 1 M concentration). The formation of a layer of aluminum oxide on the surface of the metal is a key factor in protecting it from further corrosion, as the oxide layer acts as a barrier to prevent further reaction with the surrounding environment. Content loaded aluminum forms can be used in construction for their durability and resistance to corrosion, thanks to this protective oxide layer.
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how many grams of nh3 will dissolve in 0.10 l of solution when its partial pressure is 7.6 torr
The pressure applied by a (defined) component in a gas mixture is known as partial pressure. The equilibrium pressure of NH3 is 0.00224 atm and the dissolution of ammonia (NH3) gas in water does not obey Henry's law.
To calculate how many grams of NH3 will dissolve in 0.10 L of the solution when its partial pressure is 7.6 torr, we need to use Henry's law equation: p = kH * [NH3], where p is the partial pressure of NH3, kH is Henry's law constant for NH3, and [NH3] is the molar concentration of NH3 in the solution.
Rearranging the equation, we get: [NH3] = p / kH
We can find the value of kH for NH3 in water at 25°C from a reference table or a textbook. Let's assume it is 0.90 M/atm.
Now, we need to convert the partial pressure of NH3 from torr to atm:
7.6 torr = 7.6 / 760 atm = 0.01 atm
Substituting the values into the equation, we get:
[NH3] = 0.01 atm / 0.90 M/atm = 0.011 M
This means that there are 0.011 moles of NH3 in 0.10 L of solution.
To convert moles to grams, we need to multiply by the molar mass of NH3, which is 17.03 g/mol:
0.011 mol NH3 * 17.03 g/mol = 0.19 g NH3
Therefore, 0.19 grams of NH3 will dissolve in 0.10 L of the solution when its partial pressure is 7.6 torr.
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what is the advantage of decreasing monochromator slit width in spectroscopic techniques? what is the disadvantage?
The decision to decrease the monochromator slit width should be balanced between the desired resolution and the sensitivity of the detector.
In spectroscopic techniques, the monochromator is an important component that selects a narrow range of wavelengths from the incident light in spectroscopic techniques. By decreasing the monochromator slit width, the advantage is that the resolution of the spectrum is improved. This means that the spectrum will have more defined peaks and troughs, which can aid in identifying and characterizing the sample being studied. However, the disadvantage of decreasing the monochromator slit width is that the intensity of the light reaching the detector will decrease, which may result in a lower signal-to-noise ratio. This means that the spectrum may be more difficult to interpret or may require longer exposure times to obtain a clear signal.
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What is ΔG° for the following reaction at 25 °C? COBr2(g) ⇌ CO(g) + Br2(g) Kp = 4.11 × 104
A. -26.3 KJ
B. -11.4 KJ
C. -2.63 X104 KJ
D. -2.21 KJ
ΔG° for the reaction at 25 °C is - 26.3 KJ and the correct option is option A.
ΔG° refers to the standard Gibbs free energy change of a chemical reaction under standard conditions. It is a thermodynamic parameter that quantifies the energy difference between the reactants and products of a reaction at a specified temperature (usually 25°C or 298 K), standard pressure (typically 1 atm), and standard concentrations (usually 1 M for aqueous solutions).
ΔG° represents the maximum non-expansion work that can be obtained from a reaction, and it is a measure of the spontaneity of the reaction. A negative ΔG° value indicates that the reaction is thermodynamically favorable and will proceed in the forward direction under standard conditions, while a positive ΔG° value indicates a non-spontaneous reaction.
ΔG° = -RT ln(Kp)
Where ΔG° is the standard Gibbs free energy change, R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin (25 °C = 298 K), and Kp is the equilibrium constant.
ΔG° = -(8.314 J/mol·K) × 298 K × ln(4.11 × 10⁴)
ΔG° = -26.3 kJ
Thus, the ideal selection is option A.
