Tert-butyl alcohol's 13C-NMR spectrum will only display two signals.
(I) Signal at about 31 ppm: This signal is for the more shielded and electron-rich carbon atoms and is upfield. The height of the peak on the y-axis indicates the relative quantity of carbon atoms to other peaks. Since it is three times as tall as the second signal in this instance, it is clear that this peak represents three carbon atoms.
(ii) Signal at about 70 ppm: This signal is directed downfield and pertains to the carbon atom, which is more exposed and has an environment poor in electrons. The height of these peaks is only one carbon higher than the second signal. Furthermore, the exposed environment demonstrates this carbon.
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2 no2(g) <—> n2o4(g) if the partial pressure of each gas is set a 5. 0 atm at 25°c, is the system at equilibrium?
Yes the system is at equilibrium if reactants and products are at equilibrium at 10⁻³ < K <10³.\
Chemical Equilibrium:When opposing reactions are happening at the same pace, chemical equilibrium happens.
[tex]N_2O_4 (g)[/tex] → [tex]2 NO _2(g)[/tex]
We represent the system's equation with a double arrow since the forward and reverse processes are both active in an equilibrium state.
Forward Reaction: Rate Law:
[tex]N_2O_4(g)[/tex] → [tex]2 NO_2 (g)[/tex] Rate = [tex]k_f [N_2O_4][/tex]
Reverse Reaction: Rate Law:
[tex]2 NO_2 (g)[/tex] → [tex]N_2O_4(g)[/tex] Rate = [tex]k_f [NO_2]^2[/tex]
Therefore at equilibrium;
[tex]Rate_f=Rate_r\\[/tex]
[tex]k_f[N_O_4] = k_r[NO_2]^2[/tex]
It becomes:
[tex]\frac{k_f}{k_r} = \frac{[NO_2]^2}{[N_2O_4]} \\[/tex]
[tex]K_e_q = \frac{k_f}{k_r} = \frac{[NO_2]^2}{[N_2O_4]} = a constant[/tex]
The reciprocal of the equilibrium constant of the forward reaction is the equilibrium constant of a reaction moving in the opposite direction.
The reaction is said to have a large amount of both reactants and products at equilibrium at 10⁻³ < K <10³.
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An aqueous solution has a molality of 3. 64 kcl. what is the the mass percent of kcl in the solution? enter your answer to three significant figures and in units of mass percent
The mass percentage of KCl solution is 21.34%
Calculation,
Given molality of KCl aqueous solution = 3. 64 m = 3. 64 mole/ Kg
It means 3. 64 mole of solute present in 1Kg of solvent
or , 3. 64 mole of solute present in 1000 g of solvent ( water )
Mass of solute ( KCl ) = 3. 64 mole×74.55 g/mole =271.3 g
The total mass of solution ( KCl + water ) = 271.3 g + 1000 g = 1271.3 g
Mass percentage is equal to percentage of mass of solute present in total mass of solution.
Mass percentage = 100×271.3 g/1271.3 g = 21.34%
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How much 0. 5mna2so4 solution will completely precipitate the ba2 in 0. 7l of 0. 13mbacl2 solution?
The volume required to precipitate 0.7l of 0.13 m BaCl2 is 0.04L.
Calculations of number of moles for given molarity of solutionwe use
Molarity =Moles of solute / volume of solution (in litre)
Now, for barium ions
Given,
Molarity of solution = 0.13 m
Volume of solution = 0.7L
By substituting all the value ,we have
Moles of Barium = 0.7 × 0.13
= 0.091
Chemical equationBaSO4 » Ba2+ + So2-
By stoichiometry of equation
1 mole of sulphate ion precipitate 1 mole of barium ion
So, 0.091 mole of sulphate ion precipitate
0.091 of moles of Barium ion
Calculation of volume of sulfate ionNow, calculate the volume of ions by using equation as given above
Mole of sulphate ion = 0.091 mol
Molarity concentration of sulphate ions = 0.05m
By substituting all value , we get
C = n / V
V = n/ C
= 0.091 / 0.5 = 0.04L
Thus, we calculated that the volume required to precipitate 0.7l of 0.13 m BaCl2 is 0.04L.
