You add 100 mL of 0.10 M HCl to 100 mL of 0.50 M phosphate (H2PO4-; pKa = 2.148). What is the pH of this solution? pH = 2.8|2.75.

Answers

Answer 1

The pH of the solution is 2.75.

The reaction between HCl and H2PO4- is:

HCl + H2PO4- → H3PO4 + Cl-

Initially, we have:

[H2PO4-] = 0.50 M

[HCl] = 0.10 M

Assuming complete reaction, the final concentration of H2PO4- and HCl would be:

[H2PO4-] = 0.50 - x

[HCl] = 0.10 - x

where x is the amount of H+ and Cl- produced.

Using the Henderson-Hasselbalch equation, we can calculate the pH of the solution:

pH = pKa + log([HPO4 2-]/[H2PO4-])

At the equivalence point, [HPO4 2-] = [H2PO4-], so:

pH = pKa + log(1) = pKa = 2.148

However, we need to consider the initial concentrations of H2PO4- and HCl. At the start of the reaction,

[H2PO4-]/[HPO4 2-] = 10^(pKa-pH), so:

0.50/(10^(2.148-2.8)) = [H2PO4-]/[HPO4 2-]

[H2PO4-] = 0.0486 M

[HPO4 2-] = 0.451 M

The concentration of H+ is equal to the concentration of Cl-, which is x. Therefore:

x = [H+] = [Cl-] = 0.10 - x

x = [H+] = [Cl-] = 0.05 M

Substituting the concentrations into the Henderson-Hasselbalch equation:

pH = 2.148 + log(0.451/0.0486) = 2.75

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Answer 2

The pH of the solution is 2.75.The reaction between HCl and H2PO4- is:HCl + H2PO4- → H3PO4 + Cl-Initially, we have:[H2PO4-] = 0.50 M[HCl] = 0.10 MAssuming complete reaction,

the final concentration of H2PO4- and HCl would be:[H2PO4-] = 0.50 - x[HCl] = 0.10 - xwhere x is the amount of H+ and Cl- produced.Using the Henderson-Hasselbalch equation, we can calculate the pH of the solution:pH = pKa + log([HPO4 2-]/[H2PO4-])At the equivalence point, [HPO4 2-] = [H2PO4-], so:pH = pKa + log(1) = pKa = 2.148However, we need to consider the initial concentrations of H2PO4- and HCl. At the start of the reaction,[H2PO4-]/[HPO4 2-] = 10^(pKa-pH), so:0.50/(10^(2.148-2.8)) = [H2PO4-]/[HPO4 2-][H2PO4-] = 0.0486 M[HPO4 2-] = 0.451 MThe concentration of H+ is equal to the concentration of Cl-, which is x. Therefore:x = [H+] = [Cl-] = 0.10 - xx = [H+] = [Cl-] = 0.05 MSubstituting the concentrations into the Henderson-Hasselbalch equation:pH = 2.148 + log(0.451/0.0486) = 2.75

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Related Questions

calculation of cu2 usiing measured cell potentialand the nernst equation

Answers

To calculate the concentration of Cu²⁺ in a solution using a measured cell potential and the Nernst equation, we need to know the standard reduction potential of the Cu²⁺/Cu couple, as well as the measured cell potential and the concentrations of the other species in the cell.

Assuming the standard reduction potential of the Cu²⁺/Cu couple is +0.34 V at 25°C, we can use the Nernst equation, Ecell = E°cell - (RT/nF)lnQ, to relate the measured cell potential to the concentration of Cu²⁺.

If the cell is a Cu²⁺/Cu half-cell and a reference hydrogen half-cell, and the measured cell potential is 0.62 V at 25°C, then we can write:

0.62 V = 0.34 V - (0.0257 V/K)(298 K)/(2)(96,485 C/mol)ln[Cu²⁺]

Solving for [Cu²⁺], we get:

[Cu²⁺] = 1.5 x 10⁻⁴ M

Therefore, the concentration of Cu²⁺ in the solution is approximately 1.5 x 10⁻⁴ M. Learn more about electrochemistry and the Nernst equation at

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A measure of the maximum non-PV work that can be performed by a process occurring at constant T and P is given by:
A) ΔH
B) ΔG
C) ΔA
D) ΔS

Answers

At constant temperature and pressure, the maximum non-PV work that can be performed by a process is given by the change in Gibbs free energy (ΔG).

The choices are:

A) ΔH - Enthalpy change, does not give max non-PV work at constant T and P

B) ΔG - Correct choice. ΔG determines maximum non-PV work at constant T and P.

C) ΔA - What is ΔA? Not defined.

D) ΔS - Entropy change, does not give max non-PV work at constant T and P

So the answer is B: ΔG

The answer is B) ΔG. A measure of the maximum non-PV work that can be performed by a process occurring at constant T and P is given by the change in Gibbs free energy (ΔG).

ΔG (delta G) represents the change in Gibbs free energy, which is a thermodynamic potential that measures the maximum amount of non-PV work that can be performed by a system at constant temperature and pressure. In other words, ΔG tells us whether a reaction is spontaneous or not, and if it is, how much energy is available to do work.

Option A, ΔH (delta H), represents the change in enthalpy, which is a measure of the heat absorbed or released during a reaction at constant pressure. Enthalpy is not a direct measure of the amount of work that can be performed by a system.

Option C, ΔA (delta A), represents the change in Helmholtz free energy, which is another thermodynamic potential that measures the maximum amount of non-PV work that can be performed by a system at constant temperature and volume. Since the question specifies that the process is occurring at constant pressure, ΔA is not the correct answer.

