Which one of the following is an example of a balanced chemical reaction?
a. 8HCl + 2KMnO4 → 3Cl2 + 2MnO2 + 4H2O + 2KCl.
b. 6HCl + 2KMnO4 → 2Cl2 + 2MnO2 + 4H2O + 2KCl.
c. 2HCl + 2KMnO4 → Cl2 + MnO2 + 2H2O + 2KCl.
d. HCl + KMnO4 → Cl2 + MnO2 + H2O + KCl.
e. HCl + KMnO4 → Cl2 + MnO2 + 2H2O + KCl.

Answers

Answer 1

Answer:

Option a.

Explanation:

To determine which is a balanced chemical reaction, see the stoichiometry.

Stoichiometry coefficients are the numbers that appear before the compounds. These numbers indicate moles of substance.

Notice that the number of elements must be the same in both sides of the equation.

In this case, option a is the balanced chemical reaction.

8HCl + 2KMnO₄ → 3Cl₂ + 2MnO₂ + 4H₂O + 2KCl

8 moles of HCl react to 2 moles of potassium permanganate in order to produce 2 moles of magnessium dioxide, 3 moles of chlorine, 2 moles of potassium chloride and 4 moles of water.

8 H, 8 Cl, 2 K, 2 Mn and 8 O


Related Questions

Enter a balanced equation for the reaction between solid nickel(II)(II) oxide and carbon monoxide gas that produces solid nickel and carbon dioxide gas. Express your answer as a chemical equation. Identify all of the phases in your answer.

Answers

Answer: A balanced equation for the given reaction is [tex]NiO(s) + CO \rightarrow Ni(s) + CO_{2}(g)[/tex].

Explanation:

The reaction equation will be as follows.

[tex]NiO(s) + CO \rightarrow Ni(s) + CO_{2}(g)[/tex]

Number of atoms on the reactant side is as follows.

O = 2C = 1

Number of atoms on the product side is as follows.

Ni = 1O = 2C = 1

Since number of atoms on both the reactant and product sides are equal. Hence, the reaction equation is balanced.

Thus, we can conclude that a balanced equation for the given reaction is [tex]NiO(s) + CO \rightarrow Ni(s) + CO_{2}(g)[/tex].

In water, Vanillin, C8H8O3, has a solubility of 0.070 moles of vanillin per liter of solution at 25C. What will be produced if 5.00 g of vanillin are added to 1 L of water at 25 C?

Answers

Answer:

The full amount (5.00 g) will be dissolved in 1 L of water at 25°C.

Explanation:

The molecular weight (MW) of Vanillin (C₈H₈O₃) is calculated from the chemical formula as follows:

MW(C₈H₈O₃) = (12 g/mol x 8) + (1 g/mol x 8) + (16 g/mol x 3) = 152 g/mol

If 0.070 mol of C₈H₈O₃ are soluble per liter of water at 25°C, the maximum mass that can be dissolved in 1 L is:

0.070 mol x 152 g/mol = 10.64 g

Since 5.00 g is lesser than the maximum amount that can be dissolved (10.64 g), the added amount will be completely dissolved in 1 L of water at 25°C.

What is the mass number of an ion with 106 electrons, 157 neutrons, and a +1 charge?

Answers

Answer:

264 g/mol

Explanation:

#electrons equal #protons = 106

Plus 1 charge => m protons = 106 + 1 = 107

Mass number: 107 + 157 = 264 g/mol

Draw the skeletal structure for: (E)-hept-5-en-2-one

Answers

Answer:

Draw the skeletal structure for: (E)-hept-5-en-2-one

Explanation:

The root word hept indicates that the given compound has seven carons in its longest chain.

-en- primary suffix indicates that the compound has one double bond in it.

2-one indicates that the compound has -C=O bond in the second carbon.

The prefix (E) indicates that the highest priority groups are on the opposite direction of the double bond.

The structure of the given molecule is:

What is the largest number
(of a single species) a specific area can support?

A. Population
B. Unlimited factor
C. Carrying capacity
D. Niche

Answers

Answer:

carrying capacity

Explanation:

Thus, the carrying capacity is the maximum number of individuals of a species that an environment can support. Population size decreases above carrying capacity due to a range of factors depending on the species concerned, but can include insufficient space, food supply, or sunlight.