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Nitrous acid, hno2, has a ka of 7. 1 ✕ 10-4. what are [h3o ], [no2-], and [oh -] in 0. 40 m hno2?
Nitrous acid, hno2, has an acid dissociation constant - ka of 7. 1 ✕ 10-4. what are [h3o ], [no2-], and [oh -] in 0. 40 m hno2 - 4829 M [OH^-] = 1.439 x 10^-14 M
The acid dissociation constant (Ka) is used to differentiate between strong and weak acids. Strong acids have very high Ka values. The Ka value is determined by examining the equilibrium constant for acid dissociation. The acid dissociates more readily as the Ka increases.
The original molecular definition of an acid, according to Arrhenius, is a molecule that dissociates in an aqueous solution, releasing the hydrogen ion H+ (a proton): HA A + H+. acid dissociation constant is an equilibrium constant for this dissociation reaction.
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What do the electron configurations for all the group 18 noble gases have in common?
Electron configurations for all the group 18 noble gases have eight electrons in their valence shell in common.
Noble gases are the gases that contain Eight electrons in their valence shells and are placed in Group 18 of the periodic table. The octet of Noble gases is complete. They are inert in nature since they have complete valence shells. They are not much abundant in nature due to their inert behaviour.
They are stable and realtively unreactive as compared to other members of the peiodic table.
Some other factors that remain common for noble gases:
High Ionisation energyNegligible ELectronegativityLow boiling pointsPsitive Elevtron gain enthalpyGases at Room temperatureLearn more about Noble gases here,
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How many grams are in 0.0667 moles of MgCl 2?
A.
6.35
B.
1430
C.
7.01
D.
.523
Answer:
A.) 6.35
Explanation:
To find the mass of MgCl₂, you need to multiply the given value by the molar mass. The molar mass is made up of each element's atomic mass times their quantities. It is important to arrange the conversion in a way that allows for the cancellation of units.
Atomic Mass (Mg): 24.305 g/mol
Atomic Mass (Cl): 35.453 g/mol
Molar Mass (MgCl₂): 24.305 g/mol + 2(35.453 g/mol)
Molar Mass (MgCl₂): 95.211 g/mol
0.0667 moles MgCl₂ 95.211 grams
--------------------------------- x ------------------------ = 6.35 grams MgCl₂
1 mole
Using this balance, can you estimate the mass to the nearest milligram?
Yes, we can use this balance to estimate the mass to the nearest milligram.
What is the balance?The weighing balance is the kind of scale that can be used to measure the mass of a body. We know that mass is the quantity of matter that is contained in a body and the the SI unit of mass is the kilogram.
Looking at the balance as it is graduated in milligrams, we know that measurement to the nearest gram means measurement to the nearest whole number so we can say that the answer is yes. We can use this balance to estimate the mass to the nearest milligram.
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If an ideal solution contains 3. 50 mol of a non-volatile solute and 15. 8 mol of solvent, and it has a vapor pressure of 22. 6 torr, what is the vapor pressure of the pure solvent (in torr)?
The vapour pressure of the solvent is 28.25 torr.
Raoult's law is a physical chemistry relationship with consequences for thermodynamics. The theory, put out by French chemist François-Marie Raoult in 1887, asserts that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture. As a result, the mole fraction of the solute in the solution is equal to the relative decrease in vapor pressure of a diluted solution of a nonvolatile solute.
According to Raoult's law, p = p⁰ × x
Where,
p = partial vapour pressure of the solvent
p⁰ = vapour pressure of the solvent
x = mole fraction of solvent
The mole fraction of the pure solvent = 15 .8 /19.3
= 0.81
Substitute values in the above expression,
p = p⁰ × x
22.6 = p⁰ × 0.8
p⁰ = 28.25 torr
Therefore, the vapour pressure of the solvent is 28.25 torr.
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How many moles of electrons are required to produce 99. 9 g of aluminum metal from a sample of molten aluminum fluoride?
299.7 moles of electrons are required to produce 99. 9 g of aluminum metal from a sample of molten aluminum fluoride.