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The rate constant for the gas-phase reaction H2(g) + I2(g) ⟶ 2 HI(g) has the value 4.45 × 10^–5 mol–1 dm^3 s^–1. What is the equivalent rate constant in units of molecule^–1 cm^3 s^–1?a. 7.39 × 10^–26 molecule^–1 cm^3 s^–1b. 7.39 × 10^–28 molecule^–1 cm^3 s^–1c. 7.39 × 10^–29 molecule^–1 cm^3 s^–1d. 7.39 × 10^–2 molecule^–1 cm^3 s^–1
The answer is (b) 7.39 × 10^-28 molecule^-1 cm^3 s^-1.
To convert the rate constant from units of mol^-1 dm^3 s^-1 to molecule^-1 cm^3 s^-1, we need to use the Avogadro's number (6.022 × 10^23 mol^-1).
First, we need to convert dm^3 to cm^3:
1 dm^3 = 1000 cm^3
Next, we need to convert from moles to molecules:
1 mol = 6.022 × 10^23 molecules
So, the equivalent rate constant in units of molecule^-1 cm^3 s^-1 is:
4.45 × 10^-5 mol^-1 dm^3 s^-1 x (1000 cm^3 / 1 dm^3) x (1 mol / 6.022 × 10^23 molecules)
= 7.39 × 10^-28 molecule^-1 cm^3 s^-1
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which chemical used in rocket fuel affects the thyroid gland?
Perchlorate is used in rocket fuel affects the thyroid gland.
Perchlorate, a chemical substance used in rocket fuel, fireworks, fertilisers, and other products, is one such contaminant.
Since it prevents the sodium/iodide symporter (NIS), a protein that transports iodide into the thyroid and other tissues, perchlorate is associated with thyroid disorders. Hypothyroidism, which can be brought on by decreased iodide uptake, can be extremely harmful for infants since it directly impacts how they develop in numerous ways.
Thyroxine (also known as T4), a relatively inactive prohormone, and triiodothyronine, a highly active hormone, are both produced by the thyroid gland (referred to as T3). The thyroid hormones are thyroxine and triiodothyronine taken together.
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The complete question is
Which chemical used in rocket fuel affects the thyroid gland?
A. Reproductive hormones
B. DDT
C. PCBs
D. PBDEs
E. Perchlorates
How many different elements are in the compound C6H12O6?A) 3B) 6C) 24D) All of the elements are the same.
There are three different elements present in the compound C₆H₁₂O₆. Option (A) is correct.
The molecular formula C₆H₁₂O₆ represents a carbohydrate known as glucose, a simple sugar. The elements that are present in the compound C₆H₁₂O₆ are Carbon (C), Hydrogen (H), and Oxygen (O). Glucose is a monosaccharide, i.e., a single sugar molecule that cannot be further broken down by hydrolysis.
C₆H₁₂O₆ consists of six carbon atoms, twelve hydrogen atoms, and six oxygen atoms. The carbon atoms form a six-carbon chain, which serves as the backbone of the molecule. Each carbon atom is also bonded to a hydrogen atom, except for the first and last carbons, which are each bonded to a hydroxyl group (-OH).
The hydroxyl groups of glucose make it a polar molecule, meaning it can form hydrogen bonds with other polar molecules, such as water. So, the correct option is (A) 3 different elements are present in C₆H₁₂O₆.
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Which of the following ions have an [Ar]3d5 electron configuration: Mn2+, Fe3+, and Co2+?
a) Mn2+ only
b) Fe3+ only
c) Co2+ only
d) Mn2+ and Fe3+
e) Mn2+ and Co2+
The ions with an [Ar]3d5 electron configuration are Mn2+ and Fe3+. The correct answer is d) Mn2+ and Fe3+.
We first need to find the electron configurations for their neutral atoms and then adjust for their charges.
Mn (Manganese) has an atomic number of 25, so its electron configuration is [Ar]4s2 3d5. When it loses 2 electrons (Mn2+), its configuration becomes [Ar]3d5.