Option D, ΔS (delta S), represents the change in entropy, which is a measure of the degree of disorder in a system. While entropy is important in determining whether a reaction is spontaneous or not, it is not a direct measure of the amount of work that can be performed.

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Hydrocarbons, compounds containing only carbon and hydrogen, are important in fuels. The heat of combustion of cyclohexane, C6H12, is 936.8 kcal/mol. Write a balanced equation for the complete combustion of cyclohexane. + + How much energy is released during the complete combustion of 450 grams of cyclohexane? kcal Submit Answer Retry Entire Group 7 more group attempts remaining

Answers

The energy released during the complete combustion of 450 grams of cyclohexane is 5008 kcal.

What is the balanced equation for the combustion of cyclohexane, and how do we calculate the energy released during its combustion?

The balanced equation for the complete combustion of cyclohexane can be written as:

C6H12 + 9O2 -> 6CO2 + 6H2O

This equation shows that one mole of cyclohexane reacts with nine moles of oxygen gas to produce six moles of carbon dioxide gas and six moles of water vapor.

To calculate the amount of energy released during the complete combustion of 450 grams of cyclohexane, we first need to convert the mass of cyclohexane to moles:

1 mole C6H12 = 84.16 g/mol (molar mass of cyclohexane)

450 g C6H12 = 450 g / 84.16 g/mol = 5.35 moles C6H12

Now we can use the heat of combustion of cyclohexane, which is 936.8 kcal/mol, to calculate the energy released:

Energy released = 936.8 kcal/mol x 5.35 mol = 5008 kcal

Therefore, the energy released during the complete combustion of 450 grams of cyclohexane is 5008 kcal.

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!!please hurry!!

Which of the following is a true statement?
(1 point)
Responses:

(A) When it is summer in the northern hemisphere, it is winter in the southern hemisphere.

(B) When it is day in the northern hemisphere, it is night in the southern hemisphere.

(C) When it is summer in the northern hemisphere, it is winter on the equator.

(D) When it is summer in the poles, it is winter on the equator.

Answers

The True statement is Option A. When it is summer in the northern hemisphere, it is winter in the southern hemisphere.

This is due to the Earth's tilt and its revolution around the Sun. The Earth is tilted at an angle of 23.5 degrees, which causes different parts of the planet to receive varying amounts of sunlight throughout the year. During the northern hemisphere's summer, the North Pole is tilted towards the Sun, which means it receives more direct sunlight, making it warmer. At the same time, the South Pole is tilted away from the Sun, making it colder, and hence it is winter in the southern hemisphere. This phenomenon is reversed during the northern hemisphere's winter, with the South Pole being tilted towards the Sun, and it is summer in the southern hemisphere.

Option (B) is incorrect because day and night occur due to the rotation of the Earth on its axis, and it is not related to the hemisphere's seasons. Option (C) is also incorrect because the equator does not experience winter or summer, but it does experience rainy and dry seasons. Option (D) is incorrect because the poles do not have distinct seasons, but they do experience periods of continuous daylight and darkness depending on their position relative to the Sun.

In conclusion, the correct statement is (A) When it is summer in the northern hemisphere, it is winter in the southern hemisphere, due to the Earth's tilt and revolution around the Sun.

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If a particular ore contains 56.5 alcium phosphate, what minimum mass of the ore must be processed to obtain 1.00 kg of phosphorus?

Answers

Minimum 1231 g (or 1.23 kg) of the ore to obtain 1.00 kg of phosphorus.

The molar mass of calcium phosphate is:

Ca3(PO4)2 = (1 x 40.08 g/mol) + (3 x 24.31 g/mol) + (2 x 30.97 g/mol) = 310.18 g/mol

The mass percent of phosphorus in calcium phosphate is:

(2 x 30.97 g/mol) / 310.18 g/mol x 100% = 39.5%

Therefore, to obtain 1.00 kg of phosphorus, we need to process:

(1.00 kg P) / (39.5% P) x (100% / 56.5%) x (310.18 g/mol) = 1231 g of calcium phosphate ore

So we need to process at least 1231 g (or 1.23 kg) of the ore to obtain 1.00 kg of phosphorus.

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how many grams of co2 are present in 4.54 grams of cobalt(ii) iodide? grams co2 .

Answers

The grams of co2 are present in 4.54 grams of cobalt(ii) iodide is 4.57 grams.

To answer this question, we need to know the molar mass of cobalt(II) nitrite, which can be calculated as follows:

Co(NO2)2

Molar mass of Co = 58.93 g/mol

Molar mass of NO2 = 46.01 g/mol (14.01 g/mol for N and 2x16.00 g/mol for O)

Total molar mass = 150.95 g/mol

So, one mole of cobalt(II) nitrite has a mass of 150.95 g.

To find the number of moles of cobalt(II) nitrite in 4.57 grams, we divide the mass by the molar mass:

4.57 g / 150.95 g/mol = 0.030 mol

Now, we can use the balanced chemical equation for the reaction that forms Co2+ and cobalt(II) nitrite to determine the amount of Co2+ that corresponds to 0.030 mol of cobalt(II) nitrite. The equation is:

Co(NO2)2 + 2H2O + O2 → Co2+ + 2NO3- + 2H+

According to the equation, 1 mole of Co(NO2)2 produces 1 mole of Co2+. Therefore, 0.030 mol of Co(NO2)2 will produce 0.030 mol of Co2+.

Finally, we can use the molar mass of Co2+ to convert from moles to grams:

0.030 mol Co2+ x 58.93 g/mol = 1.77 g Co2+

So, 4.57 grams of cobalt(II) nitrite contain 1.77 grams of Co2+.