Calculation,
The production of aluminium metal is given as,
[tex]Al^{+3} + 3e^{-}[/tex]→ [tex]Al[/tex]
The 3 moles of electrons require to produce 1 gm of atom of aluminium ( weight = 27 ) solution fluoride.
The number of moles of electrons are required to produce 99. 9 g of aluminum metal from a sample of molten aluminum fluoride = 3mol×99.9g/1g
The number of moles of electrons are required to produce 99. 9 g of aluminum metal from a sample of molten aluminum fluoride = 299.7 moles
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Na3po4 dissolves in water to produce an electrolytic solution. what is the osmolarity of a 2. 0 × 10-3 m na3po4 solution?
When Na3po4 dissolves in water to produce an electrolytic solution. The osmolarity of a 2. 0 × 10-3 m Na3po4 solution is 0.008osmol/L.
Osmolarity is defined as the number of osmoles of solute particles per unit volume of the solution.
In other words osmolarity is the multiple if molarity
Osmolarity = i× molarity
Here i represents the van't Hoff factor,
[tex]Na_{3}PO_{4}[/tex] ⇒ [tex]3Na^{+} + PO_{4} ^{-}[/tex]
3 Moles of [tex]Na_{} ^{+}[/tex] + 1 mole [tex]PO_{4} ^{-}[/tex] = 4
The number of moles of particles of solute produced in solution are actually called osmoles.
As a result, the van't Hoff factor will be equal to
i=4 Moles ions produced (osmoles) 1mole [tex]Na_{3} PO_{4}[/tex] .dissolved =4
Since we know that,
[tex]Na_{3} PO_{4}[/tex] = [tex]2.0 * 10^{-3} M[/tex]
Osmolarity =
[tex]4*2.0*10^{-3} M[/tex] = [tex]8.0 * 10^{-3} osmol L -10s[/tex]
Thus, the Osmolarity of given solution is 0.008 osmol/L.
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500. ml of a solution containing 1. 5 m nh3(aq) is mixed with 500. ml of a solution containing 0. 50m of hcl(aq). what is the ph of the final solution? (kb(nh3) = 1. 8 x 10-5)
The pH of the solution is determined by the hydrogen ion concentration. The pH of the solution with 1.5 M ammonia and 0.50 M hydrochloric acid is 8.77.
What is pH?The potential of the hydrogen ion in the solution is called pH which determines the basicity and acidity of the solution.
Given,
The molar concentration of 500 mL ammonia = 1.5 M
The molar concentration of 500 mL hydrochloric acid = 0.50 M
Kb (NH₃) = 1. 8 x 10⁻⁵
First, pOH is calculated as,
pOH = pKb + log [NH₃][HCl]
= - log 1. 8 x 10⁻⁵ + log [1.5][0.50]
= - log 1. 8 x 10⁻⁵ + log [3]
= 4.744 + 0.477
= 5.221
Now, pH is calculated from pOH as,
pH = 14 - pOH
= 14 - 5.221
= 8.77
Therefore, 8.77 is the pH.
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Semiconductors are more effective than metals as converters of solar radiation into electricity because?
Semiconductors show the property of both the conductor and insulator. They are more effective than metals as their valence electron can free flow by the sun's energy. Thus, option B is correct.
What are semiconductors?Semiconductors are substances and materials that exhibit intermediate properties of conductors and insulators. They are solid materials that can conduct electrical charges due to the added impurity or change in temperature.
They have a valence electron in their outer shell that can absorb the energy from the sun to get excited. This leads to the flow of the charge in the semiconducting substance more easily.
Therefore, option B. the semiconductors can absorb the extra energy is correct.
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Your question is incomplete, but most probably your full question was, Semiconductors are more effective than metals as converters of solar radiation into electricity because
A. it is easier for the atoms of a semiconductor to absorb solar energy and to move from place to place within the solid, thereby conducting electricity.
B. the energy contained in sunlight gives the valence electrons in the semiconductor atoms the extra energy they need to "flow" throughout the solid.