Fe (Iron) has an atomic number of 26, so its electron configuration is [Ar]4s2 3d6. When it loses 3 electrons (Fe3+), its configuration becomes [Ar]3d5.
Co (Cobalt) has an atomic number of 27, so its electron configuration is [Ar]4s2 3d7. When it loses 2 electrons (Co2+), its configuration becomes [Ar]3d7.
So, the ions with an [Ar]3d5 electron configuration are Mn2+ and Fe3+.
Therefore, the correct answer is d) Mn2+ and Fe3+
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determine the volume in ml of 0.141 m koh(aq) needed to reach the equivalence (stoichiometric) point in the titration of 44.29 ml of 0.153 m c6h5oh(aq). the ka of phenol is 1.0 x 10-10.
The volume of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 mL of 0.153 M C6H5OH(aq) is 48.06 mL.
To determine the volume in ml of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 ml of 0.153 M C6H5OH(aq) with the Ka of phenol being 1.0 x 10^-10, follow these steps:
1. Write the balanced chemical equation for the reaction between phenol (C6H5OH) and potassium hydroxide (KOH):
C6H5OH + KOH → C6H5O⁻ + H2O
2. Calculate the moles of phenol (C6H5OH) using the given concentration and volume:
moles of C6H5OH = 0.153 M × 0.04429 L = 0.006777 moles
3. At the equivalence point, the moles of phenol and hydroxide ions (from KOH) will be equal. Therefore, the moles of KOH required are also 0.006777 moles.
4. Calculate the volume of 0.141 M KOH(aq) needed using the moles and concentration:
Volume (L) = moles of KOH / concentration of KOH
Volume (L) = 0.006777 moles / 0.141 M = 0.04806 L
5. Convert the volume from liters to milliliters:
Volume (mL) = 0.04806 L × 1000 mL/L = 48.06 mL
So, the volume of 0.141 M KOH(aq) needed to reach the equivalence point in the titration of 44.29 mL of 0.153 M C6H5OH(aq) is 48.06 mL.
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you start with 800 parent atoms of a particular radioactive type, which decays to give stable offspring. you wait just long enough for two half lives to pass. you should expect to have how many parent atoms remaining (on average): group of answer choices 50. 100. 200. 400. 25.
Option c. 200. The number of parent atoms remaining (on average) after two half lives is 200.
The idea of half-life in radioactive rot is utilized to decide how much time it takes for half of the parent iotas to rot into stable posterity particles. After one half-life, a big part of the parent iotas will have rotted, leaving the other half. After two half-lives, the leftover half will have rotted, leaving one-fourth of the first measure of parent particles. (All things considered).
This is on the grounds that portion of the first 800 would have rotted after the principal half-life, leaving 400, and afterward 50% of those would have rotted after the last part life, leaving 200 parent molecules.
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Given that work is force x distance, and thatthe SI unit for force is Newton (Symbol N), work will have units that equal:
N
N/M
N.m
N.m2
N/m2
The units for work are given by force multiplied by distance. Since force is measured in Newtons (N) and distance is measured in meters (m), the units for work will be N.m (Newton-meters). Therefore, the answer is N.m.
The happy to help with your question. Given that work is calculated as force x distance, and the SI unit for force is Newton N, the units for work will be Work = Force x Distance Units N.m So, the correct answer is N.m Newton meters.The SI unit of work is the joule (J). It is defined as the work done by a force of one newton through a distance of one meter. One newton is equal to 1 kilogram meter per second squared. In plain English, 1 newton of force is the force required to accelerate an object with a mass of 1 kilogram 1 meter per second per second.
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Jupiter is 7.8x108 km from the Sun. Its albedo is 0.73. Calculate the effective temperature of Jupiter assuming that the Sun is the only energy source. (note: The solar "constant" follows an inverse square law, meaning that for a distance d from the Sun it’s equal to FS(d)= 1370 W m-2 (1.5E8 km/d)2
Assuming that the Sun is the only energy source, the effective temperature of Jupiter is approximately 109.96 K.
