why is the splitting between the energy levels greater for higher lying energy levels than for lower lying energy levels

Answers

Answer 1

Answer:

The splitting between energy levels is greater for higher lying energy levels than for lower lying energy levels because of the Coulomb force, which is the force of attraction or repulsion between charged particles.

In an atom, the positively charged nucleus exerts an attractive force on the negatively charged electrons, holding them in orbit around the nucleus. However, the electrons also repel each other due to their negative charges. The net result is that the energy levels of the electrons in an atom are determined by a balance between the attractive and repulsive forces acting on them.

The Coulomb force is proportional to the product of the charges of the interacting particles and inversely proportional to the square of the distance between them. As the distance between the nucleus and the electron increases, the Coulomb force becomes weaker, resulting in smaller energy differences between adjacent energy levels. Conversely, as the distance between the nucleus and the electron decreases, the Coulomb force becomes stronger, resulting in larger energy differences between adjacent energy levels.

Since higher lying energy levels are farther away from the nucleus than lower lying energy levels, the Coulomb force is weaker for the higher energy levels, resulting in larger energy differences between adjacent energy levels. This is why the splitting between energy levels is greater for higher lying energy levels than for lower lying energy levels.


Related Questions

Perform each conversion.
a) 588 cal to joules
b) 17.4 J to Calories
c) 134 kJ to Calories
d) 56.2 Cal to joules

Answers

One calorie (cal) is equivalent to 4.184 joules (J). This means that to convert calories to joules, you need to multiply the number of calories by 4.184. Conversely, to convert joules to calories, you would divide the number of joules by 4.184.

a) To convert 588 calories to joules, we use the conversion factor: 1 calorie = 4.184 joules.

588 cal x (4.184 J/cal) = 2458.112 J

Therefore, 588 calories is equal to 2458.112 joules.

b) To convert 17.4 joules to calories, we use the conversion factor: 1 calorie = 4.184 joules.

17.4 J ÷ 4.184 J/cal = 4.16 cal

Therefore, 17.4 joules is equal to 4.16 calories.

c) To convert 134 kilojoules to calories, we use the conversion factor: 1 calorie = 4.184 joules, and 1 kilojoule = 1000 joules.

134 kJ x (1000 J/kJ) x (1 cal/4.184 J) = 32026.69 cal

Therefore, 134 kilojoules is equal to 32026.69 calories.

d) To convert 56.2 Calories to joules, we use the conversion factor: 1 Calorie = 1000 calories, and 1 calorie = 4.184 joules.

56.2 Cal x (1000 cal/1 Cal) x (4.184 J/cal) = 235269.728 J

Therefore, 56.2 Calories is equal to 235269.728 joules.

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which of the following best helps to explain why the electron affinity for p pp is less favorable compared to the electron affinity for s i sis, i?

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The electron affinity for P is less favorable compared to the electron affinity for S because of there is a greater attraction between an added electron and the nucleus in P than in S, option A.

At the point when one electron is added to an impartial molecule to make an adversely charged particle, a specific measure of energy is delivered. In chemistry, this is referred to as electron affinity. Because it is difficult to measure the affinities of electrons in an atom, only a small number of chemical elements, primarily the halogens, have values.

These numbers came from measurements of the lattice energies and formation energies of the elemental ionic compounds. An element's ability to operate as an electron acceptor (an oxidising agent) is measured by their electron affinity, which is typically correlated with the type of chemical bonds they make with other elements.

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Complete question:

which of the following best helps to explain why the electron affinity for P is less favorable compared to the electron affinity for S?

there is a greater attraction between an added electron and the nucleus in P than in S.

there is a lesser attraction between an added electron and the nucleus in P than in S.

there is a no attraction between an added electron and the nucleus in P than in S.

there is a same attraction between an added electron and the nucleus in P than in S.

Which of the methods are the general methods of polymer production?.

Answers

The general methods of polymer production are addition polymerization, condensation polymerization, and ring-opening polymerization. Addition polymerization involves the addition of unsaturated monomers to form a polymer, while condensation polymerization involves the reaction of monomers with the elimination of a small molecule such as water or alcohol. Ring-opening polymerization involves the opening of cyclic monomers to form a linear polymer.

There are several general methods of polymer production, including:

1. Addition polymerization: In this method, monomers with unsaturated bonds react with one another to form a polymer chain. This process involves the breaking of the double bond and joining of the monomers to form a long chain polymer.

2. Condensation polymerization: This method involves the reaction between two or more different monomers, where the resulting polymer molecule is accompanied by the production of small molecules such as water, alcohol, or ammonia.

3. Emulsion polymerization: This is a process where the monomers are emulsified in water to form tiny droplets. A polymerization initiator is then added to the system, which causes the monomers to polymerize and form a latex of polymer particles.

4. Polycondensation: This is a method in which small molecules are linked together through a series of condensation reactions to form a polymer.

These methods are used to produce a wide range of polymers with varying properties and applications.

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Use Lewis structures to show the formation of BF4-

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The Lewis structure of BF4- can be shown by first determining: the number of valence electrons in each atom and then arranging them around the central atom (Boron) to satisfy the octet rule.

What is Lewis structure?