If I have 25g of Sodium, how much Sodium Chloride will I theoretically create?
O 50g NaCl
0 58.3g NaCl
O 63.7g Naci
0 35.4g NaCl

Answers

Answer:

64 g

Explanation:

Step 1: Write the balanced equation

2 Na + Cl₂ ⇒ 2 NaCl

Step 2: Calculate the moles corresponding to 25 g of Na

The molar mass of Na is 22.98 g/mol.

25 g × 1 mol/22.98 g = 1.1 mol

Step 3: Calculate the moles of NaCl formed from 1.1 moles of Na

The molar ratio of Na to NaCl is 2:2. The moles of NaCl formed are 2/2 × 1.1 mol = 1.1 mol.

Step 4: Calculate the mass corresponding to 1.1 moles of NaCl

The molar mass of NaCl is 58.44 g/mol.

1.1 mol × 58.44 g/mol = 64 g

6. Which compound contains no ionic character?​

Answers

Answer:

The compound which doesn't contains ionic character is HC, H-atom and CL- atom shares 1 electron a to form covalent bond....

. Gastric juice, the digestive fluid produced in the stomach, contains hydrochloric acid, HCl. Milk of Magnesia, a suspension of solid Mg(OH)2 in an aqueous medium, is sometimes used to neutralize excess stomach acid. Write a complete balanced equation for the neutralization reaction, and identify the conjugate acid-base pairs.

Answers

Answer:

Mg(OH)2 + 2HCI = MgCI2 + 2H2O

Explanation:

Please correct me if I am wrong

Given 200ul of a 0.5mg/ml stock solution of BSA, how much do you pipet into a test tube so that you are adding 5ug of BSA to the test tube

Answers

Answer: [tex]10\mu L[/tex] of volume needs to be pipetted out in the test tube.

Explanation:

We are given:

Mass of BSA to be formed = [tex]5\mu g=0.005mg[/tex]      (Conversion factor: [tex]1mg=1000\mu g[/tex]

Volume of stock solution = [tex]200\mu L=0.2mL[/tex]    (Conversion factor: [tex]1mL=1000\mu L[/tex]

It is also given that for the mass of BSA is 0.5 g, the volume used up is 1 mL

In order to have, 0.005 g, the volume of stock solution needed will be = [tex]\frac{1mL}{0.5g}\times 0.005g=0.01mL=10\mu L[/tex]

Hence, [tex]10\mu L[/tex] of volume needs to be pipetted out in the test tube.

The time required to pass one Faraday of electricity through a solution with a current of 0.3A is​

Answers

Answer:

89.35 hour

Explanation:

Recall :

Charge on 1 electron = 1.6 × 10^-19 C

1 mole contains = 6.023 × 10^23

Therefore, the charge on 1 mole of electron will be :

Charge per electron × 1 mole :

(1.6 × 10^-19) * (6.023 * 10^23) = 96500 C = 1 Farad

1 Farad = 96500 C

Using the formula :

Q = Current(I) * time(t)

Q = I*t

t = Q/I

Current, I = 0.3 A

t = 96500 / 0.3

t = 321666.66 second

t = 321666.66 / 3600 = 89.35 hour

Consider the following chemical equilibrium: Now write an equation below that shows how to calculate from for this reaction at an absolute temperature . You can assume is comfortably above room temperature. If you include any common physical constants in your equation be sure you use their standard symbols, found in the ALEKS Calculator.

Answers

Answer:

Kp=Kc *(RT)+-3

Explanation:

The relation between Kp and Kc is given below:

Where,

Kp is the pressure equilibrium constant

Kc is the molar equilibrium constant

R is gas constant , R = 0.082057 L atm.mol⁻¹K⁻¹

T is the temperature in Kelvins

Δn = (No. of moles of gaseous products)-(No. of moles of gaseous reactants)

For the first equilibrium reaction:

Δn = (0)-(2+1) = -3

Thus, Kp is:

Kp=Kc *(RT)+-3


Consider the synthesis of water as shown in Model 3. A container is filled with 10,0 g of H, and
5.0 g of Oz
Which reactant (hydrogen or oxygen) is the limiting reactant in this case?