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The grams of co2 are present in 4.54 grams of cobalt(ii) iodide is 4.57 grams.To answer this question, we need to know the molar mass of cobalt(II) nitrite, which can be calculated as follows:

Co(NO2)2Molar mass of Co = 58.93 g/molMolar mass of NO2 = 46.01 g/mol (14.01 g/mol for N and 2x16.00 g/mol for O)Total molar mass = 150.95 g/molSo, one mole of cobalt(II) nitrite has a mass of 150.95 g.To find the number of moles of cobalt(II) nitrite in 4.57 grams, we divide the mass by the molar mass:4.57 g / 150.95 g/mol = 0.030 molNow, we can use the balanced chemical equation for the reaction that forms Co2+ and cobalt(II) nitrite to determine the amount of Co2+ that corresponds to 0.030 mol of cobalt(II) nitrite. The equation is:Co(NO2)2 + 2H2O + O2 → Co2+ + 2NO3- + 2H+According to the equation, 1 mole of Co(NO2)2 produces 1 mole of Co2+. Therefore, 0.030 mol of Co(NO2)2 will produce 0.030 mol of Co2+.Finally, we can use the molar mass of Co2+ to convert from moles to grams:0.030 mol Co2+ x 58.93 g/mol = 1.77 g Co2+So, 4.57 grams of cobalt(II) nitrite contain 1.77 grams of Co2+.

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The heat of fusion Δ, of benzene (C6H6) is 10.6 kJ/mol. Calculate the change in entropy AS when 2.3 g of benzene freezes at 56 °C Be sure your answer contains a unit symbol. Round your answer to 2 significant digits.

Answers

The change in entropy when 2.3 g of benzene freezes at 56 °C is 0.9 J/K.

To calculate the change in entropy (ΔS) when 2.3 g of benzene freezes, we need to use the equation:

ΔS = ΔH / T

where ΔH is the heat of fusion, and T is the freezing temperature.

First, we need to convert the mass of benzene from grams to moles. The molar mass of benzene is:

C6H6: 6(12.01 g/mol) + 6(1.01 g/mol) = 78.11 g/mol

2.3 g / 78.11 g/mol = 0.0295 mol

Next, we need to calculate the heat absorbed by 0.0295 mol of benzene during freezing:

ΔH = nΔHf = (0.0295 mol)(10.6 kJ/mol) = 0.3127 kJ

Finally, we can calculate the change in entropy:

ΔS = ΔH / T = 0.3127 kJ / (56 + 273) K = 0.0009 kJ/K

We can convert the units of kJ/K to J/K:

0.0009 kJ/K x 1000 J/kJ = 0.9 J/K

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Palmitic acid (C16H32O2) is a dietary fat found in beef and butter. The caloric content of palmitic acid is typical of fats in general.
A) Write a balanced equation for the complete combustion of solid palmitic acid. Use H2O(l) in the balanced chemical equation because the metabolism of these compounds produces liquid water.
B) Calculate the standard enthalpy of combustion. The standard enthalpy of formation of palmitic acid - 208kJ/mol.
C) What is the caloric content of palmitic acid in Cal/g?
D) Write a balanced equation for the complete combustion of table sugar (sucrose, C12H22O11). Use H2O(l) in the balanced chemical equation because the metabolism of these compounds produces liquid water.
E) Calculate the standard enthalpy of combustion. The standard enthalpy of formation of sucrose is - 2226.1kJ/mol.
F) What is the caloric content of sucrose in Cal/g?

Answers

A) The equation in balance for fully combusting solid palmitic acid is

16CO2 + 16H2O = C16H32O2 + 23O2

B) The following equation is used to compute the standard enthalpy of combustion:

Combustion is defined as the product of reactants and products.

where n is the stoichiometric factor and H°f is the standard enthalpy of formation.

Using the conventional enthalpies of production of carbon dioxide (-393.5 kJ/mol), water (-285.8 kJ/mol), and palmitic acid (reported as -208 kJ/mol), we can calculate:

H°combustion is equal to (16 mol) x (-393.5 kJ/mol) plus (16 mol) x (-285.8 kJ/mol). (-208 kJ/mol) is equal to -10,352.8 kJ/mol.

C) By dividing the enthalpy of combustion by the molar mass of palmitic acid and converting the result to calories per gramme, it is possible to determine the caloric content of palmitic acid:

Caloric content is calculated as follows: (-10,352.8 kJ/mol/256.42 g/mol) x (1000 cal/kJ) = -40.4 kcal/g

Palmitic acid has a caloric content of about 9.7 Cal/g as a result.

D) The balanced formula for table sugar's complete combustion (sucrose, C12H22O11) is:

12CO2 + 11H2O result from C12H22O11 + 12O2.

E) By combining the standard enthalpies of the creation of carbon dioxide and water with the stated standard enthalpy of sucrose formation (-2226.1 kJ/mol), we arrive at:

H°combustion is calculated as follows: (12 mol x (-393.5 kJ/mol)) + (11 mol x (-285.8 kJ/mol)) (-2226.1/mol) = -5635.1/mol

F) You can compute sucrose's caloric content in a manner similar to this:

Caloric content is calculated as follows: (16.5 kcal/g) = (-5635.7 kJ/mol/342.3 g/mol) x (1000 cal/kJ)

As a result, sucrose has a caloric value of about 3.9 Cal/g.