A Lewis structure is a diagram or representation of the valence electrons in an atom or molecule. It is used to show the bonding between atoms in a molecule and the arrangement of electrons in the valence shell of each atom. The valence electrons are represented by dots or lines, and the arrangement of the dots and lines represents the arrangement of the electrons in the molecule.

To determine the Lewis structure of BF4-, we first need to know the number of valence electrons of each atom. Boron has three valence electrons, while each of the four fluorine atoms has seven valence electrons. The negative charge on the ion indicates that there is an extra electron, so the total number of valence electrons is 32 (3 + 4 × 7 + 1).

Next, we place the Boron atom in the center and surround it with the four fluorine atoms, each sharing a single bond with Boron. This arrangement satisfies the octet rule for each atom (except for Boron, which has only six electrons around it), and each atom has a full outer shell of electrons.

To complete the Lewis structure, we add a negative charge to the ion, indicating that it has one extra electron. This negative charge is placed outside the brackets and is associated with the entire ion, not with any specific atom.

The resulting Lewis structure for BF4- shows that the ion has a tetrahedral shape, with the four fluorine atoms arranged around the central Boron atom.

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A) Calculate pH for this strong base solution: 7. 6x10-2 M KOH

B) calculate [OH-] for 14. 0ml of 1. 10 ×10^-2 m Ca(oh)2 diluted to 580. 0ml

C) calculate [OH-] for solution formed by mixing 15ml of 1. 50×10^-2m Ba(oh)2 with 36. 0 ml of 7. 6×10^-3m NaOH​

Answers

A) Because KOH is a strong base, it totally dissociates in water to create K+ and OH- ions. As a result, the concentration of OH- in solution equals the concentration of KOH. The solution's pOH can be computed as follows:

[tex]1.12 pOH = -log[OH-] = -log(7.6x10-2)[/tex]

Because pH + pOH = 14, the solution's pH is:

pH = 14 - pOH = 14 - 1.12 = 12.88

B) Calcium hydroxide ([tex]Ca(OH)_{2}[/tex]) is a strong base that totally dissociates in water to generate [tex]Ca_{2}[/tex]+ and 2OH- ions. The OH- concentration in the diluted solution is calculated as follows:

[tex]Ca(OH)_{2}[/tex] moles = concentration x volume = 1.10x[tex]10-^{2}[/tex] x 14.0x[tex]10-^{3}[/tex] = 1.54x[tex]10-^{4}[/tex] mol

Because [tex]Ca(OH)_{2}[/tex] dissociates into two moles of OH- for every mole of Ca(OH), the total number of moles of OH- in the solution is 2 x 1.54x[tex]10-^{4}[/tex] = 3.08x[tex]10-^{4}[/tex] mol.

After dilution, the total volume of the solution is 580.0 + 14.0 = 594.0 mL. As a result, the OH- concentration in the diluted solution is:

[OH-] = 3.08 x [tex]10-^{4}[/tex] mol/0.594 L = 5.19 x [tex]10-^{4}[/tex] M

C) To compute the concentration of hydroxide ions in the mixed solution, we must first know the moles of hydroxide ions present.

This is accomplished by calculating the moles of hydroxide ions contributed by each separate solution and then adding them all together.

In the case of :

OH- ion moles = concentration volume = 1.50[tex]10-^{2}[/tex] mol/L 0.015 L = 2.25 [tex]10-^{4}[/tex] mol

In the case of NaOH:

OH- ion moles = concentration volume = 7.6 [tex]10-^{3}[/tex] mol/L 0.036 L = 2.736 [tex]10-^{4}[/tex] mol

Total OH- ion moles = 2.25 [tex]10-^{4}[/tex] mol + 2.736 [tex]10-^{4}[/tex] mol = 4.986 [tex]10-^{4}[/tex] mol

The concentration of hydroxide ions in the mixed solution can now be calculated:

15 mL + 36 mL = 51 mL = 0.051 L total volume of the combined solution

[OH-] = moles of OH- ions divided by total volume of mixed solution

(4.986 10-4 mol) / (0.051 L) = 9.77 10-3 M [OH-]

As a result, the hydroxide ion concentration in the mixed solution is

9.77 × 10-3 M.

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Gravity Filtration
1) which labs its done
2) its use
3) definition
4) process

Answers

Gravity filtration is many times utilized in substance labs to channel encourages from precipitation responses as well as drying specialists, unacceptable side things, or remaining reactants.

Although vacuum filtration is more commonly used for this purpose, it can also be used to separate strong products.

Process :

Gravity filtration is the process of passing a mixture of solid and liquid through a filter paper-lined funnel, allowing the liquid to pass through while keeping the solid on the paper .

Gravity filtration uses :

Gravity filtration is the technique for decision to eliminate strong pollutions from a natural fluid. A drying agent, undesirable side product, or leftover reactant are all examples of impurities. Although vacuum filtration is typically used for this purpose due to its speed, gravity filtration can be used to collect solid products.

Definition Gravity filtration  :

Gravity filtration is a method of filtering impurities from solutions by using gravity to pull liquid through a filter. The two main kinds of filtration used in laboratories are gravity and vacuum/suction.