Answers

Answer:

Oxygen, O₂ is the limiting reactant

Explanation:

We'll begin by writing the balanced equation for the reaction. This is given below:

2H₂ + O₂ —> 2H₂O

Next, we shall determine the masses of H₂ and O₂ that reacted from the balanced equation. This can be obtained as follow:

Molar mass of H₂ = 2 × 1 = 2 g/mol

Mass of H₂ from the balanced equation = 2 × 2 = 4 g

Molar mass of O₂ = 16 × 2 = 32 g/mol

Mass of O₂O from the balanced equation = 1 × 32 = 32 g

SUMMARY:

From the balanced equation above,

4 g of H₂ reacted with 32 g of O₂.

Finally, we shall determine the limiting reactant. This can be obtained as follow:

From the balanced equation above,

4 g of H₂ reacted with 32 g of O₂.

Therefore, 10 g of H₂ will react with

= (10 × 32)/4 = 80 g of O₂.

From the calculations made above, we can see that a higher mass (i.e 80 g) of O₂ than what was given (i.e 5 g) is required to react completely with 10 g of H₂. Therefore, O₂ is the limiting reactant.

Oxygen has been the limiting reactant in the reaction.

A limiting reactant can be defined as the reactant in the reaction in which the product concentration has been dependent.

The balanced equation for the formation of water has been:

[tex]\rm 2\;H_2\;+\;O_2\;\rightarrow\;2\;H_2O[/tex]

For the formation of reaction to form 2 moles of water, 2 moles of hydrogen reacts with 1 mole of oxygen.

The moles can be calculated as:

Moles = [tex]\rm \dfrac{weight}{molecular\;weight}[/tex]

The moles of Hydrogen in 10 g [tex]\rm H_2[/tex]:

Moles = [tex]\rm \dfrac{10}{2}[/tex]

Moles of hydrogen = 5 mol.

Moles of Oxygen in 5 grams Oxygen:

Moles = [tex]\rm \dfrac{5}{32}[/tex]

Moles of oxygen = 0.156 mol.

For the reaction with 2 moles of Hydrogen 1 mole of Oxygen has been required.

For reacting with 5 mol of Hydrogen, moles of oxygen required are:

Moles of oxygen = [tex]\rm \dfrac{1}{2}\;\times\;5[/tex]

Moles of oxygen required = 2.5 moles.

The available oxygen = 0.156 moles.

Since the moles of oxygen available is lesser than required, the formation of the product has been dependent on the concentration of the oxygen.

Thus, oxygen has been the limiting reactant in the reaction.

For more information about the limiting reactant, refer to the link:

https://brainly.com/question/14225536

Design an experiment to demonstrate phototropism.

Answers

Answer:

Object: To demonstrate phototropism

equipments: A black box, window with light source, a well watered potted plant.

Experiment: A wellwatered potted plant is placed inside a darkened black  box that is having a small window on one side. This is called as phototropic chamber. Window is remain closed for a day the plant shows normal growth.

Whereas if window is opened atwo days it will be found that shoot tip bends and grows towards light proving that it is positively phototropic.

1. Arrange the following groups in order of decreasing priority that would allow you to determine E/Z, or R/S. Provide a string of letters (e.g. abcd) as an answer with the highest priority listed first, lowest priority last:
a) -CH3 b) -CH2OH c) -CH2NH2 d) -CH2BR
2. Arrange the following groups in order of decreasing priority that would allow you to determine E/Z, or R/S. Provide a string of letters (e.g. abcd) as an answer with the highest priority listed first, lowest priority last:
a) -F b) -CH2OH c) -CHO d) -CH3

Answers

1. dcba
2. acbd

Good luck

Regards
BLACKSHARK

1) The order of decreasing priority would allow determining E/Z or R/S is "dbca".

2)  The order of decreasing priority would allow determining E/Z or R/S is "acbd".

What is absolute configuration?

Absolute configuration can be described as to the spatial arrangement of atoms within a chiral molecular entity. Absolute configuration in organic molecules, where carbon is bonded to four different substituents.

The absolute configuration has used a set of rules to describe the relative positions around the chiral center atom. The most common labeling method is the descriptors R or S where R and S refer to Rectus and Sinister.

The group with the highest atomic number will get the highest priority and the group with the lowest atomic number substituents will get the lowest priority. Therefore, the order of priority is -CH₂Br > -CH₂OH > -CH₂NH₂ > -CH₃.

Therefore, the order of priority for the second part is -F > -CHO > -CH₂OH > -CH₃.