C. metals melt much too easily under direct sunlight and, as liquids, lose their ability to conduct electricity.
D. solar radiation has sufficient energy to knock electrons completely off the metal surface, making it impossible for the electrons to "flow" from atom to atom and conduct electricity.
Choose the molecules that contains sphingosine.
a. sphingomyelins molecule
b. molecule
c. molecule
d. a phosphatidylcholine
Answer:
a phosphatidylcholine
The molecule that contains sphingosine is a phosphatidylcholine compound.
What is a compound?
Compound is defined as a chemical substance made up of identical molecules containing atoms from more than one type of chemical element.
Molecule consisting atoms of only one element is not called compound.It is transformed into new substances during chemical reactions. There are four major types of compounds depending on chemical bonding present in them.They are:
1)Molecular compounds where in atoms are joined by covalent bonds.
2) ionic compounds where atoms are joined by ionic bond.
3)Inter-metallic compounds where atoms are held by metallic bonds
4) co-ordination complexes where atoms are held by co-ordinate bonds.
They have a unique chemical structure held together by chemical bonds Compounds have different properties as those of elements because when a compound is formed the properties of the substance are totally altered.
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In the malate–aspartate shuttle, electrons are transferred from _____________ to form malate.
In the malate–aspartate shuttle, electrons are transferred from oxaloacetate to form malate.
A crucial mechanism employed by mitochondria, the malate-aspartate shuttle system, also known as the malate shuttle, enables electrons to pass through the impermeable membrane separating the cytosol as well as the mitochondrial matrix. Glycolysis produces the electrons which are required for oxidative phosphorylation.
The liver, heart, as well as kidney, include the malate-aspartate shuttle, which produces about three molecules of ATP for every cytosolic NADH molecule. Under aerobic conditions, it constitutes quantitatively the most significant shuttle for such reoxidation of cytosolic NADH in vertebrate tissues.
Therefore, In the malate–aspartate shuttle, electrons are transferred from oxaloacetate to form malate.
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Mehtyl alcohol is called wood spirit. Its molecular formula is CH3OH. Calculate the number of moles that would contain 2.5*10^21 molecules of this compound.
The 2.5 x 10²¹ molecules of CH₃OH have 0.00415 moles.
What is the mole concept?The Mole concept is used to express the amount of substance conveniently. A mole is defined as the amount of substance that contains exactly 6.022 x 10²³ elementary particles of the given substance. Here, elementary particles refer to atoms, molecules, or ions.This fixed number 6.022 x 10²³ is known as Avogadro Number and is denoted by [tex]N_A[/tex]How to calculate the number of moles?The number of moles is given by
[tex]n=\frac{m}{M}[/tex]
When given mass = molar mass of a substance, then no of moles is equal to 1 which is equivalent to 6.022 x 10²³.
We also know,
1 mole has 6.022 x 10²³ molecules of CH₃OH
According to the mole concept,
6.022 x 10²³ molecules of CH₃OH is equal to 1 mole
2.5 x 10²¹molecules of CH₃OH is equal to [tex]\frac{2.5\times10^2^1}{6.022 \times 10^2^3}[/tex] moles
Thus, 2.5 x 10²¹molecules of CH₃OH are equal to 4.15 x 10⁻³ moles or 0.00415 moles
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What is the molarity of nickel ii chloride at 0.500 liters with 1 mole of nickel ii chloride solution?
Answer:
Molarity = 2 M
Explanation:
The molarity can be found using the molarity ratio:
Molarity = moles / volume (L)
You can plug the given moles and volume into the ratio and solve.
Molarity = moles / volume
Molarity = 1 mole / 0.500 L
Molarity = 2 M
Identify the compound that would have the highest osmotic pressure when dissolved in water. nacl k2so4 mgcl2 fecl3 mgso4
The compound that would have the highest osmotic pressure when dissolved in water is [tex]FeCl_{3}[/tex] .
So, option D is correct one.
The dissociation of one molecule of [tex]FeCl_{3}[/tex] gives the maximum number of ions when dissolved in water ( 4 ions ) . Osmotic pressure is a colligative property and depends upon number of solute particles present in the solution . The solution having maximum number of solute particles will have maximum number of the osmotic pressure .