Incomplete question :

Explain the following about Gravity Filtration :

1) which labs its done

2) its use

3) definition

4) process

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nh4n03 na3p04 (nh4)3p04 nan03 which reactant is limiting, assuming we started with 30.0 grams of ammonium nitrate and 50.0 grams of sodium phosphate? what is the mass of each product that can be formed? what mass of the excess reactant(s) is left over?

Answers

The mass of each product that can be formed is; Na₃PO₄; 61.48 g, and NH₄H₂PO₄; 43.14 g, the mass of the excess reactant(s) left over is; Na₃PO₄; 0 g, and NH₄NO₃; 0 g.

Balanced chemical equation for the reaction between ammonium nitrate and sodium phosphate is;

(NH₄)₂SO₄ + 2NaNO₃ → Na₃PO₄ + 2NH₄NO₃

To determine the limiting reactant, we need to first calculate the number of moles of each reactant.

Molar mass of NH₄NO₃ = 80.04 g/mol

Number of moles of NH₄NO₃ in 30.0 g = 30.0 g / 80.04 g/mol = 0.375 mol

Molar mass of Na₃PO₄ = 163.94 g/mol

Number of moles of Na₃PO₄ in 50.0 g = 50.0 g / 163.94 g/mol

= 0.305 mol

Balanced chemical equation shows that 1 mole of NH₄NO₃ reacts with 1 mole of Na₃PO₄, so NH₄NO₃ is the limiting reactant since it has fewer moles than Na₃PO₄.

To find the mass of each product formed, we can use the mole ratio from the balanced equation.

From the equation, 1 mole of NH₄NO₃ produces 1 mole of Na₃PO₄ and 2 moles of NH₄NO₃.

Therefore, the moles of Na₃PO₄ produced will be equal to the moles of NH₄NO₃ used up, which is 0.375 mol.

Mass of Na₃PO₄ formed = 0.375 mol × 163.94 g/mol = 61.48 g

The moles of excess Na₃PO₄ left over can be calculated as follows:

Moles of Na₃PO₄ left over = Moles of Na₃PO₄ initially - Moles of Na₃PO₄ used in reaction

= 0.305 mol - 0.375 mol

= -0.07 mol

Since the result is negative, it means that all of the Na₃PO₄ is consumed in the reaction and there is no excess left.

For NH₄NO₃, the moles left over can be calculated as;

Moles of NH₄NO₃ left over = Moles of NH₄NO₃ initially - Moles of NH₄NO₃ used in reaction

= 0.375 mol - 0.375 mol

= 0 mol

Therefore, all of the NH₄NO₃ is consumed in the reaction.

Finally, we can calculate the mass of NH₄NO₃ converted to NH₄H₂PO₄(monoammonium phosphate) using the mole ratio;

From the equation, 1 mole of NH₄NO₃ produces 1 mole of NH4H2PO4.

Therefore, the mass of NH₄H₂PO₄ formed will be equal to the mass of NH₄NO₃ used up, which is;

Mass of NH4H2PO4 formed = 0.375 mol × 115.03 g/mol

= 43.14 g

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what is the volume of total gas at stp (273.15 k and 1 atm) that is produced from the combustion of 1.00 moles of methane gas? give your answer in liters (l).

Answers

The volume of total gas at STP (273.15 k and 1 atm) that is produced from the combustion is 22.4 mL.

The amount of three-dimensional space that is occupied by matter (solid, liquid, or gas) is measured by the physical quantity known as volume. It is a derived quantity that draws its foundation from the length unit. The cubic metre (m3) is the SI unit, but other volume units including litres, millilitres, ounces, and gallons are also often employed. Chemistry requires a volume definition since the discipline typically works with liquid substances, mixtures, and reactions that need for a specific amount of liquids.

Another quantity other than volume is mass. The amount of matter in an item or substance may be measured by its mass. The kilogramme (kg) is the SI unit, but lesser measurements like grammes, milligrammes, and pounds are also often employed. Usually, an electronic balance, a triple beam balance, or a normal weighing scale is used to measure it.

PV = nRT

1 x V = 1 x 0.082 x 273.15

V = 22.4 mL.

Therefore, volume of the gas is 22.4 mL.

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which statement regarding entropy is false? gasoline is burned in a car engine to form exhaust. the entropy of the gasoline increases. a layer of salt then a layer of pepper are placed in a jar then shaken. the entropy of the salt and pepper increases. a rock falls to strike the ground. the entropy of the rock and ground increases. a child builds a tower from a pile of blocks. the entropy of the blocks increases.

Answers

The statement that is false regarding entropy is "a child builds a tower from a pile of blocks. the entropy of the blocks increases." This statement is false because the process of building a tower from a pile of blocks actually decreases the entropy of the blocks.

Entropy is a measure of disorder or randomness in a system, and the pile of blocks represents a more disordered state than the organized tower. When the child builds the tower, they are creating order out of disorder, and so the entropy of the blocks is actually decreasing.

On the other hand, the other three statements are true regarding entropy. When gasoline is burned in a car engine, the entropy of the gasoline increases because the process of combustion breaks down the molecules and creates a more disordered state.

In summary, entropy is a measure of disorder or randomness in a system, and it tends to increase over time due to natural processes. The false statement is that building a tower from a pile of blocks increases the entropy of the blocks, when in fact it decreases it.