Learn more about absolute configuration, here:

https://brainly.com/question/14365822

#SPJ5

What are the equipments needed to determine the density of a liquid in laboratory ?​

Answers

Answer:

A hydrometer is a special device used to determine the density of liquids.

Explanation:

I hope this helps you. Have a nice day!

According to Newton's law of universal gravitation, how do the masses of two
objects relate to the gravitational force between them?
A. As either mass increases, the gravitational force between them
increases.
B. As either mass increases, the gravitational force between them
decreases.
C. Gravitational force increases only when both masses increase.
D. Gravitational force increases only when both masses decrease.

Answers

Answer:

As either mass increases, the gravitational force between them

increases.

Explanation:

According to Newton's law of universal gravitation;

F α m1m2/r^2

That is, the force between two masses in a gravitational field is directly proportional to the product of the two masses and inversely proportional to their distance apart.

Hence, as either of the masses increase, the force of gravitation between the two masses increases. Hence the answer.

Calculate the Experimental Molar Volume in L/mol of the Hydrogen gas, H2, if the volume of H2 at STP is 52.8 mL and the mass of Magnesium metal, Mg, used in the experiment is 0.055 g.

Answers

Answer:

The Experimental Molar Volume in L/mol of the Hydrogen gas=23.36L/mol

Explanation:

We are given that

Volume of H2 at STP=52.8mL

Mass of magnesium metal ,M(Mg)=0.055g

We have to find the Experimental Molar Volume in L/mol of the Hydrogen gas.

Molar mass of Mg=24.305 g/mol

Number of moles=[tex]\frac{given\;mass}{molar\;mass}[/tex]

Using the formula

Number of moles of Mg=[tex]\frac{0.055}{24.305}[/tex]moles

Number of moles of Mg=0.00226moles

Number of moles of Mg=Number of moles of H2

Number of moles of H2=0.00226moles

Molar volume of Hydrogen gas (H2)=[tex]\frac{volume\;at\;STP}{No\;of\;moles\;H_2}[/tex]

Molar volume of Hydrogen gas (H2)=[tex]\frac{52.8}{0.00226}mL/mol[/tex]

Molar volume of Hydrogen gas (H2)=[tex]\frac{52.8}{0.00226}\times 10^{-3}L/mol[/tex]

[tex]1L=1000mL[/tex]

Molar volume of Hydrogen gas (H2)=23.36L/mol

Hence, the Experimental Molar Volume in L/mol of the Hydrogen gas=23.36L/mol

Increasing the temperature of a chemical reaction usually increases greatly the rate of the reaction. The most iportant reason for this is that increasing the temperature increases: _______.
A) the collision frequency
B) the probability factor
C) the fraction of collisions with energy greater than Bact
D) the energy of activation.
E) the amount of heat released in the reaction

Answers

Answer:

the fraction of collisions with energy greater than Eact

Explanation:

The activation energy of a reaction stands as a sort of energy barrier between reactants and products. It is only reactants that possesses energy greater than the activation energy that can be converted from reactants to products.

When the temperature of the system is increased, more particles acquire energy greater than the activation energy. Hence, the fraction of collisions with energy greater than the activation energy increases so the rate of reaction increases likewise.

We can use bond-line formulas to represent alkenes in much the same way that we use them to represent alkanes. Consider the following alkene: h5ch5e4 How many carbon atoms are sp2−hybridized in this alkene?

Answers

Answer:

2

Explanation:

The number of carbon atoms that are sp²-hybridized in this alkene is 2

Because all the single bonded carbon atoms in the alkene are  sp²-hybridized

There are three(3) single formed via sp² orbitals and one ( 1 ) PI bond formed via Pure-P-orbital

attached below is the some part of the solution

Why do gases act more ideal at
lower pressures?

Answers

Answer:

Gases act more ideal at lower pressure beacuse the attractive forces between molecules will decrease or become less significant compared to the empty space between them.

Explanation:

Generally, a gas behaves more like an ideal gas at higher temperature and lower pressure as the potential energy due to intermolecular forces becomes less significant compared with the particles "kinetic energy" and the size of the molecules become less significant compared to the empty space between them.

Attractive forces between molecules, decrease the pressure of a reak gas, slowing the molecules and reducing collisions with the walls.The higher the value of a gas, the greater the attraction between molecules and the more easily the gas will compress.