All other given molecules gives less number of number of ions when dissolved in water as compare to of [tex]FeCl_{3}[/tex] .
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340. ml of a 0. 150 m solution of nh3(aq) is titrated with 0. 100 m hcl. calculate the ph of the solution after 350. ml of hcl has been added. (ka(nh4 ) = 5. 6 x 10-10)
340. ml of a 0. 150 m solution of nh3(aq) is titrated with 0. 100 m hcl. the ph will be 7 of the solution after 350. ml of hcl has been added. (ka(nh4 ) = 5. 6 x 10-10).
What is ph?The ph. of a solution gives information about the concentration of hydrogen ion in the solution or the solution is acidic or basic in nature if the given value is 7 then the solution is neutral or greater then 7 then basic and less then 7 then acidic.
Here, NH3 is a base while adding HCl to it the reaction gets neutralized and known as neutralizatio reaction and attend the ph. of value 7.
After due to the formation of hydronium ion the ph. would be less then 7.
Therefore, the ph. is 7.
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Lithium metal reacts with nitrogen gas to form lithium nitride. identify the balanced reaction that describes this process
Lithium metal reacts with nitrogen gas to form lithium nitride the balanced chemical equation will be 6Li + N₂ → 2Li₃N.
What is a balanced chemical reaction?In a balanced chemical reaction, the number of moles that are present at the side of the reactant must be always equal to the side of product formation this is known as a balanced chemical equation.
The balanced chemical reaction will be 6Li + N₂ → 2Li₃N.
Here 6 moles of lithium is reacting with one nitrogen but as it is in gaseous state it is N₂ after reacting with lithium it will give two moles
Therefore, balanced equation will be 6Li + N₂ → 2Li₃N
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What term is best described as the rate of a chemical reaction at any instant in time?
Answer:
instantaneous rate would be the term.
Through which conversion is energy released? adp to atp atp to adp nadp to nadph co2 and h2o to c6h12o6 and o2
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Answer:
B) ATP to ADP
Explanation:
Hope this helps! Pls give brainliest!
True or
False
Consider the equilibrium c(s) h2o(g) co(g) h2(g), δh = 2296 j. The concentration of carbon will not change if gaseous water is added to the system
The statement that the concentration of carbon will not change if gaseous water is added to the system is false. The concentration of carbon will increase.
What is concentration?Concentration of a substance is the present of a substance in a per-unit square of an area. It is the total amount of solute present in the solution.
The equilibrium is C(s) + H₂O(g) < - > CO(g) + H₂(g), ΔH = 2296 J.
If we increase or add the gaseous water in the system, the amount of carbon will increase because the carbon is a gas, and increasing the pressure will increase the volume of the gas, at Constant temperature.
Thus, the statement is false.
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A cylinder with a movable piston contains 2.00 g of helium, He , at room temperature. More helium was added to the cylinder and the volume was adjusted so that the gas pressure remained the same. How many grams of helium were added to the cylinder if the volume was changed from 2.00 L to 3.90 L
Heya....
Here's your answer.....
PV = nRT... R is a constant...
so PV/nT = constant...
P1V1 / n1T1 = P2V2 / n2T2...P is constant.T is constant.. so
V1 / n1 = V2 / n2
since n = mass / mw
V1 / (mass 1 / mw) = V2 / (mass 2 / mw)
and since molecular mass = constant
V1 / mass 1 = V2 / mass 2
mass 2 = V2 x mass 1 / V1 = 2.90L x 2.00 g / 2.00 L = 2.9 g
mass 2 - mass 1 = 2.90 g - 2.00 g = 0.90 g
ie.. 0.90 g of He was added.
Thanks...!!!
An aqueous solution of isopropanol (mm = 60.10 g/mol) has a molality of 12.79 m and a density of 1.180 g/ml. what is the molarity of isopropanol in the solution?
The molarity of an aqueous solution of isopropanol = 15.09 mol/L
Molality = 12.79 m
This gives that 12.79 moles of isopropanol is dissolved in 1000 grams of water.