To calculate the effective temperature of Jupiter, we will use the following formula:
Te = [(FS(d) * (1 - albedo)) / (4 * σ)]^(1/4)
where:
- Te is the effective temperature of Jupiter
- FS(d) is the solar constant at the distance d from the Sun
- albedo is the reflectivity of Jupiter
- σ is the Stefan-Boltzmann constant (5.67 × 10⁻⁸ W m⁻² K⁻⁴)
First, let's find the solar constant at Jupiter's distance:
FS(d) = 1370 W m⁻² * (1.5E8 km / 7.8 x 10⁻⁸ km)²
FS(d) = 1370 W m⁻² * (1.5E8 / 7.8E8)²
FS(d) ≈ 50.66 W m⁻²
Now, we can calculate Jupiter's effective temperature:
Te = [(50.66 * (1 - 0.73)) / (4 * 5.67 × 10⁻⁸)]^(1/4)
Te = [(50.66 * 0.27) / (4 * 5.67 × 10⁻⁸)]^(1/4)
Te ≈ 109.96 K
Therefore, the effective temperature of Jupiter, assuming the Sun is the only energy source, is approximately 109.96 K.
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what type of system uses diesel exhaust fluid and a catalyst to break nitrogen oxides into nitrogen and water?
Answer:
SELECTIVE CATALYTIC REDUCTION (SCR)
Explanation:
This catalytic system uses the DEF to break down the dangerous NOx emissions produced during combustion into nitrogen (N2) and water (H2O).
The standard entropy of vaporization of acetone is approximately 85 J/K⋅mol
at its boiling point.
(a) Estimate the standard enthalpy of vaporization a acetone at its normal boiling point of 56.2∘ C
.
(b) What is the entropy change of the surroundings when 10.0 g
of acetone, CH3COCH3, condenses at its normal boiling point?
(a) The estimated standard enthalpy of vaporization of acetone is 31.3 kJ/mol
The estimated standard enthalpy of vaporization of acetone at its normal boiling point of 56.2∘ C can be calculated using the Clausius-Clapeyron equation:
ΔHvap = -R*(Tb^2/T)*ln(P1/P2)
where R is the gas constant, Tb is the boiling point in Kelvin, T is the temperature in Kelvin, P1 is the vapor pressure at the initial temperature, and P2 is the vapor pressure at the final temperature.
Using the given standard entropy of vaporization and the boiling point of acetone, we can calculate the initial vapor pressure of acetone, which is 31.1 kPa. Substituting the values into the equation, we get:
ΔHvap = 31.3 kJ/mol
Tthe entropy change of the surroundings when t0.0 g of acetone condenses at its normal boiling point is -95.0 J/K.
(b) The entropy change of the surroundings can be calculated using the equation:
ΔSsurroundings = -ΔHvap/T
Substituting the values, we get:
ΔSsurroundings = -31.3 kJ/mol / (329.35 K)
ΔSsurroundings = -95.0 J/K
Therefore, the entropy change of the surroundings when t0.0 g of acetone condenses at its normal boiling point is -95.0 J/K.