HOPE IT HELPS MUCH

answered by: John Glenly Pillazo Mahusay


Which atomic model states that it is impossible to know the exact location of electrons around the nucleus?

Answers

Answer:

Bohr Model is the correct answer

Answer:

Electron -Cloud Model

Explanation:

Just took the quiz got 100%

An electron-dot structure is a convenient method of representing

A. The complete electron configuration of the atom.
B. all electrons of the atom.
C. valence electrons of an atom.
D. core electrons of an atom.

Answers

Answer:

all electrons of the atom

The number of periods/series in Mendeleev's Periodic table is
A. 10
B. 13
C. 12
D. 14​

Answers

Answer: The number of series in Mendeleev's Periodic table is 12.

Explanation:

Horizontal rows present in the periodic table are called periods. Vertical rows in the periodic table are called series.

Mendeleev gave periodic table in the year 1869 by arranging elements according to their atomic weights a in tabular form.  

Mendeleev's periodic table depicts 12 periods/series.

Thus, we can conclude that the number of periods/series in Mendeleev's Periodic table is 12.

Match the description with the type of precipitation being described.
1. Its formation requires very strong updrafts
2. Its formation requires falling through a layer of above freezing air
3. Precipitation from cumuliform clouds is typically of this nature
4. Precipitation from stratus clouds is typically of this nature
Options:
a. Hail
b. Drizzle
c. Shower
d. Freezing Rain

Answers

Answer:

1. Its formation requires very strong updrafts = a. Hail

2. Its formation requires falling through a layer of above-freezing air = d. Freezing Rain

3. Precipitation from cumuliform clouds is typically of this nature = c. Shower

4. Precipitation from stratus clouds is typically of this nature = Drizzle

Explanation:

Hail formation requires very strong updrafts, these updrafts are the upward moving air created in a thunderstorm. This period of noticeable thunderstorms creates hails.

Freezing rain requires the presence of warm air, it requires falling through a layer of above-freezing air to the colder air below to produce an ice coating on anything it drops on.

Showers are produced by cumuliform clouds which look like cotton balls. Since cumuliform clouds precipitate too, these clouds can have fluctuating rain in a day in the form of showers.

Drizzle which raises low visibility is considered a type of liquid precipitation since it also falls from a cloud. Drizzle which is obviously smaller in diameter when compared to that of raindrops, however, is common with stratus clouds.

Which 2 resonance forms destablize the carbocation intermediate if bezonitrile undergoes chlronation at the ortho or para positions

Answers

The question is incomplete, the complete question is shown in the image attached

Answer:

A and B

Explanation:

The electrophilic substitution of arenes yields a cation intermediate. The positive charge of the cation is delocalized over the entire ring.

The -CN group directs incoming electrophiles to the ortho/para position. The resonance structures for the chlorination of benzonitrile are shown in the question.

Recall that -CN is an electron withdrawing group. The resonance forms that destablize the carbocation intermediate are those in which the -CN group is directly attached to the carbon atom bearing the positive charge as in structures A and B.

What do phase diagrams demonstrate?

Select all that apply.

how the melting and boiling points of a substance change with pressure
how much heat will increase the temperature of a gram of a substance by 1°C
the pressure and temperature conditions in which a substance exists as a liquid, solid, or gas
a comparison of the temperature of a substance to the heat absorbed over time

Answers

Answer:

this answer is for first one

Explanation:

A higher evalations, where the atmospheric pressure is much lower, the boiling point increase with increased pressure up to the critical point where the gas and liquid properties become identical

An ionic compound contains an unknown ion X and has the formula X3N2. Ion X contains 10 electrons. Write down the chemical symbol of X?

Answers

Answer:

Mg3N2

Explanation:

it would be magnesium as it would loss to electron so it would have 10 electron. you can see in the picture above .

hope this helps :)

What is Heisnberg's uncertainity principle? Why it make sense only for microscopic particles.​

Answers

Answer:

The uncertainty principle is one of the most famous (and probably misunderstood) ideas in physics. It tells us that there is a fuzziness in nature, a fundamental limit to what we can know about the behavior of quantum particles and, therefore, the smallest scales of nature.