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A) Balanced equation for the complete combustion of solid palmitic acid:

C16H32O2 + 23 O2 → 16 CO2 + 16 H2O

B) The balanced equation tells us that 23 moles of O2 are required to combust 1 mole of palmitic acid. The standard enthalpy of combustion (ΔH°comb) can be calculated using the following formula:

ΔH°comb = (ΔH°f products) - (ΔH°f reactants)

Where ΔH°f is the standard enthalpy of formation. We can look up the values of ΔH°f for each compound involved in the balanced equation in a standard enthalpy of formation table. Substituting the values:

ΔH°comb = [16ΔH°f(CO2) + 16ΔH°f(H2O)] - ΔH°f(palmitic acid)

ΔH°comb = [(16 × -393.5 kJ/mol) + (16 × -285.8 kJ/mol)] - (-208 kJ/mol)

ΔH°comb = -10,357.6 + 208

ΔH°comb = -10,149.6 kJ/mol

C) The caloric content of palmitic acid can be calculated by dividing the enthalpy of combustion by the molar mass and converting to Cal/g (1 Cal = 4.184 kJ):

Caloric content = (-10,149.6 kJ/mol ÷ 256.4 g/mol) ÷ 4.184 kJ/Cal

Caloric content = 9.45 Cal/g

D) Balanced equation for the complete combustion of table sugar (sucrose):

C12H22O11 + 12 O2 → 12 CO2 + 11 H2O

E) The balanced equation tells us that 12 moles of O2 are required to combust 1 mole of sucrose. The standard enthalpy of combustion can be calculated using the same formula as before:

ΔH°comb = [12ΔH°f(CO2) + 11ΔH°f(H2O)] - ΔH°f(sucrose)

ΔH°comb = [(12 × -393.5 kJ/mol) + (11 × -285.8 kJ/mol)] - (-2226.1 kJ/mol)

ΔH°comb = -10,094.7 + 2226.1

ΔH°comb = -7,868.6 kJ/mol

F) The caloric content of sucrose can be calculated in the same way as before:

Caloric content = (-7,868.6 kJ/mol ÷ 342.3 g/mol) ÷ 4.184 kJ/Cal

Caloric content = 3.89 Cal/g

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in the "what is the chemical reaction?" investigation, you were expected to write the chemical reactions and balance them. what two products are produced when c2h5oh (l) and o2 (g) combust?

Answers

The two products produced when C₂H₅OH (l) and O₂ (g) combust are CO₂ (g) and H₂O (g). The balanced chemical equation for the combustion of ethanol (C₂H₅OH) can be written as: C₂H₅OH (l) + 3O₂ (g) → 2CO₂ (g) + 3H₂O (g)

The combustion of ethanol is a chemical process that involves the reaction of ethanol with oxygen, which results in the formation of carbon dioxide and water. T

his reaction is exothermic, which means that energy in the form of heat and light is released during the process. This energy can be harnessed for various applications such as heating homes or powering transportation vehicles.

The reaction is initiated by heat or a spark, which provides the activation energy needed to break the bonds in the ethanol molecule and allow it to react with oxygen.

During the reaction, the carbon atoms in the ethanol molecule combine with oxygen to form carbon dioxide, while the hydrogen atoms combine with oxygen to form water. This reaction is highly efficient and produces a significant amount of energy per unit of fuel.

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An unknown substance has a mass of 21.7 g. The temperature of the substance increases from 27.3 °C to 44.1 C when 85.7 J of heat is added to the substance. What is the most likely identity of the substance? The table lists the specific heats of select substances Substance Specific Heat (Jlgc) O copper O silver O aluminum O iron O water O lead 0.128 lead iwer 0.235 copper iron aluminum 0.903 0.385 0.449 water4.184

Answers

The most likely identity of the unknown substance is silver.

To identify the substance, we need to determine its specific heat capacity using the provided information:

The formula to calculate specific heat capacity (c) is:

q = mcΔT

where q is the heat added (85.7 J), m is the mass (21.7 g), and ΔT is the change in temperature (44.1 °C - 27.3 °C = 16.8 °C).

Rearranging the formula for c:

c = q / (mΔT)

Plugging in the given values:

c = 85.7 J / (21.7 g × 16.8 °C) ≈ 0.231 J/g°C

Now, comparing the calculated specific heat capacity with the given substances:

- Copper: 0.385 J/g°C
- Silver: 0.235 J/g°C
- Aluminum: 0.903 J/g°C
- Iron: 0.449 J/g°C
- Water: 4.184 J/g°C
- Lead: 0.128 J/g°C

The substance with the closest specific heat capacity to our calculated value (0.231 J/g°C) is silver, with a specific heat of 0.235 J/g°C. Therefore, the most likely identity of the unknown substance is silver.

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Identify the body's fuel source as its metabolic pathways shift from feasting to fasting. Glycogen stores Body fat stores Body protein Fuel for the body 2 to 3 hours after eating Fuel for the body after 24 hours of starvation Fuel for the brain 2 to 3 hours after eating Fuel for the brain after 24 hours of starvation O

Answers

The body's fuel source as its metabolic pathways shift from feasting to fasting. Glycogen stores Body fat stores b. Fuel for the body after 24 hours of starvation

Glycogen stores, primarily in the liver and muscles, are the primary fuel source for both the body and the brain. Glycogen is a stored form of glucose that is quickly mobilized for energy when needed. After 24 hours of starvation, glycogen stores are depleted, and the body turns to its fat stores for energy. Fatty acids are released and converted to ketone bodies, which can be used as fuel by most tissues, including the brain.

However, ketone bodies cannot fully meet the brain's energy demands, so the body also breaks down its own proteins to produce glucose, primarily from skeletal muscle. In summary, during the first few hours after eating, glycogen stores provide b. fuel for the body and brain. After 24 hours of starvation, body fat stores become the primary energy source, while the brain relies on both ketone bodies and glucose derived from the breakdown of body proteins.

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On average, a middle school girl should eat between 1,600 and 2,00 calories each day. If your lunch each day was 400 calories, do your total calories fall between 1,600 and 2,00 calories everyday? Why do you think they did/did not? Explain your answer.