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a rigid 5.00l cylinder contains 34.5 g of n2 gas. calculate the pressure, in atm, of the gas in the cylinder at 298 k.

Answers

To calculate the pressure of the gas in the cylinder, we can use the ideal gas law:

PV = nRT

where P is the pressure, V is the volume (5.00 L in this case), n is the number of moles of gas (which we can calculate from the mass of N2 given), R is the gas constant, and T is the temperature in Kelvin (298 K in this case).

First, we need to calculate the number of moles of N2 gas present in the cylinder. To do this, we can use the molar mass of N2:

N2: 2(14.0067 g/mol) = 28.0134 g/mol

So, the number of moles of N2 gas present is:

n = m/M = 34.5 g / 28.0134 g/mol = 1.2329 mol

Now, we can substitute the values into the ideal gas law:

P(5.00 L) = (1.2329 mol)(0.0821 L·atm/mol·K)(298 K)

Simplifying and solving for P, we get:

P = (1.2329 mol)(0.0821 L·atm/mol·K)(298 K) / (5.00 L)
P = 3.28 atm

Therefore, the pressure of the N2 gas in the cylinder at 298 K is 3.28 atm.
To calculate the pressure of the N2 gas in the rigid cylinder, we can use the Ideal Gas Law: PV = nRT.

Given:
Volume (V) = 5.00 L
Mass of N2 gas (m) = 34.5 g
Temperature (T) = 298 K
R (Ideal Gas Constant) = 0.0821 L atm / (mol K)

First, we need to convert the mass of N2 gas to moles (n):
Molar mass of N2 = 28.02 g/mol
n = m / Molar mass
n = 34.5 g / 28.02 g/mol
n ≈ 1.23 mol

Now, we can use the Ideal Gas Law to calculate the pressure (P):
PV = nRT
P = nRT / V
P = (1.23 mol) × (0.0821 L atm / (mol K)) × (298 K) / (5.00 L)

P ≈ 6.08 atm

So, the pressure of the N2 gas in the rigid 5.00 L cylinder at 298 K is approximately 6.08 atm.

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The pressure of the gas in the cylinder at 298 K is 7.19 atm.

To calculate the pressure of the gas in the cylinder, we need to use the Ideal Gas Law, which relates the pressure (P), volume (V), number of moles (n), and temperature (T) of a gas:

PV = nRT

Where R is the universal gas constant (0.08206 L⋅atm/mol⋅K).

We are given the volume of the cylinder (V=5.00 L), the mass of the gas (m=34.5 g), and the temperature (T=298 K). To calculate the number of moles of gas (n), we need to use the molar mass of nitrogen (N2), which is 28.02 g/mol:

n = m/M = 34.5 g / 28.02 g/mol = 1.231 mol

Now we can substitute the values into the Ideal Gas Law:

PV = nRT

P = nRT/V

P = (1.231 mol) x (0.08206 L⋅atm/mol⋅K) x (298 K) / (5.00 L)

P = 7.19 atm

It's worth noting that this calculation assumes that the gas behaves ideally, meaning that the gas molecules are point particles that do not interact with each other and that there are no intermolecular forces. In reality, gases can deviate from ideal behavior under certain conditions, but for most practical purposes, the ideal gas law provides a good approximation.

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Which element will react with sulfuric acid to produce hydrogen gas?Zincsulfurphosphoruscarbon

Answers

Zinc will react with sulfuric acid to produce hydrogen gas. When zinc is added to sulfuric acid, it undergoes a displacement reaction. The zinc replaces the hydrogen ion in the sulfuric acid and forms zinc sulfate as the product. As a result of this reaction, hydrogen gas is produced.

This reaction can be represented by the following chemical equation:
Zn + H2SO4 → ZnSO4 + H2
It is important to note that sulfuric acid is a strong acid and should be handled with care. Zinc, on the other hand, is a relatively safe metal to handle. When performing this reaction, it is important to wear appropriate protective equipment and to conduct the experiment in a well-ventilated area. Additionally, it is important to ensure that the zinc used is pure and free from any impurities that may affect the reaction. Overall, the reaction between zinc and sulfuric acid is a common laboratory experiment and is often used to demonstrate chemical reactions and gas production.

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when 70.0 ml of 3.00 m na2co3 is added to 30.0 ml of 1.00 m nahco3, the resultingconcentration of na is:

Answers

According to the question the resulting concentration of Na is 0.240 M

What is water?

Water is the most abundant substance on Earth and the most essential for all living things. Water is a tasteless, odorless, transparent liquid that is essential for all forms of life. Water is composed of two molecules of hydrogen and one molecule of oxygen, and is found in oceans, lakes, rivers, and streams, as well as in the atmosphere in the form of vapor.

The reaction of Na₂CO₃ and NaHCO₃ results in the formation of Na₂CO₃, water and CO₂.