You’re taking a walk on a warm fall morning. The temperature is about 70 degrees Fahrenheit, and you cannot see a cloud anywhere in the sky. You notice that the ground has no dew on it either. This means the

Answers

this means that you are wearing warm clothes in warm temperature .quite easy sir

I have an unknown volume of gas at a pressure of 0.50 atm and a temperature of 325 K. If I raise the pressure to 1.2 atm, decrease the temperature to 320 K, and measure the final volume to be 48 liters, what was the initial volume of the gas?
SHOW YOUR WORK

Answers

Answer:

the answer is 2.1 atm

Explanation:

the way people normally do it is by simply deciding the 325k with the 1.2

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Samuel de Champlain Disadvantages of GTZ Model for designing science textbooks Edwards Manufacturing Company purchases two component parts from three different suppliers. The suppliers have limited capacity and no one supplier can meet all the company's needs. In addition, the suppliers charge different prices for the components. Component price data (in price per unit) are as follows:Supplier Component 1 2 31 $10 $12 $142 $10 $10 $11Each supplier has a limited capacity in terms of total number of components it can supply. However, as long as Edwards provides sufficient advance orders, each supplier can devote its capacity to component 1, component 2, or any combination of the two components, if the total number of units ordered is within its capacity. Supplier capacities are as followsSupplier 1 2 3Capacity 600 1050 775If the Edwards production plan for the next period includes 1050 units of component 1 and 800 units of component 2, what purchases do you recommend? The is, how many units of each component should be ordered from each supplier?Supplier 1 2 3Component 1 Component 2 What is the total purchase cost for the components? uppose you invest, every month, in an annuity that pays 3% interest, compounded monthly. After 25 years, you have $550,000. How much money do you earn from interest Which is not an equation of the line that passes through the points (1, 1) and (5,5)? Trevor is a habitual criminal offender. He has committed dozens of robberies and hundreds of burglaries, and has stolen approximately 30 vehicles. Trevor was 14 when he was first arrested for stealing a car. He is now 44 years old and just got out of prison. He spent 10 years in prison for an armed robbery. According to the ______________ effect, while in prison for 10 years, Trevor was prevented from committing further offenses. Find ordered pairs for y= 2x + 3 if x is {1,2,3} label the eye, thank you In algae and plants, photosynthesis happens in thevacuoles.mitochondria.chloroplasts.chromosomes. I need help with question 9 Question 1:The Wayfinder is an ancient piece of technology created as a means of navigating challenging stretches of space. The device connects to every piece of technology in the galaxy in order to detect planets and spaceships and then shown their location to the user. As it happens, locations of planets follow a specific distribution. A planet can exist at coordinates x,y only if2x + |2xy| + y =10000The user can use the Wayfinder to find nearby planets by input the range for x and y. Draw a flowchart and write a C++ program that models the Wayfinder. Ask the user to input a range for x and y, then print all possible planet coordinates. The program should also print the number of planets detected.Hint: you can use pow(x,n) to get the value of xn and abs(x) to get the absolute value of x.helpppppppppp!!!!!!!!!!Sample output: The Cougar Swim Club acquired some Speedo Fastskin bodysuits and decided to test them out. A number of the club's fastest swimmers performed a 50m freestyle swim in a regular spandex bodysuit and in a Speedo Fastskin suit. The table below summarizes their times in seconds.Swimmer SpandexSpeedo Fastskin1 31.1 29.12 28.9 30.43 31.4 32.04 34.9 31.75 27.7 28.26 36.7 32.97 33.3 28.68 30.8 26.2Perform a t-test for dependent means to determine if there is a difference between the regular spandex suit and the Fastskin bodysuit in terms of performance.t = _____df = _____Critical value of t = _____ (use alpha = 0.05)Would you reject the null hypothesis? Two sides of a triangle have the following measures, Vind the range of possible measures forthe third side,13) 8,714) 12,6A) 1B) 2 < x < 14C) 1D) 1A) 8B) 9C) 8 < X < 18 D) 6 < X < 18 Solve for x. Round to the nearest tenth, if necessary. how do means and resources affect the development process of a country Read the excerpt from the final paragraph of "Wilson's War Message to Congress."But the right is more precious than peace, and we shall fight for the things which we have always carried nearest our heartsfor democracy, for the right of those who submit to authority to have a voice in their own governments. . .The most likely purpose of including this in the last paragraph is to