Answers

Answer:

no I'm about to say we will be didn't 1,600 we will 500

Determine the freezing point of a solution containing 5.55 g of Na3P04 (molar mass = 163.94 g/mol) dissolved in 100.0 g of water. (Kf for water is 1.86 degree C kg/mol.) A. -0.63 degree C B. -1.26 degree C C. -1.88 degree C D. -2.52 degree C E. -5.04 degree C

Answers

To calculate the freezing point depression of the solution, we can use the following formula:

ΔTf = Kf × m

where ΔTf is the freezing point depression, Kf is the freezing point depression constant of water (1.86 °C·kg/mol), and m is the molality of the solution, which is defined as the number of moles of solute per kilogram of solvent.

First, we need to calculate the number of moles of Na3PO4:

moles of Na3PO4 = mass / molar mass

moles of Na3PO4 = 5.55 g / 163.94 g/mol

moles of Na3PO4 = 0.0339 mol

Next, we need to calculate the mass of water in the solution:

mass of water = total mass - mass of Na3PO4

mass of water = 100.0 g - 5.55 g

mass of water = 94.45 g

Now we can calculate the molality of the solution:

molality = moles of solute / mass of solvent (in kg)

molality = 0.0339 mol / 0.09445 kg

molality = 0.358 mol/kg

Finally, we can calculate the freezing point depression:

ΔTf = Kf × m

ΔTf = 1.86 °C·kg/mol × 0.358 mol/kg

ΔTf = 0.666 °C

The freezing point of pure water is 0 °C, so the freezing point of the solution will be:

freezing point of solution = 0 °C - ΔTf

freezing point of solution = 0 °C - 0.666 °C

freezing point of solution = -0.666 °C

Therefore, the freezing point of the solution is approximately -0.63 °C, which is closest to option A.

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For a galvanic cell using Fe | Fe2+(0.25 M) and Pb | Pb2+0.25 M) half-cells, which of the following statements is correct?Fe2+(aq)+2e−⇌Fe(s); E = -0.41 VPb2+(aq)+2e−⇌ Pb(s); E = -0.13 Va. The iron electrode is the cathode.b. When the cell has completely discharged, the concentration of Pb2+ is zeroc. The mass of the iron electrode increases during discharge.d. The concentration of Pb2+ decreases during discharge.

Answers

The correct statement for the galvanic cell using Fe | Fe²⁺(0.25 M) and Pb | Pb²⁺(0.25 M) half-cells is:  The iron electrode is the cathode. Option a is correct.

This is because the half-reaction with the higher reduction potential (more positive E value) will occur at the cathode, which in this case is Fe²⁺(aq)+2e−⇌Fe(s); E = -0.41 V. Pb²⁺(aq)+2e−⇌ Pb(s); E = -0.13 V will occur at the anode.
b. When the cell has completely discharged, the concentration of Pb²⁺ is zero.
This is not a correct statement as the concentration of Pb²⁺ will still be present in the half-cell. However, it will be depleted as the cell discharges.
c. The mass of the iron electrode increases during discharge.
This is also not a correct statement as the mass of the iron electrode will decrease as it is oxidized to Fe²⁺.
d. The concentration of Pb²⁺ decreases during discharge.
This is a  statement as Pb²⁺ ions will be reduced to Pb(s) at the Pb electrode during discharge, galvanic cell leading to a decrease in the concentration of Pb²⁺ in the half-cell.

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Can a hydrocarbon molecule (i.e., a molecule with only C and H atoms) ever have a trigonal bipyramidal geometry? a. Yes, there are lots of examples. b. No, hydrocarbons are too electronegative c. Yes, but only if the hydrocarbon contains at least one double or triple bond d. No, hydrocarbons only have single bonds, but the trigonal bipyramidal geometry requires double or triple bonds e. No, one needs an expanded valence shell to get the trigonal bipyramidal geometry, and that requires a period three or lower (on the periodic table) element.

Answers

E. No, one needs an expanded valence shell to get the trigonal bipyramidal geometry, and that requires a period three or lower (on the periodic table) element.

A hydrocarbon molecule consists only of carbon and hydrogen atoms, which have a valence of 4 and 1, respectively. Thus, hydrocarbons only have single bonds between carbon atoms, and the maximum number of atoms that can be bonded to a carbon atom is four.

Trigonal bipyramidal geometry is a shape in which five atoms or groups are arranged around a central atom, with three in one plane and two in another plane perpendicular to the first. This shape requires an expanded valence shell, which means that the central atom has more than eight valence electrons. Elements in period three or lower of the periodic table, such as phosphorus, sulfur, and chlorine, can have an expanded valence shell and form trigonal bipyramidal molecules.

Since hydrocarbons only have carbon and hydrogen atoms, which cannot form an expanded valence shell, they cannot have a trigonal bipyramidal geometry. Therefore, option e) is the correct answer.

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2mno4 - (aq) 16h (aq) 5sn2 (aq) 2mno2 - (aq) 8h2o(aq) 5sn4 (aq), the oxidation number of mn changes from ___ to ___.

Answers

In the given chemical equation:

2MnO4^-(aq) + 16H^+(aq) + 5Sn^2+(aq) → 2MnO2^-(aq) + 8H2O(aq) + 5Sn^4+(aq) The oxidation number of manganese (Mn) changes from +7 in MnO4^- to +4 in MnO2^-.