Moles of Na in Na₂CO₃ = (70.0 mL x 3.00 M) / 1000 mL

                                       = 0.210 mol

Moles of Na in Na₂CO₃ = (30.0 mL x 1.00 M) / 1000 mL

                                       = 0.030 mol

Total moles of Na = 0.210 mol + 0.030 mol  

                              = 0.240 mol

Total volume of solution = 70.0 mL + 30.0 mL

                                         = 100.0 mL

Concentration of Na = (0.240 mol) / (100.0 mL)

                                  = 0.240 M

Therefore, the resulting concentration of Na is 0.240 M

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Hydration of an alkyne, C6H10. gave two ketones in approximately equal amounts. Which of the following alkynes would be expected to give these results? Multiple Choice a. 3-hexyne b. 1-hexynec. 2-hexyned. 3,3-dimethyl-1-butyne

Answers

The correct answer is option c. 2-Hexyne which is explained in the below section.

Alkynes are immiscible in water. They do now no longer react with water beneathneath regular conditions. Alkynes can also additionally react with water withinside the presence of dilute sulphuric acid and mercuric sulphate at a temperature of 333K. This effects withinside the formation of carbonyl compounds. This effects withinside the formation of carbonyl compounds. The addition of water to a triple bond, like the corresponding addition to a double bond, is called hydration. The hydration of alkynes gives ketones

 

Thus, the correct option is c.

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How many bonding electrons are in the lewis structure of n2?.

Answers

The Lewis structure of N2 shows a triple bond between the two nitrogen atoms. A triple bond consists of one sigma bond and two pi bonds. Each bond is formed by the sharing of two electrons. Therefore, in the Lewis structure of N2, there are a total of 6 bonding electrons.

To determine the number of bonding electrons in the Lewis structure of N2, follow these steps:

1. Identify the elements in the molecule: N2 consists of two nitrogen atoms (N).
2. Calculate the total number of valence electrons: Nitrogen has 5 valence electrons, and since there are two nitrogen atoms, the total valence electrons are 5 x 2 = 10.
3. Create the Lewis structure: Place the two nitrogen atoms next to each other and distribute the valence electrons as bonding and non-bonding pairs. To form a stable molecule, each nitrogen atom needs to have a complete octet (8 electrons).

The Lewis structure of N2 is:

    N ≡ N

In this structure, there is a triple bond between the two nitrogen atoms, which means there are 3 bonding pairs of electrons. Since each bonding pair consists of 2 electrons, the total number of bonding electrons in the Lewis structure of N2 is 3 x 2 = 6.

Your answer: There are 6 bonding electrons in the Lewis structure of N2.

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Copper-64 is used in the form of copper acetate to study brain tumors. it has a half-life of 12.8 h. if you begin with 15.0 mg of 64 cu-labeled copper acetate, what mass remains after 64 hour?

Answers

After 64 hours, approximately 0.47 mg of Copper-64 labeled copper acetate remains.

To solve this problem, we need to use the concept of half-life, which is the amount of time it takes for half of the radioactive substance to decay.
First, we need to determine how many half-lives have passed in 64 hours. Since the half-life of Copper-64 is 12.8 hours, we can divide 64 by 12.8 to get 5.
This means that after 64 hours, Copper-64 has undergone 5 half-lives.
To determine the amount of Copper-64 that remains, we can use the following equation:
Final mass = initial mass x (1/2)^(number of half-lives)
Plugging in the given values, we get:
Final mass = 15.0 mg x (1/2)^5
Final mass = 15.0 mg x 0.03125
Final mass = 0.46875 mg = 0.47 mg

Therefore, after 64 hours, only 0.47 mg of Copper-64 labeled copper acetate remains.

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If 0. 40 mol of h2 and 0. 15 mol of o2 were to react as completely as possible to produce h2o, what mass of reactant would remain?.

Answers

Assuming that the reaction proceeds completely, all of the hydrogen and oxygen reactants will be used up to produce water. Therefore, no reactants will remain.


The balanced chemical equation for the reaction between hydrogen and oxygen to produce water is:

2H2 + O2 → 2H2O

This equation tells us that 2 moles of hydrogen react with 1 mole of oxygen to produce 2 moles of water. Therefore, if we have 0.40 moles of hydrogen and 0.15 moles of oxygen, the limiting reactant is oxygen since it is present in lesser amount.

To calculate the amount of water produced, we can use the stoichiometry of the balanced equation. Since 1 mole of oxygen reacts with 2 moles of hydrogen to produce 2 moles of water, we need to double the amount of moles of oxygen to get the amount of moles of water produced.

Moles of water produced = 2 x 0.15 mol = 0.30 mol

This means that all of the hydrogen and oxygen reactants will be used up to produce 0.30 moles of water.

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"A 100.0 mL sample of 0.10 M NH 3 is titrated with 0.10 M HNO 3. Determine the pH of the solution after the addition of 50.0 mL of HNO 3. The K b of NH 3 is 1.8 × 10^ -5.
7.05
9.26
7.78
10.34
4.74"

Answers

pH of a 0.10 M NH3 solution after the addition of 50.0 mL of 0.10 M HNO3 is 9.26.

What is the pH of a 0.10 M NH3 solution after the addition of 50.0 mL of 0.10 M HNO3?

The balanced chemical equation for the reaction of NH3 and HNO3 is as follows:

NH3 + HNO3 → NH4+ + NO3-

Before any HNO3 is added, the solution contains NH3 and its conjugate acid, NH4+. NH3 is a weak base and reacts with water to produce OH- ions. The equilibrium expression:

NH3 + H2O ⇌ NH4+ + OH-

The K b expression for NH3 is:

Kb = [NH4+][OH-] / [NH3]

At the beginning of the titration, the concentration of NH3 is 0.10 M and the concentration of OH- is x (unknown). The concentration of NH4+ is also x because they are both produced in a 1:1 ratio.