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) Complete the reactions to form a series of equations describing the oxidation of 2 mol of glutamate to 2 mol of α‑ketoglutarate and 1 mol of urea.H2O + __________ + NAD+ ⟶ α‑ketoglutarate + NH4+ + NADH + H+NH4+ + 2 ATP + H2O + CO2 ⟶ __________ + 2 ADP + Pi + 3H+Carbamoyl phosphate + _________ ⟶ citrulline + Pi + H+Citrulline + aspartate + ATP ⟶ argininosuccinate + AMP + PPi + H+Argininosuccinate ⟶ ________ + fumarateFumarate + H2O ⟶ malateMalate + NAD + ⟶ oxaloacetate + NADH + H+Oxaloacetate + glutamate ⟶ aspartate + _________Arginine + H2O ⟶ _________ + ornithine
Here are the completed reactions for the oxidation of 2 mol of glutamate to 2 mol of α‑ketoglutarate and 1 mol of urea, with the missing terms filled in:
1. H2O + glutamate dehydrogenase + NAD+ ⟶ α‑ketoglutarate + NH4+ + NADH + H+
2. NH4+ + 2 ATP + H2O + CO2 ⟶ carbamoyl phosphate + 2 ADP + Pi + 3H+
3. Carbamoyl phosphate + ornithine ⟶ citrulline + Pi + H+
4. Citrulline + aspartate + ATP ⟶ argininosuccinate + AMP + PPi + H+
5. Argininosuccinate ⟶ arginine + fumarate
6. Fumarate + H2O ⟶ malate
7. Malate + NAD + ⟶ oxaloacetate + NADH + H+
8. Oxaloacetate + glutamate ⟶ aspartate + α-ketoglutarate
9. Arginine + H2O ⟶ urea + ornithine
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(a) What sign for ∆ S do you expect when the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm? (b) If the final pressure on the gas is 1.20 atm, calculate the entropy change for the process. (c) Do you need to specify the temperature to calcu-late the entropy change? Explain.
(a) When the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 0.750 atm, we expect a negative sign for ∆S. This is because increasing pressure causes the molecules to become more ordered, which results in a decrease in entropy.
(b) To calculate the entropy change for the process, we can use the formula:
∆S = nR ln(Vf/Vi)
where n is the number of moles of gas, R is the gas constant, and Vf and Vi are the final and initial volumes of the gas, respectively.
Since the process is isothermal, we can use the ideal gas law to relate pressure and volume:
PV = nRT
Solving for V, we get:
V = nRT/P
Using this expression for V in the entropy formula, we get:
∆S = nR ln(Pi/Pf)
Substituting the given values, we get:
∆S = (0.600 mol)(8.314 J/mol K) ln(0.750 atm/1.20 atm) = -5.6 J/K
Therefore, the entropy change for the process is -5.6 J/K.
(c) No, we do not need to specify the temperature to calculate the entropy change. This is because the process is isothermal, which means that the temperature remains constant throughout. The entropy change only depends on the initial and final pressures of the gas.
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PLEASE HELP
How many milligrams are there in 6.43x10^-20 centimeter of gaseous iron ii phosphate
From the calculation, we can see that the mass of the gas in milligrams is 1 * 10^-18 mg.
What is the molar volume of a gas?The molar volume of a gas is the volume that one mole of the gas occupies at a specific temperature and pressure. It can be calculated by dividing the molar mass of the gas by its density at the given temperature and pressure.
If 1 mole of the gas would occupy 22400 cm^3
x moles of the gas would occupy 6.43x10^-20 cm^3
x = 2.9 * 10^-24 moles
Now the mass is;
2.9 * 10^-24 moles = x/357 g/mol
x = 1 * 10^-21 g or 1 * 10^-18 mg
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An infant dose of acetaminophen (C8H9NO2) is 0.080 g. How many moles of acetaminophen are in each infant dose?
There are approximately 0.00053 moles of acetaminophen in each infant dose.
To calculate the moles of acetaminophen (C8H9NO2) in each infant dose, you'll need to use the formula:
moles = mass (g) / molar mass (g/mol)
First, determine the molar mass of acetaminophen:
C: 8 atoms × 12.01 g/mol = 96.08 g/mol
H: 9 atoms × 1.01 g/mol = 9.09 g/mol
N: 1 atom × 14.01 g/mol = 14.01 g/mol
O: 2 atoms × 16.00 g/mol = 32.00 g/mol
Total molar mass = 96.08 + 9.09 + 14.01 + 32.00 = 151.18 g/mol
Now, divide the mass of the infant dose (0.080 g) by the molar mass (151.18 g/mol):
moles = 0.080 g / 151.18 g/mol ≈ 0.00053 moles
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Consider the following equilibrium:2H2(g) + S2(g) <=> 2H2S(g) Kc=1.08 x 10^7 at 700oCa) Calculate Kpb) Does the equilibrium mixture containmostly H2 and S2 or mostlyH2S?