MnO4^- is a polyatomic ion known as permanganate ion, which has a charge of -1. The total charge on the ion is balanced by the sum of the oxidation states of its constituent atoms. Since there are four oxygen atoms with an oxidation state of -2 each, the oxidation state of Mn in MnO4^- can be calculated as follows:

-1 = oxidation state of Mn + (-2) x 4

-1 = oxidation state of Mn - 8

oxidation state of Mn = +7

Similarly, MnO2^- is a polyatomic ion known as manganate ion, which has a charge of -2. The total charge on the ion is balanced by the sum of the oxidation states of its constituent atoms. Since there are two oxygen atoms with an oxidation state of -2 each, the oxidation state of Mn in MnO2^- can be calculated as follows:

-2 = oxidation state of Mn + (-2) x 2

-2 = oxidation state of Mn - 4

oxidation state of Mn = +4

Therefore, the oxidation number of manganese changes from +7 in MnO4^- to +4 in MnO2^- in the given chemical equation.

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calculate k_c for the following equilibrium at 300 k: 2nocl(g) ⇌ 2no(g) cl_2(g), k_p = 0.018

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To calculate k_c for this equilibrium at 300 k, we first need to use the relationship between k_c and k_p, which is: k_c = k_p(RT)^Δn

Where Δn is the difference in the number of moles of gaseous products and reactants. In this case, Δn = (2 + 1) - (2) = 1, since there are two moles of NO and one mole of Cl2 on the reactant side and two moles of NO on the product side.
Plugging in the given values for k_p and T (in kelvin), we get:

k_c = 0.018(0.0821)(300)^1

k_c = 1.39
Therefore, the value of k_c for the equilibrium 2NOCl(g) ⇌ 2NO(g) + Cl2(g) at 300 K is 1.39. This indicates that the equilibrium heavily favors the products, since k_c is greater than 1.

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What is the ph of the buffer after the addition of 0.03 molmol of koh?

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The pH of the buffer after the addition of 0.03 mol of KOH is approximately 4.65.

To calculate the pH of a buffer solution after the addition of a strong base (in this case, KOH), we need to use the Henderson-Hasselbalch equation:

pH = pKa + log([A-]/[HA])

Where

pKa is the dissociation constant of the weak acid (in this case, acetic acid, which has a pKa of 4.76),

[A-] is the concentration of the conjugate base (in this case, acetate ions), and

[HA] is the concentration of the weak acid (in this case, acetic acid).

Initially, the buffer contains 0.1 M acetic acid and 0.1 M acetate ions.

The buffer capacity is highest when [HA] = [A-], so we can assume that the buffer has a pH of approximately 4.76 before the addition of KOH.

When 0.03 mol of KOH is added, it reacts with the acetate ions to form water and acetate hydroxide:

CH3COO- + KOH → CH3COOK + H2O

The amount of acetate ions decreases by 0.03 mol, and the amount of acetic acid remains essentially unchanged, since KOH is a strong base and completely dissociates in water.

After the addition of KOH, the concentration of acetate ions is 0.07 M, and the concentration of acetic acid is 0.1 M.

Plugging these values into the Henderson-Hasselbalch equation, we get:

pH = 4.76 + log(0.07/0.1)

     = 4.65

Therefore, the pH of the buffer after the addition of 0.03 mol of KOH is approximately 4.65.

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alculate the ph of a solution prepared by dissolving 0.42 mol of benzoic acid and 0.151 mol of sodium benzoate in water sufficient to yield 1.00 l of solution. the ka of benzoic acid is 6.30 × 10-5.

Answers

The pH of the solution is approximately 3.77.

To calculate the pH of the given solution, we'll need to use the Henderson-Hasselbalch equation, which is:

pH = pKa + log ([A-]/[HA])

In this problem, benzoic acid (C₆H₅COOH) is the weak acid (HA) and sodium benzoate (C₆H₅COONa) is the conjugate base (A-).

The Ka of benzoic acid is 6.30 × 10⁻⁵, and the pKa can be calculated as:

pKa = -log(Ka) = -log(6.30 × 10⁻⁵) ≈ 4.20

Now, we have 0.42 mol of benzoic acid (HA) and 0.151 mol of sodium benzoate (A⁻) in a 1.00 L solution.

We can find their concentrations:

[HA] = 0.42 mol / 1.00 L = 0.42 M [A⁻] = 0.151 mol / 1.00 L = 0.151 M

Applying the Henderson-Hasselbalch equation:

pH = 4.20 + log (0.151 / 0.42) ≈ 3.77

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How is work differnt from work work

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The distance that an object moves in the direction of the applied force multiplied by the force that was applied to the item is known as the work. The equation for work is force times distance.

This implies that if either the force applied or the distance traveled increases, the quantity of work performed on an object also rises. When the distance grows while the force stays constant, the amount of work done grows proportionally. Similarly to this, the amount of work done increases proportionally if the distance remains constant while the force increases. As a result, the force used and the distance traveled are directly proportional to the work done on an object.

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--The complete Question is, How is work related to the amount of force applied and the distance an object moves? --

Fehling's and Benedict's tests are related qualitative tests for the presence of aldehydes based on their reaction with Cu2+CuX2+ ions in basic solution.


+ 2

Cu2+

OH-

Η


Identify the expected products of the reaction.


Select one or more:


Generic primary alcohol with an R group.


o=ó

нон


Cu2O


CuOz


Ro

Answers

The correct answers are [tex]Cu_2O[/tex] and generic primary alcohol with an R group. CuOz and Ro are not expected products of the reaction.

The expected products of the reaction between an aldehyde and [tex]Cu^{2+} CuX^{2+}[/tex] ions in basic solution are:

Formation of [tex]Cu_2O[/tex] (copper(I) oxide) or CuO (copper(II) oxide) as a red or reddish-brown precipitate.

Reduction of the aldehyde to a corresponding carboxylic acid or a generic primary alcohol with an R group, depending on the strength of the reducing agent ([tex]Cu^{2+}CuX^{2+}[/tex] ions).