Kb = [x][x] / [0.10 - x]

Since the volume of the solution does not change during the titration, we can use the following expression to relate the initial moles of NH3 to the moles of NH3 remaining after the addition of HNO3:

moles NH3 = 0.10 mol/L × 0.100 L = 0.010 mol

At the equivalence point, all of the NH3 has reacted with HNO3 to form NH4+ ions. Therefore, the number of moles of HNO3 added to reach the equivalence point is also 0.010 mol.

Before the equivalence point, the reaction between NH3 and HNO3 consumes one mole of NH3 for every mole of HNO3 added. Therefore, after adding 50.0 mL of 0.10 M HNO3 (which contains 0.0050 mol of HNO3), the number of moles of NH3 remaining is:

0.010 mol - 0.0050 mol = 0.0050 mol

The volume of the solution after adding 50.0 mL of HNO3 is:

V = 100.0 mL + 50.0 mL = 0.150 L

The concentration of NH3 at this point is:

[ NH3 ] = (0.0050 mol) / (0.150 L) = 0.033 M

The concentration of NH4+ is also 0.033 M because they are produced in a 1:1 ratio with NH3.

To calculate the concentration of OH- ions, we can use the Kb expression and solve for [OH-]:

Kb = [NH4+][OH-] / [NH3]

1.8 × 10^-5 = (0.033 M)(x) / (0.033 M)

x = 1.8 × 10^-5

Therefore, the concentration of OH- ions is 1.8 × 10^-5 M.

The pH of the solution can be calculated from the concentration of OH- using the expression:

pH = 14 - pOH

pOH = -log[OH-] = -log(1.8 × 10^-5) = 4.74

pH = 14 - 4.74 = 9.26

Therefore, the pH of the solution after the addition of 50.0 mL of HNO3 is 9.26. The correct answer is B.

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What is the molar solubility of Ba(IO3)2 in a solution of 0.01 M Ba(NO3)2? (A) 3.0 x 10-5. (B) 8.4 x 10-4. (C) 5.3 x 10-4. (D) 1.2 x 10-4. (E) 6.0 x 10-6.

Answers

Therefore, the molar solubility of Ba(IO3)2 in a solution of 0.01 M Ba(NO3)2 is 5.3 x 10^-4.

To solve this problem, we need to consider the common ion effect, where the presence of Ba2+ from Ba(NO3)2 will decrease the solubility of Ba(IO3)2.

The balanced equation for the dissolution of Ba(IO3)2 in water is:

Ba(IO3)2(s) ↔ Ba2+(aq) + 2IO3-(aq)

Let x be the molar solubility of Ba(IO3)2 in the presence of 0.01 M Ba(NO3)2. Then the concentration of Ba2+ in solution is 0.01 + x, and the concentration of IO3- ions is 2x.

The solubility product expression for Ba(IO3)2 is:

Ksp = [Ba2+][IO3-]2 = x(2x)2 = 4x3

The common ion effect tells us that the solubility of Ba(IO3)2 will be reduced by the presence of Ba2+ from Ba(NO3)2. Therefore, we can write:

(0.01 + x)(2x)2 = 4x3

Simplifying and solving for x:

0.04x3 + 0.04x2 - 0.0008x = 0

x(0.04x2 + 0.04x - 0.0008) = 0

x = 0 (extraneous) or x = 5.3 x 10^-4

Therefore, the molar solubility of Ba(IO3)2 in a solution of 0.01 M Ba(NO3)2 is 5.3 x 10^-4. The answer is (C).

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Give the expression for the solubility product constant for BaF 2.

[Ba2+]2[ F]

[Ba2+][2F]

[Ba2+][F]2

Answers

The solubility product constant for BaF₂ is the product of the concentrations of the ions in the saturated solution, raised to the power of their respective stoichiometric coefficients. Thus, for BaF₂, the expression for the solubility product constant is: [Ba²⁺]2[F]2.

What is stoichiometric?

Stoichiometry is the study of the quantitative relationships between the reactants and products of a chemical reaction. It is a branch of chemistry that deals with the relative proportions of elements and compounds involved in a particular chemical reaction. Stoichiometry enables chemists to determine the amount of each reactant that is needed to produce a given amount of product. It also allows chemists to predict the amount of product that will be produced by a given reaction. Stoichiometry is an essential tool in chemistry, allowing chemists to make accurate predictions about the outcome of a given reaction.

This expression illustrates that the concentration of the Ba²⁺ ions is squared, while the concentration of the F- ions is raised to the power of two.

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Which substance will not react with hydrochloric acid to form a salt?AgZnCuCO3Ca(OH)2

Answers

When an acid reacts with a base, it forms a salt and water, in a process known as neutralization.

However, not all substances can react with hydrochloric acid (HCl) to form a salt. Calcium hydroxide (Ca(OH)2) is a base that will not react with HCl to form a salt, but rather it will form calcium chloride and water. On the other hand, Ag, Zn, Cu, and CO3 are all metals and anions that can react with HCl to form their respective chlorides. Thus, the reaction between an acid and a base can vary depending on the specific substances involved, and the resulting product will be determined by their chemical properties.