Density = 1.180 g/mL
We know that,
Density= mass/volume
volume = mass/density
= 1000/1.180
Volume = 847.46 ml
Molarity can be defined as the mass of solute per liter of the solution.
Molarity = moles × 1000/volume ------> (1)
The moles of isopropanol in 847.46 ml solution is 12.79.
On substituting in (1)
Molarity = 12.79 × 1000/847.46
Molarity= 15.09 mol/L
The molarity of aqueous solution of isopropanol is 15.09 mol/L
What is molality?
The number of moles of solute in a solution equal to 1 kg or 1000 g of solvent is referred to as its molality.
What is molarity?The amount of a substance in a specific volume of solution is known as its molarity (M). The number of moles of a solute per liter of a solution is known as molarity. The molar concentration of a solution is another name for molarity.To learn more about molality visit:
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An unknown solution has a ph of 7.1. which of these chemicals is likely to increase the ph the most when added to the solution? hf koh nh3 hno3
option (B) KOH is the correct answer
KOH is the substance that, when added to the solution, is most likely to raise the pH .
What is pH?a graph that uses a logarithmic scale with 7 as neutral, where lower values are more acidic and higher ones are more alkaline, to represent the acidity or alkalinity of a solution. The hydrogen ion concentration (c), expressed in moles per liter, determines the pH, which is equal to log10(c).It will provide the most hydronium ions at the lowest pH, and at the highest pH, it will totally dissociate into the solution. KOH entirely separates into ions.Potassium hydroxide, or KOH, is a powerful base.A solution becomes more basic as the base is included. As a result, the pH of the solution will rise. All of the others are acids and will cause the solution's pH to decrease.To learn more about pH visit:
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What is the carbon nucleophile which attacks molecular bromine in the acid-catalyzed α-bromination of a ketone?
The enol carbon or ∝-carbon nucleophile attacks at molecular bromine in the acid-catalyzed α-bromination of a ketone
Treatment of ketones with bromine in the presence of acid will results in formation of a new C-Br bond at the alpha position. The purpose of the acid is to catalysed formation of the enol from ketone , which is active nucleophile in the reaction. This reaction is called haloform reaction which is used to identify the methyl substituted ketone in the presence of aldehyde.
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Pick the word that best completes the following sentence. A
mixture is a mixture in which the composition is
uniform throughout the mixture.
a homogeneous
b heterogeneous
C compound
Which method is the most effective for measuring hydration status before and after exercise?
Urine color is the most effective method for measuring hydration status before and after exercise
Urine color is yellow color from a pigment called urochrome or urobilin. Darker pee contains less fluid, whereas lighter urine is more diluted. Dehydration may be indicated by very black urine. Don't worry if your urine doesn't match the color scheme.
Normal urine color is a pale yellow, however light amber is also acceptable. If your pee appears dark amber, you may be dehydrated and should drink additional water to compensate. Urine naturally contains yellow pigments known as urobilin or urochrome. The darker the pee, the more concentrated it is. Dehydration is the most common cause of dark urine color
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The interval shown here represents a _____.
1.) strong acid
2.) weak acid
3.) weak base
4.) strong base
The given pH scale range from [tex]0-3[/tex] indicates the strong acid.
The pH scale, which ranges from [tex]0 -14[/tex], was developed by Sorensen to quantitatively define the strength of an acid and a base.
A pH value indicates the amounts of hydrogen ions and, hydroxide ions present. The negative logarithm of the hydrogen ion concentration is referred to as pH and is represented by:
[tex]pH = -log [H^{+} ][/tex]
For acids, the pH value is always less than [tex]7[/tex].
For bases, the pH value is always more than [tex]7[/tex].
For neutral solution, pH value is equal to [tex]7[/tex].
Thus, for the provided pH scale range [tex]0-3[/tex], it represents strong acid which will give large concentration of protons on dissociation. since lower pH value indicates higher concentration of protons created by an acid.
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Choose the chemical equation that is correctly balanced. 2ca(s) cl2(g) → cacl2(s) 4mg(s) o2(g) → 2mgo(s) li(s) cl2(g) → 2licl(s) c(s) o2(g) → co2(g)