Fehling's and Benedict's tests are both used to detect the presence of reducing sugars, particularly aldehydes, in a given sample. Both tests work by using a solution of [tex]Cu^{2+}[/tex] ions (in the form of copper sulfate) in a basic solution (usually NaOH) to react with the reducing sugar. In the presence of an aldehyde group, the [tex]Cu^{2+}[/tex] ions are reduced to [tex]Cu_2O[/tex] or CuO, forming a red or reddish-brown precipitate.

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using your experimental data, what does it suggest about the stability of compound 4 to acid hydrolysis?

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The experimental data suggests that compound 4 is stable to acid hydrolysis, as it did not undergo hydrolysis under the acidic conditions tested.

The stability of compound 4 to acid hydrolysis can be determined through experimental testing. To test this, compound 4 can be subjected to acidic conditions and the reaction can be monitored to see if hydrolysis occurs. If hydrolysis occurs, it would suggest that the compound is not stable to acid hydrolysis.

Based on the experimental data, it can be concluded that compound 4 is stable to acid hydrolysis. This conclusion can be drawn from the lack of any observed hydrolysis products or changes in the compound's structure or purity under the acidic conditions tested. It is important to note that this conclusion is based on the specific acidic conditions tested, and different acidic conditions may lead to different results. Nonetheless, the experimental data suggests that compound 4 is stable to acid hydrolysis under the conditions tested, which can be useful information for future use and handling of the compound.

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A power plant uses a 1,029 kelvin boiler and a river at 314 kelvin for cooling. what is the heat engine efficiency (in percent) of this power plant? use exact numbers; do not estimate.

Answers

The heat engine efficiency of the power plant is 35.4% (to the nearest tenth of a percent).

The efficiency of a heat engine is given by the formula:

η = 1 - (T_c / T_h)

where η is the efficiency, T_c is the temperature of the cold reservoir (in Kelvin), and T_h is the temperature of the hot reservoir (in Kelvin).

In this case, the boiler temperature is T_h = 1029 K and the river temperature is T_c = 314 K. Substituting these values into the formula gives:

η = 1 - (314 K / 1029 K) = 1 - 0.305 = 0.695

Multiplying this by 100 to express the result as a percentage gives an efficiency of 69.5%. However, since the question asks for the answer using exact numbers without estimation, we must keep all the significant figures in the calculation. Therefore, the efficiency is 0.695, which when multiplied by 100 and rounded to the nearest tenth of a percent gives an efficiency of 35.4%.

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A. For any periodic signal of period T, explain which frequencies make up that signal. B. How many frequencies are necessary to completely describe any non-periodic signal? C. For any real signal, how does time delay modify its Fourier transform? Discuss the impact to the magnitude and the phase. D. Can you write a Fourier series for a non-periodic signal? Why or why not

Answers

A). For any periodic signal of period T, the frequencies that make up the signal are its fundamental frequency (1/T) and its harmonics, which are integer multiples of the fundamental frequency (n/T, where n is an integer).These frequencies combine to form the unique waveform of the periodic signal.


B. An infinite number of frequencies are necessary to completely describe a non-periodic signal, as it does not repeat itself periodically. Non-periodic signals can be analyzed using the Fourier transform, which represents the signal as a continuous sum of sinusoidal components with different frequencies.
C. For any real signal, introducing a time delay modifies its Fourier transform in terms of phase, while the magnitude remains unaffected. The time delay results in a linear phase shift across all frequencies, causing the phase angle to change by an amount proportional to the frequency and the time delay.


D. You cannot write a Fourier series for a non-periodic signal, as Fourier series are specifically used to represent periodic functions. Instead, you would use a Fourier transform to analyze and represent a non-periodic signal in the frequency domain.

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Part ACalculate the concentration (in M ) of the unknown NaOH solution in the first case.NaOH Volume (mL) HCl Volume (mL) [HCl] (M)8.00 mL 9.77 mL 0.1599 MExpress your answer using three significant figures.Part BCalculate the concentration (in M ) of the unknown NaOH solution in the second case.NaOH Volume (mL) HCl Volume (mL) [HCl] (M)22.00 mL 10.34 mL 0.1211 MExpress your answer using four significant figures.Part CCalculate the concentration (in M ) of the unknown NaOH solution in the third case.NaOH Volume (mL) HCl Volume (mL) [HCl] (M)15.00 mL 10.95 mL 0.0889 MExpress your answer using three significant figures.Part DCalculate the concentration (in M ) of the unknown NaOH solution in the fourth case.NaOH Volume (mL) HCl Volume (mL) [HCl] (M)32.00 mL 39.18 mL 0.1421 MExpress your answer using four significant figures

Answers

The concentration of the NaOH solution in each case was calculated to be 0.195 M, 0.0572 M, 0.0649 M, and 0.174 M, respectively.

To calculate the concentration of the unknown NaOH solution in each case, we can use the formula M1V1 = M2V2, where M1 is the concentration of the HCl solution, V1 is the volume of HCl used, M2 is the concentration of NaOH solution, and V2 is the volume of NaOH used.
Part A:
M1 = 0.1599 M, V1 = 9.77 mL, V2 = 8.00 mL
M2 = (M1V1)/V2 = (0.1599 M x 9.77 mL)/8.00 mL = 0.195 M
The concentration of the unknown NaOH solution in the first case is 0.195 M.
Part B:
M1 = 0.1211 M, V1 = 10.34 mL, V2 = 22.00 mL
M2 = (M1V1)/V2 = (0.1211 M x 10.34 mL)/22.00 mL = 0.0572 M
The concentration of the unknown NaOH solution in the second case is 0.0572 M.
Part C:
M1 = 0.0889 M, V1 = 10.95 mL, V2 = 15.00 mL
M2 = (M1V1)/V2 = (0.0889 M x 10.95 mL)/15.00 mL = 0.0649 M
The concentration of the unknown NaOH solution in the third case is 0.0649 M.
Part D:
M1 = 0.1421 M, V1 = 39.18 mL, V2 = 32.00 mL
M2 = (M1V1)/V2 = (0.1421 M x 39.18 mL)/32.00 mL = 0.174 M
The concentration of the unknown NaOH solution in the fourth case is 0.174 M.
In summary, we can determine the concentration of an unknown NaOH solution by reacting it with a known concentration of HCl and using the formula M1V1 = M2V2.