The equilibrium mixture contains mostly H2S, as the reaction strongly favors the formation of H2S.
a) To calculate Kp, we need to use the equation Kp = Kc(RT)Δn, where Δn is the change in the number of moles of gas between the products and reactants. In this case, Δn = (2 + 1) - (2) = 1 (since there are 2 moles of H2 and 1 mole of S2 on the left side, and 2 moles of H2S on the right side). We also need to convert the temperature from Celsius to Kelvin by adding 273.15: T = 700 + 273.15 = 973.15 K. Finally, we need to use the value of R in the correct units: R = 0.08206 L·atm/K·mol. Putting it all together, we get:
Kp = Kc(RT)Δn
Kp = (1.08 x 10^7)(0.08206 L·atm/K·mol)(973.15 K)^1
Kp = 9.10 x 10^5 atm
b) To determine which gases are present in the equilibrium mixture, we can compare the reaction quotient Qc (which is the same as Kc when the system is at equilibrium) to Kc. If Qc < Kc, then the forward reaction (to form H2S) is favored, and the mixture will contain mostly H2S. If Qc > Kc, then the reverse reaction (to form H2 and S2) is favored, and the mixture will contain mostly H2 and S2.
Let's assume that we start with equal initial concentrations of H2 and S2 (we don't know the actual concentrations, but this is a reasonable assumption to make). Then, at equilibrium, we have:
Kc = [H2S]^2 / ([H2]^2 [S2])
Kc = (2x)^2 / (x^2 x)
Kc = 4 / x
where x is the equilibrium concentration of either H2 or S2 (since they are equal initially). We can rearrange this equation to solve for x:
x = sqrt(4/Kc) = 6.14 x 10^-4 M
Now we can calculate Qc using this value of x:
Qc = [H2S]^2 / ([H2]^2 [S2])
Qc = (2x)^2 / (x^2 x)
Qc = 4 / x
Qc = 6.51 x 10^6
Since Qc > Kc, the reverse reaction is favored, and the equilibrium mixture will contain mostly H2 and S2.
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Sulfur is a component of proteins and vitamin B1B1. Sulfur has four naturally occurring isotopes: 5-325-32, S-33S-33, S-345-34, and s-365-36. Which of these isotopes is most likely in greatest abundance given sulfur's atomic mass of 32.07 amu?
A. S-32
B. S-34
C. S-36
D. 5-33
Given that sulfur's atomic mass is 32.07 amu, the isotope most likely in greatest abundance is S-32 option (A). What is an isotope? An isotope is a separate nuclear species of the same given element, having the same atomic number and occupying the same position on the Periodic table, but differing in nucleon number due to change in number of neutrons.
Stable isotopes of the element are non-radioactive and do not decay. These isotopes are stable as their proton to neutron ratio is high. The atomic number of sulfur is 16, implying that there are 16 protons. For each of the options, the number of neutrons would be: (Atomic mass- atomic number):
A. 32-16=16
B. 34-16= 18
C. 36-16= 20
D. 33-16= 17
The proton to neutron ratio is lowest for S-32, which is 1. This makes it the most stable isotope, and hence the most abundant in nature.
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25.0 ml of a 0.100 m solution of nh3 is titrated with 0.150 m hcl. after 10.0 ml of the hcl has been added, the resultant solution is: a) basic and before the equivalence point. b) basic and after the equivalence point. c) acidic and before the equivalence point. d) acidic and after the equivalence point. e) neutral and at the equivalence point
When 25.0 ml of a 0.100 m solution of nh3 is a titration with 0.150 m HCL After 10.0 ml of the HCL has been added, the resultant solution is basic and before the equivalence point.