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Which one of the following salts produces acidic aqueous solutions?
a. sodium chloride
b. sodium acetate
c. ammonium chloride
d. calcium nitrate
e. rubidium perchlorate

Answers

The correct answer is c. ammonium chloride. When ammonium chloride is dissolved in water, it undergoes hydrolysis, which means that it reacts with water to form acidic species.

Specifically, the ammonium ion (NH4+) reacts with water to form hydronium ions (H3O+), which are responsible for the acidic properties of the solution. The chloride ion (Cl-) has no effect on the acidity of the solution.
In contrast, sodium chloride (a) and calcium nitrate (d) are both salts that produce neutral aqueous solutions. Sodium acetate (b) is a salt that produces a basic aqueous solution due to the presence of the acetate ion (CH3COO-), which reacts with water to form hydroxide ions (OH-). Rubidium perchlorate (e) is a salt that is also neutral in aqueous solution.
It's worth noting that the acidity of a salt solution depends on the relative strengths of the conjugate acid-base pairs involved. In the case of ammonium chloride, the ammonium ion is a weak acid (pKa = 9.24), while water is a much stronger base (pKa = 15.7), so the reaction between them favors the formation of hydronium ions and leads to an acidic solution.

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Which phenomenon best shows the wave nature of electrons?.

Answers

The phenomenon of electron diffraction best shows the wave nature of electrons, as it demonstrates that electrons can exhibit diffraction patterns similar to those of waves.

When electrons are diffracted by a crystal, they form a pattern of bright spots and dark areas, which indicates that they are interfering with each other like waves. This is analogous to the diffraction pattern produced by light passing through a narrow slit or a diffraction grating.

The wave nature of electrons was first proposed by Louis de Broglie, who suggested that all matter has both particle and wave-like properties. The discovery of electron diffraction confirmed de Broglie's hypothesis and provided strong evidence for the wave-particle duality of matter.

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which of the following is detected by the methyl red (mr) test? multiple choice lactic acid acetoin 2,3 butanediol low ph

Answers

Low pH is detected by the methyl red (MR) test. The MR test is a commonly used microbiological test to determine the ability of an organism to produce and maintain stable acid end-products from glucose fermentation. Option D.

The test is performed by adding a pH indicator called methyl red to the test tube containing the bacterial culture and observing the color change of the solution. If the pH is low (acidic), the methyl red indicator turns red, indicating a positive test. On the other hand, if the pH is higher (less acidic), the methyl red indicator turns yellow, indicating a negative test. Therefore, the MR test is used to distinguish between mixed acid fermenters (positive MR test) and non-mixed acid fermenters (negative MR test) based on their ability to produce acidic end-products.

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Full Question

which of the following is detected by the methyl red (mr) test? multiple choice

lactic

acid acetoin

2,3 butanediol

low ph

Which best contrasts electric doorbells and audio speakers? Doorbells involve rapid changes in the direction of current, and speakers do not. Speakers involve rapid changes in the direction of current, and doorbells do not. Doorbells require closed circuits in order to work, and speakers do not. Speakers require closed circuits in order to work, and doorbells do not.

Answers

The best contrasts between electric doorbells and audio speakers is that speakers involve rapid changes in the direction of current, and doorbells do not.

An electric circuit is a path of flow of electric current whereby work may be done by the electric current flowing in the circuit. Electric doorbell require a closed circuit while audio speakers do not. Speakers involve rapid changes in the direction of current, and doorbells do not. When we push the button of a doorbell then the circuit completes and the current starts flowing through the circuit. The electromagnet is activated. It causes a buzzer to go off.  The hammer strikes the bars which creates sound.

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How could we increase the solubility of BaCO3 in water?
(A) add Ba(NO3)2. (B) add Na2CO3. (C) add NaOH. (D) add HCl. (E) add NaCl.

Answers

Adding an acid such as HCl (option D) would increase the solubility of BaCO3 by protonating the carbonate ion and shifting the equilibrium towards the dissolved species, Ba2+ and HCO3-.

BaCO3 is sparingly soluble in water due to its low solubility product constant. To increase its solubility, we need to shift the equilibrium towards the dissolved species. One way to achieve this is by adding an acid such as HCl, which will react with the carbonate ion, releasing CO2 and forming soluble BaCl2 and HCO3-. This reaction effectively removes CO3-2 from the equilibrium, leading to an increase in the solubility of BaCO3. The other options (A, B, C, and E) do not have the same effect on the solubility of BaCO3 in water.

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Using Werner's definition of valence, which property is the same as oxidation number, primary valence or secondary valence?

Answers

The property that is the same as oxidation number in Werner's definition of valence is the secondary valence.

Werner's definition of valence is based on the idea that metal ions have two types of valences: primary and secondary. The primary valence refers to the ion's oxidation state, while the secondary valence refers to the number of ions or molecules that can coordinate with the metal ion in a complex.

In Werner's theory, coordination complexes are formed when ligands coordinate with a central metal ion through the formation of coordinate covalent bonds. The number of ligands that can coordinate with the metal ion is determined by the secondary valence of the metal ion.