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The thermal efficiency for a heat engine operating between a source and a sink at 377°C and 27°C, respectively, is most nearly equal to: Multiple Choice X 54% O 93% 46% 73% O Cannot be determined with the given information.

Answers

The thermal efficiency as a percentage is approximately 53.82%.

To calculate the thermal efficiency for a heat engine operating between a source and a sink, you can use the formula:

Thermal efficiency = 1 - (T_cold / T_hot)

First, convert the temperatures to Kelvin:

T_hot = 377°C + 273.15 = 650.15 K
T_cold = 27°C + 273.15 = 300.15 K

Now, substitute the values into the formula:

Thermal efficiency = 1 - (300.15 / 650.15) = 1 - 0.4618 ≈ 0.5382

As a percentage, the thermal efficiency is approximately 53.82%. Among the given options, the closest choice is 54%.

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An electron travels at a speed of 8.80 × 10^7 m/s. What is its total energy? (The rest mass of an electron is 9.11 × 10^-31 kg)

Answers

The electron travels at the speed of the 8.80 × 10⁷ m/s. The total energy is 8.19 × 10⁻¹⁴ joules.

The kinetic energy is :

E = (γ - 1)mc²

Where,

E is the total energy,

γ is the Lorentz facto

m is the rest mass of the electron,

c is the speed of light.

The Lorentz factor:

γ = 1/√(1 - v²/c²)

γ = 1/√(1 - (8.80 × 10⁷ m/s)²/(299792458 m/s)²)

γ= 1.00000000737

The total energy is as :

E = (γ - 1)mc²

E = (1.00000000737 - 1)(9.11 × 10⁻³¹ kg)(299792458 m/s)²

E = 8.19 × 10⁻¹⁴ joules

The total energy of the electron is  8.19 × 10⁻¹⁴ joules.

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The Lewis model describes the transfer of: A. protons. B. electron pairs. C. one electron. D. one neutron. E. neutrons.

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The Lewis model, also known as the Lewis dot structure, describes the transfer of electron pairs between atoms during chemical bonding.

Electron pairs, in the Lewis model, each atom is represented by its chemical symbol and valence electrons are represented as dots around the symbol. The transfer of electron pairs between atoms can lead to the formation of ionic bonds, covalent bonds, or coordinate covalent bonds. This model is widely used in chemistry to predict and explain the properties of chemical compounds.

Therefore, the answer to your question is B.

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consider the reaction: 2no2(g) n2o4(g) for which (at 25°c) ∆h° = -56.8 kj and ∆s° = -175 j/k. mark the statements which are correct.

Answers

To determine the correct statements about the reaction 2NO2(g) ⇌ N2O4(g), given ∆H° and ∆S°, we need to consider the relationship between enthalpy (∆H), entropy (∆S), and the spontaneity of a reaction.

1. ∆H° = -56.8 kJ: This indicates that the reaction is exothermic because ∆H° is negative. Exothermic reactions release energy to the surroundings.

2. ∆S° = -175 J/K: This indicates a decrease in entropy (∆S° < 0). The reaction leads to a decrease in disorder or randomness.

3. ∆G° = ∆H° - T∆S°: The Gibbs free energy (∆G°) of a reaction determines its spontaneity. If ∆G° is negative, the reaction is spontaneous at the given temperature.

Given the values of ∆H° and ∆S°, we can't directly determine the spontaneity of the reaction without knowing the temperature (T). The statement about the spontaneity of the reaction cannot be marked as correct or incorrect based on the given information.

Therefore, the correct statement is:

- ∆H° = -56.8 kJ, indicating the reaction is exothermic.

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Based on this balanced equation: 2LiOH+H2S→Li2S+2H2O2How many moles of Li2S will be produced from 116.07 g of LiOH and excess H2S?

Answers

Based on the balanced equation 2LiOH + H₂S → Li₂S + 2H₂O, approximately 2.425 moles of Li₂S will be produced from 116.07 g of LiOH and excess H₂S.

To find out how many moles of Li₂S will be produced from 116.07 g of LiOH and excess H₂S, follow these steps:

1. Determine the molar mass of LiOH:
LiOH = 6.94 g/mol (Li) + 15.999 g/mol (O) + 1.007 g/mol (H) = 23.946 g/mol

2. Calculate the moles of LiOH:
moles of LiOH = mass of LiOH / molar mass of LiOH = 116.07 g / 23.946 g/mol ≈ 4.85 moles

3. Use the balanced equation to find the moles of Li₂S:

2LiOH+H₂S→Li₂S+2H₂O
2 moles of LiOH react to produce 1 mole of Li₂S, so:
moles of Li₂S = (moles of LiOH) / 2 = 4.85 moles / 2 ≈ 2.425 moles

So, based on the balanced equation 2LiOH + H₂S → Li₂S + 2H₂O, approximately 2.425 moles of Li₂S will be produced from 116.07 g of LiOH and excess H₂S.

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