At the start of the titration, we have a solution of NH3, which is a weak base, and we add HCl, which is a strong acid. As we add HCl, it reacts with NH3 to form NH4Cl, which is a salt.
The balanced equation for the reaction is: NH3 + HCl → NH4Cl
We can see that for every mole of HCl added, one mole of NH3 is consumed. Therefore, at the equivalence point, all the NH3 will be consumed and the solution will contain only NH4Cl, which is a neutral salt.
Since only 10.0 ml of the 0.150 M HCl has been added to 25.0 ml of 0.100 M NH3, the solution is still before the equivalence point. The pH of the solution will be basic because NH3 is a weak base and has not been completely neutralized by the HCl.
Therefore, the correct answer is (a) basic and before the equivalence point.
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Determine the relative acidity of two species, and explain why they're ranked that way. Choose one: O Compounds A and B are equally acidio O Compound B is mc tre sci ld than compound O Compound A is more acidic than compound B
Compound B is more acidic than Compound A because it is stated that "Compound B is more acidic than Compound A".
The relative acidity of Compound A and Compound B can be determined by comparing their ability to donate a proton (H+ ion). The compound that can donate a proton more easily is more acidic. In this case, it can be assumed that both compounds are organic acids.
If Compound A has a stronger electron-withdrawing group than Compound B, it will be more acidic because the electron-withdrawing group makes the proton more easily removable. Therefore, if Compound A has a higher electronegativity or more electron-withdrawing groups than Compound B, it will be more acidic.
Without knowing the structures of the two compounds, it is difficult to make a definite determination. However, based on the information given, we can conclude that Compound B is more acidic than Compound A because it is stated that "Compound B is more acidic than Compound A".
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Why is it necessary to shield yourself from gamma radiation and beta and alpha particles, but not from radiowaves or microwaves? O a. Radiowaves and microwaves do not have much penetrating power. O b. Radiowaves and microwaves are lower in energy, so they are not ionizing. c. Radiowaves and microwaves are higher in energy, so they pass through the body without adverse effect. d. Radiowaves and microwaves are not electromagnetic radiation. e. Gamma radiation and beta and alpha particles are not ionizing,
It is necessary to shield yourself from gamma radiation and beta and alpha particles, but not from radiowaves or microwaves because Radiowaves and microwaves do not have much penetrating power. Hence option a is correct.
Gamma rays have such a strong penetrating force that stopping them may need several inches of a thick substance, like lead, or perhaps a few feet of concrete. The human body can be totally penetrated by gamma rays, which can then generate ionizations that harm DNA and tissue.
It needs solid materials like lead or concrete to absorb their energy and halt -rays since they are harder to stop than - or -particles.
A sheet of paper can stop alpha particles. Approximately one centimeter of plastic is used to prevent beta particles. The outer layers of skin cells and clothing offer some defense against beta particles outside the body.
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what is the energy (in kj) of a mole of photons with λ = 720 nm?
Answer:
The energy of a mole of photons with λ = 720 nm is 2.765 x 10^-22 kJ/mol.
Explanation:
To calculate the energy of a mole of photons with λ = 720 nm, we first need to convert the wavelength to meters.
720 nm = 720 x 10^-9 meters
We can then use the equation:
E = hc/λ
where h is Planck's constant (6.626 x 10^-34 J s), c is the speed of light (2.998 x 10^8 m/s), and λ is the wavelength in meters.
Plugging in the values, we get:
E = (6.626 x 10^-34 J s) x (2.998 x 10^8 m/s) / (720 x 10^-9 m)
E = 2.765 x 10^-19 J
To convert joules to kilojoules, we divide by 1000:
E = 2.765 x 10^-19 J / 1000
E = 2.765 x 10^-22 kJ
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