The oxidation number of the metal ion is determined by the number of electrons it has gained or lost during the formation of the complex. The secondary valence of the metal ion, on the other hand, is determined by the number of ligands it can coordinate with.

Therefore, in Werner's theory of valence, the secondary valence is equivalent to the oxidation number, as both describe the number of bonds or electrons associated with the central metal ion in a complex.

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based on the chemical reaction represented above. which of the following provides the best justification that the given conditions can be used to decrease the cell potential

Answers

Based on the reduction potentials given, the following gives the balanced chemical equation and the correct standard cell potential for a galvanic cell is 2Sc(s)+3Mn²⁺(aq)⇄2Sc³⁺(aq)+3Mn(s) E°=+0.90V, option D.

Electrons are transferred from one species to another during oxidation-reduction processes. If the reaction occurs spontaneously, energy is released. As a result, the energy that has been released is put to good use. To deal with this energy, the reaction must be divided into the two half-reactions of oxidation and reduction. The reactions are injected into them to move the electrons from one end to the other end using two separate containers and wire. Thus, a voltaic cell is produced.

The Gibbs energy of the spontaneous redox reaction in the voltaic cell is primarily responsible for the electrical work produced by a galvanic cell. A salt bridge and two half cells are often its only components. A metallic electrode submerged in an electrolyte completes each half cell. Metallic wires are used to link these two half-cells outside to a voltmeter and a switch. A salt bridge is not always necessary when both electrodes are submerged in the same electrolyte.

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Complete question:

Based on the reduction potentials given in the table above, which of the following gives the balanced chemical equation and the correct standard cell potential for a galvanic cell involving Sc3+(aq) and Mn2+(aq) ?

A

2Sc3+(aq)+3Mn(s)⇄2Sc(s)+3Mn2+(aq) E°=−0.90V

B

2Sc3+(aq)+3Mn(s)⇄2Sc(s)+3Mn2+(aq) E°=−0.62V

C

2Sc(s)+3Mn2+(aq)⇄2Sc3+(aq)+3Mn(s) E°=+0.62V

D

2Sc(s)+3Mn2+(aq)⇄2Sc3+(aq)+3Mn(s) E°=+0.90V

the enthalpy of formation of cu2 is -219 kj/mol. if you were to substitute the same amoun t of copper for zinc in this experiment, wold you expect the temp change to be higher than, equal to, or lower than what you observed for zinc

Answers



The temperature change to be lower than what was observed for zinc.

Enthalpy of formation is the energy change when one mole of a compound is formed from its constituent elements in their standard states. The negative value of -219 kJ/mol for the enthalpy of formation of Cu2 indicates that the formation of Cu2 releases energy. This means that the reaction is exothermic, and that the temperature will increase during the reaction.

If copper were substituted for zinc in this experiment, we would expect a similar exothermic reaction to occur. However, since the enthalpy of formation for copper is different than that of zinc, the amount of energy released during the reaction will be different. Copper has a lower enthalpy of formation than zinc, which means that the reaction will release less energy. This, in turn, means that the temperature change will be lower than what was observed for zinc.

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How many moles of h2so4 are present in 1. 63 liters of a 0. 954 m solution?.

Answers

There are approximately 1.554 moles of H2SO4 present in 1.63 liters of a 0.954 M solution.

To determine the number of moles of H2SO4 present in the solution, we can use the formula:

moles = concentration x volume

First, we need to convert the volume from liters to cubic meters:

1.63 L = 0.00163 m3

Next, we can plug in the values we know:

moles = 0.954 mol/L x 0.00163 m3

moles = 0.00155142 mol

Therefore, there are approximately 0.00155 moles of H2SO4 present in 1.63 liters of a 0.954 M solution.

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Which one of the following salts produces acidic solutions when it is dissolved in water?
a. KCH3COO
b. KF
c. KOCl
d. KBr
e. NH4NO3

Answers

The correct answer is e. NH4NO3.
NH4NO3, or ammonium nitrate, produces acidic solutions when dissolved in water. This is due to the acidic nature of the ammonium ion (NH4+) and the neutral nature of the nitrate ion (NO3-).

When NH4NO3 dissolves in water, it dissociates into NH4+ and NO3- ions. The NH4+ ion reacts with water (H2O) to produce the weak acid NH4OH (ammonium hydroxide) and a hydronium ion (H3O+), making the solution acidic.
In contrast, the other salts in the list produce neutral or basic solutions:
a. KCH3COO: Potassium acetate is a salt of a strong base (KOH) and a weak acid (CH3COOH), so it produces a basic solution.
b. KF: Potassium fluoride is a salt of a strong base (KOH) and a weak acid (HF), so it produces a basic solution.
c. KOCl: Potassium hypochlorite is a salt of a strong base (KOH) and a weak acid (HOCl), so it produces a basic solution.
d. KBr: Potassium bromide is a salt of a strong base (KOH) and a strong acid (HBr), so it produces a neutral solution.
In summary, NH4NO3 is the salt that produces acidic solutions when dissolved in water due to the acidic nature of the ammonium ion (NH4+) and the neutral nature of the nitrate ion (NO3-).

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